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1. 发明授权

US09920230B2 Use of low GWP refrigerants comprising CF3I with stable lubricants 有权
公开(公告)号：US09920230B2
公开(公告)日：2018-03-20
申请号：US13022902
申请日：2011-02-08
申请人： Raymond H. Thomas , Rajiv R. Singh , George J. Samuels , Ian Shankland , David P. Wilson , Roy P. Robinson , Michael Van Der Puy , John L. Welch , Gregory J. Shafer , Mark W. Spatz , Ryan Hulse
发明人： Raymond H. Thomas , Rajiv R. Singh , George J. Samuels , Ian Shankland , David P. Wilson , Roy P. Robinson , Michael Van Der Puy , John L. Welch , Gregory J. Shafer , Mark W. Spatz , Ryan Hulse
IPC分类号： C09K5/04
CPC分类号： C09K5/045 , C09K2205/122 , C10N2240/30
摘要： The invention pertains to heat transfer compositions, particularly to automobile refrigerants comprising a hydrofluoroalkene, an iodocarbon, and at least one lubricant having hydrogen atoms and carbon atoms, wherein no more than 17% of the total number of hydrogen atoms which are attached to a carbon atom are tertiary hydrogen atoms.

2. 发明申请

US20080111100A1 USE OF LOW GWP REFRIGERANTS COMPRISING CF3I WITH STABLE LUBRICANTS 审中-公开
标题翻译：使用包含CF3I的稳定润滑剂的低GWP制冷剂
公开(公告)号：US20080111100A1
公开(公告)日：2008-05-15
申请号：US11937267
申请日：2007-11-08
申请人： RAYMOND H. THOMAS , Rajiv R. Singh , George J. Samuels , Ian Shankland , David P. Wilson , Roy P. Robinson , Michael Van Der Puy , John L. Welch , Gregory J. Shafer , Mark W. Spatz , Ryan Hulse
发明人： RAYMOND H. THOMAS , Rajiv R. Singh , George J. Samuels , Ian Shankland , David P. Wilson , Roy P. Robinson , Michael Van Der Puy , John L. Welch , Gregory J. Shafer , Mark W. Spatz , Ryan Hulse
IPC分类号： C09K5/04 , B60H1/32 , F25B45/00 , F28F99/00
CPC分类号： C09K5/045 , C09K2205/122 , C10N2240/30
摘要： The invention pertains to heat transfer compositions, particularly to automobile refrigerants comprising a hydrofluoroalkene, an iodocarbon, and at least one lubricant having hydrogen atoms and carbon atoms, wherein no more than 17% of the total number of hydrogen atoms which are attached to a carbon atom are tertiary hydrogen atoms.
摘要翻译：本发明涉及传热组合物，特别是涉及包含氢氟烯烃，碘化碳和至少一种具有氢原子和碳原子的润滑剂的汽车制冷剂，其中不超过连接到碳上的氢原子总数的17％原子是叔氢原子。

3. 发明授权

US08033120B2 Compositions and methods containing fluorine substituted olefins 有权
标题翻译：含氟取代烯烃的组合物和方法
公开(公告)号：US08033120B2
公开(公告)日：2011-10-11
申请号：US12426948
申请日：2009-04-20
申请人： Rajiv R. Singh , Hang T. Pham , David P. Wilson , Raymond H. Thomas , Ian Shankland
发明人： Rajiv R. Singh , Hang T. Pham , David P. Wilson , Raymond H. Thomas , Ian Shankland
IPC分类号： C09K5/04
CPC分类号： C07C19/08 , C07C21/18 , C08J9/146 , C08J2203/162 , C08J2205/052 , C08J2207/04 , C08J2323/06 , C08J2325/06 , C08J2375/00 , C09K5/045 , C09K2205/126 , C09K2205/24 , C10M111/02 , C10M111/04 , C10M171/008 , C10M2207/2835 , C10M2207/2895 , C10M2209/1033 , C10M2209/1095 , C10M2211/0225 , C10M2211/063 , C11D7/28 , C11D7/505 , C23G5/02845
摘要： The use of pentafluoropropene (HFO-1225) and tetrafluoropropene (HFO-1234) in refrigeration equipment is disclosed. These materials are generally useful as refrigerants for heating and cooling, as blowing agents, as aerosol propellants, as solvent composition, and as fire extinguishing and suppressing agents.
摘要翻译：公开了在制冷设备中使用五氟丙烯（HFO-1225）和四氟丙烯（HFO-1234）。这些材料通常可用作加热和冷却的制冷剂，作为发泡剂，作为气溶胶推进剂，作为溶剂组合物，以及作为灭火剂和抑制剂。

