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1. 发明授权

US06835366B1 Chemical derivatization of single-wall carbon nanotubes to facilitate solvation thereof, and use of derivatized nanotubes 失效
标题翻译：单壁碳纳米管的化学衍生化以促进其溶剂化，以及衍生的纳米管的使用
公开(公告)号：US06835366B1
公开(公告)日：2004-12-28
申请号：US09787473
申请日：2001-03-16
申请人： John L. Margrave , Edward T. Mickelson , Robert Hauge , Peter Boul , Chad Huffman , Jie Liu , Richard E. Smalley , Ken Smith , Daniel T. Colbert
发明人： John L. Margrave , Edward T. Mickelson , Robert Hauge , Peter Boul , Chad Huffman , Jie Liu , Richard E. Smalley , Ken Smith , Daniel T. Colbert
IPC分类号： D01F912
CPC分类号： B01J21/18 , B01J23/74 , B01J23/755 , B01J35/006 , B01J35/06 , B82Y30/00 , B82Y40/00 , C01B32/174 , C01B2202/02 , C01B2202/06 , D01F11/121 , Y10S977/74 , Y10S977/748 , Y10S977/75 , Y10S977/843 , Y10S977/848
摘要： This invention is directed to making chemical derivatives of carbon nanotubes and to uses for the derivatized nanotubes, including making arrays as a basis for synthesis of carbon fibers. In one embodiment, this invention also provides a method for preparing single wall carbon nanotubes having substituents attached to the side wall of the nanotube by reacting single wall carbon nanotubes with fluorine gas and recovering fluorine derivatized carbon nanotubes, then reacting fluorine derivatized carbon nanotubes with a nucleophile. Some of the fluorine substituents are replaced by nucleophilic substitution. If desired, the remaining fluorine can be completely or partially eliminated to produce single wall carbon nanotubes having substituents attached to the side wall of the nanotube. The substituents will, of course, be dependent on the nucleophile, and preferred nucleophiles include alkyl lithium species such as methyl lithium. Alternatively, fluorine may be fully or partially removed from fluorine derivatized carbon nanotubes by reacting the fluorine derivatized carbon nanotubes with various amounts of hydrazine, substituted hydrazine or alkyl amine. The present invention also provides seed materials for growth of single wall carbon nanotubes comprising a plurality of single wall carbon nanotubes or short tubular molecules having a catalyst precursor moiety covalently bound or physisorbed on the outer surface of the sidewall to provide the optimum metal cluster size under conditions that result in migration of the metal moiety to the tube end.
摘要翻译：本发明涉及制备碳纳米管的化学衍生物和衍生纳米管的用途，包括制备阵列作为碳纤维合成的基础。在一个实施方案中，本发明还提供了通过使单壁碳纳米管与氟气反应并回收氟衍生的碳纳米管，制备具有连接到纳米管侧壁上的取代基的单壁碳纳米管的方法，然后使氟衍生的碳纳米管与亲核试剂一些氟取代基被亲核取代取代。如果需要，可以完全或部分地除去剩余的氟以产生具有连接到纳米管的侧壁上的取代基的单壁碳纳米管。取代基当然取决于亲核试剂，优选的亲核试剂包括烷基锂物质如甲基锂。或者，可以通过使氟衍生的碳纳米管与各种量的肼，取代的肼或烷基胺反应，从氟衍生的碳纳米管中完全或部分地除去氟。本发明还提供用于生长单壁碳纳米管的种子材料，其包含多个单壁碳纳米管或具有在侧壁的外表面上共价结合或物理吸附的催化剂前体部分的短管状分子，以提供最佳金属簇尺寸导致金属部分迁移到管端的条件。

