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1. 发明申请

WO2007019370A2 HYDROPHILIZED FIBER SUBSTRATE AND METHOD FOR HYDROPHILIZING A HYDROPHOBIC SURFACE OF A FIBER SUBSTRATE 审中-公开
标题翻译：亲水性纤维基材和使亲水性疏水表面亲水化的方法
公开(公告)号：WO2007019370A2
公开(公告)日：2007-02-15
申请号：PCT/US2006/030573
申请日：2006-08-04
申请人： RHODIA INC.
发明人： TALINGTING-PABALAN, Ruela , OTTER, Graham , WOODWARD, Gary
IPC分类号： B32B21/02
CPC分类号： D06M15/667 , A61F13/51121 , A61F2013/530299 , A61L15/60 , D06M13/285 , D06M2101/20
摘要： A hydrophilized fiber, comprising a fiber having a hydrophobic surface and a phosphinate compound according to formula (I), wherein A is an organic group comprising one or more monomeric units derived from an ethylenically unsaturated monomer or an organic group according to formula (II), A1 is an organic group according to formula (III), B, R 4 , and R 10 are each independently methylene or poly(methylene), which may optionally be substituted on one or more of such methylene units, and which may optionally be interrupted at one or more positions by an oxygen atom, R 1 , R 2 , R 3 , R 5 , R 6 , R 7 ,R 8 , R 9 , R 11 , R 12 , and R 13 are each independently H, alkyl, alkoxyl, cycloalkyl, alkenyl, aryl, aralkyl, alkaryl or heterocyclyl, m, n, and n1 are each independently O or an integer of from 1 to about 100, provided that m cannot be O if n' is O, q and s are each independently 0 or an integer of from 1 to about 50, and p, r, and r1 are each independently an integer of from 1 to about 20, or a salt thereof, disposed on at least a portion of such hydrophobic surface in an amount effective to increase the hydrophilicity of such portion of such hydrophobic surface is useful as a component of a hydrophilized fabric and a disposable absorbent article.
摘要翻译：亲水化纤维，其包含具有疏水性表面的纤维和式（I）的次膦酸酯化合物，其中A是包含一个或多个衍生自烯属不饱和单体的单体单元或根据式（II）的有机基团，A 1是根据式（III）的有机基团，B，R 4和R 10各自独立地为亚甲基或聚（亚甲基），其可以任选地在一个或多个这种亚甲基单元上被取代，并且其可以任选地在一个或多个位置被氧原子，R 1，R 2， R 3，R 5，R 6，R 7，R 8，R 8，R 8， R 9，R 11，R 12和R 13各自独立地为H，烷基，环烷基，环烷基，烷氧基，环烷基，烯基，芳基，芳烷基，烷芳基或杂环基，m，n和n1各自独立地为0或1至约100的整数，条件是如果n'为O，q和m不能为0 s各自独立地为0或1至约50的整数，且p，r和r1各自独立地为1至约20的整数，或其盐，置于该疏水表面的至少一部分上有效增加此类疏水表面的这种部分的亲水性的量可用作亲水化织物和一次性吸收制品的组分。

2. 发明申请

WO2009123732A2 DEMULSIFIERS AND METHODS FOR USE IN PHARMACEUTICAL APPLICATIONS 审中-公开
标题翻译：用于药物应用的破乳剂和方法
公开(公告)号：WO2009123732A2
公开(公告)日：2009-10-08
申请号：PCT/US2009/002056
申请日：2009-04-02
申请人： RHODIA INC. , TALINGTING-PABALAN, Ruela , DAHANAYAKE, Manilal, S. , WOODWARD, Gary , ADAM, Herve
发明人： TALINGTING-PABALAN, Ruela , DAHANAYAKE, Manilal, S. , WOODWARD, Gary , ADAM, Herve
IPC分类号： B01D17/05
CPC分类号： A61K9/107 , A61K47/10 , A61K47/20 , B01D17/047
摘要： Demulsifiers containing an anionic surfactant selected from alkylsulfosuccinates, alkylsufonates, alkylphosphonic acids, and their salts; a nonionic surfactant selected from ethylene oxide/propylene oxide copolymers, ethoxylated fatty acids of polyethylene glycol, terpene alkoxylates, and modified alkanolamides; or a combination of an anionic and a nonionic surfactant, and methods of use thereof in breaking emulsions.
摘要翻译：含有选自烷基磺基琥珀酸盐，烷基磺酸盐，烷基膦酸及其盐的阴离子表面活性剂的破乳剂; 选自环氧乙烷/环氧丙烷共聚物，聚乙二醇的乙氧基化脂肪酸，萜烯烷氧基化物和改性链烷醇酰胺的非离子表面活性剂; 或阴离子和非离子表面活性剂的组合，以及它们在破乳中的使用方法。

