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1. 发明申请

US20090203931A1 Coloured Silsesquioxanes 失效
标题翻译：彩色倍半硅氧烷
公开(公告)号：US20090203931A1
公开(公告)日：2009-08-13
申请号：US12308044
申请日：2007-06-08
申请人： Reinhold Ohrlein , Gabriele Baisch
发明人： Reinhold Ohrlein , Gabriele Baisch
IPC分类号： C07F7/10
CPC分类号： C08G77/045 , C07F7/21 , C08G77/38 , C08G77/388 , C09B69/008
摘要： The invention relates tp dye-functionalized silsesquioxane clusters, a process for their manufacture and their use as colorants, wherein the compounds (functionalized clusters or nano-particles) are characterized by the general formula (I) wherein CAGE is a moiety of the formula (IA) D is a chromophoric moiety, and the other symbols have the meanings as defined in the specification, or salts thereof.
摘要翻译：本发明涉及tp染料官能化的倍半硅氧烷簇，其制备方法及其作为着色剂的用途，其中化合物（官能团或纳米颗粒）由通式（I）表征，其中CAGE是式 IA）D是发色部分，其它符号具有本说明书中定义的含义，或其盐。

2. 发明申请

US20080125601A1 PROCESS FOR THE PREPARATION OF 7-AMINO SYN 3,5-DIHYDROXY HEPTANOIC ACID DERIVATIVES, INTERMEDIATES THEREOF AND METHODS FOR THEIR PREPARATION 失效
标题翻译：制备7-氨基-3,5-二羟基丙酸衍生物的方法，其中间体及其制备方法
公开(公告)号：US20080125601A1
公开(公告)日：2008-05-29
申请号：US11941347
申请日：2007-11-16
申请人： Reinhold Ohrlein , Gabriele Baisch , Hans Jorg Kirner , Stephan Burkhardt , Martin Studer , Frank Bienewald
发明人： Reinhold Ohrlein , Gabriele Baisch , Hans Jorg Kirner , Stephan Burkhardt , Martin Studer , Frank Bienewald
IPC分类号： C07C233/08
CPC分类号： C07C69/67 , C07C69/716 , C07C69/732 , C07C69/738 , C07C227/32 , C07C229/22 , C07C235/06 , C07C235/74 , C12P7/62 , Y02P20/55
摘要： Synthesis methods for the preparation of intermediates which are suitable for the preparation of statin derivatives, and especially to synthesis methods for the intermediate of formula (VI) wherein Ra′ and Rc′ are each independently of the other hydrogen or hydroxy-protecting group, or together are a bridging hydroxy-protecting group; and Rb is a carboxy-protecting group.
摘要翻译：制备适于制备他汀类衍生物的中间体的合成方法，特别是其中R a和R c的中间体的合成方法各自独立地为氢或羟基保护基，或者一起是桥羟基保护基; R b是羧基保护基。

3. 发明申请

US20070142662A1 Process for the preparation of 7-amino syn 3,5-dihydroxy heptanoic acid derivatives via 6-cyano syn 3,5-dihydroxy hexanoic acid derivatives 失效
标题翻译：通过6-氰基顺式3,5-二羟基己酸衍生物制备7-氨基顺式3,5-二羟基庚酸衍生物的方法
公开(公告)号：US20070142662A1
公开(公告)日：2007-06-21
申请号：US11657808
申请日：2007-01-24
申请人： Reinhold Ohrlein , Gabriele Baisch , Hans Jurg Kirner , Frank Bienewald , Stephan Burkhardt , Martin Studer
发明人： Reinhold Ohrlein , Gabriele Baisch , Hans Jurg Kirner , Frank Bienewald , Stephan Burkhardt , Martin Studer
IPC分类号： C07C227/04
CPC分类号： C07C69/67 , C07C69/716 , C07C69/732 , C07C69/738 , C07C227/32 , C07C229/22 , C07C235/06 , C07C235/74 , C12P7/62 , Y02P20/55
摘要： The invention relates to novel synthesis methods for the preparation of the intermediates, which are suitable for the preparation of statin derivatives, especially to novel synthesis methods of the intermediate of formula VI wherein Ra and Rc are each independently of the other hydrogen or a hydroxy-protecting group or together are a bridging hydroxy-protecting group, and Rb is a carboxy-protecting group, which methods are carried out by conversion of the intermediate of formula XIX wherein Ra and Rc are each independently of the other hydrogen or a hydroxy-protecting group, and Rb is a carboxy-protective group.
摘要翻译：本发明涉及用于制备适于制备他汀类衍生物的中间体的新型合成方法，特别涉及式VI中间体的新型合成方法，其中R a a， C 1各自独立地为另一个氢或羟基保护基团，或者一起是桥接羟基保护基团，并且R b是羧基保护基团，该方法进行通过其中R a a和R c C分别独立于另一个氢或羟基保护基的式XIX的中间体的转化，并且R b' SUB>是羧基保护基。

