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1. 发明授权

US07204970B2 Single-wall carbon nanotubes from high pressure CO 有权
标题翻译：单壁碳纳米管由高压CO
公开(公告)号：US07204970B2
公开(公告)日：2007-04-17
申请号：US10730630
申请日：2003-12-08
申请人： Richard E. Smalley , Ken A. Smith , Daniel T. Colbert , Pavel Nikolaev , Michael J. Bronikowski , Robert K. Bradley , Frank Rohmund
发明人： Richard E. Smalley , Ken A. Smith , Daniel T. Colbert , Pavel Nikolaev , Michael J. Bronikowski , Robert K. Bradley , Frank Rohmund
IPC分类号： C01B11/02
CPC分类号： B01J4/002 , B01J3/04 , B01J3/042 , B01J19/121 , B01J19/26 , B01J2219/0875 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , C01B2202/36 , D01F9/1278 , Y10S977/75 , Y10S977/751 , Y10S977/843 , Y10S977/845 , Y10S977/951 , Y10T428/30
摘要： The present invention discloses the process of supplying high pressure (e.g., 30 atmospheres) CO that has been preheated (e.g., to about 1000° C.) and a catalyst precursor gas (e.g., Fe(CO)5) in CO that is kept below the catalyst precursor decomposition temperature to a mixing zone. In this mixing zone, the catalyst precursor is rapidly heated to a temperature that results in (1) precursor decomposition, (2) formation of active catalyst metal atom clusters of the appropriate size, and (3) favorable growth of SWNTs on the catalyst clusters. Preferably a catalyst cluster nucleation agency is employed to enable rapid reaction of the catalyst precursor gas to form many small, active catalyst particles instead of a few large, inactive ones. Such nucleation agencies can include auxiliary metal precursors that cluster more rapidly than the primary catalyst, or through provision of additional energy inputs (e.g., from a pulsed or CW laser) directed precisely at the region where cluster formation is desired. Under these conditions SWNTs nucleate and grow according to the Boudouard reaction. The SWNTs thus formed may be recovered directly or passed through a growth and annealing zone maintained at an elevated temperature (e.g., 1000° C.) in which tubes may continue to grow and coalesce into ropes.
摘要翻译：本发明公开了提供已被预热（例如，约1000℃）的高压（例如30个大气压）的CO和催化剂前体气体（例如Fe（CO）5） >）在CO中，其保持低于催化剂前体分解温度至混合区。在该混合区中，将催化剂前体快速加热到导致（1）前体分解的温度，（2）形成适当尺寸的活性催化剂金属原子簇，和（3）在催化剂簇上的SWNT的有利生长。优选使用催化剂簇成核剂来使催化剂前体气体快速反应以形成许多小的活性催化剂颗粒，而不是几个大的非活性催化剂颗粒。这样的成核机构可以包括比主要催化剂更快地聚集的辅助金属前体，或者通过提供精确地指向需要簇形成的区域的额外的能量输入（例如来自脉冲或CW激光）。在这些条件下，SWNT根据Boudouard反应成核并生长。如此形成的SWNT可以直接回收或通过保持在高温（例如1000℃）的生长和退火区域，其中管可以继续生长并聚结成绳索。

