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1. 发明授权

US4739019A Curable epoxy based compositions having reduced shrinkage during cure 失效
标题翻译：可固化的环氧基组合物在固化期间具有降低的收缩率
公开(公告)号：US4739019A
公开(公告)日：1988-04-19
申请号：US938923
申请日：1986-12-08
申请人： Raymond F. Schappert , Robert M. Piccirilli
发明人： Raymond F. Schappert , Robert M. Piccirilli
IPC分类号： C08L67/00 , C08G59/00 , C08G59/18 , C08G59/40 , C08G59/50 , C08L63/00 , C08L63/02 , C08L63/04 , C08L67/02
CPC分类号： C08G59/50 , C08L63/00
摘要： A curable composition is composed of(a) one or more epoxide group containing materials containing at least two epoxide groups per molecule;(b) a positive amount of an effectively thermoplastic polyester, which does not react into the curable composition and is present as a blended ingredient, which does not exceed 40 percent by weight based on the total weight of the epoxide and polyester components of the composition, said polyester having a weight average molecular weight of from about 1,000 to about 8,000, being non-reactive with the one or more epoxide group containing materials and being insoluble in the one or more epoxide group containing materials of (a); and(c) a curing agent adapted to cure the one or more epoxide group containing materials of (a).
摘要翻译：可固化组合物由（a）每分子含有至少两个环氧基团的一种或多种含环氧基团的材料组成; （b）正极量的有效热塑性聚酯，其不会与可固化组合物反应，并且以混合成分的形式存在，其不超过基于组合物的环氧化物和聚酯组分的总重量的40重量％所述聚酯具有约1,000至约8,000的重均分子量，与一种或多种含环氧基团的材料不反应并且不溶于所述一种或多种含环氧基团的材料（a）; 和（c）适于固化含有（a）的一种或多种含环氧基的材料的固化剂。

2. 发明授权

US4822683A Method for preparing an adhesive bond with a curable composition having reduced shrinkage during cure 失效
标题翻译：用于固化时具有降低的收缩率的可固化组合物制备粘合剂粘合剂的方法
公开(公告)号：US4822683A
公开(公告)日：1989-04-18
申请号：US117262
申请日：1987-11-06
申请人： Raymond F. Schappert , Robert M. Piccirilli
发明人： Raymond F. Schappert , Robert M. Piccirilli
IPC分类号： C08G59/50 , C08L63/00 , B32B27/38 , C09J5/02
CPC分类号： C08G59/50 , C08L63/00 , Y10T428/31515
摘要： A method of forming an adhesive bond between two surfaces to form a bonded structure involves the stepsI. applying to at least one of the surfaces a curable composition containing:(i) one or more epoxide group containing materials containing at least two epoxide groups per molecule;(ii) a positive amount of an effectively thermoplastic polyester, which does not react into the curable composition and is present as a blended ingredient, which does not exceed 40 percent by weight based on the total weight of the epoxide and polyester components of the composition, said polyester having a weight average molecular weight from about 1,000 to about 8,000, being nonreactive with the one or more epoxide group containing materials of (a) and being insoluble in the one or more epoxide group containing materials of (i); and(iii) a curing agent adapted to cure the epoxide group containing materials of (i); andII. at least partially curing the curable composition to form the bonded structure.
摘要翻译：在两个表面之间形成粘合剂结合以形成粘合结构的方法包括步骤I.将至少一个表面施加到可固化组合物上，所述可固化组合物含有：（i）含有至少两个环氧基团的一种或多种含环氧基团的材料分子; （ii）正极量的有效热塑性聚酯，其不会与可固化组合物反应并以混合成分存在，其不超过基于组合物的环氧化物和聚酯组分的总重量的40重量％所述聚酯具有约1,000至约8,000的重均分子量，与（a）的一种或多种含环氧基团的材料不反应并且不溶于含有（i）的一种或多种含环氧基的物质; 和（iii）适于固化含有（i）的材料的环氧基的固化剂; 和II。至少部分固化可固化组合物以形成键合结构。