4. 发明申请

US20060105441A1 Process for the preparation of indole derivatives by enzymatic acylation 审中-公开
标题翻译：通过酶酰化制备吲哚衍生物的方法
公开(公告)号：US20060105441A1
公开(公告)日：2006-05-18
申请号：US10548356
申请日：2004-03-03
申请人： Reinhold Ohrlein , Nicole End , Gabriele Baisch
发明人： Reinhold Ohrlein , Nicole End , Gabriele Baisch
IPC分类号： C12P7/40 , C07D209/18
CPC分类号： C07D209/24
摘要： A process for the preparation of compounds of formula (1), by enzymatic acylation to form compounds of formulae (3a) and (3a) and then reacting the compound of formula (3a) with a compound introducing the radical of formula —CH2—COOR8, R8 being an organic radical, and then reducing, and optionally hydrolysing, the resulting compound of formula (4).
摘要翻译：通过酶促酰化制备式（1）化合物以形成式（3a）和（3a）化合物的方法，然后使式（3a）化合物与引入式-CH

5. 发明申请

US20050124820A1 Enzymatic process for preparing organosilicon group containing photoinitiators 有权
公开(公告)号：US20050124820A1
公开(公告)日：2005-06-09
申请号：US10506698
申请日：2003-02-25
申请人： Reinhold Ohrlein , Kai-Uwe Schoning , Gabriele Baisch , Jemima Schmidt , Gisele Baudin , Tunja Jung
发明人： Reinhold Ohrlein , Kai-Uwe Schoning , Gabriele Baisch , Jemima Schmidt , Gisele Baudin , Tunja Jung
IPC分类号： C12N11/08 , C07F7/08 , C07F7/10 , C12P9/00 , C07F7/04
CPC分类号： C07F7/0889 , C12P9/00
摘要： The invention relates to a process for preparing organosilicon group containing photoinitiators of the formula (I), wherein m is a number from 1 to 200; q is 0 or 1; A is IN—C(O)—O—CHR3—Y— or IN—C(O)—NH—CHR3—Y—; A′ is A or R1′; R1 and R1′, R2 and R2′ are C1-C18alkyl or phenyl, or —(O)q—SiR1R1′R2; R3 is hydrogen or C1-C6alkyl, Y is a divalent group selected from C1-C10alkeylene, C2-C10alkenylene or —(CH2)b—O—(CH2)a—; and b are each independently of the other a number of 1 to 6; IN is a photolabile functional moiety of the formula (II) or (III), wherein R4 is hydrogen or —C(O)—C(O)—OH or —C(O)—C(O)—OC1-C6alkyl and n is 1-3; R5 and R6 are C1-C1-2alkyl or together are cycloC5-C7alkyl; R7 is hydroxy, C1-C6alkoxy or morpholinyl; X is —(CH2)a—, —(CH2)b—O—(CH2)a— or —(CH2)b—O—CO—(CH2)a—; a and b are each independently of the other a number of 1 to 6; whereby the process is characterized in that a photolabile functional moiety containing a carboxy group (IN—COOH) or an alkoxycarbonyl group (IN—CO—OC1-C6alkyl) is reacted with a carbinol- or amino terminated organosilicon compound of the formula (IV), wherein m, R1 and R1′, R2 and R2′ are as defined above and B is —Y—CHR3—OH or —Y—CHR3—NH2; B′ is B or R1′, in the presence of an enzyme which catalyzes the esterification, transesterification or amidation reaction.