2. 发明授权

US06827919B1 Process for producing single wall nanotubes using unsupported metal catalysts and single wall nanotubes produced according to this method 失效
标题翻译：使用未负载的金属催化剂和根据该方法生产的单壁纳米管制备单壁纳米管的方法
公开(公告)号：US06827919B1
公开(公告)日：2004-12-07
申请号：US09607126
申请日：2000-06-29
申请人： David Moy , Asif Chishti
发明人： David Moy , Asif Chishti
IPC分类号： D01F912
CPC分类号： B82Y30/00 , B01J3/04 , B01J3/042 , B01J19/121 , B01J19/26 , B01J2219/0875 , B82Y40/00 , C01B32/162 , C01B2202/02 , D01F9/127 , D01F9/1278 , Y10S977/742 , Y10S977/75 , Y10S977/842 , Y10S977/843 , Y10S977/896
摘要： A process for producing hollow, single-walled carbon nanotubes by catalytic decomposition of one or more gaseous carbon compounds by first forming a gas phase mixture carbon feed stock gas comprising one or more gaseous carbon compounds, each having one to six carbon atoms and only H, O, N, S or Cl as hetero atoms, optionally admixed with hydrogen, and a gas phase metal containing compound which is unstable under reaction conditions for said decomposition, and which forms a metal containing catalyst which acts as a decomposition catalyst under reaction conditions; and then conducting said decomposition reaction under decomposition reaction conditions, thereby producing said nanotubes.
摘要翻译：一种通过一种或多种气态碳化合物的催化分解来制备中空单壁碳纳米管的方法，首先形成一种气相混合物碳原料气体，其包含一种或多种具有1-6个碳原子的气态碳化合物，并且仅H ，O，N，S或Cl作为杂原子，任选与氢混合，以及含有气相金属的化合物，在用于所述分解的反应条件下不稳定，并且在反应条件下形成用作分解催化剂的含金属催化剂 ; 然后在分解反应条件下进行所述分解反应，从而制备所述纳米管。

3. 发明授权

US06787229B1 Three-dimensional carbon fibers and method and apparatus for their production 失效
标题翻译：三维碳纤维及其生产方法和装置
公开(公告)号：US06787229B1
公开(公告)日：2004-09-07
申请号：US10338436
申请日：2003-01-08
申请人： Nazim Z. Muradov
发明人： Nazim Z. Muradov
IPC分类号： D01F912
CPC分类号： B82Y30/00 , D01F9/1271 , Y10T428/2918 , Y10T428/30
摘要： This invention relates to novel three-dimensional (3D) carbon fibers which are original (or primary) carbon fibers (OCF) with secondary carbon filaments (SCF) grown thereon, and, if desired, tertiary carbon filaments (TCF) are grown from the surface of SCF forming a filamentous carbon network with high surface area. The methods and apparatus are provided for growing SCF on the OCF by thermal decomposition of carbonaceous gases (CG) over the hot surface of the OCF without use of metal-based catalysts. The thickness and length of SCF can be controlled by varying operational conditions of the process, e.g., the nature of CG, temperature, residence time, etc. The optional activation step enables one to produce 3D activated carbon fibers with high surface area. The method and apparatus are provided for growing TCF on the SCF by thermal decomposition of carbonaceous gases over the hot surface of the SCF using metal catalyst particles.
摘要翻译：本发明涉及新生成的三维（3D）碳纤维，它们是在其上生长的具有次碳纤维（SCF）的原始（或初级）碳纤维（OCF），如果需要，叔碳纤维（TCF）从 SCF的表面形成具有高表面积的丝状碳网络。提供了通过在OCF的热表面上热分解碳质气体（CG）而不使用金属基催化剂在OCF上生长SCF的方法和装置。 SCF的厚度和长度可以通过改变工艺的操作条件来控制，例如CG的性质，温度，停留时间等。可选择的活化步骤使得能够生产具有高表面积的3D活性炭纤维。提供的方法和装置用于通过使用金属催化剂颗粒在SCF的热表面上热分解碳质气体来在SCF上生长TCF。