3. 发明授权

US4410667A Elastomeric coating compositions 失效
标题翻译：弹性涂料组合物
公开(公告)号：US4410667A
公开(公告)日：1983-10-18
申请号：US343784
申请日：1982-01-29
申请人： Samuel Porter, Jr. , Robert M. Piccirilli , Wen-Hsuan Chang , James B. O'Dwyer , Kyu-Wang Lee
发明人： Samuel Porter, Jr. , Robert M. Piccirilli , Wen-Hsuan Chang , James B. O'Dwyer , Kyu-Wang Lee
IPC分类号： C08G18/12 , C08G18/40 , C08G18/42 , C09D167/00 , C08L67/02 , C08L75/04 , C08L61/24 , C08L61/28
CPC分类号： C08G18/12 , C08G18/4081 , C08G18/423 , C09D167/00
摘要： Thermosetting elastomeric coating compositions are disclosed. The resinous binder of the coating compositions is based on a hard polyester polyol containing cyclic moieties plasticized with a blend of soft polyurethane polyols, one of which has a high molecular weight and one of which has a low molecular weight, and cured with a curing agent capable of reacting with active hydrogens, for example, an aminoplast curing agent. The coating compositions are resistant to solvent popping and are particularly useful on elastomeric substrates such as high density polyurethane foams, as well as on metal substrates such as steel and aluminum.
摘要翻译：公开了热固性弹性体涂料组合物。涂料组合物的树脂粘合剂基于硬聚酯多元醇，其含有用软聚氨酯多元醇共混物增塑的环状部分，其中一种具有高分子量，其中一种具有低分子量，并用固化剂固化能够与活性氢反应，例如氨基塑料固化剂。涂料组合物对溶剂爆裂具有抗性，并且在弹性体基材例如高密度聚氨酯泡沫以及金属基材如钢和铝上特别有用。

4. 发明授权

US4788108A Ultraviolet light curable compositions based on iminated unsaturated polyesters for application to porous substrates 失效
标题翻译：基于用于多孔基材的亚胺化不饱和聚酯的紫外线光固化组合物
公开(公告)号：US4788108A
公开(公告)日：1988-11-29
申请号：US62029
申请日：1987-06-15
申请人： John B. Saunders, Jr. , Robert M. Piccirilli , William J. Schillinger , Ken W. Niederst
发明人： John B. Saunders, Jr. , Robert M. Piccirilli , William J. Schillinger , Ken W. Niederst
IPC分类号： B05D7/24 , B27K5/00 , C08G63/91 , C09D167/06 , B32B27/10 , C08G63/46
CPC分类号： B05D7/08 , C08G63/918 , C09D167/06 , B05D3/067 , Y10T428/3179
摘要： Disclosed is a curable filler composition which resists absorption into a porous substrate, particularly one derived from wood, comprising: (1) a liquid, ungelled binder of an unsaturated polyester resin having number average molecular weight of from 500 to 3,000 derived from an ethylenically unsaturated carboxylic acid or anhydride thereof, the unsaturated polyester resin having been iminated with an alkylenimine, (2) one or more ethylenically unsaturated compounds different from and cocurable with the unsaturated polyester resin, (3) pigment, (4) a free radical initiator, and (5) optionally a carrier solvent for the filler composition.Disclosed is a method of minimizing absorption of a filler composition into a warm or hot porous substrate.Also disclosed is a porous substrate, particularly one derived from wood, having adhered to a substrate thereof the cured filler composition.
摘要翻译：公开了一种可吸收多孔基材的可固化填料组合物，特别是衍生自木材的可固化填料组合物，其包括：（1）数均分子量为500-3000的不饱和聚酯树脂的液态未凝胶粘合剂，其衍生自烯属不饱和羧酸或其酸酐，不饱和聚酯树脂已用亚烷基亚胺，（2）一种或多种烯不饱和化合物与不饱和聚酯树脂不同并可共嵌出，（3）颜料，（4）自由基引发剂和（5）任选的填料组合物的载体溶剂。公开了一种使填料组合物吸收到温热或多孔基材中的方法。还公开了一种多孔基材，特别是衍生自木材的多孔基材，其粘附到其基材上固化的填料组合物。

