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1. 发明授权

US5173213A Corrosion and anti-foulant composition and method of use 失效
标题翻译：腐蚀和防垢剂的组成和使用方法
公开(公告)号：US5173213A
公开(公告)日：1992-12-22
申请号：US790196
申请日：1991-11-08
申请人： Richard F. Miller , John Petersen
发明人： Richard F. Miller , John Petersen
IPC分类号： C10G70/04 , C23F11/14
CPC分类号： C23F11/14 , C10G70/048
摘要： The corrosion and fouling of metal surfaces in contact with corrosive acid fluids or acid salts in the presence of an aqueous medium is reduced by contacting the surfaces with a composition which comprises (a) an anti-fouling amount of a hydroxyl amine compound of the formulaR.sub.1 R.sub.2 N--OHwherein R.sub.1 and R.sub.2 are independently hydrogen or a hydrocarbyl or inertly substituted hydrocarbyl or both R.sub.1 and R.sub.2 are collectively a divalent hydrocarbyl combined with said nitrogen to form a heterocyclic ring, and (b) a corrosion-inhibiting amount of a reaction product of or a mixture for the purpose of a reaction product of a polyalkylene polyamine and an alkynediol. The polyalkylene polyamine is one that contains from 2-10 amine groups, each separated from another by an alkylene group having from 2-6 carbon atoms. The alkynediol has from 2 to 6 carbon atoms.
摘要翻译：在水性介质存在下，与腐蚀性酸性流体或酸式盐接触的金属表面的腐蚀和结垢通过使表面与包含（a）抗结垢量的式 R1R2N-OH其中R1和R2独立地是氢或烃基或惰性取代的烃基，或者R1和R2两者一起是与所述氮组合形成杂环的二价烃基，和（b）腐蚀抑制量的反应产物的聚亚烷基多胺和炔二醇的反应产物的混合物。聚亚烷基多胺是含有2-10个胺基的聚亚烷基多胺，各自由具有2-6个碳原子的亚烷基彼此分开。炔二醇具有2至6个碳原子。

2. 发明授权

US4806028A Bearing race keeper ring retention sleeve 失效
标题翻译：轴承座圈保持套筒
公开(公告)号：US4806028A
公开(公告)日：1989-02-21
申请号：US208694
申请日：1988-06-20
申请人： Richard F. Miller , David A. Foster
发明人： Richard F. Miller , David A. Foster
IPC分类号： F16C35/063 , F16D1/072 , F16C43/04
CPC分类号： F16D1/072 , F16C35/063 , F16C19/186
摘要： A self crimping retention sleeve is slipped over the end of a bearing shaft and closely over a pair of race piece keeper rings and deformed radially inwardly into a shaft retention groove by the application of an axial force inwardly on the sleeve, allowing the sleeve to be installed with very limited radial access.
摘要翻译：自动压接保持套筒在轴承轴的端部滑动并且靠近一对座圈保持环，并且通过在套筒上向内施加轴向力而径向向内变形成轴保持槽，允许套筒为安装非常有限的径向通道。

3. 发明授权

US4726811A Hydrocarbon oils with improved pour points 失效
标题翻译：具有改善倾点的烃油
公开(公告)号：US4726811A
公开(公告)日：1988-02-23
申请号：US832396
申请日：1986-02-24
申请人： Richard F. Miller
发明人： Richard F. Miller
IPC分类号： C08F210/02 , C10L1/197 , C10L1/26
CPC分类号： C10L1/1973 , C08F210/02
摘要： Hydrocarbon oils containing, as a pour point depressant, a terpolymer of a vinyl ester having a total of 4 to 8 carbon atoms, vinyl alcohol and ethylene, the copolymer having a weight average molecular weight of about 1,000 to 100,000.
摘要翻译：含有作为倾点下降剂的含碳原子数为4〜8的乙烯基酯的三元共聚物的烃油为乙烯醇和乙烯，所述共聚物的重均分子量为约1,000〜100,000。