6. 发明申请

US20140296518A1 Colored Charged Silsesquioxanes 有权
标题翻译：彩色充电倍半硅氧烷
公开(公告)号：US20140296518A1
公开(公告)日：2014-10-02
申请号：US13855415
申请日：2013-04-02
申请人： Reinhold Ohrlein , Gabriele Baisch
发明人： Reinhold Ohrlein , Gabriele Baisch
IPC分类号： G02F1/00
CPC分类号： C08G77/392 , C08G77/045 , C08G77/388 , C09B1/503 , C09B1/54 , C09B5/2481 , C09B69/008 , C09B69/101 , G02F2001/1678 , G02F2203/34
摘要： The present invention provides compounds of formula wherein is wherein is and electrophoretic devices comprising the compounds of formula (1A) or (1B).
摘要翻译：本发明提供下式的化合物，其中是和包含式（1A）或（1B）化合物的电泳装置。

7. 发明申请

US20070028805A1 (Meth)acrylamide phosphorus monomer compositions 失效
标题翻译：（甲基）丙烯酰胺磷单体组成
公开(公告)号：US20070028805A1
公开(公告)日：2007-02-08
申请号：US11477256
申请日：2006-06-29
申请人： Liliana Craciun , Orest Polishchuk , George Schriver , Gabriele Baisch , Reinhold Ohrlein
发明人： Liliana Craciun , Orest Polishchuk , George Schriver , Gabriele Baisch , Reinhold Ohrlein
IPC分类号： C09C1/36
CPC分类号： C09D143/02 , C07F9/4009 , C07F9/4056 , C07F9/5728 , C08F230/02 , C08K3/013 , C09C3/10 , C09D5/086 , C09J133/26 , C09J143/02 , Y10T428/254 , Y10T428/2857 , Y10T428/2887 , Y10T428/2913 , Y10T428/2933 , Y10T428/294 , Y10T428/2958 , Y10T428/2998 , Y10T428/31504 , Y10T428/31623 , Y10T428/31645 , Y10T428/31649 , Y10T428/31681 , Y10T428/31692 , Y10T428/31699 , Y10T428/31765 , Y10T428/31855 , Y10T428/31935
摘要： The present invention relates to polymerizable N-substituted acrylamide phosphorus-containing monomers, organic polymers formed from the same. Incorporation of said monomers into adhesives, pigment dispersants, coatings or films for polar surfaces or particles gives improved adhesive, anti-corrosive, and flame retardant properties.
摘要翻译：本发明涉及可聚合的N-取代丙烯酰胺含磷单体，由其形成的有机聚合物。将所述单体并入粘合剂，颜料分散剂，用于极性表面或颗粒的涂料或薄膜中提供了改进的粘合剂，抗腐蚀性和阻燃性能。

8. 发明申请

US20050033086A1 Process for the preparation of 7-amino syn 3,5-dihydroxy heptanoic acid derivatives via 6-cyano syn 3,5-dihydroxy hexanoic acid derivatives 失效
标题翻译：通过6-氰基顺式3,5-二羟基己酸衍生物制备7-氨基顺式3,5-二羟基庚酸衍生物的方法
公开(公告)号：US20050033086A1
公开(公告)日：2005-02-10
申请号：US10481704
申请日：2002-07-02
申请人： Reinhold Ohrlein , Gabriele Baisch , Hans Kirner , Frank Bienewald , Stephan Burkhardt , Martin Studer
发明人： Reinhold Ohrlein , Gabriele Baisch , Hans Kirner , Frank Bienewald , Stephan Burkhardt , Martin Studer
IPC分类号： C07C67/307 , C07B53/00 , C07B61/00 , C07C67/30 , C07C67/31 , C07C69/67 , C07C69/675 , C07C69/708 , C07C69/716 , C07C69/732 , C07C69/738 , C07C227/06 , C07C227/16 , C07C227/32 , C07C229/22 , C07C231/02 , C07C235/06 , C07C235/74 , C07C247/12 , C07C253/30 , C07D207/34 , C12P7/62
CPC分类号： C07C69/67 , C07C69/716 , C07C69/732 , C07C69/738 , C07C227/32 , C07C229/22 , C07C235/06 , C07C235/74 , C12P7/62 , Y02P20/55
摘要： The invention relates to novel synthesis methods for the preparation of the intermediates, which are suitable for the preparation of statin derivatives, especially to novel synthesis methods of the intermediate of formula VI wherein Ra and Rc are each independently of the other hydrogen or a hydroxy-protecting group or together are a bridging hydroxy-protecting group, and Rb is a carboxy-protecting group, which methods are carried out by conversion of the intermediate of formula XIX wherein Ra and Rc are each independently of the other hydrogen or a hydroxy-protecting group, and Rb is a carboxy-protective group.
摘要翻译：本发明涉及适用于制备他汀类衍生物的中间体的新型合成方法，特别是式VI中间体的新合成方法，其中R a和R c各自独立地为氢或羟基 - 保护基或一起是桥接羟基保护基，Rb是羧基保护基，该方法通过式XIX的中间体转化而进行，其中R a和R c各自独立地为氢或羟基保护基基团，Rb是羧基保护基。

