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1. 发明申请

US20080111100A1 USE OF LOW GWP REFRIGERANTS COMPRISING CF3I WITH STABLE LUBRICANTS 审中-公开
标题翻译：使用包含CF3I的稳定润滑剂的低GWP制冷剂
公开(公告)号：US20080111100A1
公开(公告)日：2008-05-15
申请号：US11937267
申请日：2007-11-08
申请人： RAYMOND H. THOMAS , Rajiv R. Singh , George J. Samuels , Ian Shankland , David P. Wilson , Roy P. Robinson , Michael Van Der Puy , John L. Welch , Gregory J. Shafer , Mark W. Spatz , Ryan Hulse
发明人： RAYMOND H. THOMAS , Rajiv R. Singh , George J. Samuels , Ian Shankland , David P. Wilson , Roy P. Robinson , Michael Van Der Puy , John L. Welch , Gregory J. Shafer , Mark W. Spatz , Ryan Hulse
IPC分类号： C09K5/04 , B60H1/32 , F25B45/00 , F28F99/00
CPC分类号： C09K5/045 , C09K2205/122 , C10N2240/30
摘要： The invention pertains to heat transfer compositions, particularly to automobile refrigerants comprising a hydrofluoroalkene, an iodocarbon, and at least one lubricant having hydrogen atoms and carbon atoms, wherein no more than 17% of the total number of hydrogen atoms which are attached to a carbon atom are tertiary hydrogen atoms.
摘要翻译：本发明涉及传热组合物，特别是涉及包含氢氟烯烃，碘化碳和至少一种具有氢原子和碳原子的润滑剂的汽车制冷剂，其中不超过连接到碳上的氢原子总数的17％原子是叔氢原子。

2. 发明授权

US09920230B2 Use of low GWP refrigerants comprising CF3I with stable lubricants 有权
公开(公告)号：US09920230B2
公开(公告)日：2018-03-20
申请号：US13022902
申请日：2011-02-08
申请人： Raymond H. Thomas , Rajiv R. Singh , George J. Samuels , Ian Shankland , David P. Wilson , Roy P. Robinson , Michael Van Der Puy , John L. Welch , Gregory J. Shafer , Mark W. Spatz , Ryan Hulse
发明人： Raymond H. Thomas , Rajiv R. Singh , George J. Samuels , Ian Shankland , David P. Wilson , Roy P. Robinson , Michael Van Der Puy , John L. Welch , Gregory J. Shafer , Mark W. Spatz , Ryan Hulse
IPC分类号： C09K5/04
CPC分类号： C09K5/045 , C09K2205/122 , C10N2240/30
摘要： The invention pertains to heat transfer compositions, particularly to automobile refrigerants comprising a hydrofluoroalkene, an iodocarbon, and at least one lubricant having hydrogen atoms and carbon atoms, wherein no more than 17% of the total number of hydrogen atoms which are attached to a carbon atom are tertiary hydrogen atoms.

3. 发明申请

US20080157023A1 FLUOROCARBON STABILIZERS 审中-公开
标题翻译：氟化物稳定剂
公开(公告)号：US20080157023A1
公开(公告)日：2008-07-03
申请号：US11937194
申请日：2007-11-08
申请人： George J. Samuels , Samuel F. Yana Motta , Gregory J. Shafer , Rajiv R. Singh , Mark W. Spatz , Raymond H. Thomas , Michael Van Der Puy , John L. Welch , David P. Wilson , Gary Zyhowski
发明人： George J. Samuels , Samuel F. Yana Motta , Gregory J. Shafer , Rajiv R. Singh , Mark W. Spatz , Raymond H. Thomas , Michael Van Der Puy , John L. Welch , David P. Wilson , Gary Zyhowski
IPC分类号： C09K5/00 , C09K5/04
CPC分类号： C10M171/008 , C09K5/045 , C09K2205/122 , C09K2205/126 , C10M2203/065 , C10M2203/1025 , C10M2203/1065 , C10M2205/0285 , C10M2205/223 , C10M2207/023 , C10M2207/026 , C10M2207/042 , C10M2207/044 , C10M2207/046 , C10M2207/08 , C10M2207/144 , C10M2207/2805 , C10M2207/289 , C10M2209/043 , C10M2209/1023 , C10M2209/1033 , C10M2215/14 , C10M2215/223 , C10M2215/224 , C10M2215/225 , C10M2219/068 , C10M2219/082 , C10M2219/084 , C10M2219/106 , C10M2223/04 , C10M2223/045 , C10M2223/049 , C10N2210/02 , C10N2210/06 , C10N2220/302 , C10N2230/06 , C10N2240/30
摘要： The invention pertains to heat transfer compositions, particularly to automobile refrigerants comprising a hydrofluoroalkene, an iodocarbon, a lubricant and a metal stabilizer.
摘要翻译：本发明涉及传热组合物，特别涉及包含氢氟烯烃，碘化碳，润滑剂和金属稳定剂的汽车制冷剂。