2. 发明授权

US06761870B1 Gas-phase nucleation and growth of single-wall carbon nanotubes from high pressure CO 有权
标题翻译：单壁碳纳米管从高压CO气相成核和生长
公开(公告)号：US06761870B1
公开(公告)日：2004-07-13
申请号：US09830642
申请日：2002-07-01
申请人： Richard E. Smalley , Ken A. Smith , Daniel T. Colbert , Pavel Nikolaev , Michael J. Bronikowski , Robert K. Bradley , Frank Rohmund
发明人： Richard E. Smalley , Ken A. Smith , Daniel T. Colbert , Pavel Nikolaev , Michael J. Bronikowski , Robert K. Bradley , Frank Rohmund
IPC分类号： D01F912
CPC分类号： B01J4/002 , B01J3/04 , B01J3/042 , B01J19/121 , B01J19/26 , B01J2219/0875 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , C01B2202/36 , D01F9/1278 , Y10S977/75 , Y10S977/751 , Y10S977/843 , Y10S977/845 , Y10S977/951 , Y10T428/30
摘要： The present invention discloses the process of supplying high pressure (e.g., 30 atmospheres) CO that has been preheated (e.g., to about 1000° C.) and a catalyst precursor gas (e.g., Fe(CO)5) in CO that is kept below the catalyst precursor decomposition temperature to a mixing zone. In this mixing zone, the catalyst precursor is rapidly heated to a temperature that results in (1) precursor decomposition, (2) formation of active catalyst metal atom clusters of the appropriate size, and (3) favorable growth of SWNTs on the catalyst clusters. Preferably a catalyst cluster nucleation agency is employed to enable rapid reaction of the catalyst precursor gas to form many small, active catalyst particles instead of a few large, inactive ones. Such nucleation agencies can include auxiliary metal precursors that cluster more rapidly than the primary catalyst, or through provision of additional energy inputs (e.g., from a pulsed or CW laser) directed precisely at the region where cluster formation is desired. Under these conditions SWNTs nucleate and grow according to the Boudouard reaction. The SWNTs thus formed may be recovered directly or passed through a growth and annealing zone maintained at an elevated temperature (e.g., 1000° C.) in which tubes may continue to grow and coalesce into ropes.
摘要翻译：本发明公开了在被保留的CO中提供已被预热（例如，约1000℃）的高压（例如，30个大气压）的CO和催化剂前体气体（例如，Fe（CO）5）的过程。催化剂前体分解温度低于混合区。在该混合区中，将催化剂前体快速加热到导致（1）前体分解的温度，（2）形成适当尺寸的活性催化剂金属原子簇，和（3）在催化剂簇上的SWNT的有利生长。优选使用催化剂簇成核剂来使催化剂前体气体快速反应以形成许多小的活性催化剂颗粒，而不是几个大的非活性催化剂颗粒。这样的成核机构可以包括比主要催化剂更快地聚集的辅助金属前体，或者通过提供精确地指向需要簇形成的区域的额外的能量输入（例如来自脉冲或CW激光）。在这些条件下，SWNT根据Boudouard反应成核并生长。如此形成的SWNT可以直接回收或通过保持在高温（例如1000℃）的生长和退火区域，其中管可以继续生长并聚结成绳索。

3. 发明申请

US20090169463A1 ARRAY OF FULLERENE NANOTUBES 失效
标题翻译： FULLERENE NANOTUBES的阵列
公开(公告)号：US20090169463A1
公开(公告)日：2009-07-02
申请号：US11507964
申请日：2006-08-22
申请人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Kenneth A. Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
发明人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Kenneth A. Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
IPC分类号： C01B31/00
CPC分类号： G11C13/025 , B01J19/081 , B01J19/087 , B01J19/10 , B01J19/121 , B01J19/126 , B01J19/129 , B01J21/185 , B01J23/74 , B01J23/755 , B01J23/8913 , B01J37/0238 , B01J37/349 , B01J2219/00078 , B01J2219/0892 , B82B3/00 , C01B32/152 , C01B32/162 , C01B32/17 , C01B2202/02 , D01F9/12 , D01F9/127 , D21H27/00 , G11B9/1418 , G11B9/1445 , G11B9/1472 , G11B9/149 , G11C13/0014 , G11C13/0019 , G11C2213/16 , G11C2213/71 , G11C2213/81 , H01G9/2059 , H01L31/0352 , H01L31/06 , H01L31/18 , H01M4/133 , H01M4/525 , H01M4/583 , H01M4/587 , H01M4/625 , H01M10/0525 , Y02E10/542 , Y02E60/122 , Y02P70/521 , Y02P70/54 , Y10S977/70 , Y10S977/742 , Y10S977/745 , Y10S977/748 , Y10S977/75 , Y10S977/753 , Y10S977/789 , Y10S977/842 , Y10S977/843 , Y10S977/845 , Y10S977/847 , Y10S977/848 , Y10S977/849 , Y10S977/882 , Y10S977/948 , Y10T428/24058 , Y10T428/2918 , Y10T428/292 , Y10T428/30
摘要： This invention relates generally to forming an array of fullerene nanotubes. In one embodiment, a macroscopic molecular array is provided comprising at least about 106 fullerene nanotubes in generally parallel orientation and having substantially similar lengths in the range of from about 5 to about 500 nanometers.
摘要翻译：本发明一般涉及形成富勒烯纳米管阵列。在一个实施方案中，提供了宏观分子阵列，其包括大致平行取向的至少约106个富勒烯纳米管，并且具有在约5至约500纳米范围内的基本相似的长度。