4. 发明授权

US07534366B2 Compositions containing fluorine substituted olefins 有权
标题翻译：含氟取代烯烃的组合物
公开(公告)号：US07534366B2
公开(公告)日：2009-05-19
申请号：US10694273
申请日：2003-10-27
申请人： Rajiv R. Singh , Hang T. Pham , David P. Wilson , Raymond H. Thomas , Ian Shankland
发明人： Rajiv R. Singh , Hang T. Pham , David P. Wilson , Raymond H. Thomas , Ian Shankland
IPC分类号： C09K5/04
CPC分类号： C23G5/02803 , C07C19/08 , C07C21/18 , C08J9/146 , C08J2205/052 , C08J2207/04 , C09K5/045 , C09K2205/126 , C11D7/28 , C11D7/505
摘要： The use of pentafluoropropene (HFO-1225) and tetrafluoropropene (HFO-1234) in refrigeration equipment is disclosed. These materials are generally useful as refrigerants for heating and cooling, as blowing agents, as aerosol propellants, as solvent composition, and as fire extinguishing and suppressing agents.
摘要翻译：公开了在制冷设备中使用五氟丙烯（HFO-1225）和四氟丙烯（HFO-1234）。这些材料通常可用作加热和冷却的制冷剂，作为发泡剂，作为气溶胶推进剂，作为溶剂组合物，以及作为灭火剂和抑制剂。

5. 发明授权

US08609909B2 Process for the purification of hydrofluoroolefins 有权
标题翻译：纯化氢氟烯烃的方法
公开(公告)号：US08609909B2
公开(公告)日：2013-12-17
申请号：US12696613
申请日：2010-01-29
申请人： Ryan Hulse , Rajiv Ratna Singh , Ian Shankland , Michael Van Der Puy
发明人： Ryan Hulse , Rajiv Ratna Singh , Ian Shankland , Michael Van Der Puy
IPC分类号： C07C17/386 , B01D3/36
CPC分类号： B01D11/0426 , B01D11/0492
摘要： Processes for the preparation and purification of hydrofluoroolefins such as tetrafluorinated propenes. A process is provided for separating a first hydrofluoroolefin from a second hydrofluoroolefin by a) providing a mixture including a first hydrofluoroolefin and a second hydrofluoroolefin, which first hydrofluoroolefin is preferentially more reactive with an amine than the second hydrofluoroolefin; b) adding a sufficient amount of an amine to the mixture to form a combination including the second hydrofluoroolefin and a reaction product of the first hydrofluoroolefin and the amine; and then c) separating the reaction product from the combination. This is particularly useful for removing 1,2,3,3,3-pentafluoropropene (HFO-1225ye) impurities from the hydrofluoroolefin 2,3,3,3-tetrafluoropropene (HFO-1234yf). HFO-1234yf is a refrigerant with low global warming potential.
摘要翻译：用于制备和纯化氢氟烯烃如四氟化丙烯的方法。提供了一种通过以下方法提供第一氢氟烯烃与第二氢氟烯烃的分离：a）提供包含第一氢氟烯烃和第二氢氟烯烃的混合物，该第一氢氟烯烃优选比第二氢氟烯烃更能反应胺; b）向混合物中加入足够量的胺以形成包含第二氢氟烯烃和第一氢氟烯烃与胺的反应产物的组合; 然后c）将反应产物与组合物分离。这对于从氢氟烯烃2,3,3,3-四氟丙烯（HFO-1234yf）中除去1,2,3,3,3-五氟丙烯（HFO-1225ye）杂质是特别有用的。 HFO-1234yf是一种全球变暖潜力较低的制冷剂。