4. 发明申请

US20080111099A1 HEAT TRANSFER COMPOSITIONS WITH A HYDROFLUOROALKENE, AN IODOCARBON AND ADDITIVES 审中-公开
标题翻译：加氢转移组合物，氢碘化物，碘化物和添加剂
公开(公告)号：US20080111099A1
公开(公告)日：2008-05-15
申请号：US11937094
申请日：2007-11-08
申请人： Rajiv R. Singh , Raymond H. Thomas , George J. Samuels , David P. Wilson , Michael Van Der Puy , John L. Welch , Gregory J. Shafer , Mark W. Spatz
发明人： Rajiv R. Singh , Raymond H. Thomas , George J. Samuels , David P. Wilson , Michael Van Der Puy , John L. Welch , Gregory J. Shafer , Mark W. Spatz
IPC分类号： C09K5/00 , F25D31/00 , F25B45/00
CPC分类号： C09K5/045 , C09K2205/122 , C09K2205/126 , C10M171/008 , C10M2203/065 , C10M2203/1025 , C10M2203/1065 , C10M2205/0285 , C10M2207/042 , C10M2207/2805 , C10M2207/2835 , C10M2209/043 , C10M2209/1023 , C10M2209/1033 , C10N2220/302 , C10N2240/30
摘要： The invention pertains to heat transfer compositions, particularly to automobile refrigerants comprising a hydrofluoroalkene, an iodocarbon, a polyol ester and at least one compound comprising trifluoromethane, methyl iodide, heptafluorobutane or propene.
摘要翻译：本发明涉及传热组合物，特别涉及包含氢氟烯烃，碘化碳，多元醇酯和至少一种包含三氟甲烷，甲基碘，七氟丁烷或丙烯的化合物的汽车制冷剂。

5. 发明申请

US20080116417A1 IODINE AND IODIDE REMOVAL METHOD 审中-公开
标题翻译：碘和碘去除方法
公开(公告)号：US20080116417A1
公开(公告)日：2008-05-22
申请号：US11937283
申请日：2007-11-08
申请人： George J. Samuels , Samuel F. Yana Motta , Gregory J. Shafer , Rajiv R. Singh , Mark W. Spatz , Raymond H. Thomas , Michael Van Der Puy , John L. Welch , Gary Zyhowski , David P. Wilson
发明人： George J. Samuels , Samuel F. Yana Motta , Gregory J. Shafer , Rajiv R. Singh , Mark W. Spatz , Raymond H. Thomas , Michael Van Der Puy , John L. Welch , Gary Zyhowski , David P. Wilson
IPC分类号： C09K5/00
CPC分类号： C09K5/045 , C07C17/38 , C07C21/18
摘要： A method for removing iodine and iodide ions from heat transfer compositions which contain a hydrofluoroalkene, an iodocarbon, and iodine and iodide ions. Iodine and iodide ions from such heat transfer compositions by contacting the composition with a molecular sieve, ion exchange resin, clay or alumina, metal impregnated with a metal which is capable of reacting with iodine and iodide ions.
摘要翻译：从含有氢氟烯烃，碘化碳和碘和碘离子的传热组合物中除去碘和碘离子的方法。通过使组合物与分子筛，离子交换树脂，粘土或氧化铝接触，浸渍有能够与碘和碘离子反应的金属的金属，来自这种传热组合物的碘和碘离子。