5. 发明授权

US4569966A Polymeric microparticles 失效
标题翻译：聚合微粒
公开(公告)号：US4569966A
公开(公告)日：1986-02-11
申请号：US602048
申请日：1984-04-19
申请人： Robert M. Piccirilli , David T. McKeough , Wen-Hsuan Chang
发明人： Robert M. Piccirilli , David T. McKeough , Wen-Hsuan Chang
IPC分类号： C08G18/00 , C08G18/08 , C08G18/10 , C08G18/12 , C08G18/36 , C08G18/42 , C08G18/62 , C08G18/64 , C09D7/12 , C09D167/00 , C09D175/06 , C09D3/72
CPC分类号： C08G18/12 , C08G18/0823 , C08G18/0871 , C08G18/10 , C08G18/36 , C08G18/4288 , C08G18/6229 , C08G18/6407 , C09D167/00 , C08G2150/20 , C08G2220/00 , Y10T428/31 , Y10T428/315 , Y10T428/31504 , Y10T428/31511 , Y10T428/31551 , Y10T428/31594 , Y10T428/31678 , Y10T428/31688 , Y10T428/31794
摘要： Polymeric microparticles and dispersions of polymeric microparticles in a liquid hydrocarbon are disclosed. The dispersions are prepared by reacting in dispersed form a preformed NCO-prepolymer containing a segment solvated by the liquid hydrocarbon and a segment insoluble in the liquid hydrocarbon with an active hydrogen-containing compound. Reaction proceeds to form polymeric microparticles which are dispersed in the liquid hydrocarbon. Also disclosed are the use of the polymeric microparticles in coating compositions and articles coated with the coating compositions.
摘要翻译：公开了聚合微粒在液态烃中的聚合物微粒和分散体。分散体通过分散形式制备，其中预制的NCO-预聚物含有由液态烃溶剂化的链段和不溶于液态烃的链段与含活性氢的化合物。反应进行以形成分散在液态烃中的聚合物微粒。还公开了在涂料组合物和用涂料组合物涂覆的制品中使用聚合物微粒。

6. 发明授权

US4693846A Urethane-modified rosin esters 失效
标题翻译：聚氨酯改性松香酯
公开(公告)号：US4693846A
公开(公告)日：1987-09-15
申请号：US861171
申请日：1986-05-09
申请人： Robert M. Piccirilli , Roger M. Christenson , Frederick A. Falk , Joseph M. Makhlouf
发明人： Robert M. Piccirilli , Roger M. Christenson , Frederick A. Falk , Joseph M. Makhlouf
IPC分类号： C08G18/34 , C08G18/32 , C08G18/42 , C08G18/64 , C09D11/08 , C09D11/10 , C09F1/04 , C08L93/04
CPC分类号： C08G18/4205 , C08G18/3221 , C08G18/6492 , C09D11/08 , C09F1/04
摘要： The present invention encompasses a urethane-modified rosin ester which is derived from an isocyanate and a hydroxyl-functional rosin esterification product of a dimerized rosin. The urethane-modified rosin esters, having a high softening point and good compatibility with hydrocarbon solvents, good gelability and good squalene resistance, are particularly suitable as binders for inks such as fast conversion lithographic inks.
摘要翻译：本发明包括衍生自二聚松香的异氰酸酯和羟基官能化松香酯化产物的氨基甲酸酯改性松香酯。具有高软化点和与烃溶剂的良好相容性，良好的胶凝性和良好的抗角鲨烯耐性的氨基甲酸酯改性松香酯特别适用于油墨如快速转化平版印刷油墨的粘合剂。

7. 发明授权

US4410668A Elastomeric coating compositions 失效
标题翻译：弹性涂料组合物
公开(公告)号：US4410668A
公开(公告)日：1983-10-18
申请号：US344082
申请日：1982-01-29
申请人： Robert M. Piccirilli , Wen-Hsuan Chang , Samuel Porter, Jr. , James B. O'Dwyer , Kyu-Wang Lee
发明人： Robert M. Piccirilli , Wen-Hsuan Chang , Samuel Porter, Jr. , James B. O'Dwyer , Kyu-Wang Lee
IPC分类号： C08G18/10 , C08G18/40 , C08J9/36 , C09D167/00 , C08L61/32 , C08L67/04
CPC分类号： C08G18/10 , C08G18/4081 , C08J9/365 , C09D167/00
摘要： Thermosetting elastomeric coating compositions are disclosed. The resinous binder of the coating compositions is based on a hard polyester polyol containing cycloaliphatic moieties plasticized with a soft polyurethane polyol and cured with a curing agent capable of reacting with active hydrogens, for example, an aminoplast curing agent. The coating compositions are particularly useful on elastomeric substrates such as high density polyurethane foams, as well as on metal substrates such as steel and aluminum.
摘要翻译：公开了热固性弹性体涂料组合物。涂料组合物的树脂粘合剂是基于硬聚酯多元醇，其含有用软质聚氨酯多元醇增塑的脂环族部分，并用能够与活性氢例如氨基塑料固化剂反应的固化剂固化。涂料组合物特别适用于弹性体基材，如高密度聚氨酯泡沫，以及金属基材如钢和铝。