6. 发明申请

US20100193347A1 PROCESS FOR THE PURIFICATION OF HYDROFLUOROOLEFINS 有权
标题翻译：氢氟菊酯的纯化方法
公开(公告)号：US20100193347A1
公开(公告)日：2010-08-05
申请号：US12696613
申请日：2010-01-29
申请人： Ryan Hulse , Rajiv Ratna Singh , Ian Shankland , Michael Van Der Puy
发明人： Ryan Hulse , Rajiv Ratna Singh , Ian Shankland , Michael Van Der Puy
IPC分类号： B01D3/36
CPC分类号： B01D11/0426 , B01D11/0492
摘要： Processes for the preparation and purification of hydrofluoroolefins such as tetrafluorinated propenes. A process is provided for separating a first hydrofluoroolefin from a second hydrofluoroolefin by a) providing a mixture comprising a first hydrofluoroolefin and a second hydrofluoroolefin, which first hydrofluoroolefin is preferentially more reactive with an amine than the second hydrofluoroolefin; b) adding a sufficient amount of an amine to the mixture to form a combination comprising the second hydrofluoroolefin and a reaction product of the first hydrofluoroolefin and the amine; and then c) separating the reaction product from the combination. This is particularly useful for removing 1,2,3,3,3-pentafluoropropene (HFO-1225ye) impurities from the hydrofluoroolefin 2,3,3,3-tetrafluoropropene (HFO-1234yf). HFO-1234yf is a refrigerant with low global warming potential.
摘要翻译：用于制备和纯化氢氟烯烃如四氟化丙烯的方法。提供了一种通过以下方法提供第一氢氟烯烃与第二氢氟烯烃的分离：a）提供包含第一氢氟烯烃和第二氢氟烯烃的混合物，该第一氢氟烯烃优选比第二氢氟烯烃更能反应胺; b）向混合物中加入足量的胺以形成包含第二氢氟烯烃和第一氢氟烯烃与胺的反应产物的组合; 然后c）将反应产物与组合物分离。这对于从氢氟烯烃2,3,3,3-四氟丙烯（HFO-1234yf）中除去1,2,3,3,3-五氟丙烯（HFO-1225ye）杂质是特别有用的。 HFO-1234yf是一种全球变暖潜力较低的制冷剂。

7. 发明申请

US20100237279A1 AZEOTROPE-LIKE COMPOSITIONS OF PENTAFLUOROPROPANE, CHLOROTRIFLUOROPROPENE, AND HYDROGEN FLUORIDE 有权
标题翻译： P OR OP E IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE IDE
公开(公告)号：US20100237279A1
公开(公告)日：2010-09-23
申请号：US12693208
申请日：2010-01-25
申请人： Ryan Hulse , Rajiv R. Singh , Hsueh S. Tung , Ian Shankland
发明人： Ryan Hulse , Rajiv R. Singh , Hsueh S. Tung , Ian Shankland
IPC分类号： C07C21/18 , C09K3/00
CPC分类号： C07C19/08 , C07C17/206 , C07C17/25 , C07C17/383 , C07C21/18
摘要： The invention is directed to a ternary azeotrope-like mixture consisting essentially of effective amounts of 1,1,1,3,3-pentafluoropropane, 1-chloro-3,3,3-trifluoropropene, and hydrogen fluoride.
摘要翻译：本发明涉及基本上由有效量的1,1,1,3,3-五氟丙烷，1-氯-3,3,3-三氟丙烯和氟化氢组成的三元共沸混合物。

