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    • 7. 发明授权
    • 1-Hydroxymethyl-2-acyl cyclopropane derivatives and esters and cyclic
condensation products thereof, organoleptic uses of same and processes
for preparing same
    • 1-羟甲基-2-酰基环丙烷衍生物及其酯及其环状缩合产物,其感官用途及其制备方法
    • US4536330A
    • 1985-08-20
    • US589510
    • 1984-03-14
    • Richard M. BodenMarie R. HannaTheodore J. Tyszkiewicz
    • Richard M. BodenMarie R. HannaTheodore J. Tyszkiewicz
    • A23G4/00A23G4/06A23L27/20C11D3/50C11B9/00
    • A23G4/06A23L27/203C11D3/50Y10S514/88Y10S514/881
    • Described are 1-hydroxymethyl-2-acyl cyclopropane derivatives defined according to the structure: ##STR1## wherein Z represents hydrogen, acyl having the structure: ##STR2## and substituted oxyacyl having the structure: ##STR3## and cyclic condensation products thereof having the structure: ##STR4## wherein R.sub.1, R.sub.2 and R.sub.3 represent C.sub.1 -C.sub.10 alkyl; wherein R.sub.1 ' represents C.sub.1 -C.sub.10 alkylidene and wherein R.sub.4, R.sub.5, R.sub.6 and R.sub.7 represent hydrogen or C.sub.1 -C.sub.3 lower alkyl; processes for preparing same by means of a reaction of a halomethyloxirane or substituted halomethyloxirane with a substituted 1,3-propanedione derivative; and organoleptic uses of such 1-hydroxymethyl-2-acyl cyclopropane derivatives in augmenting or enhancing the aroma or taste of perfume compositions, perfumed articles (e.g. solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, perfumed polymers, hair preparations and shampoos), colognes, foodstuffs, chewing gums, toothpastes, medicinal products and chewing tobaccos.
    • 描述的是根据以下结构定义的1-羟甲基-2-酰基环丙烷衍生物:其中Z代表氢,具有以下结构的酰基:具有以下结构的取代的氧酰基:其具有下式的环状缩合产物: 结构:其中R 1,R 2和R 3表示C 1 -C 10烷基; 其中R1'表示C1-C10亚烷基,其中R4,R5,R6和R7表示氢或C1-C3低级烷基; 通过卤代环氧丙烷或取代的卤代甲基环氧乙烷与取代的1,3-丙二酮衍生物的反应制备其的方法; 以及这种1-羟甲基-2-酰基环丙烷衍生物在增强或增强香料组合物,香料制品(例如固体或液体阴离子,阳离子,非离子或两性离子洗涤剂,织物柔软剂组合物,织物柔软剂制品)中的香味或味道的感官用途, 加香聚合物,头发制剂和洗发剂),古龙水,食品,口香糖,牙膏,药用产品和咀嚼烟草。
    • 8. 发明授权
    • 2-Alkylidenyl-3-oxabicyclo[3.1.0]hexanes
    • 2-烷基亚基-3-氧杂二环[3.1.0]己烷
    • US4570008A
    • 1986-02-11
    • US662680
    • 1984-10-19
    • Richard M. BodenMarie R. HannaTheodore J. Tyszkiewicz
    • Richard M. BodenMarie R. HannaTheodore J. Tyszkiewicz
    • A23G4/00A23G4/06A23L27/20C11D3/50C07D307/93
    • A23G4/06A23L27/203C11D3/50
    • Described are 1-hydroxymethyl-2-acyl cyclopropane derivatives defined according to the structure: ##STR1## wherein Z represents hydrogen, acyl having the structure: ##STR2## and substituted oxyacyl having the structure: ##STR3## and cyclic condensation products thereof having the structure: ##STR4## wherein R.sub.1, R.sub.2 and R.sub.3 represent C.sub.1 --C.sub.10 alkyl; wherein R.sub.1 ' represents C.sub.1 --C.sub.10 alkylidene and wherein R.sub.4, R.sub.5, R.sub.6 and R.sub.7 represent hydrogen or C.sub.1 --C.sub.3 lower alkyl; processes for preparing same by means of a reaction of a halomethyloxirane or substituted halomethyloxirane with a substituted 1,3-propanedione derivative; and organoleptic uses of such 1-hydroxymethyl-2-acyl cyclopropane derivatives in augmenting or enhancing the aroma or taste of perfume compositions, perfumed articles (e.g. solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, perfumed polymers, hair preparations and shampoos), colognes, foodstuffs, chewing gums, toothpastes, medicinal products and chewing tobaccos.