4. 发明授权

US06787122B2 Method of making nanotube-based material with enhanced electron field emission properties 有权
标题翻译：制备具有增强的电子场发射特性的纳米管基材料的方法
公开(公告)号：US06787122B2
公开(公告)日：2004-09-07
申请号：US09881684
申请日：2001-06-18
申请人： Otto Z. Zhou
发明人： Otto Z. Zhou
IPC分类号： D01F912
CPC分类号： B82Y10/00 , C30B29/605 , C30B33/00 , H01J9/025 , H01J2201/30469 , Y10S977/742 , Y10S977/842
摘要： A method of reducing electronic work function, reducing threshold field emission values, converting semiconducting behavior to metallic behavior, increasing the electron density state at the Fermi level, and increasing electron emission site density, of nanostructure or nanotube-containing material, the method including: forming openings in the nanotube-containing material; introducing a foreign species such as an alkali metal into at least some of the openings; and closing the openings, thereby forming capsules filled with the foreign species, and forming field emission cathode and flat panel displays using these capsules.
摘要翻译：一种减少电子功函数，降低阈值场发射值，将半导体行为转换为金属行为，增加费米能级电子密度状态，增加纳米结构或含纳米管材料的电子发射位点密度的方法，该方法包括：在含纳米管的材料中形成开口; 将诸如碱金属的外来物质引入到至少一些开口中; 并关闭开口，从而形成填充有异物的胶囊，并使用这些胶囊形成场发射阴极和平板显示器。

5. 发明授权

US06749712B2 Method of utilizing sol-gel processing in the production of a macroscopic two or three dimensionally ordered array of single wall nonotubes (SWNTs) 失效
标题翻译：在制备单壁纳米管（SWNT）的宏观二维或三维有序阵列中使用溶胶 - 凝胶加工的方法
公开(公告)号：US06749712B2
公开(公告)日：2004-06-15
申请号：US09938287
申请日：2001-08-23
申请人： Cynthia A. Kuper
发明人： Cynthia A. Kuper
IPC分类号： D01F912
CPC分类号： D01F11/14 , B82Y30/00 , B82Y40/00 , C01B32/168 , C01B32/174 , C01B2202/02 , C01B2202/08 , Y10S977/75 , Y10S977/848
摘要： A method for fabricating of macroscopic two or three dimensionally ordered arrays of single wall nanotubes (SWNTs) comprising the following steps: chemically treating purified SWNTs using the sol gel process to add chemically reactive groups to either the tube ends or tube bodies in order to functionalize the SWNTs; suspending the functionalized SWNTs in an appropriate liquid medium such that a colloid is produced; treating the colloid with a chemical or heat to promote coupling of the individual functionalized SWNTs to each other; and heating the coupled SWNTs to evaporate any excess liquid so as to provide a final product comprising an array of covalently bound functionalized SWNTs.
摘要翻译：一种用于制造单壁纳米管（SWNT）的宏观二维或三维有序阵列的方法，包括以下步骤：使用溶胶凝胶法将纯化的单壁碳纳米管化学处理，以将化学反应性基团添加到管末端或管体中以便官能化 SWNTs; 将官能化的SWNT悬浮在合适的液体介质中，使得产生胶体; 用化学或热处理胶体促进各个功能化的单壁碳纳米管彼此的耦合; 并加热耦合的SWNT以蒸发任何多余的液体，以便提供包含共价结合的官能化SWNT阵列的最终产物。

