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    • 2. 发明专利
    • Toner and manufacturing method of the toner, and image formation device and image formation method using the toner
    • 调色剂的调色剂和制造方法,图像形成装置和使用色调剂的图像形成方法
    • JP2013064819A
    • 2013-04-11
    • JP2011202751
    • 2011-09-16
    • Ricoh Co Ltd株式会社リコー
    • NAGATOMO NOBUYASUKOJIMA TOMOYUKISATO SACHIKOOGAWA SATORUHONDA TAKAHIROITO DAISUKEKUSAHARA TERUKIINOUE DAISUKEAWAMURA JUNICHIUCHINOKURA OSAMU
    • G03G9/08G03G9/087G03G15/08
    • PROBLEM TO BE SOLVED: To provide an image formation device and a toner having excellent low-temperature fixability, in which toner aggregation does not occur even under a highly humid environment and charge stability can be secured.SOLUTION: A toner material at least including binder resin or binder resin precursor is dissolved or dispersed to obtain an organic solvent liquid. The organic solvent liquid is emulsified or dispersed in an aqueous medium including a stabilizer to obtain an O/W type emulsion or dispersion liquid. From the O/W type emulsion or dispersion liquid, an organic solvent is removed to obtain an electrostatic charge image developing toner. The electrostatic charge image developing toner includes an external additive. The external additive has an average particle diameter of 50-200 nm. A specific surface area A before hydrophobic treatment and a specific surface area B after hydrophobic treatment on the external additive satisfy a mathematical formula (1): 6/(D.ρ)≤A-B≤A/2 ... formula (1), where ρ represents an absolute specific gravity of the external additive, and D represents particle size of the external additive.
    • 要解决的问题:为了提供一种图像形成装置和具有优异的低温定影性的调色剂,即使在高湿度环境下也不会发生调色剂聚集,并且可以确保电荷稳定性。 解决方案:将至少包含粘合剂树脂或粘合剂树脂前体的调色剂材料溶解或分散以获得有机溶剂液体。 将有机溶剂液体乳化或分散在包含稳定剂的水性介质中,得到O / W型乳液或分散液。 从O / W型乳液或分散液中除去有机溶剂,得到静电荷图像显影调色剂。 静电荷图像显影调色剂包括外部添加剂。 外用添加剂的平均粒径为50-200nm。 憎水处理前的比表面积A和疏水处理后的外用添加剂的比表面积B满足数学式(1):6 /(D.ρ)≤AB≤A/ 2 ...式(1) 其中ρ表示外部添加剂的绝对比重,D表示外部添加剂的粒径。 版权所有(C)2013,JPO&INPIT
    • 3. 发明专利
    • Toner, developer, image forming apparatus and image forming method
    • 调色剂,开发者,图像形成装置和图像形成方法
    • JP2013015673A
    • 2013-01-24
    • JP2011148332
    • 2011-07-04
    • Ricoh Co Ltd株式会社リコー
    • HOZUMI MAMORUAWAMURA JUNICHIKUSAHARA TERUKIITO DAISUKEOGAWA SATORUHONDA TAKAHIROHIROHARA KIWAKOUCHINOKURA OSAMUKOJIMA TOMOYUKISATO SACHIKONAGATOMO NOBUYASUWATANABE MASAKI
    • G03G9/08G03G9/087
    • G03G9/08755G03G9/0804G03G9/08782G03G9/08797
    • PROBLEM TO BE SOLVED: To provide toner and the like, which achieves good fixing property at 150°C or lower, has a high effect of suppressing contamination inside a copying machine or the like by volatile wax dust or generation of dust to the outside by exhaust, even when the toner is used in a high-speed copying machine, and can give a favorable fixed image.SOLUTION: Toner comprises a binder resin, a release agent and colorant. The binder resin comprises a crystalline polyester resin and a non-crystalline polyester resin. The release agent shows an endothermic peak temperature of 60°C to 80°C in the second temperature rise in differential scanning calorimetry; and the release agent is ester wax satisfying 1.1 (Pa s)≤ηa≤2.0 (Pa s) and 0.001≤ηb/ηa≤1.00, where ηa represents complex viscosity (Pa s) of the release agent obtained by measurement of dynamic viscoelasticity at measurement frequency of 6.28 rad/s and ηb represents complex viscosity (Pa s) of the release agent measured by measurement of dynamic viscoelasticity at measurement frequency of 62.8 rad/s.