9. 发明申请

US20050014954A1 Pyrrole synthesis 审中-公开
标题翻译：吡咯合成
公开(公告)号：US20050014954A1
公开(公告)日：2005-01-20
申请号：US10496282
申请日：2002-11-14
申请人： Reinhold Ohrlein , Gabriele Baisch
发明人： Reinhold Ohrlein , Gabriele Baisch
IPC分类号： C07D207/32 , C07D207/323 , C07D207/33 , C07D207/337 , C07D207/34 , C07D209/08 , C07D405/06 , C07F7/18 , C07F9/535 , C07F9/655 , C07D207/30
CPC分类号： C07D207/323 , C07D207/337 , C07D209/08 , C07F9/5355 , C07F9/6552
摘要： The invention relates to a novel process for the preparation of N-substituted pyrroles, especially of formula (V), wherein the radicals are as defined in the description, by intermolecular aza-Wittig reaction starting from organic azides and 1,4-dioxo compounds. The invention relates also to novel iminophosphorane intermediates for this synthesis. The resulting pyrroles are useful, for example, in the organic synthesis of pharmaceuticals or other active substances and chemicals.
摘要翻译：本发明涉及一种用于制备N-取代的吡咯，特别是式（Ⅴ）的新方法，其中基团如描述中所定义，通过分子间氮杂 - 维蒂希反应从有机叠氮化物和1,4-二氧代化合物开始。本发明还涉及用于该合成的新型亚氨基磷酰中间体。得到的吡咯可用于例如药物或其它活性物质和化学品的有机合成。