6. 发明授权

US06432536B1 Articles comprising highly crystalline graphite and method for their preparation 失效
标题翻译：包含高结晶石墨的制品及其制备方法
公开(公告)号：US06432536B1
公开(公告)日：2002-08-13
申请号：US08455057
申请日：1995-05-31
申请人： Daniel H. Hecht , David A. Schulz
发明人： Daniel H. Hecht , David A. Schulz
IPC分类号： D01F912
CPC分类号： C04B35/83 , C04B2235/5252 , C04B2235/5268 , C04B2235/614 , C04B2235/77 , C04B2235/96 , C04B2235/9607 , Y10T428/30
摘要： Self-reinforcing, pitch-based carbon articles having an unique combination of excellent thermal conductivity and outstanding mechanical properties are produced by carbonizing acid-treated mesophase pitch fiber, preferably in the form of a preform structure The carbon articles having varying degrees of porosity are particularly desirable for use in thermal management and stiffness applications, and in carbon vapor infiltration processes employed in making complex solid carbon articles.
摘要翻译：通过将酸处理的中间相沥青纤维碳化，优选以预成型结构的形式，生产具有优异导热性和优异机械性能的独特组合的自增强沥青基碳制品具有不同孔隙率的碳制品特别是适用于热管理和刚度应用，以及用于制备复杂固体碳制品的碳蒸汽渗透方法。

7. 发明授权

US06428892B2 Carbon fibers, acrylic fibers and process for producing the acrylic fibers 有权
标题翻译：碳纤维，丙烯酸纤维和生产丙烯酸纤维的方法
公开(公告)号：US06428892B2
公开(公告)日：2002-08-06
申请号：US09761310
申请日：2001-01-17
申请人： Yoji Matsuhisa , Makoto Kibayashi , Katsumi Yamasaki , Akira Okuda
发明人： Yoji Matsuhisa , Makoto Kibayashi , Katsumi Yamasaki , Akira Okuda
IPC分类号： D01F912
CPC分类号： D01F9/22 , D01F6/18 , D01F11/14 , Y10T428/2913 , Y10T428/2918 , Y10T428/292 , Y10T428/2964 , Y10T428/2967 , Y10T428/30
摘要： Disclosed are carbon fibers consisting of a plurality of single filaments, wherein the carbon fibers as a resin impregnated strand are characterized by satisfying the following relations: &sgr;≧11.1−0.75 d where &sgr; is the tensile strength of said carbon fibers as a resin impregnated strand in GPa, and d is the average diameter of said single filaments in &mgr;m, and RD≦0.05 where RD is the difference in crystallinity between the inner and outer layers of each of the single filaments evaluated with RAMAN, and an acrylic fibers for producing the carbon fibers and a process for producing the acrylic fibers.
摘要翻译：公开了由多根单丝组成的碳纤维，其中作为树脂浸渍线的碳纤维的特征在于满足以下关系：σ= 11.1-0.75d，其中σ是作为浸渍树脂的所述碳纤维的拉伸强度 GPa中的单丝的平均直径，d是所述单丝的平均直径，RD <= 0.05，其中RD是用拉曼评估的每个单丝的内层和外层之间的结晶度差异，以及用于生产碳纤维和生产丙烯酸纤维的方法。

8. 发明授权

US06372192B1 Carbon fiber manufacturing via plasma technology 失效
标题翻译：通过等离子体技术制造碳纤维
公开(公告)号：US06372192B1
公开(公告)日：2002-04-16
申请号：US09493474
申请日：2000-01-28
申请人： Felix L. Paulauskas , Kenneth D. Yarborough , Thomas T. Meek
发明人： Felix L. Paulauskas , Kenneth D. Yarborough , Thomas T. Meek
IPC分类号： D01F912
CPC分类号： D01F9/22 , D01F9/12 , D01F9/145 , D01F9/16
摘要： The disclosed invention introduces a novel method of manufacturing carbon and/or graphite fibers that avoids the high costs associated with conventional carbonization processes. The method of the present invention avoids these costs by utilizing plasma technology in connection with electromagnetic radiation to produce carbon and/or graphite fibers from fully or partially stabilized carbon fiber precursors. In general, the stabilized or partially stabilized carbon fiber precursors are placed under slight tension, in an oxygen-free atmosphere, and carbonized using a plasma and electromagnetic radiation having a power input which is increased as the fibers become more carbonized and progress towards a final carbon or graphite product. In an additional step, the final carbon or graphite product may be surface treated with an oxygen-plasma treatment to enhance adhesion to matrix materials.
摘要翻译：所公开的发明引入了制造碳和/或石墨纤维的新方法，其避免了与常规碳化方法相关的高成本。本发明的方法通过利用与电磁辐射相关的等离子体技术从完全或部分稳定的碳纤维前体产生碳和/或石墨纤维来避免这些成本。通常，将稳定的或部分稳定化的碳纤维前体放置在无氧气氛中的轻微张力下，并且使用等离子体和电磁辐射进行碳化，其具有随着纤维变得更加碳化而进一步向功率输入增加的功率输入碳或石墨产品。在另外的步骤中，最终的碳或石墨产品可以用氧等离子体处理进行表面处理，以增强与基体材料的粘合性。

