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1. 发明授权

US06242537B1 Gel-free process for making hydrogenated functionalized anionically polymerized polymers 有权
标题翻译：制备氢化官能化阴离子聚合聚合物的无凝胶工艺
公开(公告)号：US06242537B1
公开(公告)日：2001-06-05
申请号：US09260239
申请日：1999-03-02
申请人： Robert Charles Bening , Carl Lesley Willis , Charles Roy Donaho , Daniel Earl Goodwin , Zaida Diaz , John David Wilkey
发明人： Robert Charles Bening , Carl Lesley Willis , Charles Roy Donaho , Daniel Earl Goodwin , Zaida Diaz , John David Wilkey
IPC分类号： C08F804
CPC分类号： C08C19/44 , C08C19/42 , C08F8/00 , C08F12/00
摘要： This invention relates to a gel-free process for making hydrogenated functionalized polymers that mitigates the problem of ionic gel. When multi-alkali metal initiators are used to make these polymers anionically, the process comprises anionically polymerizing at least one monomer with a multi-alkali metal initiator, usually a lithium alkyl, in a hydrocarbon solvent, capping the polymer by adding to the polymer a capping agent that reacts with the ends of the polymer chains such that strongly associating chain ends are formed wherein a strongly associating polymer gel is formed, adding a trialkyl aluminum compound to the polymer gel, whereby the gel dissipates, optionally terminating the polymerization by addition of an alcohol, washing the polymer with aqueous acid, preferably aqueous mineral acid, most preferably phosphoric acid, wherein there is at least one mole of phosphoric acid per mole of alkali metal and at least three moles of phosphoric acid per mole of aluminum, and hydrogenating the polymer with a hydrogenation catalyst. In a second embodiment, the present invention relates to a process for making such polymers which comprises anionically polymerizing them as described and adding a trialkyl aluminum compound prior to the addition of the functionalizing agent and washing the product prior to hydrogenation as described above. In the first embodiment, a gel is formed and then removed. In the second embodiment, the gel never is formed because of the presence of the trialkyl aluminum compound.
摘要翻译：本发明涉及一种用于制备氢化官能化聚合物的无凝胶方法，其减轻了离子凝胶的问题。当使用多碱金属引发剂阴离子制造这些聚合物时，该方法包括在烃溶剂中将至少一种单体与多碱金属引发剂（通常为烷基锂）进行阴离子聚合，通过向聚合物加入聚合物形成与聚合物链的端部反应的封端剂，从而形成强缔合的链端，其中形成强缔合的聚合物凝胶，将三烷基铝化合物加入到聚合物凝胶中，由此凝胶消散，任选地通过加入聚合物终止聚合醇，用酸水溶液洗涤聚合物，优选无机酸水溶液，最优选磷酸，其中每摩尔铝存在至少1摩尔磷酸/摩尔碱金属和至少3摩尔磷酸/摩尔氢化该聚合物与氢化催化剂。在第二个实施方案中，本发明涉及一种制备这种聚合物的方法，其包括如上所述阴离子聚合它们，并且在加入官能化试剂之前加入三烷基铝化合物并在如上所述的氢化之前洗涤产物。在第一实施方案中，形成凝胶然后除去。在第二实施方案中，由于存在三烷基铝化合物，所以不会形成凝胶。

