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    • 2. 发明授权
    • Adherent, removable barrier film for tire carcass
    • 用于轮胎胎体的粘附,可移除的阻隔膜
    • US07332047B2
    • 2008-02-19
    • US10308773
    • 2002-12-03
    • Ramendra Nath MajumdarBrian Matthew LoganLewis Timothy Lukich
    • Ramendra Nath MajumdarBrian Matthew LoganLewis Timothy Lukich
    • B29D30/00F16F15/34
    • B29D30/0662B29C37/0025B29C37/0075B29D30/0685B29D2030/0686B29D2030/0695B29D2030/0697B60C5/14B60C11/00B60C11/1346B60C13/00B60C13/002B60C19/00B60C19/003Y10T152/10495
    • A bond of a rubbery component to a virgin surface of a tire's cured innerliner which virgin surface has never been contaminated by the remnants of a release agent left after buffing with a wire brush and solvent-cleaning the cured innerliner, is unexpectedly stronger than a bond of the component to the contaminated but “cleaned surface”, cleaned as indicated. As an alternative, buffing with a wire brush results in a textured surface that impairs adhesion of a balance pad. Therefore, a pneumatic tire is provided with a virgin surface protected against contamination by a release agent at the curing temperature of the tire; protection is provided by a self-supporting barrier film of sulfur non-vulcanizable, expandable, thermoformable synthetic resinous material; and, a method is provided for maintaining a virgin cured surface within all or part of either the exterior or interior of a pneumatic tire's rubber carcass which is conventionally cured. The barrier film which is substantially inextensible at ambient temperature, is removable without tearing into pieces from the protected surface of the cured tire. When the interior surface is provided by an innerliner, any component to be included within the interior of the carcass may be adhesively secured to the virgin surface of the innerliner more securely than has been heretofore possible.
    • 橡胶组分与轮胎的固化内衬的原始表面的粘合,其中原始表面从未被用丝刷抛光后留下的脱模剂的残余物和溶剂清洁固化的内衬层所污染,其意外地比粘合强 的污染但“被清洁的表面”,按照指示进行清洁。 作为替代方案,用丝刷抛光导致纹理表面损坏平衡垫的粘附。 因此,充气轮胎具有在轮胎的固化温度下防止脱模剂污染的原始表面; 由硫磺不可硫化,可膨胀,可热成形的合成树脂材料的自支撑阻挡膜提供保护; 并且提供了一种在常规固化的充气轮胎的橡胶胎体的外部或内部的全部或部分内部维持原始固化表面的方法。 在环境温度下基本上不可延伸的阻挡膜是可移除的,而不会从硫化轮胎的受保护表面撕裂成块。 当内表面由内衬层提供时,包括在胎体内部的任何部件可以比以前更可靠地与内衬的原始表面粘结固定。
    • 3. 发明授权
    • Cured applique or label with protective film on arcuate sidewall or tread of pneumatic tire
    • 固化贴花或带有保护膜的标签在充气轮胎的弧形侧壁或胎面上
    • US07153381B2
    • 2006-12-26
    • US10308798
    • 2002-12-03
    • Ramendra Nath MajumdarLewis Timothy LukichMarvin Wayne Tipton
    • Ramendra Nath MajumdarLewis Timothy LukichMarvin Wayne Tipton
    • B29D30/72B60C13/00
    • G09F3/0297B29C2037/80B29D2030/726B29L2031/744B60C13/001G09F3/04
    • An applique having a vulcanizable adhesive layer is co-cured on a rubber article by precuring the applique of predominantly pale natural rubber optionally imprinted with a bar code; coating the upper surface of the applique with a protective self-supporting film of polyamide less than 0.050 mm (2 mils) thick, or a non-self-supporting film of polyurethane less than 25.4 μm, 0.0254 mm (1 mil) thick; adhering the applique to the article at a chosen location; curing the article in a curing mold; and, removing a cured article from the mold with the protective film adhering to the surface of the applique, the surface of which is essentially free from visually observable cracks. The hot flow of rubber in the curing mold does not substantially change the location of the applique which is embedded in the article. If the film does not remain adhered to a cured tire and drops into the mold, it is difficult to retrieve and, when a subsequent article is cured in the same mold, results in a scrap tire.
    • 具有可硫化粘合剂层的贴花通过预先固化主要为浅灰色天然橡胶的贴花而可选地印有条形码,在橡胶制品上共固化; 用小于0.050mm(2密耳)厚的聚酰胺的保护性自支撑膜或不超过25.4μm,0.0254mm(1密耳)厚的聚氨酯的非自支撑膜涂覆贴花的上表面; 将贴纸贴在选定位置的文章上; 在固化模具中固化物品; 并且将固化的物品从模具中除去附着在贴花表面上的保护膜,其表面基本上没有视觉可见的裂纹。 固化模具中橡胶的热流量基本上不改变嵌入在制品中的贴花的位置。 如果胶片不保持粘附在固化轮胎上并落入模具中,则很难回收,并且当后续制品在相同模具中固化时,导致废轮胎。
    • 4. 发明授权
    • Use of fullerene carbon in curable rubber compounds
    • 在可固化橡胶化合物中使用富勒烯碳
    • US5750615A
    • 1998-05-12
    • US757713
    • 1996-11-26
    • Lewis Timothy LukichThomas Edwin DuncanColleen Marie Lansinger
    • Lewis Timothy LukichThomas Edwin DuncanColleen Marie Lansinger
    • B60C1/00B29D30/04B29K9/00C08K3/04C08K3/36C08L9/00C08L21/00
    • C08K3/04Y10S423/40Y10S977/753
    • This invention relates to curable rubber compositions containing a fullerene form of carbon which is used as a reinforcing agent in the rubber compositions, the fullerene form of carbon being used in place of at least a portion of, or in addition to, the normally used forms of carbon black reinforcement additives. The invention particularly relates to tires having treads composed of such rubber composition(s). The fullerenes may optionally have surface modifications such as partial or complete hydrogen or functional group substitution. The fullerene form of non-conventional carbon reinforcement of rubber composition(s) may exist as discrete particles, aggregates of particles and/or agglomerates. The carbon fullerene has a lower specific gravity than conventional carbon black, thereby allowing a reduced weight tire or other article made from the rubber compound(s) for comparable volumes of carbon black used.
    • 本发明涉及含有富勒烯形式的碳的可固化橡胶组合物,其用作橡胶组合物中的增强剂,所述富勒烯形式的碳用于代替正常使用的形式的至少一部分或除了常规使用的形式 的炭黑增强添加剂。 本发明特别涉及具有由这种橡胶组合物构成的胎面的轮胎。 富勒烯可以任选地具有表面改性,例如部分或完全氢或官能团取代。 橡胶组合物的非常规碳增强物的富勒烯形式可以作为离散颗粒,颗粒和/或附聚物的聚集体存在。 碳富勒烯具有比常规炭黑更低的比重,从而允许减少重量的轮胎或由橡胶化合物制成的其它制品用于使用相当体积的炭黑。