9. 发明授权

US06790426B1 Carbonaceous nanotube, nanotube aggregate, method for manufacturing a carbonaceous nanotube 有权
标题翻译：碳纳米管，纳米管集合体，碳质纳米管的制造方法
公开(公告)号：US06790426B1
公开(公告)日：2004-09-14
申请号：US09615104
申请日：2000-07-13
申请人： Takashi Ohsaki
发明人： Takashi Ohsaki
IPC分类号： D01F912
CPC分类号： B82Y30/00 , B82Y40/00 , C01B32/16 , C01B32/162 , C01B2202/22 , C01B2202/36 , D01F9/127 , Y10S977/742
摘要： A carbonaceous nanotube has a hollow part with an inner diameter of, at most, 5 nm, and a thickness part of, at most, 10 nm. The thickness part is formed of carbon atoms and hydrogen atoms, optionally containing at least one transition metal atom. Such a carbonaceous nanotube has excellent conductivity and excellent wettability.
摘要翻译：碳质纳米管具有内径为至多5nm的中空部分，并且厚度部分至多为10nm。厚度部分由碳原子和氢原子形成，任选地含有至少一个过渡金属原子。这种碳纳米管具有优异的导电性和优异的润湿性。

10. 发明授权

US06783746B1 Preparation of stable nanotube dispersions in liquids 有权
标题翻译：在液体中制备稳定的纳米管分散体
公开(公告)号：US06783746B1
公开(公告)日：2004-08-31
申请号：US10021767
申请日：2001-12-12
申请人： Zhiqiang Zhang , Frances E. Lockwood
发明人： Zhiqiang Zhang , Frances E. Lockwood
IPC分类号： D01F912
CPC分类号： D01F9/127 , B82Y30/00 , Y10S977/787 , Y10S977/842
摘要： The introduction of nanotubes in a liquid provides a means for changing the physical and/or chemical properties of the liquid. Improvements in heat transfer, electrical properties, viscosity, and lubricity can be realized upon dispersion of nanotubes in liquids; however, nanotubes behave like hydrophobic particles and tend to clump together in liquids. Methods of preparing stable dispersions of nanotubes are described and surfactants/dispersants are identified which can disperse carbon nanotubes in aqueous and petroleum liquid medium. The appropriate dispersant is chosen for the carbon nanotube and the water or oil based medium and the dispersant is dissolved into the liquid medium to form a solution. The carbon nanotube is added to the dispersant containing the solution with agitation, ultrasonication, and/or combinations thereof.
摘要翻译：在液体中引入纳米管提供了改变液体的物理和/或化学性质的手段。可以在将纳米管分散在液体中时实现热传递，电性能，粘度和润滑性的改善; 然而，纳米管表现为疏水性颗粒，并且倾向于在液体中聚集在一起。描述了制备稳定的纳米管分散体的方法，并鉴定了能够将碳纳米管分散在含水和石油液体介质中的表面活性剂/分散剂。选择合适的分散剂用于碳纳米管和水或油基介质，并将分散剂溶解在液体介质中以形成溶液。在搅拌，超声波处理和/或其组合下将碳纳米管加入含有该溶液的分散剂中。

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