4. 发明授权

US07419624B1 Methods for producing composites of fullerene nanotubes and compositions thereof 有权
标题翻译：富勒烯纳米管复合材料的制备方法及其组成
公开(公告)号：US07419624B1
公开(公告)日：2008-09-02
申请号：US11507974
申请日：2006-08-22
申请人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Ken Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
发明人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Ken Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
IPC分类号： B82B1/00
CPC分类号： G11C13/025 , B01J19/081 , B01J19/087 , B01J19/10 , B01J19/121 , B01J19/126 , B01J19/129 , B01J21/185 , B01J23/74 , B01J23/755 , B01J23/8913 , B01J37/0238 , B01J37/349 , B01J2219/00078 , B01J2219/0892 , B82B3/00 , C01B32/152 , C01B32/162 , C01B32/17 , C01B2202/02 , D01F9/12 , D01F9/127 , D21H27/00 , G11B9/1418 , G11B9/1445 , G11B9/1472 , G11B9/149 , G11C13/0014 , G11C13/0019 , G11C2213/16 , G11C2213/71 , G11C2213/81 , H01G9/2059 , H01L31/0352 , H01L31/06 , H01L31/18 , H01M4/133 , H01M4/525 , H01M4/583 , H01M4/587 , H01M4/625 , H01M10/0525 , Y02E10/542 , Y02E60/122 , Y02P70/521 , Y02P70/54 , Y10S977/70 , Y10S977/742 , Y10S977/745 , Y10S977/748 , Y10S977/75 , Y10S977/753 , Y10S977/789 , Y10S977/842 , Y10S977/843 , Y10S977/845 , Y10S977/847 , Y10S977/848 , Y10S977/849 , Y10S977/882 , Y10S977/948 , Y10T428/24058 , Y10T428/2918 , Y10T428/292 , Y10T428/30
摘要： This invention relates generally to a method for producing composites of fullerene nanotubes and compositions thereof. In one embodiment, the present invention involves a method of producing a composite material that includes a matrix and a fullerene nanotube material embedded within said matrix. In another embodiment, a method of producing a composite material containing fullerene nanotube material is disclosed. This method includes the steps of preparing an assembly of a fibrous material; adding the fullerene nanotube material to the fibrous material; and adding a matrix material precursor to the fullerene nanotube material and the fibrous material.
摘要翻译：本发明一般涉及富勒烯纳米管复合材料的制造方法及其组合物。在一个实施方案中，本发明涉及一种生产复合材料的方法，所述复合材料包括嵌入所述基质内的基质和富勒烯纳米管材料。在另一个实施方案中，公开了一种制备含有富勒烯纳米管材料的复合材料的方法。该方法包括准备纤维材料组件的步骤; 将富勒烯纳米管材料添加到纤维材料中; 并向所述富勒烯纳米管材料和所述纤维材料添加基质材料前体。

5. 发明授权

US07338915B1 Ropes of single-wall carbon nanotubes and compositions thereof 失效
标题翻译：单壁碳纳米管的绳索及其组成
公开(公告)号：US07338915B1
公开(公告)日：2008-03-04
申请号：US09722950
申请日：2000-11-27
申请人： Richard E. Smalley , Daniel T. Colbert , Ting Guo , Andrew G. Rinzler , Pavel Nikolaev , Andreas Thess
发明人： Richard E. Smalley , Daniel T. Colbert , Ting Guo , Andrew G. Rinzler , Pavel Nikolaev , Andreas Thess
IPC分类号： C01B31/00
CPC分类号： B82Y30/00 , B82Y15/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , C01B2202/22 , C01B2202/36 , Y02P20/134 , Y10S428/903 , Y10S977/742 , Y10S977/743 , Y10S977/75 , Y10S977/751 , Y10S977/842 , Y10S977/844 , Y10S977/938 , Y10T428/2913 , Y10T442/50 , Y10T442/624
摘要： This invention provides a method of making single-wall carbon nanotubes by laser vaporizing a mixture of carbon and one or more Group VIII transition metals. Single-wall carbon nanotubes preferentially form in the vapor and the one or more Group VIII transition metals catalyzed growth of the single-wall carbon nanotubes. In one embodiment of the invention, one or more single-wall carbon nanotubes are fixed in a high temperature zone so that the one or more Group VIII transition metals catalyze further growth of the single-wall carbon nanotube that is maintained in the high temperature zone. In another embodiment, two separate laser pulses are utilized with the second pulse timed to be absorbed by the vapor created by the first pulse.
摘要翻译：本发明提供了一种通过激发汽化碳和一种或多种第八族过渡金属的混合物来制备单壁碳纳米管的方法。单壁碳纳米管优先在蒸气中形成，并且一个或多个VIII族过渡金属催化单壁碳纳米管的生长。在本发明的一个实施方案中，一个或多个单壁碳纳米管固定在高温区域中，使得一种或多种第VIII族过渡金属催化保持在高温区域中的单壁碳纳米管的进一步生长。在另一个实施例中，利用两个单独的激光脉冲，第二脉冲定时被第一脉冲产生的蒸气吸收。

