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1. 发明申请

US20070240609A1 Photoinitiators 有权
公开(公告)号：US20070240609A1
公开(公告)日：2007-10-18
申请号：US11578595
申请日：2005-04-11
申请人： Rinaldo Husler , Thomas Horni , Andre Fuchs , Tunja Jung , Reinhard Sommerlade
发明人： Rinaldo Husler , Thomas Horni , Andre Fuchs , Tunja Jung , Reinhard Sommerlade
IPC分类号： D21H17/07 , C08F2/48 , C08J3/28
CPC分类号： C07C45/46 , B33Y70/00 , C07C45/58 , C07C45/63 , C07C45/64 , C07C45/71 , C07C45/74 , C07C49/792 , C07C49/82 , C07C49/83 , C07C49/84 , C07C69/96 , C07C271/12 , C07C317/24 , C07D295/108 , C07D295/112 , C07D493/08 , C08F2/50 , C07C49/76 , C07C49/80 , C07C49/813
摘要： The invention relates to novel photoinitators of formulae (V), (II), (III), (IV), (V) and (VI) wherein R1 and R2 are each independently of the other C1-C8alkyl; C1-C4alkyl substituted by OH, C1-C4alkoxy, —COO(C1-C8alkyl), (C1-C4alkyl)-COO—, —CN, benzyl, phenyl or by —N(R15)(R16); C3-C6alkerlyl, benzyl, —CH2—C6H4—(C1-C4alkyl) or phenyl; or R1 and R2 together are unbranched or branched C2-C9alkylene or C3-C6-oxa- or -azaalkylene; R3, R4, R5 and R6 are each independently of the others hydrogen, C1-C8alkyl, C3-C6alkenyl, benzyl, —CH2—C6H4—(C1-C4alkyl) or phenyl; R3 and R4 together and/or R5 and R6 together are unbranched or branched C2-C9alkylene; A is Cl, Br, —O—R9, —N(R11)(R12) or —S—R18, A′ is —O—, —NH— or —NR11—; A″ is Cl, Br, —O—R9, —N(R11)(R12) or —S—R18 or hydrogen, X is —O—R10 or —N(R13)(R14), n is an integer from 1 to 10, preferably an integer from 1 to 4, especially 1, 2 or 3; R7 is a linker; R8 is a bivalent C2-C3alkylele radical.

2. 发明申请

US20060270748A1 Novel trifunctional photoinitiators 有权
公开(公告)号：US20060270748A1
公开(公告)日：2006-11-30
申请号：US10552952
申请日：2004-05-04
申请人： Reinhard Sommerlade , Rinaldo Husler , Stephen Ilg , Andre Fuchs , Souad Boulmaaz , Jean-Luc Birbaum
发明人： Reinhard Sommerlade , Rinaldo Husler , Stephen Ilg , Andre Fuchs , Souad Boulmaaz , Jean-Luc Birbaum
IPC分类号： C08F2/50
CPC分类号： G03F7/0295 , B33Y70/00 , C07C45/46 , C07C45/63 , C07C45/64 , C07C45/71 , C07C49/784 , C07C49/813 , C07C49/83 , C07C49/84 , C07C225/22 , C07C271/20 , C07C2601/14 , C08F2/50 , G03F7/029 , G03F7/031
摘要： The Invention relates to novel ketones of formulae (I) and (II) wherein R1, R2, R3 and R4 are, for example, C1-C8alkyl, R5 is, for example, hydrogen, A is CI, Br, -0-R7, —NR8R9 or —S—R16, A′ is —O—, —NH— or —NR8—, X and Y are each independently of the other —O—R10 or —N(R11)(R12), n is an integer from 1 to 10, R6 is, for example, an n-valent radical of linear or branched C2-C20alkyl the carbon chain of which may be interrupted by cyclohexanediyl, phenylene, —CH(OH)—, —C(C2H5)(CH2—CH2—OH)—, —C(CH3)(CH2—CH2—OH)—, —C(CH2—CH2—OH)2—, —N(CH3)—, —N(C2H5)—, —N(CH2—CH2—OH)—, —CO—O—, —O—CO—, —P(CH2—CH2—OH)—, —P(O)(CH2—CH2—OH)—, -0-P(O—CH2—CH2—OH)—O—, -0-P(O)(0-CH2—CH2—OH)—O—, —O-cyclohexanediyl-C(CH3)2-Cyclohexanediyl-O—, —O-phenylene-C(CH3)2-phenylene-O—, —O-phenylene-CH2-phenylene-O—, —Si(CH3)2—, -0-Si(CH3)2—O—, —O—Si(CH3)(0-CH3)—O—, —Si(CH3)(R17)—O—Si(CH3)(R18)—, 5-(2-hydroxyethyl)-[1,3,5]triazinane-2,4,6-trione-1,3-diyl and/or by from one to nine oxygen atoms.