8. 发明授权

US4639492A Phenolic-modified rosin esters 失效
标题翻译：酚改性松香酯
公开(公告)号：US4639492A
公开(公告)日：1987-01-27
申请号：US764028
申请日：1985-08-09
申请人： Joseph M. Makhlouf , Frederick A. Falk , Robert M. Piccirilli
发明人： Joseph M. Makhlouf , Frederick A. Falk , Robert M. Piccirilli
IPC分类号： C08G8/34 , C09D11/02 , C09F1/04 , C09F7/08
CPC分类号： C09F1/04 , C08G8/34 , C09D11/02
摘要： The present invention encompasses a phenolic-modified rosin ester which is derived from a rosin esterification product of a dimerized rosin and a phenolic resin. The phenolic-modified rosin esters, having a high softening point and good compatibility with hydrocarbon solvents and good gelability, are particularly suitable as binders for inks such as lithographic inks.
摘要翻译：本发明包括衍生自二聚松香和酚醛树脂的松香酯化产物的酚改性松香酯。具有高软化点和与烃溶剂的良好相容性和良好的胶凝性的酚改性松香酯特别适用于油墨如平版印刷油墨的粘合剂。

9. 发明授权

US4419407A Elastomeric coating compositions 失效
标题翻译：弹性涂料组合物
公开(公告)号：US4419407A
公开(公告)日：1983-12-06
申请号：US343785
申请日：1982-01-29
申请人： Robert M. Piccirilli , Wen-Hsuan Chang , Samuel Porter, Jr. , James B. O'Dwyer , Kyu-Wang Lee
发明人： Robert M. Piccirilli , Wen-Hsuan Chang , Samuel Porter, Jr. , James B. O'Dwyer , Kyu-Wang Lee
IPC分类号： C09D161/20 , C08G18/10 , C08G18/40 , C08G18/42 , C09D167/00 , C09D167/02 , C09D175/00 , C09D175/04 , C09D175/06 , B32B27/40
CPC分类号： C09D167/00 , C08G18/10 , C08G18/4009 , C08G18/423 , C09D175/04 , Y10T428/31551
摘要： High solids thermosetting elastomeric coating compositions are disclosed. The resinous binder of the coating compositions is based on a hard polyester polyol containing cyclic moieties plasticized with a soft polyurethane polyol and cured with a curing agent capable of reacting with active hydrogens, for example, an aminoplast curing agent. The coating compositions are particularly useful on elastomeric substrates such as high density polyurethane foams, as well as on metal substrates such as steel and aluminum.
摘要翻译：公开了高固体热固性弹性体涂料组合物。涂料组合物的树脂粘合剂是基于硬聚酯多元醇，其含有用软质聚氨酯多元醇增塑的环状部分，并用能够与活性氢例如氨基塑料固化剂反应的固化剂固化。涂料组合物特别适用于弹性体基材，如高密度聚氨酯泡沫，以及金属基材如钢和铝。

10. 发明授权

US4205115A Polyester coating composition 失效
标题翻译：聚酯涂料组合物
公开(公告)号：US4205115A
公开(公告)日：1980-05-27
申请号：US897963
申请日：1978-04-19
申请人： Robert M. Piccirilli , Wen-Hsuan Chang , David T. McKeough , Samuel Porter, Jr.
发明人： Robert M. Piccirilli , Wen-Hsuan Chang , David T. McKeough , Samuel Porter, Jr.
IPC分类号： C08G63/00 , C08G18/42 , C08G18/46 , C08G63/12 , C08G63/20 , C08G63/685 , C09D167/00 , C09D167/02 , C09D177/00 , B32B27/40 , B32B27/06 , B32B27/36
CPC分类号： C08G63/20 , C08G18/4205 , C08G18/4219 , C08G18/4615 , C09D167/00 , Y10T428/263 , Y10T428/31551 , Y10T428/31794 , Y10T428/31797 , Y10T428/31942
摘要： Coating compositions having a high degree of elasticity, as well as toughness, durability and good metallic pigment pattern control are disclosed. This combination of properties makes the coatings particularly desirable for use on elastomeric substrates such as those associated with automobiles. The coating compositions comprise as a resinous component, an ungelled hydroxyl-containing polyester of high weight average molecular weight. The polyesters can be cured with a curative such as an aminoplast to give coatings having outstanding elastomeric properties and good pigment dispersibility, particularly good metallic pigment pattern control, properties not normally associated with polyesters for use in coating applications.
摘要翻译：公开了具有高弹性以及韧性，耐久性和良好的金属颜料图案控制的涂料组合物。这种性质的组合使得涂层特别适用于弹性体基底，例如与汽车相关的基底。涂料组合物包含作为树脂组分的高均匀分子量的未凝胶化含羟基聚酯。聚酯可以用诸如氨基塑料的固化剂固化，得到具有突出的弹性性质和良好的颜料分散性的涂料，特别是良好的金属颜料图案控制，通常不与用于涂料应用的聚酯缔合的性质。

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