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    • 1. 发明授权
    • Color photographic print material
    • 彩色照相打印材料
    • US06890707B2
    • 2005-05-10
    • US10612809
    • 2003-07-02
    • Ralf WeimannMarkus GeigerCuong LyKlaus SinzgerBeate WeberHeinz Wiesen
    • Ralf WeimannMarkus GeigerCuong LyKlaus SinzgerBeate WeberHeinz Wiesen
    • G03C5/08G03C1/035G03C1/09G03C5/04G03C7/00G03C7/30G03C7/34G03C7/392G03C1/08G03C7/25G03C7/32
    • G03C7/346G03C1/09G03C5/04G03C7/30G03C7/3022G03C7/39204G03C2001/03517G03C2001/093G03C2200/19
    • A print material having a support, at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, characterised in that the silver halide crystals of the red-sensitive layer have a chloride content of at least 95 mol %, contain 20 to 500 nmol of iridium per mol of silver halide and the cyan coupler is of the formula in which R1 means a hydrogen atom or an alkyl group, R2 means an alkyl, aryl or hetaryl group, R3 means an alkyl or aryl group, R4 means an alkyl, alkenyl, alkoxy, aryloxy, acyloxy, acylamino, sulfonyloxy, sulfamoylamino, sulfonamido, ureido, hydroxycarbonyl, hydroxycarbonylamino, carbamoyl, alkylthio, arylthio, alkylamino or arylamino group or a hydrogen atom and Z means a hydrogen atom or a group eliminable under the conditions of chromogenic development, is distinguished in that it is equally ideally suitable for analogue and scanning exposure and exhibits very good latent image stability.
    • 具有载体的印刷材料,至少一种含有至少一种青色成色剂的感红卤化银乳剂层,至少一种包含至少一种品红成色剂的至少一种感光卤化银乳剂层和至少一种感蓝卤化银乳剂 含有至少一种黄色成色剂的层,其特征在于,红色敏感层的卤化银晶体的氯化物含量为至少95摩尔%,每摩尔卤化银含有20-500nmol的铱,青色成色剂为 其中R 1表示氢原子或烷基的式R 2是指烷基,芳基或杂芳基,R 3表示 烷基或芳基,R 4表示烷基,烯基,烷氧基,芳氧基,酰氧基,酰氨基,磺酰氧基,氨磺酰氨基,亚磺酰氨基,脲基,羟基羰基,羟基羰基氨基,氨基甲酰基,烷硫基,芳硫基,烷基氨基或芳基氨基 基团或氢原子,Z表示氢原子或取代基 在显色发展的条件下,其特征在于它同样理想地适用于模拟和扫描曝光,并且表现出非常好的潜像稳定性。
    • 2. 发明授权
    • Colour photographic silver halide material
    • 彩色照相卤化银材料
    • US06783924B2
    • 2004-08-31
    • US10612560
    • 2003-07-02
    • Ralf WeimannMarkus GeigerCuong LyKlaus SinzgerBeate WeberHeinz Wiesen
    • Ralf WeimannMarkus GeigerCuong LyKlaus SinzgerBeate WeberHeinz Wiesen
    • G03C108
    • G03C1/18G03C1/127G03C5/04G03C7/30G03C7/3006G03C7/346G03C7/3926G03C7/39276G03C2200/19
    • A color photographic silver halide material comprising a substrate, at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, characterised in that the silver halide crystals of the red-sensitive layer have a chloride content of at least 95 mol %, the cyan coupler corresponding to formula wherein R1 represents a hydrogen atom or an alkyl group, R2 represents an alkyl, aryl or hetaryl group R3 represents an alkyl or aryl group, R4 represents an alkyl, alkenyl, alkoxy, aryloxy, acyloxy, acylamino, sulphonyloxy, sulphamoylamino, sulphonamido, ureido, hydroxycarbonyl, hydroxycarbonylamino, carbamoyl, alkylthio, arylthio, alkylamino or arylamino group or a hydrogen atom and Z represents a hydrogen atom or a group which may be split off under the conditions of chromogenic development and the red-sensitive layer contains at least one compound of formula wherein R5 represents H, CH3 or OCH3, R6 represents H, OH, CH3, OCH3, NHCO—R7, COOR7, SO2NH2, NHCONH2 or NHCONH—CH3 and R7 represents C1 to C4 alkyl, is distinguished by very good stability in storage simultaneously with very good latent image stability.