    • 待解决的问题:为了提供在150℃以下的良好定影性能的调色剂等具有通过挥发性蜡粉尘或产生粉尘而抑制复印机等内部的污染的高效果 即使在高速复印机中使用调色剂的情况下,也可以通过排气进行外部的定影,并且能够赋予良好的固定图像。 调色剂包括粘合剂树脂,脱模剂和着色剂。 粘合剂树脂包括结晶聚酯树脂和非结晶聚酯树脂。 脱模剂在差示扫描量热法中的第二升温中显示出60℃至80℃的吸热峰温度; 并且脱模剂为满足1.1(Pa·s)≤n * a≤2.0(Pa s)和0.001≤η * SP> b /η * a≤1.00,其中η * a表示得到的脱模剂的复数粘度(Pa s) 通过在6.28rad / s的测量频率下测量动态粘弹性,并且η表示通过在测量频率下测量动态粘弹性测量的脱模剂的复数粘度(Pa s) 62.8 rad / s。 版权所有(C)2013,JPO&INPIT
    • 4. 发明专利
    • Toner for electrostatic charge development
    • 用于静电充电开发的调色剂
    • JP2013007843A
    • 2013-01-10
    • JP2011139708
    • 2011-06-23
    • Ricoh Co Ltd株式会社リコー
    • YOSHIDA RYUTAAWAMURA JUNICHIKUSAHARA TERUKIOGAWA SATORUHONDA TAKAHIROITO DAISUKEKOJIMA TOMOYUKIINOUE DAISUKESATO YUKIFUMISATO SACHIKOUCHINOKURA OSAMU
    • G03G9/087G03G9/08
    • PROBLEM TO BE SOLVED: To provide a toner exhibiting high glossiness without inhibiting low-temperature fixability and a hot offset property.SOLUTION: The toner is obtained by: preparing an organic solvent solution or dispersion of a toner resin material containing a binder resin, a prepolymer comprising a modified polyester resin and an active hydrogen group-containing compound together with a colorant and a release agent; subjecting the solution or dispersion to a crosslinking reaction and/or an elongation reaction in an aqueous medium dispersion liquid; and removing the solvent. The prepolymer is derived from an unmodified polyester that is a precursor of the prepolymer; and the unmodified polyester is a polyester having an alcohol having a carbon ring as a copolymer component. The molecular weight Mpt at the maximum peak of the unmodified polyester satisfies 14000≤Mpt≤21000. An average number F of functional groups that is reactive for elongation or crosslinking, included in one molecule of the prepolymer, satisfies 1.8≤F≤2.2. A gel fraction G as an insoluble content in methyl acetate included in the toner satisfies 13≤G≤21 (wt.%).
    • 要解决的问题:提供在不抑制低温定影性和热偏移性的情况下显示高光泽度的调色剂。 解决方案:调色剂是通过以下步骤获得的:制备含有粘合剂树脂的调色剂树脂材料的有机溶剂溶液或分散体,包含改性聚酯树脂和含活泼氢基团的化合物的预聚物以及着色剂和释放 代理人 使溶液或分散体在水性介质分散液中进行交联反应和/或伸长反应; 并除去溶剂。 预聚物衍生自作为预聚物前体的未改性聚酯; 未改性聚酯是具有作为共聚物成分的碳环的醇的聚酯。 未改性聚酯的最大峰的分子量Mpt满足14000≤Mpt≤21000。 包含在一分子预聚物中的伸长或交联反应的官能团的平均数F满足1.8≤F≤2.2。 包含在调色剂中的乙酸甲酯中不溶物含量的凝胶分数G满足13≤G≤21(重量%)。 版权所有(C)2013,JPO&INPIT
    • 6. 发明专利
    • Manufacturing method of toner
    • 调色剂的制造方法
    • JP2012189967A
    • 2012-10-04
    • JP2011055824
    • 2011-03-14
    • Ricoh Co Ltd株式会社リコー
    • HOZUMI MAMORUAWAMURA JUNICHIOGAWA SATORUKUSAHARA TERUKIYOSHIDA RYUTAINOUE DAISUKEITO DAISUKEUCHINOKURA OSAMUNAGATOMO NOBUYASUSATO SACHIKOHONDA TAKAHIRO
    • G03G9/087
    • PROBLEM TO BE SOLVED: To provide a manufacturing method of a toner being excellent in low-temperature fixability, heat-resistant preservability and hot-offset resistance and allowing formation of an image with high glossiness.SOLUTION: A manufacturing method of toner comprises a step of preparing a composition containing a compound having a crystalline polyester, a certain amorphous polyester, a prepolymer and an amino group; a mold release agent and a colorant, by aging a liquid comprising a particle in an aqueous medium using an organic solvent. The number of the isocyanate group of the prepolymer is 1.8 or more and 2.2 or less, as an average value. In the first temperature rising of differential scanning calorimetry of the particle, if the glass transition point and the height of the endothermic peak from the crystalline polyester per unit mass of the particle before aging are defined as Tg[°C] and H[μW/mg] respectively and if the glass transition point and the height of the endothermic peak of the particle after aging are defined as Tg[°C] and H[μW/mg] respectively, the following two formulas: 1.3≤H/H≤1.6 and 0≤Tg-Tg≤1.0 are satisfied.