3. 发明申请

US20050228062A1 Incorporable photoinitiator 有权
标题翻译：可并入的光引发剂
公开(公告)号：US20050228062A1
公开(公告)日：2005-10-13
申请号：US10512300
申请日：2003-04-17
申请人： Jean-Pierre Wolf , Rinaldo Husler , Wolfgang Peter , Reinhard Sommerlade , Souad Boulmaaz
发明人： Jean-Pierre Wolf , Rinaldo Husler , Wolfgang Peter , Reinhard Sommerlade , Souad Boulmaaz
IPC分类号： C07D303/22 , C07C69/716 , C07C271/20 , C07C275/62 , C08F2/50 , C08G2/00
CPC分类号： C08F2/50 , B33Y70/00
摘要： Compounds of formula (I), wherein Y is, for example, C3-C,12alkylene, butenylene, butynylene, or C4-C,12alkylene interrupted one or more times by non-consecutive —O— or —NR2—; R1 is a reactive group selected from OH, SH, NR3R4, —(CO)—OH, —(CO)—NH2, SO3H, —C(R5)═CR6R7, oxiranyl, —O—(CO)—NH—R8—NCO and —O—(CO)—R9—(CO)—X; R2 is hydrogen, C1-C4alkyl or C2-C4 hydroxyalkyl; R3 and R4 are each independently of the other hydrogen, C1-C4alkyl or C2-C4hydroxyalkyl; R5, R6 and R7 are each independently of the others hydrogen or methyl; R8 is, for example, linear or branched C4-C12alkylene, or phenylene; R9 is, for example, linear branched C1-C16alkylene, —CH═CH—, —CH═CH—CH2—, C6-cycloalkylene, phenylene or naphthylene; and X, X1 and X2 are each independently of the others OH, Cl, OCH3 or OC2H5; are suitable as photoinitiators that can be incorporated in a formulation to be cured.
摘要翻译：式（I）的化合物，其中Y为例如C 3 -C 12亚烷基，亚丁烯基，亚丁炔基或C 4-14亚烷基， C 1 -C 12亚烷基被非连续的-O-或-NR 2 - 2间隔一次或多次; R 1是选自OH，SH，NR 3 R 4， - （CO）-OH， - （CO） - NH 2，SO 3 H，-C（R 5） - CR 6 R 7， /（CO）-NH-R 8 -NCO和-O-（CO）-R 9 - （CO）-X; R 2是氢，C 1 -C 4烷基或C 2 -C 4烷基或C 2 -C 4 - 羟基烷基; R 3和R 4分别独立地为氢，C 1 -C 4烷基或C 1 -C 4烷基， S 2 -C 4羟烷基; R 5，R 6和R 7各自独立地为氢或甲基; R 8是例如直链或支链C 4 -C 12亚烷基或亚苯基; R 9是例如直链支链C 1 -C 16亚烷基，-CH-CH-，-CH-CH-CH 3，亚磺酰基，亚苯基或亚萘基; 和X，X 1和X 2各自独立地为OH，Cl，OCH 3或OC 2