8. 发明申请

US20080121837A1 Compositions containing fluorine substituted olefins 审中-公开
标题翻译：含氟取代烯烃的组合物
公开(公告)号：US20080121837A1
公开(公告)日：2008-05-29
申请号：US11773959
申请日：2007-07-06
申请人： Rajiv R. Singh , Ian Shankland , Ryan Hulse
发明人： Rajiv R. Singh , Ian Shankland , Ryan Hulse
IPC分类号： C09K5/02
CPC分类号： C09K5/045 , C09K2205/122 , C09K2205/126
摘要： Disclosed are heat transfer compositions, and methods of using and selecting heat transfer compositions, in which the composition comprises a first component comprising difluoromethane (R-32), and at least one second component selected from group consisting of CF3I, 1,2,3,3,3-pentafluoropropene (HFO 1225ye), and combinations of these, and optionally, but preferably, at least one third component selected from the group consisting of fluorinated C2-C3 compounds, including any combination of two or more fluorinated C2-C3 compounds.
摘要翻译：公开了传热组合物，以及使用和选择传热组合物的方法，其中组合物包含包含二氟甲烷（R-32）的第一组分和至少一种选自CF 3 I，1,2,3 ，3,5-五氟丙烯（HFO 1225ye），以及它们的组合，以及任选但优选至少一种选自氟化C 2 -C 3化合物的第三组分，包括两种或更多种氟化C 2 -C 3 化合物。

9. 发明授权

US08075797B2 Azeotrope-like compositions of pentafluoropropane, chlorotrifluoropropene, and hydrogen fluoride 有权
标题翻译：五氟丙烷，三氟氟丙烯和氟化氢的类共沸组合物
公开(公告)号：US08075797B2
公开(公告)日：2011-12-13
申请号：US12693208
申请日：2010-01-25
申请人： Ryan Hulse , Rajiv R. Singh , Hsueh S. Tung , Ian Shankland
发明人： Ryan Hulse , Rajiv R. Singh , Hsueh S. Tung , Ian Shankland
IPC分类号： C09K5/00 , C09K5/04 , C07C17/00 , C07C19/08 , C07C21/18 , C07C23/00 , C07C25/13 , C11D7/50 , C11D17/00 , C11D17/08
CPC分类号： C07C19/08 , C07C17/206 , C07C17/25 , C07C17/383 , C07C21/18
摘要： The invention is directed to a ternary azeotrope-like mixture consisting essentially of effective amounts of 1,1,1,3,3-pentafluoropropane, 1-chloro-3,3,3-trifluoropropene, and hydrogen fluoride.
摘要翻译：本发明涉及基本上由有效量的1,1,1,3,3-五氟丙烷，1-氯-3,3,3-三氟丙烯和氟化氢组成的三元共沸混合物。

10. 发明授权

US08065882B2 Compositions containing fluorine substituted olefins 有权
标题翻译：含氟取代烯烃的组合物
公开(公告)号：US08065882B2
公开(公告)日：2011-11-29
申请号：US12412342
申请日：2009-03-26
申请人： Rajiv R. Singh , Hang T. Pham , Ian Shankland , Raynond H. Thomas , David P. Wilson
发明人： Rajiv R. Singh , Hang T. Pham , Ian Shankland , Raynond H. Thomas , David P. Wilson
IPC分类号： C09K5/04
CPC分类号： C09K5/045 , A01N29/00 , A23L27/202 , A23V2002/00 , A61K9/008 , A61K47/06 , A61L2/18 , A62D1/00 , A62D1/0028 , A62D1/0057 , B01J31/0231 , B01J37/03 , B01J37/035 , C07C21/18 , C08J9/146 , C08J2203/164 , C08J2207/04 , C08J2325/06 , C09D7/20 , C09K3/00 , C09K3/30 , C09K21/08 , C09K2205/12 , C09K2205/126 , C09K2205/22 , C09K2205/24 , C11B9/0007 , C11D3/245 , C11D11/0047 , C11D17/0043 , Y02A40/965
摘要： Disclosed are the use of fluorine substituted olefins, including tetra- and penta-fluoropropenes, in a variety of applications, including connection with blowing agents, foams, foamable compositions, foaming methods, heat transfer compositions and methods, propellants, and solvating methods.
摘要翻译：公开了在各种应用中使用氟取代的烯烃，包括四氟和五氟丙烯，包括与发泡剂，泡沫，可发泡组合物，发泡方法，传热组合物和方法，推进剂和溶剂化方法的连接。

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