    • 要解决的问题:提供低温定影性,耐热保存性和耐热粘合性优异的调色剂的制造方法,并且可以形成具有高光泽度的图像。 调色剂的制造方法包括:制备含有结晶性聚酯,某种无定形聚酯,预聚物和氨基的化合物的组合物的工序; 脱模剂和着色剂,通过使用有机溶剂在含水介质中老化包含颗粒的液体。 预聚物的异氰酸酯基数为1.8以上且2.2以下,作为平均值。 在颗粒的差示扫描量热法的第一次升温中,如果玻璃化转变点和来自结晶聚酯的每单位质量的老化前的颗粒的吸热峰的高度定义为Tg 1 [℃]和H 1 [μW/ mg],如果玻璃化转变点和老化后颗粒的吸热峰的高度定义为 Tg 2 [℃]和H 2 [μW/ mg],以下两个公式:1.3≤H 2 / H 1 ≤1.6和0≤Tg 2 -Tg 1 ≤1.0。 版权所有(C)2013,JPO&INPIT
    • 8. 发明专利
    • Toner, two-component developer, and image forming apparatus
    • 调色剂,双组分显影剂和图像形成装置
    • JP2013190647A
    • 2013-09-26
    • JP2012057366
    • 2012-03-14
    • Ricoh Co Ltd株式会社リコー
    • KOJIMA TOMOYUKINAGATOMO NOBUYASUSATO SACHIKOUCHINOKURA OSAMUAWAMURA JUNICHIOGAWA SATORUHONDA TAKAHIROITO DAISUKEKUSAHARA TERUKIWATANABE MASAKIINOUE DAISUKE
    • G03G9/08G03G9/087G03G15/08
    • G03G9/0825G03G9/097G03G9/09708
    • PROBLEM TO BE SOLVED: To provide a toner that satisfies all of low-temperature fixability, heat-resistance storability, transferability, and a filming property even in a long period of use; developer using the toner; and an image forming apparatus.SOLUTION: A toner of the present invention contains toner base particles containing at least a binder resin and colorant, and at least an external additive. The external additive contains at least adhered particles; the adhered particles are non-spherical secondary particles formed by primary particles adhering to each other; and the particle size distribution index of the adhered particles is represented by the following formula (1), wherein, Dbrepresents the particle diameter of the adhered particles at a point when an accumulated value is 50 number%, when the particle diameter (nm) of the adhered particles is an abscissa, and the accumulated value (number%) of the adhered particles is an ordinate, and the accumulated distribution of the adhered particles is drawn from the small-particle side; and Dbrepresents the particle diameter of the adhered particles at a point when the accumulated value is 10 number%.
    • 要解决的问题:即使在长时间使用中也可提供满足低温定影性,耐热性保存性,转印性和成膜性全部的调色剂; 显影剂使用墨粉; 和图像形成装置。解决方案:本发明的调色剂含有至少含有粘合剂树脂和着色剂的调色剂基础颗粒和至少一种外部添加剂。 外部添加剂至少含有粘附的颗粒; 粘附的颗粒是由一次颗粒彼此附着形成的非球形二次颗粒; 粘附粒子的粒径分布指数由下式(1)表示,其中,当累积值为50数量%时,Db表示粘附粒子的粒径,当粒径(nm)为 附着粒子为横坐标,附着粒子的累计值(%)为纵坐标,附着粒子的累积分布从小粒子侧抽出; 并且Db表示在累积值为10数量%的点处的附着粒子的粒径。
    • 9. 发明专利
    • Image forming apparatus and toner for developing electrostatic charge image
    • 图像形成装置和调色剂用于开发静电荷图像
    • JP2012189876A
    • 2012-10-04
    • JP2011054359
    • 2011-03-11
    • Ricoh Co Ltd株式会社リコー
    • SATO SACHIKOHONDA TAKAHIROKOJIMA TOMOYUKIUCHINOKURA OSAMUAWAMURA JUNICHIOGAWA SATORUINOUE DAISUKE
    • G03G9/08G03G9/087
    • PROBLEM TO BE SOLVED: To provide a toner containing crystalline polyester which suppresses aggregation of the toner in a high temperature and high humidity environment markedly, while suppressing degradation in a filming property and toner fluidity that may occur as a side effect, and stabilizes a charging property of the toner, and to provide an image forming apparatus mounted with the toner.SOLUTION: In an image forming apparatus of this invention, a toner for forming an image is obtained by dispersing an oil phase into an aqueous medium, the oil phase including at least a crystalline polyester resin and at least one kind or more of non-crystalline polyester resins as a binding resin component in an organic solvent and by removing the organic solvent from the thus obtained dispersion liquid. The toner includes, on a surface of toner base particles, an additive containing at least two or more kinds of fine particles of silica. The silica includes both silica A from a sol-gel process and silica B from a dry process, and the silica A from a sol-gel process has an average primary particle diameter of 20 to 120 nm, and the silica A absorbs 0.01 g or more of moisture by allowing the silica A to stand for 1 week.