3. 发明申请

WO2009029062A1 PROCESS FOR MAKING A PLANT GROWTH REGULATOR 审中-公开
标题翻译：制造植物生长调节剂的方法
公开(公告)号：WO2009029062A1
公开(公告)日：2009-03-05
申请号：PCT/US2007/018758
申请日：2007-08-24
申请人： RHODIA INC.
发明人： PALMER, Francine , ELLIS, James , HORN, James , ANDERSON, Eugene, J. , SHAMBLEE, Dwight, A. , WOODWARD, Gary
IPC分类号： C05B11/10 , C05B1/00 , A01N57/18
CPC分类号： A01N57/20 , C05B15/00 , C05F11/10 , A01N2300/00
摘要： A method for making a plant growth regulator includes the step of reacting vinyl chloride with a phosphorous reagent.
摘要翻译：制备植物生长调节剂的方法包括使氯乙烯与磷试剂反应的步骤。

4. 发明申请

WO2008073233A2 SCALE SQUEEZE TREATMENT SYSTEMS AND METHODS 审中-公开
标题翻译：规模化处理系统和方法
公开(公告)号：WO2008073233A2
公开(公告)日：2008-06-19
申请号：PCT/US2007/024689
申请日：2007-11-30
申请人： RHODIA INC.
发明人： DE CAMPO, Floryan , COLACO, Allwyn , LANGLOIS, Bruno , JONES, Chris , WOODWARD, Gary
IPC分类号： C09K8/54
CPC分类号： C09K8/528
摘要： An aqueous composition for treating hydrocarbon wells contains (a) a scale inhibitor and (b) a viscoelastic surfactant, and further contains from 0 to less than1 % by weight of acid selected from the group consisting of hydrochloric acid, sulfuric acid, phosphoric acid, formic acid, acetic acid, citric acid, maleic acid, hydrofluoric acid, and mixtures thereof.
摘要翻译：用于处理烃井的含水组合物包含（a）防垢剂和（b）粘弹性表面活性剂，并且还含有0至小于1重量％的选自盐酸，硫酸，磷酸，甲酸，乙酸，柠檬酸，马来酸，氢氟酸及其混合物。

5. 发明申请

WO2008051584A3 PROCESS FOR THE PREPARATION OF HIGHLY PURIFIED, DIALKYDITHIOPHOSPHINIC COMPOUNDS 审中-公开
公开(公告)号：WO2008051584A3
公开(公告)日：2008-05-02
申请号：PCT/US2007/022591
申请日：2007-10-25
申请人： RHODIA INC.
发明人： LIU, Leo, Zhaoqing , WOODWARD, Gary
IPC分类号： C07F9/22
摘要： An improved process for production of dialkyldithiophosphinic acid including sulfurizing a purified dialkylphosphinic acid by: reacting a hypophosphorous acid or salt with a stoichiometric excess of an alpha olefin in the presence of a free radical initiator to form a reaction product comprising monoalkylphosphinic acid and dialkylphosphinic acid; adding sufficient aqueous base to the reaction product to i) form the salts of the phosphinic acids, and ii) establish an aqueous phase and an organic phase, wherein a monoalkylphosphinic acid solubilizes into an aqueous phase; separating the organic phase from the aqueous phase; acidifying the organic phase and removing the olefin from the organic phase; isolating the purified dialkylphosphinic acid product; and sulfurizing the purified dialkylphosphinic acid product to form a dialkydithiophosphinic acid. The present invention also provides a process for preparing purified dialkylthiophosphinic chloride, and a process for preparing purified dialkylmonothiophosphinic acids.

