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    • 10. 发明公开
    • TONER FOR DEVELOPING ELECTROSTATIC IMAGES, TONER KITS, AND IMAGE FORMATION EQUIPMENT
    • TONER ZUM ENTWICKELN ELEKTROSTATISCHER BILDER,TONER-KITS UNDBILDERZEUGUNGSGERÄTE
    • EP1944656A1
    • 2008-07-16
    • EP06822832.9
    • 2006-11-01
    • Ricoh Company, Ltd.
    • SUGIURA, HidekiFUSHIMI, HiroyukiUCHINOKURA, OsamuHONDA, TakahiroTOMITA, MasamiSHU, HyoUMEHARA, Ken
    • G03G9/087G03G9/09
    • G03G9/08755G03G9/0806G03G9/0819G03G9/08753G03G9/08795G03G9/08797G03G9/091G03G9/0912G03G9/0914G03G9/0922
    • A toner is provided that comprises a colorant and a binder resin, wherein the binder resin comprises a polyester resin that is prepared by a polycondensation reaction in the presence of at least a titanium-containing catalyst expressed by General Formula (I) or (II), the toner has a volume average particle diameter of 2.0 µm to 10.0 µm and a ratio Dv/Dn within a range of 1.00 to 1.40, in which Dv represents a volume average particle diameter and Dn represents a number average particle diameter,

              Ti(-X) m (-OH) n      General Formula (I)

              O=Ti(-X) p (-OR) q      General Formula (II)

      in General Formulas (I) and (II), X represents a residue of a mono-alkanolamine of 2 to 12 carbon atoms or a polyalkanolamine from which a hydrogen atom of one hydroxyl group is removed; other hydroxyl group(s) and still other hydroxyl group(s), within the polyalkanolamine molecule that has a directly bonding Ti atom, may polycondense to form a ring structure; other hydroxyl group(s) and still other hydroxyl group(s) may polycondense intermolecularly to form a repeating structure; and the polymerization degree is 2 to 5 in a case of forming the repeating structure; R represents one of a hydrogen atom and alkyl groups of 1 to 8 carbon atoms that may have 1 to 3 ether bonds; "m" is an integer of 1 to 4; "n" is an integer of 0 to 3; the sum of "m" and "n" is 4; "p" is an integer of 1 or 2; "q" is an integer of 0 or 1; the sum of "p" and "q" is 2; and in a case that "m" and "p" is 2 or more, the respective Xs may be identical or different each other.
    • 提供了一种调色剂,其包含着色剂和粘合剂树脂,其中所述粘合剂树脂包含在至少由通式(I)或(II)表示的含钛催化剂的存在下通过缩聚反应制备的聚酯树脂, ,调色剂的体积平均粒径为2.0μm〜10.0μm,Dv / Dn的比例在1.00〜1.40的范围内,Dv表示体积平均粒径,Dn表示数均粒径,€ ƒ€ƒ€ƒ€ƒ€ƒ€ƒTi(-X)m(-OH)n€ƒ€ƒ€ƒ€ƒ一般公式(I)€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ ƒ€ƒO= Ti(-X)p(-OR)q€ƒ€ƒ€ƒ通用式(I)和(II)中的通式(II),X表示单链烷醇胺的残基 2至12个碳原子或去除一个羟基的氢原子的聚烷醇胺; 在具有直接键合Ti原子的聚链烷醇胺分子内的其它羟基和其它羟基可以缩聚形成环结构; 其他羟基和其他羟基可以分子间缩聚形成重复结构; 在形成重复结构的情况下聚合度为2〜5。 R表示氢原子和可以具有1〜3个醚键的1〜8个碳原子的烷基; “m”为1〜4的整数, “n”为0〜3的整数, “m”和“n”之和为4; “p”是1或2的整数; “q”是0或1的整数; “p”和“q”之和为2; 在“m”和“p”为2以上的情况下,各个X可以相同也可以不同。