6. 发明授权

US07108841B2 Method for forming a patterned array of single-wall carbon nanotubes 有权
标题翻译：用于形成单壁碳纳米管的图案化阵列的方法
公开(公告)号：US07108841B2
公开(公告)日：2006-09-19
申请号：US10033092
申请日：2001-12-28
申请人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Ken Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
发明人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Ken Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
IPC分类号： D01F9/12
CPC分类号： G11C13/025 , B01J19/081 , B01J19/087 , B01J19/10 , B01J19/121 , B01J19/126 , B01J19/129 , B01J21/185 , B01J23/74 , B01J23/755 , B01J23/8913 , B01J37/0238 , B01J37/349 , B01J2219/00078 , B01J2219/0892 , B82B3/00 , C01B32/152 , C01B32/162 , C01B32/17 , C01B2202/02 , D01F9/12 , D01F9/127 , D21H27/00 , G11B9/1418 , G11B9/1445 , G11B9/1472 , G11B9/149 , G11C13/0014 , G11C13/0019 , G11C2213/16 , G11C2213/71 , G11C2213/81 , H01G9/2059 , H01L31/0352 , H01L31/06 , H01L31/18 , H01M4/133 , H01M4/525 , H01M4/583 , H01M4/587 , H01M4/625 , H01M10/0525 , Y02E10/542 , Y02E60/122 , Y02P70/521 , Y02P70/54 , Y10S977/70 , Y10S977/742 , Y10S977/745 , Y10S977/748 , Y10S977/75 , Y10S977/753 , Y10S977/789 , Y10S977/842 , Y10S977/843 , Y10S977/845 , Y10S977/847 , Y10S977/848 , Y10S977/849 , Y10S977/882 , Y10S977/948 , Y10T428/24058 , Y10T428/2918 , Y10T428/292 , Y10T428/30
摘要： This invention relates generally to forming a patterned array of single-wall carbon nanotubes (SWNT). In one embodiment, a nanoscale array of microwells is provided on a substrate; a metal catalyst is deposited in each microwells; and a stream of hydrocarbon or CO feedstock gas is directed at the substrate under conditions that effect growth of single-wall carbon nanotubes from each microwell.
摘要翻译：本发明一般涉及形成单壁碳纳米管（SWNT）的图案化阵列。在一个实施例中，在衬底上提供纳米尺寸的微孔阵列; 在每个微孔中沉积金属催化剂; 并且在从每个微孔产生单壁碳纳米管的生长的条件下，烃或CO原料气流被引导到基底。

