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1. 发明授权

US4126739A Copolymers, having a uniform structure, of cyclic dienes and their use 失效
标题翻译：具有均匀结构的共聚物的环状二烯及其用途
公开(公告)号：US4126739A
公开(公告)日：1978-11-21
申请号：US853049
申请日：1977-11-21
申请人： Richard Hoene , Heinz-Hilmar Bankowsky , Eduard Hartmann , Hans-Uwe Schenck , Paul Boerzel
发明人： Richard Hoene , Heinz-Hilmar Bankowsky , Eduard Hartmann , Hans-Uwe Schenck , Paul Boerzel
IPC分类号： C08F232/00 , C09D11/106 , C08F222/00 , C08F222/08
CPC分类号： C09D11/106 , C08F232/00
摘要： Copolymers, having a uniform structure, of cyclic dienes are obtained by heating a mixture of from 35 to 96% by weight of cyclopentadiene, dicyclopentadiene and/or methyldicyclopentadiene, which may or may not be partially replaced by methylcyclopentadiene or tricyclopentadiene or methyltricyclopentadiene, from 1 to 30% by weight of maleic anhydride, maleic acid or a monoalkyl maleate, which maleic acid or maleic acid derivatives may be partially replaced by other .alpha.,.beta.-olefinically unsaturated monocarboxylic acids or dicarboxylic acids of 3 to 5 carbon atoms, and from 3 to 45% by weight of one or more vinyl-aromatics to 230.degree.-320.degree. C, during which heating the mixture does not remain at from 30.degree. to 230.degree. C for more than 5 hours, and preferably for not more than 2 hours. The copolymers may be used as binders for printing inks and coatings, and as additives in adhesives.
摘要翻译：具有均匀结构的环状二烯的共聚物通过加热35至96重量％的环戊二烯，二环戊二烯和/或甲基二环戊二烯的混合物，其可以或可以不被甲基环戊二烯或三环戊二烯或甲基三环戊二烯部分替代，从1 至30重量％的马来酸酐，马来酸或马来酸单烷基酯，马来酸或马来酸衍生物可以部分地被其他α，β-烯属不饱和单羧酸或3至5个碳原子的二羧酸部分地替代，并且3 至45重量％的一种或多种乙烯基芳族化合物至230℃-320℃，在此期间加热混合物在30℃至230℃下不保持5小时以上，优选不超过2小时。共聚物可用作印刷油墨和涂料的粘合剂，以及作为粘合剂中的添加剂。

2. 发明授权

US4164613A Manufacture of polymers in bead form from water-soluble, ethylenically unsaturated monomers 失效
标题翻译：从水溶性烯属不饱和单体制造珠粒形聚合物
公开(公告)号：US4164613A
公开(公告)日：1979-08-14
申请号：US817254
申请日：1977-07-20
申请人： Richard Hoene , Dietmar Jung , Hans-Uwe Schenck , Herbert Spoor
发明人： Richard Hoene , Dietmar Jung , Hans-Uwe Schenck , Herbert Spoor
IPC分类号： C08F2/00 , C08F2/16 , C08F2/18 , C08F2/20 , C08F2/32
CPC分类号： C08F2/32
摘要： Production of polymers in bead form by forming a water-in-oil suspension of an aqueous solution containing at least one water-soluble ethylenically unsaturated monomer in an inert hydrophobic liquid organic dispersion medium and polymerizing the suspended monomer in the presence of a polymerization initiator and a protective colloid obtained by polymerizing (A) 60 to 100% by weight of at least one monomer selected from the group consisting of cyclopentadiene, dicyclopentadiene, tricyclopentadiene and alkyl-substituted derivatives thereof, and (B) 0 to 40% by weight, based on the mixture of (A) and (B), of a mono- or diethylenically unsaturated monomer copolymerizable with (A).
摘要翻译：通过在惰性疏水性液体有机分散介质中形成含有至少一种水溶性烯键式不饱和单体的水溶液的油包水悬浮液并在聚合引发剂存在下聚合悬浮的单体和通过聚合（A）60-100重量％的至少一种选自环戊二烯，二环戊二烯，三环戊二烯及其烷基取代的衍生物的单体获得的保护胶体，和（B）0至40重量％在（A）和（B）的混合物上可与（A）共聚的单烯属不饱和单体。

