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    • 4. 发明公开
    • TONER FOR DEVELOPING ELECTROSTATIC IMAGES, TONER KITS, AND IMAGE FORMATION EQUIPMENT
    • TONER ZUM ENTWICKELN ELEKTROSTATISCHER BILDER,TONER-KITS UNDBILDERZEUGUNGSGERÄTE
    • EP1944656A1
    • 2008-07-16
    • EP06822832.9
    • 2006-11-01
    • Ricoh Company, Ltd.
    • SUGIURA, HidekiFUSHIMI, HiroyukiUCHINOKURA, OsamuHONDA, TakahiroTOMITA, MasamiSHU, HyoUMEHARA, Ken
    • G03G9/087G03G9/09
    • G03G9/08755G03G9/0806G03G9/0819G03G9/08753G03G9/08795G03G9/08797G03G9/091G03G9/0912G03G9/0914G03G9/0922
    • A toner is provided that comprises a colorant and a binder resin, wherein the binder resin comprises a polyester resin that is prepared by a polycondensation reaction in the presence of at least a titanium-containing catalyst expressed by General Formula (I) or (II), the toner has a volume average particle diameter of 2.0 µm to 10.0 µm and a ratio Dv/Dn within a range of 1.00 to 1.40, in which Dv represents a volume average particle diameter and Dn represents a number average particle diameter,

              Ti(-X) m (-OH) n      General Formula (I)

              O=Ti(-X) p (-OR) q      General Formula (II)

      in General Formulas (I) and (II), X represents a residue of a mono-alkanolamine of 2 to 12 carbon atoms or a polyalkanolamine from which a hydrogen atom of one hydroxyl group is removed; other hydroxyl group(s) and still other hydroxyl group(s), within the polyalkanolamine molecule that has a directly bonding Ti atom, may polycondense to form a ring structure; other hydroxyl group(s) and still other hydroxyl group(s) may polycondense intermolecularly to form a repeating structure; and the polymerization degree is 2 to 5 in a case of forming the repeating structure; R represents one of a hydrogen atom and alkyl groups of 1 to 8 carbon atoms that may have 1 to 3 ether bonds; "m" is an integer of 1 to 4; "n" is an integer of 0 to 3; the sum of "m" and "n" is 4; "p" is an integer of 1 or 2; "q" is an integer of 0 or 1; the sum of "p" and "q" is 2; and in a case that "m" and "p" is 2 or more, the respective Xs may be identical or different each other.
    • 提供了一种调色剂,其包含着色剂和粘合剂树脂,其中所述粘合剂树脂包含在至少由通式(I)或(II)表示的含钛催化剂的存在下通过缩聚反应制备的聚酯树脂, ,调色剂的体积平均粒径为2.0μm〜10.0μm,Dv / Dn的比例在1.00〜1.40的范围内,Dv表示体积平均粒径,Dn表示数均粒径,€ ƒ€ƒ€ƒ€ƒ€ƒ€ƒTi(-X)m(-OH)n€ƒ€ƒ€ƒ€ƒ一般公式(I)€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ ƒ€ƒO= Ti(-X)p(-OR)q€ƒ€ƒ€ƒ通用式(I)和(II)中的通式(II),X表示单链烷醇胺的残基 2至12个碳原子或去除一个羟基的氢原子的聚烷醇胺; 在具有直接键合Ti原子的聚链烷醇胺分子内的其它羟基和其它羟基可以缩聚形成环结构; 其他羟基和其他羟基可以分子间缩聚形成重复结构; 在形成重复结构的情况下聚合度为2〜5。 R表示氢原子和可以具有1〜3个醚键的1〜8个碳原子的烷基; “m”为1〜4的整数, “n”为0〜3的整数, “m”和“n”之和为4; “p”是1或2的整数; “q”是0或1的整数; “p”和“q”之和为2; 在“m”和“p”为2以上的情况下,各个X可以相同也可以不同。
    • 9. 发明公开
    • TONER FOR DEVELOPING ELECTROSTATIC LATENT IMAGE, AND IMAGING DEVICE USING THE SAME
    • TONER ZUM ENTWICKELN EINES LATENTEN ELEKTROSTATISCHEN BILDES UND BILDERZEUGUNGSEINRICHTUNG DAMIT
    • EP1995639A1
    • 2008-11-26
    • EP07738473.3
    • 2007-03-13
    • Ricoh Company, Ltd.
    • TOMITA, MasamiUMEHARA, Ken
    • G03G9/087C08J3/12G03G9/08
    • G03G9/08793C08G63/85G03G9/08795G03G9/08797
    • Provided is an electrostatic image developing toner excellent in blocking resistance at high temperature and humidity, as well as in low temperature-fixing property, having a polyester resin toner binder. Provided is the electrostatic image developing toner containing at least one noncrystalline polyester resin and a crystalline polyester resin, wherein the polyester resins are formed in the presence of at least one titanium-containing catalyst expressed in the following Formulas:

              Ti(-X)m(-OH)n

              O=Ti(-X)p(-OR)q

      where X is a residue resulting from removing an H atom in one hydroxyl group from (poly)alkanolamine having 2 to 12 carbon atoms, R represents an H atom or an alkyl group that has 1 to 8 carbon atoms and may contain 1 to 3 ether bonds, m, n, p, and q are integers; m, n, p, and q are 1-4, 0-3, 1-2, 0-1,respectively; and the sum of m and n, and p and q are 4 and 2, respectively.
    • 本发明提供一种具有聚酯树脂调色剂粘合剂的耐高温和湿度下的耐粘连性以及低温定影性的静电图像显影调色剂。 提供了含有至少一种非结晶性聚酯树脂和结晶性聚酯树脂的静电图像显影调色剂,其中聚酯树脂在至少一种以下公式表示的含钛催化剂存在下形成:€ƒ€ƒ€ ƒ€ƒ€ƒ€ƒTi(-X)m(-OH)n€ƒ€ƒ€ƒ€ƒ€ƒ€ƒO= Ti(-X)p(-OR)q其中X是 从具有2至12个碳原子的(多)链烷醇胺除去一个羟基中的H原子得到的残基,R表示H原子或具有1至8个碳原子并可以含有1至3个醚键的烷基,m ,n,p和q是整数; m,n,p和q分别为1-4,0-3,1-2,0-1; m和n之和,p和q分别为4和2。