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    • 4. 发明授权
    • Nitrogen containing dispersant-viscosity improvers
    • 含氮分散剂 - 粘度改进剂
    • US06265358B1
    • 2001-07-24
    • US08984676
    • 1997-12-03
    • Carmen V. LucianiRichard M. LangeDaniel M. Vargo
    • Carmen V. LucianiRichard M. LangeDaniel M. Vargo
    • C10M14900
    • C10L1/238C10L1/143C10L1/2475C10M133/58C10M143/00C10M149/10C10M151/02C10M159/12
    • A composition comprising a hydrocarbon polymer having {overscore (M)}n ranging from 20,000 to about 500,000, when the polymer is not a star polymer, and up to about GPC peak molecular weight of 4,000,000 when the polymer is a star polymer having attached thereto pendant groups Aa and Bb wherein each A is independently a member of the group of formula —Q—Kk wherein each Q is independently an aliphatic or aromatic hydrocarbon group, each K is independently a member selected from the group consisting of amide groups, nitrile groups, ester groups and carboxylic acid groups, and each k is independently a number ranging from 1 to about 3, and when k≧2, groups —K on adjacent carbon atoms, taken together, may constitute a succinimide group, and a is 0 or a number ranging from 1 to about 50; and each B is independently a member of the group of formula: wherein each X is independently O, S, or NRb, each Rb is independently H, NH2, hydrocarbyl, hydroxyhydrocarbyl, or aminohydrocarbyl, each s is independently 1 or 2, and each Z is independently a hydrocarbyl group, optionally substituted with one or more carboxylic acid groups or amide groups, each Ra is independently an ethylene group, a propylene group, which groups optionally have hydrocarbyl or hydroxyhydrocarbyl substituents, or wherein J is H, SH, NH2, or OH, and tautomers thereof; and b is a number ranging from 1 to about 50 with the proviso that when X is O, then b ranges from 2 to about 50.
    • 当聚合物不是星形聚合物时,当聚合物是附着于其上的星形聚合物时,包含具有聚碳酸酯(M)} n范围为20,000至约500,000的烃聚合物的组合物,并且当聚合物是附着于其上的星形聚合物时,高达约GPC的峰值分子量为4,000,000 侧基Aa和Bb,其中每个A独立地是式-Q-Kk基团的成员,其中每个Q独立地是脂族或芳族烃基,每个K独立地是选自酰胺基,腈基 ,酯基和羧酸基团,并且每个k独立地为1至约3的数,当k> = 2时,相邻碳原子上的基团K可以一起构成琥珀酰亚胺基团,a为0 或从1到约50的数字; 并且每个B独立地是下式基团的成员:其中每个X独立地是O,S或NR b,每个R b独立地是H,NH 2,烃基,羟基烃基或氨基烃基,各自独立地是1或2, Z独立地是任选被一个或多个羧酸基或酰胺基取代的烃基,每个R a独立地是亚乙基,丙烯基,任选地具有烃基或羟基烃基取代基,或者其中J是H,SH,NH 2, 或OH,及其互变异构体; 并且b是1至约50的数,条件是当X为O时,b的范围为2至约50。
    • 6. 发明授权
    • Nitrogen containing dispersant-viscosity improvers
    • 含氮分散剂 - 粘度改进剂
    • US06486101B2
    • 2002-11-26
    • US09845653
    • 2001-04-30
    • Carmen V. LucianiRichard M. LangeDaniel M. Vargo
    • Carmen V. LucianiRichard M. LangeDaniel M. Vargo
    • C10M14900
    • C10L1/238C10L1/143C10L1/2475C10M133/58C10M143/00C10M149/10C10M151/02C10M159/12
    • A composition comprising a hydrocarbon polymer having {overscore (M)}n ranging from 20,000 to about 500,000, when the polymer is not a star polymer, and up to about GPC peak molecular weight of 4,000,000 when the polymer is a star polymer having attached thereto pendant groups Aa and Bb wherein each A is independently a member of the group of formula —Q—Kk wherein each Q is independently an aliphatic or aromatic hydrocarbon group, each K is independently a member selected from the group consisting of amide groups, nitrile groups, ester groups and carboxylic acid groups, and each k is independently a number ranging from 1 to about 3, and when k≧2, groups —K on adjacent carbon atoms, taken together, may constitute a succinimide group, and a is 0 or a number ranging from 1 to about 50; and each B is independently a member of the group of formula: wherein each X is independently O, S, or NRb, each Rb is independently H, NH2, hydrocarbyl, hydroxyhydrocarbyl, or aminohydrocarbyl, each s is independently 1 or 2, and each Z is independently a hydrocarbyl group, optionally substituted with one or more carboxylic acid groups or amide groups, each Ra is independently an ethylene group, a propylene group, which groups optionally have hydrocarbyl or hydroxyhydrocarbyl substituents, or wherein J is H, SH, NH2, or OH, and tautomers thereof; and b is a number ranging from 1 to about 50 with the proviso that when X is O, then b ranges from 2 to about 50.