10. 发明申请

US20110123468A1 USE OF BENZOTROPOLONE DERIVATIVES AS UV ABSORBERS AND ANTIOXIDANTS AND THEIR USE IN SUNSCREENS AND/OR COSMETIC COMPOSITIONS 有权
公开(公告)号：US20110123468A1
公开(公告)日：2011-05-26
申请号：US13000163
申请日：2009-06-18
申请人： Barbara Wagner , Reinhold Ohrlein , Bernd Herzog , Kai Eichin , Gabriele Baisch , Stephanie Portmann
发明人： Barbara Wagner , Reinhold Ohrlein , Bernd Herzog , Kai Eichin , Gabriele Baisch , Stephanie Portmann
IPC分类号： A61K8/49 , A61K8/37 , A61K31/235 , A61K31/351 , C07C69/76 , C07D307/34 , A61K31/375 , A61K31/665 , A61Q19/04 , A61P39/06
CPC分类号： A61Q17/04 , A61K8/35 , A61Q19/08 , C07C49/747 , C07C62/38 , C07C69/712 , C07C69/757 , C07C305/18 , C07C2602/12 , C07F9/4006 , C07H15/18 , C07H15/203 , C07H15/26
摘要： Described is the use of benzotropolone and their derivatives, especially the compounds of formula (1); wherein R2, R3, R4, R5 and R6 independently of one another are hydrogen; OH; C1-C30alkyl, C2-C30al-kenyl, C1-C30alkoxy, C3-C12cycloalkyl or C1C30hydroxyalkyl, which may be substituted by one or more E and/or interrupted by one or more D; C6-C20aryl, which may be substituted by one or more G; C4-C20heteroaryl, which may be substituted by one or more G, C2-C18alkenyl, C2-C18alkynyl, C7-C25aralkyl, CN, or —CO—R17; C1-C30mono- or dialkylamino; COR9; COOR9; CONR9R10; CN; SO2R9; OCOOR9; OCOR9; NHCOOR9; NR9COR10; NH2; *—(CO)—NH—(CH2)n1—(PO)—(OR11)2; —(CO)—O—(CH2)n1—(PO)—(OR11)2; sulphate; sulphonate; phosphate; phosphonate; —(CH2)n2—[O—(SO2)]n3—OR11; —O—(CH2)n4(CO)n5—R11; —(O)n6—(CH2)n7—(PO)—(OR9)2; —(O)n6—(CH2)n7—SO2—OR9; halogen; organosilanyl; organo-siloxanyl; or a sugar residue linked directly in an α- or β-mode via the anomeric oxygen to the benzotropolone system or via a linear or branched alkylene, alkenylene, alkadiene or alkatriene spacer (sugar-(CH2)n—(X1)1 or 0-benzotropolone system, wherein n=1-10 and X1=—O—; —(CO)—; —O—CO—; —COO—, —NH—; —S—; —SO2—); R1, R7 and R8 independently of one another are hydrogen; C1C12alkyl or C3-C12-cycloalkyl, which may be substituted by one or more E and/or interrupted by one or more D; C6-C20aryl, which may be substituted by one or more G; C4-C20heteroaryl, which may be substituted by one or more G, C2-C18alkenyl, C2-C18alkynyl, C7-C25aralkyl, or COOR9; COR9; CONR9R10; SO3R9; SO2R9; PO3(R9)2; PO2(R9)2; organosilanyl; organosiloxanyl; or a sugar residue linked directly in an α- or β-mode via the anomeric oxygen to the benzotropolone system or via a linear or branched alkylene, alkenylene, alkadiene or alkatriene spacer (sugar-(CH2)n—(X2)1 or 0—*, wherein n=1-10 and X2=—C(═O)—; —O—CO—*); R9 and R10 independently from each other are hydrogen; C1C18alkyl or C3-C12-cycloalkyl which may be substituted by one or more E and/or interrupted by one or more D; C6-C20aryl, which may be substituted by one or more G; C4-C20heteroaryl, which may be substituted by one or more G; organosilanyl; organosiloxanyl; or a sugar residue linked directly in an α- or β-mode via the anomeric oxygen or via a linear or branched alkylene, alkenylene, alkadiene or alkatriene spacer (sugar-(CH2)n—*, wherein n=1-10); or R9 and R10 together form a five or six membered ring, R11 is hydrogen; or C1-C5alkyl; n1, n2, n4 and n7 independently from each other are a number from 1 to 5; n3, n5 and n6 independently from each other are a 0; or 1; D is —CO—; —COO—; —S—; —SO—; —SO2-; —O—; —NR14—; —S1R19R20—; —POR11—; —CR12═CR13—; or —C≡C—; and E is —OR18; —SR18; —NR14R15; —NR14COR15; —COR17; —COOR16; —CONR14R15; —CN; halogen; Or SO3R18; SO2R18; PO3(R18)2; PO2(R18)2; organosilanyl; organosiloxanyl; or a sugar residue linked directly in an α- or β-mode via the anomeric oxygen or via a linear or branched alkylene, alkenylene, alkadiene or alkatriene spacer (sugar-(CH2)n-(X1)1 or 0—*, wherein n=1-10 and X1=—O—; —C(═O)—; —O—CO—; —COO—; —NH—; —S—; —SO2—); G is E; C1-C18alkyl, which is optionally interrupted by D; C1-C18perfluoroalkyl; C1-C18alkoxy, which is optionally substituted by E and/or interrupted by D; wherein R12, R13, R14 and R15 independently of each other are hydrogen; C6-C18aryl which is optionally substituted by OH, C1-C18alkyl or C1-C18alkoxy; C1-C18alkyl, which is optionally interrupted by —O—; or Ri4 and Ri5 together form a five or six membered ring, Ri6 is hydrogen; C6-Ci8aryl which is optionally substituted by OH, C1-C18alkyl or d-C18alkoxy; C1-C18alkyl which is optionally interrupted by —O—; R17 is H; C6-C18aryl which is optionally substituted by OH, C1-C18alkyl or C1-C18alkoxy; or d-C18alkyl which is optionally interrupted by —O—; R18 is hydrogen; C6-C18aryl, which is optionally substituted by OH, C1-C18alkyl or d-C18alkoxy; C1-C18alkyl, which is optionally interrupted by —O—; R19 and R20 independently of each other are hydrogen; C1-C18alkyl; C6-C18aryl which is optionally substituted by C1-C18alkyl; and R21 is C1-C18alkyl; or C6-C18aryl, which is substituted by C1-C18alkyl; * means, that this radical is directed to the benzotropolone moiety; for the protection of human and animal hair and skin against UV radiation.

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