6. 发明申请

US20080110833A1 IODINE REMOVAL WITH ACTIVATED CARBON 审中-公开
标题翻译：用活性炭除去碘
公开(公告)号：US20080110833A1
公开(公告)日：2008-05-15
申请号：US11937167
申请日：2007-11-08
申请人： George J. Samuels , Samuel F. Yana Motta , Gregory J. Shafer , Rajiv R. Singh , Mark W. Spatz , Raymond H. Thomas , Michael Van Der Puy , John L. Welch , Gary Zyhowski , David P. Wilson
发明人： George J. Samuels , Samuel F. Yana Motta , Gregory J. Shafer , Rajiv R. Singh , Mark W. Spatz , Raymond H. Thomas , Michael Van Der Puy , John L. Welch , Gary Zyhowski , David P. Wilson
IPC分类号： B01D17/00
CPC分类号： B01D15/00 , B01J20/20 , C10N2240/30
摘要： A method for removing iodine from heat transfer compositions which contain a hydrofluoroalkene, an iodocarbon, and iodine. Iodine from such heat transfer compositions by contacting the composition with activated carbon.
摘要翻译：从含有氢氟烯烃，碘化碳和碘的热转印组合物中除去碘的方法。通过使组合物与活性炭接触，来自这种传热组合物的碘。

7. 发明申请

US20090283712A1 SESQUITERPENE STABILIZED COMPOSITIONS 有权
标题翻译： SESQUITERPENE稳定组合物
公开(公告)号：US20090283712A1
公开(公告)日：2009-11-19
申请号：US12467061
申请日：2009-05-15
申请人： Gary Zyhowski , Rajiv Ratna Singh , Raymond H. Thomas , Mark W. Spatz , Roy P. Robinson , George J. Samuels , Gregory J. Shafer , Michael Van Der Puy , David P. Wilson , John L. Welch , Ronald P. Vogl , Samuel F. Yana Motta
发明人： Gary Zyhowski , Rajiv Ratna Singh , Raymond H. Thomas , Mark W. Spatz , Roy P. Robinson , George J. Samuels , Gregory J. Shafer , Michael Van Der Puy , David P. Wilson , John L. Welch , Ronald P. Vogl , Samuel F. Yana Motta
IPC分类号： C09K5/04 , C09K3/00 , C07C21/18 , C07C17/42
CPC分类号： C09K5/044 , C07C17/42 , C09K5/045 , C09K2205/126 , C07C21/18 , C07C19/16
摘要： Provided is a composition comprising (a) at least one halogenated compound selected from the group consisting of C3-C5 hydrofluoroolefin, CF3I, and combinations thereof, and (b) an effective stabilizing amount of a sesquiterpene selected from the group consisting of farnesol, farnesene, and mixtures thereof.
摘要翻译：提供了一种组合物，其包含（a）至少一种选自C 3 -C 5氢氟烯烃，CF 3 I及其组合的卤代化合物，和（b）有效稳定量的倍半萜烯，选自法呢醇，法呢烯，及其混合物。

8. 发明授权

US08133407B2 Sesquiterpene stabilized compositions 有权
标题翻译：倍半萜稳定组合物
公开(公告)号：US08133407B2
公开(公告)日：2012-03-13
申请号：US12467061
申请日：2009-05-15
申请人： Gary Zyhowski , Rajiv Ratna Singh , Raymond H. Thomas , Mark W. Spatz , Roy P. Robinson , George J. Samuels , Gregory J. Shafer , Michael Van Der Puy , David P. Wilson , John L. Welch , Ronald P. Vogl , Samuel F. Yana Motta
发明人： Gary Zyhowski , Rajiv Ratna Singh , Raymond H. Thomas , Mark W. Spatz , Roy P. Robinson , George J. Samuels , Gregory J. Shafer , Michael Van Der Puy , David P. Wilson , John L. Welch , Ronald P. Vogl , Samuel F. Yana Motta
IPC分类号： C09K5/00 , C11D3/24
CPC分类号： C09K5/044 , C07C17/42 , C09K5/045 , C09K2205/126 , C07C21/18 , C07C19/16
摘要： Provided is a composition comprising (a) at least one halogenated compound selected from the group consisting of C3-C5 hydrofluoroolefin, CF3I, and combinations thereof, and (b) an effective stabilizing amount of a sesquiterpene selected from the group consisting of farnesol, farnesene, and mixtures thereof.
摘要翻译：提供了一种组合物，其包含（a）至少一种选自C 3 -C 5氢氟烯烃，CF 3 I及其组合的卤代化合物，和（b）有效稳定量的倍半萜烯，选自法呢醇，法呢烯，及其混合物。