4. 发明授权

US4611073A Preparation of higher silicon carboxylates in improved yields using an inert gas 失效
标题翻译：使用惰性气体制备较高硅羧酸盐，产率提高
公开(公告)号：US4611073A
公开(公告)日：1986-09-09
申请号：US814127
申请日：1985-12-27
申请人： Richard F. Miller , Marilyn W. Blaschke
发明人： Richard F. Miller , Marilyn W. Blaschke
IPC分类号： C07F7/02
CPC分类号： C07F7/025
摘要： Silicon tetracarboxylates of higher acids are prepared by contacting silicon tetracarboxylates of lower fatty acids with higher fatty acids at a temperature sufficiently high to vaporize the lower fatty acid by-product. The reaction may be carried out in the presence of an inert gas, if desired.
摘要翻译：通过在足够高的温度下将低级脂肪酸的四羧酸四羧酸与高级脂肪酸接触以蒸发低级脂肪酸副产物来制备高级酸的四羧酸硅。如果需要，反应可以在惰性气体存在下进行。

5. 发明授权

US4510041A Method for minimizing fouling of heat exchanger 失效
标题翻译：减少热交换器结垢的方法
公开(公告)号：US4510041A
公开(公告)日：1985-04-09
申请号：US639893
申请日：1984-08-10
申请人： Richard F. Miller , Michael P. Nicholson
发明人： Richard F. Miller , Michael P. Nicholson
IPC分类号： C10G9/16
CPC分类号： C10G9/16 , Y10S585/95
摘要： Hydrocarbon processing equipment is protected against fouling during the processing of hydrocarbons at elevated temperatures by adding to the equipment small amounts of at least one N,N'-dimer of phenothiazine or a substituted phenothiazine and at least one mono- or ditertiary alkylphenol.
摘要翻译：通过向设备中加入少量的至少一种吩噻嗪的N，N'-二聚体或取代的吩噻嗪和至少一种一价或二价烷基苯酚，在加氢烃期间保护烃加工设备免受结垢。

6. 发明授权

US4495105A Preparation of higher tin carboxylates in improved yields using an inert gas 失效
标题翻译：使用惰性气体以更高的产率制备较高的羧酸锡
公开(公告)号：US4495105A
公开(公告)日：1985-01-22
申请号：US473836
申请日：1983-03-09
申请人： Richard F. Miller
发明人： Richard F. Miller
IPC分类号： C07C51/41 , C07F7/22 , C10G11/04
CPC分类号： C10G11/04 , C07C51/412 , C07F7/2244
摘要： Tin carboxylates of higher carboxylic acids can be prepared in high yields by:(a) reacting either stannous oxide with an anhydride of a lower organic acid,(b) reacting the product from (a) with at least one higher carboxylic acid, and(c) recovering the tin carboxylate of said higher carboxylic acid.
摘要翻译：可以通过以下方式以高产率制备高级羧酸的羧酸锡：（a）使氧化亚锡与低级有机酸的酸酐反应，（b）将来自（a）的产物与至少一种较高级羧酸和（ c）回收所述较高级羧酸的羧酸锡。

7. 发明授权

US4488997A Method for the preparation of higher antimony tricarboxylates 失效
标题翻译：制备较高锑三羧酸盐的方法
公开(公告)号：US4488997A
公开(公告)日：1984-12-18
申请号：US412409
申请日：1982-08-27
申请人： Richard F. Miller , John Link
发明人： Richard F. Miller , John Link
IPC分类号： C07C51/41 , C11C1/00
CPC分类号： C07C51/412
摘要： Antimony tricarboxylates of higher carboxylic acids can be prepared by(a) reacting antimony oxide with an anhydride of a lower organic acid,(b) reacting the product from (a) with at least one higher carboxylic acid at a temperature sufficient to vaporize volatile material and removing said volatile material, and(c) recovering the antimony tricarboxylate of said higher carboxylic acid.
摘要翻译：高级羧酸的三羧酸锑可以通过（a）使氧化锑与较低有机酸的酸酐反应来制备，（b）使得产物（a）与至少一种较高级羧酸在足以蒸发挥发性物质的温度下反应并除去所述挥发性物质，和（c）回收所述较高级羧酸的三羧酸锑。