2. 发明授权

US06242538B1 Process for making hydrogenated gel-free functionalized anionically polymerized polymers 有权
标题翻译：制备无凝胶的官能化阴离子聚合聚合物的方法
公开(公告)号：US06242538B1
公开(公告)日：2001-06-05
申请号：US09304915
申请日：1999-05-04
申请人： Robert Charles Bening , Carl Lesley Willis , John David Wilkey , Zaida Diaz
发明人： Robert Charles Bening , Carl Lesley Willis , John David Wilkey , Zaida Diaz
IPC分类号： C08F804
CPC分类号： C08F8/04
摘要： This invention relates to a process for making gel-free functionalized polymers. When multi-lithium initiators are used to make these polymers anionically, the process comprises anionically polymerizing at least one monomer with a multi-lithium initiator in a hydrocarbon solvent, functionalizing the polymer by adding to the polymer a capping agent that reacts with the ends of the polymer chains such that strongly-associating chain ends are formed wherein a polymer gel is formed, adding a trialkyl aluminum compound to the polymer gel, whereby the gel dissipates, adding a sufficient amount of a proton source to provide at least 1 mole of protons per mole of lithium ions and at least 2 moles of protons per mole of aluminum wherein the proton source is an organic acid with a pKa of 11 or less or a mixture of the organic acid and an alkanol, provided that sufficient organic acid is added to provide at least 0.4 moles of protons per mole of lithium ions, hydrogenating the polymer with a hydrogenation catalyst, and optionally washing the polymer with aqueous mineral acid in sufficient.
摘要翻译：本发明涉及一种制备不含凝胶的官能化聚合物的方法。当使用多锂引发剂阴离子制造这些聚合物时，该方法包括在烃溶剂中使多个锂引发剂的至少一种单体阴离子聚合，通过向聚合物中添加与端基反应的封端剂官能化聚合物聚合物链使得形成强缔合的链端，其中形成聚合物凝胶，将三烷基铝化合物加入到聚合物凝胶中，由此凝胶消散，加入足够量的质子源以提供至少1摩尔的质子每摩尔锂离子和至少2摩尔质子/摩尔铝，其中质子源是pKa为11或更低的有机酸或有机酸和链烷醇的混合物，条件是将足够的有机酸加入到每摩尔锂离子提供至少0.4摩尔质子，用氢化催化剂氢化聚合物，并任选地用无机酸水溶液洗涤聚合物足够了

3. 发明授权

US5847072A Removal of lithium from polymer cements 失效
标题翻译：从聚合物水泥中去除锂
公开(公告)号：US5847072A
公开(公告)日：1998-12-08
申请号：US652261
申请日：1996-05-23
申请人： Zaida Diaz , John David Wilkey
发明人： Zaida Diaz , John David Wilkey
IPC分类号： C04B41/60 , B01J39/04 , C08C2/04 , C08F6/00 , C08F6/02 , C08F6/08 , C08F6/24
CPC分类号： B01J39/043 , C08C2/04 , C08F6/02
摘要： The selectivity of ion exchange processes for the removal of lithium from acids is improved when weak acids such as citric and acetic, are used in the wash step. An added improvement is realized by a two stage process of contacting the acid solution first with an ion exchange resin functional to remove the nickel and aluminum compounds from the acid solution; and then contacting the acid solution with an ion exchange resin which is more selective to remove the alkali metal compound from the acid solution.
摘要翻译：在洗涤步骤中使用弱酸（如柠檬酸和乙酸）时，离子交换方法从酸中除去锂的选择性得到改善。通过使酸溶液首先与用于从酸溶液中除去镍和铝化合物的离子交换树脂接触的两阶段方法实现了另外的改进; 然后使酸溶液与离子交换树脂接触，该离子交换树脂从酸溶液中除去碱金属化合物更具选择性。

4. 依法登记的发明

USH1703H Removal of lithium from polymer cements 失效
标题翻译：从聚合物水泥中去除锂
公开(公告)号：USH1703H
公开(公告)日：1998-01-06
申请号：US652191
申请日：1996-05-23
申请人： John David Wilkey , Zaida Diaz , Dale Lee Handlin, Jr.
发明人： John David Wilkey , Zaida Diaz , Dale Lee Handlin, Jr.
IPC分类号： C08C2/04 , C08F6/02 , C08F297/02 , C08F8/00
CPC分类号： C08C2/04 , C08F6/02 , C08F297/02
摘要： A process for preparing a polymer cement which is relatively free of alkali metal salt by preparing the polymer cement with a polymerization terminating agent which is an acid which leaves alkali metal salt in the cement which is readily removable by centrifugation.
摘要翻译：一种制备聚合物胶浆的方法，该聚合物胶浆通过用聚合终止剂制备聚合物胶泥，该聚合终止剂是在水泥中留下碱金属盐的酸，该酸可以通过离心而容易地除去。