9. 发明申请

US20080312392A1 PROCESS FOR PREPARING A POLYMER FROM ALLYLOXYTRIFLUOROPROPENES 审中-公开
标题翻译：从聚乙烯吡咯烷酮制备聚合物的方法
公开(公告)号：US20080312392A1
公开(公告)日：2008-12-18
申请号：US12196721
申请日：2008-08-22
申请人： HARIDASAN K. NAIR , Rajiv R. Singh , Gregory J. Shafer
发明人： HARIDASAN K. NAIR , Rajiv R. Singh , Gregory J. Shafer
IPC分类号： C08F4/42 , C08F16/12
CPC分类号： C08F14/18 , C07C41/06 , C08F2/00 , C07C43/17
摘要： A process for preparing a polymer comprising the step of: polymerizing: (i) an allyloxytrifluoropropene derivative selected from the group consisting of compounds represented by the formula: CF3CH═CH(OCH2CR═CH2); CF3CH═C(OCH2CR═CH2)2; CF3CH═CF(OCH2CR═CH2); and any mixtures thereof; wherein R is selected from the group consisting of: hydrogen and methyl; and optionally (ii) an ethylenically unsaturated comonomer; wherein the copolymerizing step is carried out in the presence of a catalyst, under conditions sufficient to produce the copolymer.
摘要翻译：一种制备聚合物的方法，包括以下步骤：聚合：（i）选自由下式表示的化合物的烯丙氧基三氟丙烯衍生物：<？in-line-formula description =“In-line Formulas”end =“lead “> CF 3 CH-CH（OCH 2 CR-CH 2）; <？在线公式描述=”在线公式“end =”tail“？> <？in-line-formula description =”In-line Formulas“end =“lead”→CF 3 CH-C（OCH 2 CR-CH 2）2; <βin-line-formula description =“In-line Formulas”end =“tail”？> <？in-line-formula description = CF 3 CH-CF（OCH 2 CR-CH 2）; 和<？in-line-formula description =“In-line Formulas”end =“tail”？>它们的任何混合物; 其中R选自：氢和甲基; 和任选的（ⅱ）烯属不饱和共聚单体; 其中所述共聚步骤在催化剂存在下，在足以产生所述共聚物的条件下进行。

10. 发明授权

US07531701B2 Allyloxytrifluoropropenes 失效
标题翻译：烯丙氧基三氟丙烯
公开(公告)号：US07531701B2
公开(公告)日：2009-05-12
申请号：US11900081
申请日：2007-09-10
申请人： Haridasan K. Nair , Rajiv R. Singh , Gregory J. Shafer
发明人： Haridasan K. Nair , Rajiv R. Singh , Gregory J. Shafer
IPC分类号： C07C43/17 , C07C41/01
CPC分类号： C08F14/18 , C07C41/06 , C08F2/00 , C07C43/17
摘要： A process for the preparation of an allyloxytrifluoropropene derivative of the formula CF3CH═CR1(OCH2CR═CH2) wherein R1 is hydrogen, fluoro, or an allyloxy group represented by the formula —OCH2CR═CH2 wherein R is hydrogen or methyl including contacting (I) a compound represented by the formula CF3CH═CR2R3 wherein R2 is selected from the group consisting of hydrogen, chloro, and fluoro and wherein R3 is chloro or fluoro; and (ii) an allyl alcohol derivative of the formula HOCH2CR═CH2 wherein R is selected from the group consisting of: hydrogen and methyl; wherein the contacting is carried out in the presence of a base and optionally a solvent at a temperature and length of time sufficient to produce the allyloxytrifluoropropene derivative. A process for the preparation of polymers of the allyloxytrifluoropropene derivatives is also provided.
摘要翻译：制备式CF 3 CH-CR 1（OCH 2 CR-CH 2）的烯丙氧基三氟丙烯衍生物的方法，其中R 1是氢，氟或由式-OCH 2 CR-CH 2表示的烯丙氧基，其中R是氢或甲基，包括与（I）由式CF 3 CH-CR 2 R 3表示的化合物，其中R 2选自氢，氯和氟，并且其中R 3是氯或氟; 和（ii）式HOCH 2 CR-CH 2的烯丙醇衍生物，其中R选自：氢和甲基; 其中所述接触在碱和任选的溶剂的存在下，在足以产生烯丙氧基三氟丙烯衍生物的温度和时间长度下进行。还提供了制备烯丙氧基三氟丙烯衍生物的聚合物的方法。

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