6. 发明申请

WO2010019172A1 DEMULSIFIERS IN SOLVENT BASE FOR SEPARATING EMULSIONS AND METHODS OF USE 审中-公开
标题翻译：用于分离乳液的溶剂基中的分解剂和使用方法
公开(公告)号：WO2010019172A1
公开(公告)日：2010-02-18
申请号：PCT/US2009/000062
申请日：2009-01-07
申请人： RHODIA INC. , TALINGTING-PABALAN, Ruela , WOODWARD, Gary , DAHANAYAKE, Manilal, S. , ADAM, Herve
发明人： TALINGTING-PABALAN, Ruela , WOODWARD, Gary , DAHANAYAKE, Manilal, S. , ADAM, Herve
IPC分类号： C09K3/00
CPC分类号： B01D17/047
摘要： Demulsifiers containing an anionic surfactant selected from alkylsulfosuccinates, alkylphosphonic acids, and their salts; a nonionic surfactant selected from ethylene oxide/propylene oxide copolymers, ethoxylated fatty acids of polyethylene glycol, terpene alkoxylates, and modified alkanolamides; and solvent bases comprising blends of dibasic esters. Methods for breaking emulsions using such demulsifiers and solvent bases are also disclosed.
摘要翻译：含有选自烷基磺基琥珀酸盐，烷基膦酸及其盐的阴离子表面活性剂的破乳剂; 选自环氧乙烷/环氧丙烷共聚物，聚乙二醇的乙氧基化脂肪酸，萜烯烷氧基化物和改性链烷醇酰胺的非离子表面活性剂; 和包含二元酯共混物的溶剂基料。还公开了使用这种破乳剂和溶剂基来破乳的方法。

7. 发明申请

WO2009023724A2 METHOD FOR SEPARATING CRUDE OIL EMULSIONS 审中-公开
标题翻译：分离原油乳液的方法
公开(公告)号：WO2009023724A2
公开(公告)日：2009-02-19
申请号：PCT/US2008/073035
申请日：2008-08-13
申请人： RHODIA, INC. , TALINGTING-PABALAN, Ruela , WOODWARD, Gary , DAHANAYAKE, Manilal , ADAM, Herve
发明人： TALINGTING-PABALAN, Ruela , WOODWARD, Gary , DAHANAYAKE, Manilal , ADAM, Herve
IPC分类号： B01D17/04
CPC分类号： B01D17/047
摘要： A method for breaking an emulsion of oil and water comprising contacting the emulsion with a demulsifier comprising a terpene alkoxylate is disclosed.
摘要翻译：公开了一种破坏油和水的乳液的方法，包括使乳液与包含萜烯烷氧基化物的破乳剂接触。

8. 发明申请

WO2008140729A1 POLYSACCHARIDE BASED SCALE INHIBITOR 审中-公开
标题翻译：基于多糖的鳞片抑制剂
公开(公告)号：WO2008140729A1
公开(公告)日：2008-11-20
申请号：PCT/US2008/005885
申请日：2008-05-08
申请人： RHODIA INC.
发明人： DECAMPO, Floryan , KESAVAN, Subramanian , WOODWARD, Gary
IPC分类号： C09K8/54
CPC分类号： C07H3/00 , C02F5/10 , C02F2103/08 , C02F2103/10 , C08B37/0096 , C08L5/00 , C09K8/528
摘要： A depolymerized-carboxyalkyl polysaccharide formed by de polymerizing a polysaccharide having from 0.5 to 3.0 degrees of substitution and reducing the molecular weight of said polysaccharide before or after said depolymerizing provides a biodegradable scale inhibitor useful to prevent deposition of scale comprising, for example, calcium, barium, sulfate and salts thereof. The depolymerized carboxyalkyl polysaccharide is particularly useful in off shore oil production squeeze treatments and in the treatment of scale formed in industrial water treatment.
摘要翻译：通过使具有0.5至3.0度取代度并在所述解聚之前或之后降低所述多糖的分子量的多糖形成的解聚羧基烷基多糖提供了可用于防止沉积包含例如钙，钡，硫酸盐及其盐。解聚的羧基烷基多糖特别可用于离岸油生产挤压处理和在工业水处理中形成的垢中的处理。