    • 一种彩色照相卤化银材料,其包含基材,至少一种含有至少一种青色成色剂的感红卤化银乳剂层,至少一种包含至少一种品红色成色剂的至少一种感绿卤化银乳剂层和至少一种蓝色敏感性 含有至少一种黄色成色剂的卤化银乳剂层,其特征在于,所述红色感光层的卤化银晶体的氯化物含量为至少95摩尔%,对应于其中的青色成色剂R 1表示氢原子或 烷基,R 2表示烷基,芳基或杂芳基R 3表示烷基或芳基,R 4表示烷基,烯基,烷氧基,芳氧基,酰氧基,酰氨基,磺酰氧基,氨磺酰氨基,磺酰氨基,脲基 ,羟基羰基,羟基羰基氨基,氨基甲酰基,烷硫基,芳硫基,烷基氨基或芳基氨基或氢原子,Z表示氢原子或可以在条件o f显色发育和红敏层含有至少一种糠醛的化合物,R 5表示H,CH 3或OCH 3,R 6表示H,OH,CH 3,OCH 3,NHCO-R 7,COOR 7, SO 2 NH 2,NHCONH 2或NHCONH-CH 3和R 7表示C 1至C 4烷基,其特征在于非常好的保存稳定性,同时具有非常好的潜像稳定性。
    • 3. 发明授权
    • Color photographic print material
    • 彩色照相打印材料
    • US06806042B2
    • 2004-10-19
    • US10612132
    • 2003-07-02
    • Ralf WeimannMarkus GeigerCuong LyKlaus SinzgerBeate WeberHeinz Wiesen
    • Ralf WeimannMarkus GeigerCuong LyKlaus SinzgerBeate WeberHeinz Wiesen
    • G03C108
    • G03C7/346G03C5/04G03C7/30G03C7/3022G03C7/3882G03C7/3885G03C2001/03517G03C2200/19
    • A print material having a support, at least one red-sensitive silver halide emulsion layer containing at least one cyan coupler, at least one green-sensitive silver halide emulsion layer containing at least one magenta coupler and at least one blue-sensitive silver halide emulsion layer containing at least one yellow coupler, characterised in that the red-sensitive layer contains at least one oil former, the cyan coupler is of the formula in which R1 means a hydrogen atom or an alkyl group, R2 means an alkyl, aryl or hetaryl group, R3 means an alkyl or aryl group, R4 means an alkyl, alkenyl, alkoxy, aryloxy, acyloxy, acylamino, sulfonyloxy, sulfamoylamino, sulfonamido, ureido, hydroxycarbonyl, hydroxycarbonylamino, carbamoyl, alkylthio, arylthio, alkylamino or arylamino group or a hydrogen atom and Z means a hydrogen atom or a group eliminable under the conditions of chromogenic development, and the ratio by weight of oil former to cyan coupler is less than 1:1, is distinguished by excellent colour reproduction.
    • 具有载体的印刷材料,至少一种含有至少一种青色成色剂的感红卤化银乳剂层,至少一种包含至少一种品红成色剂的至少一种感光卤化银乳剂层和至少一种感蓝卤化银乳剂 该层包含至少一个黄色成色剂,其特征在于该红色敏感层含有至少一种成油剂,青色成色剂是式(1)表示氢原子或烷基,R 2表示烷基 ,芳基或杂芳基,R 3表示烷基或芳基,R 4表示烷基,烯基,烷氧基,芳氧基,酰氧基,酰氨基,磺酰氧基,氨磺酰氨基,亚磺酰氨基,脲基,羟基羰基,羟基羰基氨基,氨基甲酰基, ,芳硫基,烷基氨基或芳基氨基或氢原子,Z表示氢原子或在显色条件下可消除的基团,成油剂与青色成色剂的重量比小于1:1,由ex 细胞色彩再现。