5. 发明授权

US6153727A Extraction of metal residues from polymer cements 失效
标题翻译：从聚合物水泥中提取金属残留物
公开(公告)号：US6153727A
公开(公告)日：2000-11-28
申请号：US135725
申请日：1998-08-18
申请人： John David Wilkey , Zaida Diaz
发明人： John David Wilkey , Zaida Diaz
IPC分类号： C08F6/02 , C08F6/00
CPC分类号： C08F6/02
摘要： There is provided a method of removing metal residues from a polymer cement, the method comprising polymerizing a monomer with a metal-based polymerization initiator to give a polymer cement having metal polymerization initiator residue; adding an organic-soluble acid having a pKa no greater than about 4.5 to the polymer cement, thereby forming an acid containing organic phase; mixing the organic phase with an aqueous phase containing a mineral acid; and recovering the polymer cement substantially free of metal residue.
摘要翻译：提供了从聚合物水泥中除去金属残留物的方法，该方法包括用金属基聚合引发剂使单体聚合，得到具有金属聚合引发剂残基的聚合物粘合剂; 向聚合物胶浆中加入pKa不大于约4.5的有机溶解酸，从而形成含酸的有机相; 将有机相与含有无机酸的水相混合; 并回收基本上不含金属残渣的聚合物胶浆。

6. 发明授权

US5767207A Removal of lithium from polymer cements 失效
标题翻译：从聚合物水泥中去除锂
公开(公告)号：US5767207A
公开(公告)日：1998-06-16
申请号：US652084
申请日：1996-05-23
申请人： John David Wilkey , Zaida Diaz
发明人： John David Wilkey , Zaida Diaz
IPC分类号： C08C2/04 , C08F6/02 , C08F297/02
CPC分类号： C08C2/04 , C08F297/02 , C08F6/02
摘要： A process for preparing a polymer cement which is relatively free of alkali metal salt by preparing the polymer cement with a polymerization terminating agent which is a diketone which leaves alkali metal salt in the cement which is readily removable by centrifugation.
摘要翻译：一种制备聚合物胶浆的方法，该聚合物胶浆通过制备具有聚合终止剂的聚合物粘合剂来制备聚合物粘合剂，所述聚合终止剂是在水泥中留下碱金属盐的二酮，其可通过离心容易地除去。

7. 发明授权

US5750032A Removal of lithium from polymer cements 失效
标题翻译：从聚合物水泥中去除锂
公开(公告)号：US5750032A
公开(公告)日：1998-05-12
申请号：US652260
申请日：1996-05-23
申请人： Zaida Diaz , John David Wilkey
发明人： Zaida Diaz , John David Wilkey
IPC分类号： C02F1/42 , B01D15/04 , B01J39/04 , B01J47/02 , C01B17/90 , C01B25/238 , C08C2/04 , C08F6/02
CPC分类号： B01J39/043 , C08C2/04 , C08F6/02 , Y10S423/14
摘要： Process for removing an alkali metal compound from an acid solution also containing nickel and aluminum compounds, which requires contacting the acid solution first with an ion exchange resin functional to remove the nickel and aluminum compounds from the acid solution; and then contacting the acid solution with an ion exchange resin which is more selective to remove the alkali metal compound from the acid solution.
摘要翻译：从含有镍和铝化合物的酸溶液中除去碱金属化合物的方法，其需要首先使酸溶液与用于从酸溶液中除去镍和铝化合物的离子交换树脂接触; 然后使酸溶液与离子交换树脂接触，该离子交换树脂从酸溶液中除去碱金属化合物更具选择性。