    • 描述的是根据以下结构定义的1-羟甲基-2-酰基环丙烷衍生物:其中Z代表氢,具有以下结构的酰基:具有以下结构的取代的氧酰基:其具有下式的环状缩合产物: 结构:其中R 1,R 2和R 3表示C 1 -C 10烷基; 其中R1'表示C1-C10亚烷基,其中R4,R5,R6和R7表示氢或C1-C3低级烷基; 通过卤代环氧丙烷或取代的卤代甲基环氧乙烷与取代的1,3-丙二酮衍生物的反应制备其的方法; 以及这种1-羟甲基-2-酰基环丙烷衍生物在增强或增强香料组合物,香料制品(例如固体或液体阴离子,阳离子,非离子或两性离子洗涤剂,织物柔软剂组合物,织物柔软剂制品)中的香味或味道的感官用途, 加香聚合物,头发制剂和洗发剂),古龙水,食品,口香糖,牙膏,药用产品和咀嚼烟草。
    • 9. 发明授权
    • Organoleptic uses of esters of 1-hydroxymethyl-2-acyl cylopropane
    • 感官使用1-羟甲基-2-酰基环丙烷的酯
    • US4554095A
    • 1985-11-19
    • US630693
    • 1984-07-13
    • Richard M. BodenMarie R. HannaTheodore J. Tyszkiewicz
    • Richard M. BodenMarie R. HannaTheodore J. Tyszkiewicz
    • A23G4/00A23G4/06A23L27/20C11D3/50A61K7/46
    • A23G4/06A23L27/203C11D3/50
    • Described are 1-hydroxymethyl-2-acyl cyclopropane derivatives defined according to the structure: ##STR1## wherein Z represents hydrogen, acyl having the structure: ##STR2## and substituted oxyacyl having the structure: ##STR3## and cyclic condensation products thereof having the structure: ##STR4## wherein R.sub.1, R.sub.2 and R.sub.3 represent C.sub.1 -C.sub.10 alkyl; wherein R.sub.1 ' represents C.sub.1 -C.sub.10 alkylidene and wherein R.sub.4, R.sub.5, R.sub.6 and R.sub.7 represent hydrogen or C.sub.1 -C.sub.3 lower alkyl; processes for preparing same by means of a reaction of a halomethyloxirane or substituted halomethyloxirane with a substituted 1,3-propanedione derivative; and organoleptic uses of such 1-hydroxymethyl-2-acyl cyclopropane derivatives in augmenting or enhancing the aroma or taste of perfume compositions, perfumed articles (e.g. solid or liquid anionic, cationic, nonionic or zwitterionic detergents, fabric softener compositions, fabric softener articles, perfumed polymers, hair preparations and shampoos), colognes, foodstuffs, chewing gums, toothpastes, medicinal products and chewing tobaccos.
    • 描述的是根据以下结构定义的1-羟甲基-2-酰基环丙烷衍生物:其中Z代表氢,具有以下结构的酰基:具有以下结构的取代的氧酰基:其具有下式的环状缩合产物: 结构:其中R 1,R 2和R 3表示C 1 -C 10烷基; 其中R1'表示C1-C10亚烷基,其中R4,R5,R6和R7表示氢或C1-C3低级烷基; 通过卤代环氧丙烷或取代的卤代甲基环氧乙烷与取代的1,3-丙二酮衍生物的反应制备其的方法; 以及这种1-羟甲基-2-酰基环丙烷衍生物在增强或增强香料组合物,香料制品(例如固体或液体阴离子,阳离子,非离子或两性离子洗涤剂,织物柔软剂组合物,织物柔软剂制品)中的香味或味道的感官用途, 加香聚合物,头发制剂和洗发剂),古龙水,食品,口香糖,牙膏,药用产品和咀嚼烟草。