3. 发明授权

US4371676A Preparation of cyclopentadiene/acetylenically unsaturated compound copolymers 失效
标题翻译：环戊二烯/炔属不饱和化合物共聚物的制备
公开(公告)号：US4371676A
公开(公告)日：1983-02-01
申请号：US251920
申请日：1981-04-07
申请人： Richard Hoene
发明人： Richard Hoene
IPC分类号： C08F232/00 , C08F238/00 , C08F38/00 , C08F36/00
CPC分类号： C08F238/00 , C08F232/00
摘要： A process for the preparation of cyclopentadiene copolymers, wherein cyclopentadiene, dicyclopentadiene, tricyclopentadiene, their C.sub.1 -C.sub.3 -alkyl derivatives or co-dimers of cyclopentadiene with a diene of 4 or 5 carbon atoms are reacted with acetylenically unsaturated compounds, with or without other copolymerizable olefinically unsaturated monomers, at from 200.degree. to 320.degree. C. The cyclopentadiene polymers prepared according to the invention may be used, for example, as resin additives for surface coatings, tackifiers in adhesives or resins for printing inks.
摘要翻译：环戊二烯，二环戊二烯，三环戊二烯，其环戊二烯与4或5个碳原子的二烯的共二聚体与炔属不饱和化合物反应制备环戊二烯共聚物的方法，具有或不具有其它可共聚的烯属不饱和单体，在200℃至320℃。根据本发明制备的环戊二烯聚合物可用作例如表面涂料的树脂添加剂，粘合剂中的增粘剂或用于印刷油墨的树脂。

4. 发明授权

US4286959A Disperse dye formulations 失效
标题翻译：分散染料配方
公开(公告)号：US4286959A
公开(公告)日：1981-09-01
申请号：US18765
申请日：1979-03-08
申请人： Dieter Horn , Ewald Daubach , Erwin Hahn , Herbert Uhrig , Richard Hoene , Herbert Naarmann
发明人： Dieter Horn , Ewald Daubach , Erwin Hahn , Herbert Uhrig , Richard Hoene , Herbert Naarmann
IPC分类号： C09B67/00 , C09B67/38 , D06P1/00 , D06P3/54 , C09B67/22
CPC分类号： D06P3/54 , C09B67/008 , C09B67/0092 , D06P1/0016
摘要： The invention seeks to provide a free-flowing formulation of one or more disperse dyes, with which packages can be dyed homogeneously by the HT process without filtering out of the dye, and which is suitable for the thermosol dyeing process. According to the invention such a formulation comprises one or more disperse dyes (a) enclosed in a matrix of one or more polymers (b) which are soluble, or colloidally soluble, both in water and in an organic solvent, in the form of a solid solution in a state of molecular dispersion or of extremely fine subdivision so that in an X-ray spectrum the dye appears amorphous.The formulations may contain additional assistants conventionally present when dyeing hydrophobic fibers. The formulations contain the disperse dye in an extremely fine state of subdivision. Because of the latter, the formulations give level package dyeings, without filtration of the dye, and very level dyeings when used by the thermofixing process.
摘要翻译：本发明寻求提供一种或多种分散染料的自由流动配方，通过该方法可以通过HT方法将包装均匀地染色，而不过滤出染料，并且适用于热溶胶染色方法。根据本发明，这种制剂包含一种或多种分散染料（a），其包封在一种或多种聚合物（b）的基质中，所述聚合物（b）在水和有机溶剂中都是可溶于或胶体可溶的，形式为在分子分散状态或极细细分的状态下的固溶体，使得在X射线光谱中，染料看起来是无定形的。当染色疏水性纤维时，制剂可以含有通常存在的其它助剂。制剂含有极细细分的分散染料。由于后者，制剂在不过滤染料的情况下给予水平的包装染色，而当用热固定方法使用时，会产生非常高的染色。

5. 发明授权

US4172102A Low-shrink unsaturated polyester molding compositions 失效
标题翻译：低收缩不饱和聚酯成型组合物
公开(公告)号：US4172102A
公开(公告)日：1979-10-23
申请号：US855871
申请日：1977-11-30
申请人： Richard Hoene , Anton Hesse , Kurt Demmler , Horst Lawonn
发明人： Richard Hoene , Anton Hesse , Kurt Demmler , Horst Lawonn
IPC分类号： C08L51/08 , C08L67/06 , C08L75/06
CPC分类号： C08L51/08 , C08L67/06
摘要： Unsaturated polyester molding compositions which contain ethylenically unsaturated polyesters, copolymerizable ethylenically unsaturated monomeric compounds and a polyalkylene ether copolymer have improved shelf life, can be cured with little shrinkage and after curing give a smooth surface with high gloss.
摘要翻译：含有烯键式不饱和聚酯，可共聚烯键式不饱和单体化合物和聚亚烷基醚共聚物的不饱和聚酯成型组合物具有改善的保质期，可以几乎收缩固化，固化后可得到高光泽的光滑表面。

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