4. 发明申请

US20060241323A1 Process for the preparation of 1-phenylindan photoinitiators 有权
标题翻译： 1-苯基吲哚类光引发剂的制备方法
公开(公告)号：US20060241323A1
公开(公告)日：2006-10-26
申请号：US10553777
申请日：2004-04-26
申请人： Rinaldo Husler , Thomas Horni
发明人： Rinaldo Husler , Thomas Horni
IPC分类号： C07C45/46
CPC分类号： C08F2/50 , C07C45/46 , C07C45/63 , C07C45/64 , C07C45/81 , C07C49/792 , C07C49/813 , C07C49/83
摘要： The invention relates to a process for the preparation of a crystalline isomeric mixture of compounds of formulae (I) and (II) which process comprises the following steps: a) the slow addition of aluminium chloride, in portions, to a solution comprising 1,1,3-trimethyl-3-phenylindan and isobutyric acid halide in a suitable solvent at a reaction temperature of from −20° C. to 20° C., an isomeric mixture consisting of compounds of formulae (Ia) and (IIa) being obtained; b) enol chlorination of compounds (Ia) and (IIa), an isomeric mixture consisting of compounds of formulae (Ib) and (IIb) being obtained; c) hydrolysis of the chlorinated isomeric mixture from step b). The invention relates also to the preparation of the individual compounds (I) and (II).
摘要翻译：本发明涉及一种制备式（I）和（II）化合物的结晶异构体混合物的方法，该方法包括以下步骤：a）将氯化铝缓慢加入到包含1， 1,3-二甲基-3-苯基茚基和异丁酸卤化物在合适的溶剂中，在-20℃至20℃的反应温度下，由式（Ia）和（IIa）化合物组成的异构体混合物为获得; b）化合物（Ia）和（IIa）的烯醇氯化，得到由式（Ib）和（IIb）的化合物组成的异构体混合物; c）步骤b）中氯化异构体混合物的水解。本发明还涉及单个化合物（I）和（II）的制备。

5. 发明申请

US20050004249A1 Novel disfunctional photoinitiators 有权
标题翻译：新型失活光引发剂
公开(公告)号：US20050004249A1
公开(公告)日：2005-01-06
申请号：US10494593
申请日：2002-10-31
申请人： Andre Fuchs , Rinaldo Husler , Christian Schregenberger , Martin Kunz
发明人： Andre Fuchs , Rinaldo Husler , Christian Schregenberger , Martin Kunz
IPC分类号： C07B61/00 , C07C45/46 , C07C45/63 , C07C45/64 , C07C45/66 , C07C45/81 , C07C49/83 , C08F2/50 , C09D7/12 , C09D11/00 , C09D201/00 , G03F7/031 , C08F2/46 , C07C45/00 , C07C49/213 , C07C49/225 , C07C49/563 , C07C49/76 , C08J3/28
CPC分类号： G03F7/031 , B33Y70/00 , C07C45/46 , C07C45/63 , C07C45/64 , C07C45/81 , C07C49/83 , C08F2/50 , C07C49/784 , C07C49/813
摘要： The invention relates to α-hydroxy ketones of formula I or IIa; or mixtures of compounds of formula I and II; or mixtures of compounds of formulae Ia and IIa
摘要翻译：本发明涉及式I或IIa的α-羟基酮; 或式I和II化合物的混合物; 或式Ia和IIa化合物的混合物

6. 发明申请

US20060160915A1 Photocurable compositions 审中-公开
标题翻译：可光固化组合物
公开(公告)号：US20060160915A1
公开(公告)日：2006-07-20
申请号：US10544509
申请日：2004-02-09
申请人： Andre Fuchs , Rinaldo Husler , Thomas Bolle
发明人： Andre Fuchs , Rinaldo Husler , Thomas Bolle
IPC分类号： C08F2/50
CPC分类号： C08F2/50 , C08K5/07 , G03F7/031
摘要： Benzophenone derivatives of formula I R1, R2 and R3 are each independently of the others hydrogen or C1-C4alkyl, cyclopentyl or cyclohexyl; R4, R5 and R6 are each independently of the others hydrogen, C1-C4alkyl, cyclopentyl or cyclohexyl; R7 and R8 are each independently of the other hydrogen, C1-C4alkyl, cyclopentyl or cyclohexyl; with the provisos that (i) at least one radical R1, R2, R3, R4, R5, R6, R7, R8 is other than hydrogen; (ii) when all radicals R4, R5 , R6, R7 and R8 are hydrogen and only one radical R1, R2, R3 is C1-C4alkyl, that radical must be in the meta-position of the phenyl ring; and (iii) when all radicals R1, R2, R3, R7 and R8 are hydrogen and two of the radicals R4, R5 and R6 are hydrogen and the remaining radical R4, R5 or R6 is C1-C4alkyl, that alkyl radical is not bonded in the para-position on the phenyl ring; are found to be especially suitable in photocurable compositions in respect of solubility, reactivity and a low level of yellowing.
摘要翻译：式IR 1 R 2，R 2和R 3的二苯甲酮衍生物各自独立地为氢或C 1〜 -C 4烷基，环戊基或环己基; R 4，R 5和R 6各自独立地为氢，C 1 -C 3 烷基，环戊基或环己基; R 7和R 8分别独立地为氢，C 1 -C 4烷基，环戊基或环己基条件是（i）至少一个基团R 1，R 2，R 3，R 4， R 5，R 6，R 7，R 8不同于氢; R 5，R 7，R 7，（ii）当所有基团R 4，R 5，R 6，R 7和R 7， 8是氢，只有一个基团R 1，R 2，R 3是C 1 H 2， -C 4 - 烷基，该基团必须在苯环的间位; 和（iii）当所有基团R 1，R 2，R 3，R 7和R SUB > 8 是氢，基团R 4，R 5和R 6中的两个是氢，剩余的基团R' R 4，R 5或R 6是C 1 -C 4烷基，该C 1 -C 4烷基，烷基在苯环的对位不结合; 在溶解性，反应性和黄化程度方面都被认为特别适用于光固化组合物。