9. 发明申请

WO2007017647A1 IMPROVED AMINOPHOSPHINATE CO-POLYMER 审中-公开
标题翻译：改进的氨基磷酸酯共聚物
公开(公告)号：WO2007017647A1
公开(公告)日：2007-02-15
申请号：PCT/GB2006/002920
申请日：2006-08-04
申请人： RHODIA INC. , WOODWARD, Gary , OTTER, Graham , ZAFAR, Shazia , BENDEJACQ, Denis , ANTHONY, Olivier
发明人： WOODWARD, Gary , OTTER, Graham , ZAFAR, Shazia , BENDEJACQ, Denis , ANTHONY, Olivier
IPC分类号： C08G79/04
CPC分类号： C08G79/02 , C08G79/04 , C08K5/5313 , C08L53/00 , C11D3/3784 , C08L2666/02
摘要： The present invention relates to a co-polymer or oligomer thereof, of the formula (I) wherein: -R and R' are each independently selected from hydrogen, a hydroxyl group, a carboxyl group, an alkyl, aryl or alkaryl group or a hydroxy - or carboxy - substituted alkyl, aryl or alkaryl group, provided that R and R' together have a total of less than 23 carbon atoms; -X is hydrogen or a cation or an alkyl group; - n and n', identical or different, are greater than or equal to 0; - each of R y groups, which may be the same or different, and each of the R x groups, which may be the same or different, is hydrogen, an optionally substituted alkyl, cycloalkyl, alkenyl, aryl, aralkyl, alkaryl or alkoxyalkyl group of 1 -20 carbon atoms each of which may be optionally substituted once or more than once; - R z is an alkane group or a substituted alkane group or a heterocyclic group; - m and m', identical or different, are zero or from 1 to 100; - p is zero or from 1 to 100; and - each of the R v groups, which may be the same or different, is hydrogen, an optionally substituted alkyl, cycloalkyl, alkenyl, aryl, aralkyl, alkaryl or alkoxyalkyl group of 1 -20 carbon atoms each of which may be optionally substituted once or more than once.
摘要翻译：本发明涉及式（I）的共聚物或低聚物，其中：-R和R'各自独立地选自氢，羟基，羧基，烷基，芳基或烷芳基或羟基或羧基取代的烷基，芳基或烷芳基，条件是R和R'总共具有少于23个碳原子; -X是氢或阳离子或烷基; - n和n'相同或不同，大于或等于0; 每个R y可以相同或不同，R x可以相同或不同的每一个可以是氢，任选地取代的烷基，环烷基，烯基，芳基，芳烷基，烷芳基或1〜20个碳原子的烷氧基烷基，其中每个可以任选被一次或多于一次取代; R z是烷烃基或取代的烷烃基或杂环基; - m和m'相同或不同，为零或1至100; - p为零或1至100; 和 - 可以相同或不同的每一个R 12是氢，1-20个碳原子的任选取代的烷基，环烷基，烯基，芳基，芳烷基，烷芳基或烷氧基烷基其中每一个可以任选地被一次或多于一次地取代。

10. 发明授权

EP2084168B1 PROCESS FOR THE PREPARATION OF HIGHLY PURIFIED, DIALKYDITHIOPHOSPHINIC COMPOUNDS 有权
标题翻译：制备高纯度，二烷基二硫代磷杂环化合物的方法
公开(公告)号：EP2084168B1
公开(公告)日：2012-06-27
申请号：EP07861503.6
申请日：2007-10-25
申请人： Rhodia, Inc.
发明人： LIU, Leo Zhaoqing , WOODWARD, Gary
IPC分类号： C07F9/34 , C07F9/30
CPC分类号： C07F9/34 , C07F9/301
摘要： An improved process for production of dialkyldithiophosphinic acid including sulfurizing a purified dialkylphosphinic acid by: reacting a hypophosphorous acid or salt with a stoichiometric excess of an alpha olefin in the presence of a free radical initiator to form a reaction product comprising monoalkylphosphinic acid and dialkylphosphinic acid; adding sufficient aqueous base to the reaction product to i) form the salts of the phosphinic acids, and ii) establish an aqueous phase and an organic phase, wherein a monoalkylphosphinic acid solubilizes into an aqueous phase; separating the organic phase from the aqueous phase; acidifying the organic phase and removing the olefin from the organic phase; isolating the purified dialkylphosphinic acid product; and sulfurizing the purified dialkylphosphinic acid product to form a dialkydithiophosphinic acid. The present invention also provides a process for preparing purified dialkylthiophosphinic chloride, and a process for preparing purified dialkylmonothiophosphinic acids.
摘要翻译：一种改进的生产二烷基二硫代次膦酸的方法，包括：将硫化的二烷基次膦酸硫化，方法是：使次磷酸或盐与化学计量过量的α-烯烃在自由基引发剂存在下反应，形成包含单烷基次膦酸和二烷基次膦酸的反应产物; 向反应产物中加入足够的碱水溶液以i）形成次膦酸的盐，和ii）建立水相和有机相，其中单烷基次膦酸溶解到水相中; 将有机相与水相分离; 酸化有机相并从有机相中除去烯烃; 分离纯化的二烷基次膦酸产物; 并且将纯化的二烷基次膦酸产物硫化以形成二烷基二硫代次膦酸。本发明还提供了制备纯化的二烷基硫代亚膦酰氯的方法，以及制备纯化的二烷基单硫代亚膦酸的方法。

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