    • 要解决的问题:提供一种含有结晶聚酯的调色剂,其显着地抑制调色剂在高温高湿环境中的聚集,同时抑制作为副作用可能发生的成膜性和调色剂流动性的降低,以及 稳定调色剂的带电性,并提供安装有调色剂的图像形成装置。 解决方案:在本发明的图像形成装置中,用于形成图像的调色剂是通过将油相分散到水性介质中获得的,所述油相至少包括结晶聚酯树脂和至少一种或多种 非结晶性聚酯树脂作为有机溶剂中的粘合树脂成分,并从由此得到的分散液中除去有机溶剂。 调色剂在调色剂基础颗粒的表面上包括含有至少两种或更多种二氧化硅微粒的添加剂。 二氧化硅包括来自溶胶 - 凝胶法的二氧化硅A和来自干法的二氧化硅B,来自溶胶 - 凝胶法的二氧化硅A的平均一次粒径为20〜120nm,二氧化硅A吸收0.01g或 更多的水分通过使二氧化硅A放置1周。 版权所有(C)2013,JPO&INPIT
    • 10. 发明专利
    • Electrostatic charge developing toner
    • 静电充电发电机
    • JP2011203717A
    • 2011-10-13
    • JP2011014780
    • 2011-01-27
    • Ricoh Co Ltd株式会社リコー
    • KUSAHARA TERUKIAWAMURA JUNICHISUGIMOTO TSUTOMUSHU HYOSUZUKI TOMOMIUCHINOKURA OSAMUHONDA TAKAHIROKOJIMA TOMOYUKIOGAWA SATORUINOUE DAISUKESATO YUKIFUMIITO DAISUKEYOSHIDA RYUTASATO SACHIKO
    • G03G9/087G03G9/08G03G9/10G03G15/08
    • G03G9/0821G03G9/08755G03G9/08782G03G9/08795G03G9/08797
    • PROBLEM TO BE SOLVED: To provide an electrostatic charge image developing toner which is excellent in the image quality, cleanability and coloring property of an image and in low temperature fixability and toner preservability, in a recycling system using a color toner.SOLUTION: The electrostatic charge developing toner is obtained by granulation from a dispersion in which an oil phase containing a toner composition in an organic solvent is dispersed in an aqueous medium. A binder resin in the toner composition contains a low molecular resin component, wherein a resin softening coefficient (A) of the low molecular resin component represented by expression: A=|(lnG'(r1)-lnG'(r2))/(T1-T2)| is >0.165, and when a flow start temperature (°C) of the low molecular resin component measured with an elevated flow tester is designated as Tfb, a storage modulus (dyne/cm) G'(Tfb) is ≤1×10. In the expression, T1 is a temperature (°C) at which a storage modulus G'(r1) becomes 1×10(dyne/cm), and T2 is a temperature (°C) at which a storage modulus G'(r2) becomes 1×10, as measured with a rheometer at a frequency of 1 Hz and a strain of 1 deg.
    • 要解决的问题:提供一种在使用彩色调色剂的回收系统中提供图像质量,图像的清洁性和着色性以及低温定影性和调色剂保存性的静电电荷图像显影调色剂。溶液:静电 通过将含有有机溶剂中的调色剂组合物的油相分散在水性介质中的分散体造粒得到电荷显影调色剂。 调色剂组合物中的粘合剂树脂含有低分子量树脂组分,其中由式A = |(lnG'(r1)-lnG'(r2))/( T1-T2)| > 0.165,并且当用升高的流动测试仪测量的低分子量树脂组分的流动开始温度(℃)被指定为Tfb时,储能模量(dyne / cm)G'(Tfb)≤1×10。 在该表达式中,T1是储能模量G'(r1)变为1×10(dyne / cm)的温度(℃),T2是储存模量G'(r2)的温度(℃) )变为1×10,如用流变仪在1Hz的频率和1度的应变下测量的。