    • 一种组合物,其包含具有(超过(Mn在20,000至约500,000,当聚合物不是星形聚合物时的Mn,当聚合物是附着于侧基Aa的星形聚合物时至多约GPC峰值分子量为4,000,000)的烃聚合物 和Bb,其中每个A独立地是式-Q-Kk基团的成员,其中每个Q独立地是脂族或芳族烃基,每个K独立地是选自酰胺基,腈基,酯基 和羧酸基团,并且各个k独立地为1至约3的数,当k> = 2时,相邻碳原子上的基团K可以一起构成琥珀酰亚胺基团,a为0或数 每个B独立地是下式基团的成员:其中每个X独立地是O,S或NR b,每个R b独立地是H,NH 2,烃基,羟基烃基或氨基烃基,各自是 ind 每个Z独立地是任选被一个或多个羧酸基或酰胺基取代的烃基,每个R a独立地是亚乙基,丙烯基,任选地具有烃基或羟基烃基取代基,或者其中J 是H,SH,NH 2或OH及其互变异构体; 并且b是1至约50的数,条件是当X为O时,b的范围为2至约50。
    • 8. 发明授权
    • Nitrogen containing dispersant-viscosity improvers
    • 含氮分散剂 - 粘度改进剂
    • US06288013B1
    • 2001-09-11
    • US08984301
    • 1997-12-03
    • Matthew R. SivikRichard M. LangePaul E. AdamsDaniel M. Vargo
    • Matthew R. SivikRichard M. LangePaul E. AdamsDaniel M. Vargo
    • C10M13344
    • C10L1/238C10L1/143C10L1/1608C10L1/1616C10L1/198C10L1/221C10L1/232C10L1/2383C10L1/2406C10L1/2456C10L1/2475C10L1/2493C10L1/303C10M133/58C10M143/00C10M151/00C10M2209/084C10M2215/04C10M2215/042C10M2215/064C10M2215/22C10M2215/221C10M2215/225C10M2215/226C10M2215/26C10M2215/30C10M2217/00C10M2217/02C10M2217/028C10M2217/04C10M2217/046C10M2217/06C10M2219/046C10M2219/087C10M2219/088C10M2219/089C10M2221/041C10M2223/045C10M2229/02C10M2229/05C10N2210/02C10N2240/10C10N2240/101C10N2240/104C10N2240/106
    • A composition comprising a hydrocarbon polymer having {overscore (M)}n ranging from 20,000 to about 500,000, when the polymer is not a star polymer, and up to about GPC peak molecular weight of 4,000,000 when the polymer is a star polymer having attached thereto pendant groups Aa and Bb wherein each A is independently selected from members of the group consisting of: groups of the formula wherein R3 is H or hydrocarbyl, R4 is a divalent hydrocarbylene group, n=0 or 1, and each of R9 and R10 is independently H, alkoxyhydrocarbyl, hydroxyhydrocarbyl, hydrocarbyl, aminohydrocarbyl, N-alkoxyalkyl- or hydroxyalkyl-substituted aminohydrocarbyl, or a group of the formula &Parenopenst;Y&Parenclosest;cR11—M, wherein each Y is independently a group of the formula each R11 is a divalent hydrocarbyl group, R12 is as defined above for R9 and R10, and M is H, hydrocarbyl, amino, an amide group, an amide-containing group, an acylamino group, an imide group, or an imide-containing group, and c is 0 or a number ranging from 1 to about 100, or one of R9 and R10 taken together with the adjacent N constitute a N—N group; and each B is independently selected from members of the group of formula: wherein each X is independently O, S, or NRb, each Rb is independently H, NH2, hydrocarbyl, hydroxy-hydrocarbyl or aminohydrocarbyl, and each Z is independently a group of the formula wherein each of R3, R4, and n is as defined hereinabove; Ra is an ethylene group, a propylene group, which groups optionally have hydrocarbyl or hydroxyhydrocarbyl substituents, or wherein J is H, SH, NH2, or OH, and tautomers thereof; a is 0 or a number ranging from 1 to about 50, and b is a number ranging from 1 to about 30.