8. 发明授权

US08026198B2 Shale hydration inhibition agent(s) and method of use 有权
标题翻译：页岩水化抑制剂及其使用方法
公开(公告)号：US08026198B2
公开(公告)日：2011-09-27
申请号：US12411709
申请日：2009-03-26
申请人： Richard F. Miller
发明人： Richard F. Miller
IPC分类号： C09K8/54 , C09K8/32 , C09K8/28 , C09K8/02 , C09K8/06 , C09K8/60 , C09K8/00 , E21B21/00
CPC分类号： C09K8/22 , C09K2208/12
摘要： A water-based drilling fluid and method of using same are presented in this disclosure, which fluid is used in drilling wells through a formation containing a shale that swells in the presence of water. The drilling fluid comprises an aqueous based continuous phase; a weighting material; and a shale hydration inhibition agent (SHIA) selected from the group consisting of propylamine derivatives, hydrogenated poly(propyleneimine) dendrimers (HPPID), and polyamine twin dendrimers (PTD). In some embodiments, the SHIA of this disclosure is not hydrolyzed at a temperature in the range of from about 100° F. to about 500° F. The drilling fluid may further comprise a fluid loss control agent, an encapsulating agent, other additives, and combinations thereof. A method of reducing shale swelling during wellbore drilling is also described. The method comprises circulating in the subterranean well a water-based drilling fluid comprising an aqueous based continuous phase, a weighting material, and a SHIA.
摘要翻译：在本公开内容中提出了一种水基钻井液及其使用方法，该流体通过含有在水存在下膨胀的页岩的地层在钻井中使用。钻井液包含基于水的连续相; 称重材料和选自丙胺衍生物，氢化聚（丙烯亚胺）树枝状大分子（HPPID）和聚胺双树枝状大分子（PTD））的页岩水合抑制剂（SHIA）。在一些实施方案中，本公开的SHIA在约100°F至约500°F的温度范围内不水解。钻井液还可包含流体损失控制剂，包封剂，其它添加剂，及其组合。还描述了在井眼钻井期间减少页岩膨胀的方法。该方法包括在地下井中循环包含水基连续相，加权材料和SHIA的水基钻井液。

9. 发明申请

US20090247429A1 SHALE HYDRATION INHIBITION AGENT(S) AND METHOD OF USE 有权
标题翻译： SHALE HYDR抑制剂（S）及其使用方法
公开(公告)号：US20090247429A1
公开(公告)日：2009-10-01
申请号：US12411709
申请日：2009-03-26
申请人： Richard F. Miller
发明人： Richard F. Miller
IPC分类号： C09K8/06
CPC分类号： C09K8/22 , C09K2208/12
摘要： A water-based drilling fluid and method of using same are presented in this disclosure, which fluid is used in drilling wells through a formation containing a shale that swells in the presence of water. The drilling fluid comprises an aqueous based continuous phase; a weighting material; and a shale hydration inhibition agent (SHIA) selected from the group consisting of propylamine derivatives, hydrogenated poly(propyleneimine) dendrimers (HPPID), and polyamine twin dendrimers (PTD). In some embodiments, the SHIA of this disclosure is not hydrolyzed at a temperature in the range of from about 100° F. to about 500° F. The drilling fluid may further comprise a fluid loss control agent, an encapsulating agent, other additives, and combinations thereof. A method of reducing shale swelling during wellbore drilling is also described. The method comprises circulating in the subterranean well a water-based drilling fluid comprising an aqueous based continuous phase, a weighting material, and a SHIA.
摘要翻译：在本公开内容中提出了一种水基钻井液及其使用方法，该流体通过含有在水存在下膨胀的页岩的地层在钻井中使用。钻井液包含基于水的连续相; 称重材料和选自丙胺衍生物，氢化聚（丙烯亚胺）树枝状大分子（HPPID）和聚胺双树枝状大分子（PTD））的页岩水合抑制剂（SHIA）。在一些实施方案中，本公开的SHIA在约100°F至约500°F的温度范围内不水解。钻井液还可包含流体损失控制剂，包封剂，其它添加剂，及其组合。还描述了在井眼钻井期间减少页岩膨胀的方法。该方法包括在地下井中循环包含水基连续相，加权材料和SHIA的水基钻井液。

10. 发明授权

US4781748A Aqueous nitrogenous fertilizer solutions having reduced corrosivity 失效
标题翻译：具有降低腐蚀性的含水氮肥溶液
公开(公告)号：US4781748A
公开(公告)日：1988-11-01
申请号：US919955
申请日：1986-10-17
申请人： Richard F. Miller , Marilyn W. Blaschke
发明人： Richard F. Miller , Marilyn W. Blaschke
IPC分类号： C05G3/00 , C23F11/14 , C05G1/02
CPC分类号： C05G3/0076 , C23F11/147 , Y10S71/904
摘要： The corrosive effects of liquid nitrogen-based fertilizer compositions on metal surfaces is reduced by adding to the fertilizer compositions small amounts of amine oxides.
摘要翻译：通过向肥料组合物中添加少量的氧化胺来减少液氮基肥料组合物对金属表面的腐蚀作用。

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