7. 发明授权

US06979709B2 Continuous fiber of single-wall carbon nanotubes 失效
标题翻译：单壁碳纳米管连续纤维
公开(公告)号：US06979709B2
公开(公告)日：2005-12-27
申请号：US10033076
申请日：2001-12-28
申请人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Kenneth A. Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
发明人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Kenneth A. Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
IPC分类号： B01J8/06 , B01J19/08 , B01J19/10 , B01J19/12 , B01L7/00 , B82B3/00 , C01B31/02 , D01F9/12 , D01F9/127 , G01Q70/06 , G01Q70/12 , G11B9/00 , G11C13/02 , H01G9/20 , H01L31/0352 , H01L31/06 , H01L31/18 , H01M4/133 , H01M4/52 , H01M4/525 , H01M4/58 , H01M4/583 , H01M4/587 , H01M4/62 , H01M10/0525 , H01M10/36
CPC分类号： G11C13/025 , B01J19/081 , B01J19/087 , B01J19/10 , B01J19/121 , B01J19/126 , B01J19/129 , B01J21/185 , B01J23/74 , B01J23/755 , B01J23/8913 , B01J37/0238 , B01J37/349 , B01J2219/00078 , B01J2219/0892 , B82B3/00 , C01B32/152 , C01B32/162 , C01B32/17 , C01B2202/02 , D01F9/12 , D01F9/127 , D21H27/00 , G11B9/1418 , G11B9/1445 , G11B9/1472 , G11B9/149 , G11C13/0014 , G11C13/0019 , G11C2213/16 , G11C2213/71 , G11C2213/81 , H01G9/2059 , H01L31/0352 , H01L31/06 , H01L31/18 , H01M4/133 , H01M4/525 , H01M4/583 , H01M4/587 , H01M4/625 , H01M10/0525 , Y02E10/542 , Y02E60/122 , Y02P70/521 , Y02P70/54 , Y10S977/70 , Y10S977/742 , Y10S977/745 , Y10S977/748 , Y10S977/75 , Y10S977/753 , Y10S977/789 , Y10S977/842 , Y10S977/843 , Y10S977/845 , Y10S977/847 , Y10S977/848 , Y10S977/849 , Y10S977/882 , Y10S977/948 , Y10T428/24058 , Y10T428/2918 , Y10T428/292 , Y10T428/30
摘要： This invention relates generally to carbon fiber produced from single-wall carbon nanotube (SWNT) molecular arrays. In one embodiment, the present invention involves a macroscopic carbon fiber comprising at least 106 signal-wall carbon nanotubes in generally parallel orientation.
摘要翻译：本发明一般涉及由单壁碳纳米管（SWNT）分子阵列产生的碳纤维。在一个实施方案中，本发明涉及包含大致平行取向的至少10 6个信号壁碳纳米管的宏观碳纤维。

8. 发明授权

US06969504B2 Electrical conductors comprising single-wall carbon nanotubes 失效
标题翻译：电导体包括单壁碳纳米管
公开(公告)号：US06969504B2
公开(公告)日：2005-11-29
申请号：US10426781
申请日：2003-04-30
申请人： Richard E. Smalley , Daniel T. Colbert , Ting Guo , Andrew G. Rinzler , Pavel Nikolaev , Andreas Thess
发明人： Richard E. Smalley , Daniel T. Colbert , Ting Guo , Andrew G. Rinzler , Pavel Nikolaev , Andreas Thess
IPC分类号： C01B31/02 , D01F9/12
CPC分类号： B82Y30/00 , B82Y15/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , C01B2202/22 , C01B2202/36 , Y02P20/134 , Y10S428/903 , Y10S977/742 , Y10S977/743 , Y10S977/75 , Y10S977/751 , Y10S977/842 , Y10S977/844 , Y10S977/938 , Y10T428/2913 , Y10T442/50 , Y10T442/624
摘要： The present invention concerns electrical conductors comprising armchair single-wall carbon nanotubes. Such electrical conductors made by the invention are metallic, i.e., they will conduct electrical charges with a relatively low resistance. The amount of armchair single-wall carbon nanotubes in the electrical conductor can be greater than 10%, greater than 30%, greater than 50%, greater than 75%, and greater than 90%, of the single-wall carbon nanotubes in the electrical conductor.
摘要翻译：本发明涉及包括扶手椅单壁碳纳米管的电导体。由本发明制造的这种电导体是金属的，即它们将以相对较低的电阻进行电荷。电导体中的扶手椅单壁碳纳米管的量可以大于单壁碳纳米管的10％，大于30％，大于50％，大于75％和大于90％的单壁碳纳米管电导体。