    • 当聚合物不是星形聚合物时,当聚合物是附着于其上的星形聚合物时,包含具有聚碳酸酯(M)} n范围为20,000至约500,000的烃聚合物的组合物,并且当聚合物是附着于其上的星形聚合物时,高达约GPC的峰值分子量为4,000,000 侧链基团Aa和Bb,其中每个A独立地选自以下组中的一个成员:糠醛的基团R 3是H或烃基,R 4是二价亚烃基,n = 0或1,R 9和R 10各自独立地 H,烷氧基烃基,羟基烃基,烃基,氨基烃基,N-烷氧基烷基或羟基烷基取代的氨基烃基,或式&Parenopenst; Y&Parenclosest; cR11-M的基团,其中每个Y独立地是下式的基团R 11是二价烃基 R 12如上述R 9和R 10所定义,M为H,烃基,氨基,酰胺基,含酰胺基,酰氨基,酰亚胺基或含酰亚胺基,c为0或 一个 数字范围从1到大约100,或者R9和R10中的一个与相邻的N一起构成N-N基团; 并且每个B独立地选自下式基团的成员:其中每个X独立地是O,S或NR b,每个R b独立地是H,NH 2,烃基,羟基 - 烃基或氨基烃基,并且每个Z独立地是 R 3,R 4和n中的每一个如上所定义; R a是亚乙基,丙烯基,其任选具有烃基或羟基烃基取代基,或其中J是H,SH,NH 2或OH及其互变异构体; a为0或1至约50的数,b为1至约30的数。
    • 9. 发明授权
    • Radial polymers prepared by stabilized free radical polymerization
    • US07034079B2
    • 2006-04-25
    • US10101672
    • 2002-03-19
    • Daniel C. VisgerRichard M. Lange
    • Daniel C. VisgerRichard M. Lange
    • C08F281/00
    • C10M145/12C08F293/005C08L53/00C10M149/06C10M149/08
    • A process for preparing a radial polymer comprising at least 3 polymeric arms and a central core comprising a polymerized di- or polyfunctional monomer, said process comprising the steps, (a) polymerizing at an elevated temperature, a charge comprising at least one free radical-polymerizable monomer to prepare a stabilized active polymer block (A) using a free radical polymerization process, wherein a stable free radical agent is employed during the polymerization, thereby preserving the stabilized active polymerization site at the terminus of the polymer; optionally (b) adding at least one additional free radical-polymerizable monomer, at least one of which is different from the monomers making up the first charge of monomers, to the stabilized active polymer block (A); and further reacting the mixture using a free radical process to effect copolymerization of said monomers, thereby preparing an A-B block copolymer having a stabilized active polymerization site at the terminus of the polymer; then (c) adding at least one coupling agent comprising a polyfunctional monomer and reacting the stabilized active polymers from (a) or (b) with a coupling agent to form a radial polymer. The present invention also relates to polymers, including block copolymers prepared by the above process, additive concentrates for preparing lubricating oil compositions and lubricating oil compositions. In other embodiments, the present invention relates to block copolymers having more than two blocks.