7. 发明申请

US20050239971A1 New difunctional photoinitators 有权
标题翻译：新型双功能光电二极管
公开(公告)号：US20050239971A1
公开(公告)日：2005-10-27
申请号：US10521650
申请日：2003-07-10
申请人： Rinaldo Husler , Andre Fuchs
发明人： Rinaldo Husler , Andre Fuchs
IPC分类号： B05D3/02 , B05D3/06 , B05D5/00 , C07C45/46 , C07C45/63 , C07C45/64 , C07C45/68 , C07C49/83 , C07C49/84 , C08F2/46 , C08F2/50 , C08F20/34 , C09D4/00 , C09D4/02 , C09D5/00 , C09D5/03 , C09D7/12 , C09D11/02 , G03F7/031 , C08F265/00
CPC分类号： G03F7/031 , B33Y70/00 , C07C45/46 , C07C45/63 , C07C45/64 , C07C45/68 , C07C49/83 , C07C49/84 , C08F2/50 , Y10S522/909 , C07C49/784 , C07C49/813
摘要： The invention relates to novel photoinitiators of formula (I) wherein A is —O—, —CH2−, CH(CH3)— or —C(CH3)2−, and R is methyl or trimethylsilyl, and R may in addition be hydrogen when A is simultaneously the group —C(CH3)2−. The invention relates also to compositions comprising (A) at least one ethylenically unsaturated compound, (B) a photoinitiator of formula (I), (C) optionally further binders or additives, (D) optionally further photoinitiators or co-initiators. Compositions comprising (A) an ethylenically unsaturated compound that contains at least one aminoacrylate, (B) a photoinitiator of formula (II) or (III), (C) optionally further binders or additives, (D) optionally further photoinitiators or co-initiators.
摘要翻译：本发明涉及式（I）的新型光引发剂，其中A是-O-，-CH 2 - ，CH（CH 3） - 或-C（CH _{3）2 - ，且R是甲基或三甲基甲硅烷基，当A同时为基团-C（CH 3）3）时，R另外可以是氢。 2 - 。本发明还涉及包含（A）至少一种烯键式不饱和化合物，（B）式（I）的光引发剂，（C）任选的其它粘合剂或添加剂的组合物，（D）任选的其它光引发剂或共引发剂。包含（A）含有至少一个氨基丙烯酸酯的烯属不饱和化合物，（B）式（II）或（III）的光引发剂，（C）任选的其它粘合剂或添加剂的组合物，（D）任选的其它光引发剂或共引发剂。}