8. 发明授权

US5300218A Reduction of diesel engine particulate emissions by contacting diesel fuel with a carbon molecular sieve adsorbent 失效
标题翻译：通过将柴油燃料与碳分子筛吸附剂接触来减少柴油发动机的颗粒物排放
公开(公告)号：US5300218A
公开(公告)日：1994-04-05
申请号：US902604
申请日：1992-06-23
申请人： Leonard B. Graiff , Peter B. Van Benthuysen , Danny Y. Ngan , Zaida Diaz , David M. Austgen, Jr.
发明人： Leonard B. Graiff , Peter B. Van Benthuysen , Danny Y. Ngan , Zaida Diaz , David M. Austgen, Jr.
IPC分类号： C10G25/00 , C10G25/05 , F02B3/06
CPC分类号： C10G25/003 , C10G25/05 , F02B3/06
摘要： This invention is a method for reducing the particulate emissions tendency of diesel fuel. Also the piston ring sticking, and deposit formation tendency of diesel fuel on the injector and combustion chamber of an internal combustion diesel fuel are reduced. The diesel fuel under the method of this invention is fed to at least one adsorbent bed in which the diesel fuel is contacted with one or more adsorbents under suitable process conditions such that there is a reduction in content of impurities in the fuel which cause the particulate emission causing tendency, piston ring sticking, and deposit formation tendency of the diesel fuel on the injector and/or combustion chamber.
摘要翻译：本发明是减少柴油的颗粒物排放趋势的方法。而且内燃柴油燃料的喷射器和燃烧室上的活塞环粘附和柴油燃料的沉积形成趋势也减少。将本发明方法的柴油燃料送入至少一个吸附剂床，在该吸附床中柴油燃料在合适的工艺条件下与一种或多种吸附剂接触，使得燃料中的杂质含量降低，导致颗粒物排放引起趋势，活塞环粘附，以及柴油燃料在喷射器和/或燃烧室上的沉积物形成倾向。

9. 发明授权

US5212285A Removal of hydrogenation catalyst from polymer solutions by catalyzed precipitation 失效
标题翻译：通过催化降解从聚合物溶液中除去氢化催化剂
公开(公告)号：US5212285A
公开(公告)日：1993-05-18
申请号：US537738
申请日：1990-06-14
申请人： Zaida Diaz , Carma J. Gibler
发明人： Zaida Diaz , Carma J. Gibler
IPC分类号： C08F6/08 , C08C2/04 , C08F6/00
CPC分类号： C08C2/04
摘要： A process is provided comprising the steps of contacting a Group VIII metal hydrogenation catalyst residue containing polymer solution with a chelating resin, the chelating resin comprising iminodiacetate ions, and recovering a polymer solution comprising less than 5 ppm by weight, based on the solution, of the hydrogenation catalyst residue metal. In a preferred embodiment, the chelating resin is contacted with the hydrogenation catalyst residue containing polymer solution by mixing particles of the chelating resin with the hydrogenation catalyst residue containing polymer solution under agitation, and the polymer solution containing less than 5 ppm of hydrogenation catalyst metals is recovered from the chelating resin and resulting precipitated hydrogenation catalyst residues by filtration.

10. 发明授权

US4683347A Glycerine purification process 失效
标题翻译：甘油净化过程
公开(公告)号：US4683347A
公开(公告)日：1987-07-28
申请号：US877051
申请日：1986-06-23
申请人： Zaida Diaz , James H. Miller
发明人： Zaida Diaz , James H. Miller
IPC分类号： C07C29/86 , C07C31/22
CPC分类号： C07C29/86 , Y02P20/544
摘要： The level of impurities such as glycerol-based acetals and/or ketals in glycerine, particularly glycerol-dimethylketal, is reduced by extraction of the glycerine with supercritical or near critical carbon dioxide.
摘要翻译：通过用超临界或近临界二氧化碳萃取甘油来减少甘油中甘油基缩醛和/或缩酮等杂质，特别是甘油二甲基缩酮的水平。

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