9. 发明授权

US07655302B2 Continuous fiber of fullerene nanotubes 失效
标题翻译：富勒烯纳米管的连续纤维
公开(公告)号：US07655302B2
公开(公告)日：2010-02-02
申请号：US11508111
申请日：2006-08-22
申请人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Ken Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
发明人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Ken Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
IPC分类号： D01F9/12
CPC分类号： G11C13/025 , B01J19/081 , B01J19/087 , B01J19/10 , B01J19/121 , B01J19/126 , B01J19/129 , B01J21/185 , B01J23/74 , B01J23/755 , B01J23/8913 , B01J37/0238 , B01J37/349 , B01J2219/00078 , B01J2219/0892 , B82B3/00 , C01B32/152 , C01B32/162 , C01B32/17 , C01B2202/02 , D01F9/12 , D01F9/127 , D21H27/00 , G11B9/1418 , G11B9/1445 , G11B9/1472 , G11B9/149 , G11C13/0014 , G11C13/0019 , G11C2213/16 , G11C2213/71 , G11C2213/81 , H01G9/2059 , H01L31/0352 , H01L31/06 , H01L31/18 , H01M4/133 , H01M4/525 , H01M4/583 , H01M4/587 , H01M4/625 , H01M10/0525 , Y02E10/542 , Y02E60/122 , Y02P70/521 , Y02P70/54 , Y10S977/70 , Y10S977/742 , Y10S977/745 , Y10S977/748 , Y10S977/75 , Y10S977/753 , Y10S977/789 , Y10S977/842 , Y10S977/843 , Y10S977/845 , Y10S977/847 , Y10S977/848 , Y10S977/849 , Y10S977/882 , Y10S977/948 , Y10T428/24058 , Y10T428/2918 , Y10T428/292 , Y10T428/30
摘要： This invention relates generally to carbon fiber produced from fullerene nanotube arrays. In one embodiment, the present invention involves a macroscopic carbon fiber comprising at least 106 fullerene nanotubes in generally parallel orientation.
摘要翻译：本发明一般涉及由富勒烯纳米管阵列产生的碳纤维。在一个实施方案中，本发明涉及包含大致平行取向的至少106个富勒烯纳米管的宏观碳纤维。

10. 发明授权

US07390767B2 Method for producing a catalyst support and compositions thereof 有权
标题翻译：催化剂载体的制备方法及其组合物
公开(公告)号：US07390767B2
公开(公告)日：2008-06-24
申请号：US11507973
申请日：2006-08-22
申请人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Ken Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
发明人： Richard E. Smalley , Daniel T. Colbert , Hongjie Dai , Jie Liu , Andrew G. Rinzler , Jason H. Hafner , Ken Smith , Ting Guo , Pavel Nikolaev , Andreas Thess
IPC分类号： B82B3/00
CPC分类号： G11C13/025 , B01J19/081 , B01J19/087 , B01J19/10 , B01J19/121 , B01J19/126 , B01J19/129 , B01J21/185 , B01J23/74 , B01J23/755 , B01J23/8913 , B01J37/0238 , B01J37/349 , B01J2219/00078 , B01J2219/0892 , B82B3/00 , C01B32/152 , C01B32/162 , C01B32/17 , C01B2202/02 , D01F9/12 , D01F9/127 , D21H27/00 , G11B9/1418 , G11B9/1445 , G11B9/1472 , G11B9/149 , G11C13/0014 , G11C13/0019 , G11C2213/16 , G11C2213/71 , G11C2213/81 , H01G9/2059 , H01L31/0352 , H01L31/06 , H01L31/18 , H01M4/133 , H01M4/525 , H01M4/583 , H01M4/587 , H01M4/625 , H01M10/0525 , Y02E10/542 , Y02E60/122 , Y02P70/521 , Y02P70/54 , Y10S977/70 , Y10S977/742 , Y10S977/745 , Y10S977/748 , Y10S977/75 , Y10S977/753 , Y10S977/789 , Y10S977/842 , Y10S977/843 , Y10S977/845 , Y10S977/847 , Y10S977/848 , Y10S977/849 , Y10S977/882 , Y10S977/948 , Y10T428/24058 , Y10T428/2918 , Y10T428/292 , Y10T428/30
摘要： This invention relates generally to a method for producing fullerene nanotube catalyst supports and compositions thereof. In one embodiment, fullerene nanotubes or fullerene nanotube structures can be employed as the support material. A transition metal catalyst is added to the fullerene nanotubes. In a preferred embodiment, the catalyst metal cluster is deposited on the open nanotube end by a docking process that insures optimum location for the subsequent growth reaction. The metal atoms may be subjected to reductive conditions.
摘要翻译：本发明一般涉及富勒烯纳米管催化剂载体及其组合物的制备方法。在一个实施方案中，可以使用富勒烯纳米管或富勒烯纳米管结构作为载体材料。向富勒烯纳米管中加入过渡金属催化剂。在优选的实施方案中，通过对接工艺将催化剂金属簇沉积在开放的纳米管末端上，确保最终的位置用于随后的生长反应。金属原子可以经历还原条件。

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