8. 发明授权

US5306600A Oxygen-containing titanocenes, and the use thereof 失效
标题翻译：含氧二茂钛及其用途
公开(公告)号：US5306600A
公开(公告)日：1994-04-26
申请号：US975042
申请日：1992-11-12
申请人： Eginhard Steiner , Harry Beyeler , Martin Riediker , Vincent Desobry , Kurt Dietliker , Rinaldo Husler
发明人： Eginhard Steiner , Harry Beyeler , Martin Riediker , Vincent Desobry , Kurt Dietliker , Rinaldo Husler
IPC分类号： C07F7/28 , C07F17/00 , C08F2/50 , C09D4/00 , G03F7/029
CPC分类号： C07F17/00 , C08F2/50 , G03F7/029 , Y10S430/124 , Y10S430/148 , Y10S526/943
摘要： Titanocenes of the formula I ##STR1## in which R.sup.1 are cyclopentadienyl.sup..crclbar. groups and R.sup.2 and R.sup.3 are aromatic radicals which are substituted in both ortho-positions by fluorine and, in addition, are substituted by an acyloxy group are suitable as photoinitiators for the photopolymerization of ethylenically unsaturated compounds.
摘要翻译：其中R 1是环戊二烯基（ - ）基团并且R 2和R 3是在两个邻位被氟取代并且被酰氧基取代的芳族基团的式I化合物（I）的十六碳烯是合适的作为烯属不饱和化合物的光聚合的光引发剂。

9. 发明授权

US5210110A Silylated acylphosphine oxides 失效
标题翻译：苯乙烯磷酰氧化物
公开(公告)号：US5210110A
公开(公告)日：1993-05-11
申请号：US793759
申请日：1991-11-18
申请人： Werner Rutsch , Rinaldo Husler
发明人： Werner Rutsch , Rinaldo Husler
IPC分类号： C07F9/53 , C07F9/32 , C07F9/40 , C07F9/6596 , C08F2/50 , C08J7/04 , C08K5/53 , C08K5/5397 , C08L23/00 , G03C1/06 , G03F7/029 , G03F7/075
CPC分类号： C07F9/3294 , C07F9/409 , C07F9/6596 , C08F2/50 , G03F7/029 , G03F7/0755
摘要： Silylated acylphosphine oxides of formula I ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 are defined in the specification, are highly suitable as photoinitiators for the photopolymerization of compounds which can be polymerized by means of free radicals, namely ethylenically unsaturated compounds.
摘要翻译：式I中的R 1，R 2和R 3在本说明书中定义的式（I）的甲硅烷基酰基氧化膦非常适合作为可通过自由基即烯属不饱和化合物聚合的化合物的光聚合的光引发剂。

10. 发明授权

US4739052A Phenyl ketone derivatives 失效
标题翻译：苯基酮衍生物
公开(公告)号：US4739052A
公开(公告)日：1988-04-19
申请号：US783377
申请日：1985-10-02
申请人： Rinaldo Husler , Rudolf Kirchmayr , Werner Rutsch
发明人： Rinaldo Husler , Rudolf Kirchmayr , Werner Rutsch
IPC分类号： C07D319/24 , C07C45/46 , C07C45/63 , C07C49/84 , C07C67/00 , C07C225/16 , C07C225/18 , C07C229/38 , C07C235/72 , C07C255/13 , C07C301/00 , C07C309/63 , C07D217/20 , C07D265/30 , C07D295/10 , C07D295/108 , C07D303/48 , C07D307/91 , C07F7/18 , C08F2/00 , C08F2/50 , C09D11/10 , G03F7/031 , C07C97/10
CPC分类号： C07D295/108 , C07C45/46 , C07C45/63 , C07C49/84 , C07D303/48 , C07D307/91 , C08F2/50 , G03F7/031
摘要： Compounds of the formula I, II or III ##STR1## in which Ar and Ar' are an oxygen-containing aromatic radical, R.sup.1 and R.sup.2 are a monovalent hydrocarbon radical which is substituted or unsubstituted, or R.sup.1 and R.sup.2 together form alkylene, oxaalkylene or azaalkylene, R.sup.3 is a direct bond or a divalent hydrocarbon radical, X and X' are a monovalent amino group and Y is a divalent amino or diamino group, are excellent photoinitiators for the photocuring of colored, especially pigmented, compositions containing an olefinically unsaturated, photopolymerizable binder.
摘要翻译：其中Ar和Ar'是含氧芳族基团的式I，II或III化合物其中R 1和R 2是一价烃基，其中是取代或未取代的，或者R 1和R 2一起形成亚烷基，氧杂亚烷基或氮杂亚烷基，R 3是直接键或二价烃基，X和X'是一价氨基，Y是二价氨基或二氨基，是优异的光引发剂用于对含有烯属不饱和的可光聚合粘合剂的着色的，特别是着色的组合物进行光固化。

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