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1. 发明申请

US20050154235A1 Method for producing ethyldimethylamine and triethylamine 失效
标题翻译：乙基二甲基胺和三乙胺的制备方法
公开(公告)号：US20050154235A1
公开(公告)日：2005-07-14
申请号：US10506514
申请日：2003-03-03
申请人： Ralf Bohling , Ulrich Steinbrenner , Frank Funke , Gunter Muller , Gunter Gaus , Christoph Benisch
发明人： Ralf Bohling , Ulrich Steinbrenner , Frank Funke , Gunter Muller , Gunter Gaus , Christoph Benisch
IPC分类号： C07B61/00 , C07C209/60 , C07C211/05 , C07C211/08 , C07C29/08
CPC分类号： C07C209/60 , C07C211/05 , C07C211/08
摘要： The present invention describes a process for the preparation of ethyldimethylamine and triethylamine with the following steps: (i) reaction of a mixture of diethylamine and dimethylamine with ethylene in the presence of a catalyst from the group of alkali metal dimethylamides, alkali metal diethylamides and alkali metal hydrides (ii) removal of the catalyst (iii) distillation separation of the resulting mixture in triethylamine and ethyldimethylamine and optionally diethylamine and dimethylamine (iv) optional return of the catalyst and of the starting amines to the reaction. The process according to the invention permits the coproduction of ethyldimethylamine and diethylamine in a simple process.
摘要翻译：本发明描述了一种用于制备乙基二甲基胺和三乙胺的方法，其步骤如下：（i）二乙胺和二甲基胺的混合物与乙烯在催化剂存在下由碱金属二甲基酰胺，碱金属二乙基酰胺和碱金属氢化物（ii）除去催化剂（iii）将所得混合物蒸馏分离在三乙胺和乙基二甲胺和任选的二乙胺和二甲胺中（iv）任选地将催化剂和起始胺返回到反应中。根据本发明的方法允许以简单的方法共同生产乙基二甲胺和二乙胺。

2. 发明授权

US07253322B2 Method for producing ethyldimethylamine and triethylamine 失效
标题翻译：乙基二甲基胺和三乙胺的制备方法
公开(公告)号：US07253322B2
公开(公告)日：2007-08-07
申请号：US10506514
申请日：2003-03-03
申请人： Ralf Böhling , Ulrich Steinbrenner , Frank Funke , Günter Müller , Günter Gaus , Christoph Benisch
发明人： Ralf Böhling , Ulrich Steinbrenner , Frank Funke , Günter Müller , Günter Gaus , Christoph Benisch
IPC分类号： C07C209/60
CPC分类号： C07C209/60 , C07C211/05 , C07C211/08
摘要： The present invention describes a process for the preparation of ethyldimethylamine and triethylamine with the following steps: (i) reaction of a mixture of diethylamine and dimethylamine with ethylene in the presence of a catalyst from the group of alkali metal dimethylamides, alkali metal diethylamides and alkali metal hydrides (ii) removal of the catalyst (iii) distillation separation of the resulting mixture in triethylamine and ethyldimethylamine and optionally diethylamine and dimethylamine (iv) optional return of the catalyst and of the starting amines to the reaction. The process according to the invention permits the coproduction of ethyldimethylamine and diethylamine in a simple process.
摘要翻译：本发明描述了一种用于制备乙基二甲基胺和三乙胺的方法，其步骤如下：（i）二乙胺和二甲胺的混合物与乙烯在催化剂存在下由碱金属二甲基酰胺，碱金属二乙基酰胺和碱金属氢化物（ii）除去催化剂（iii）将所得混合物蒸馏分离在三乙胺和乙基二甲胺和任选的二乙胺和二甲胺中（iv）任选地将催化剂和起始胺返回到反应中。根据本发明的方法允许以简单的方法共同生产乙基二甲胺和二乙胺。

3. 发明授权

US06677486B2 Hydrogenation of nitriles over Raney catalysts 失效
标题翻译：在阮内催化剂上氢化腈
公开(公告)号：US06677486B2
公开(公告)日：2004-01-13
申请号：US09985982
申请日：2001-11-07
申请人： Andreas Ansmann , Christoph Benisch , Frank Funke , Frank Ohlbach , Martin Merger
发明人： Andreas Ansmann , Christoph Benisch , Frank Funke , Frank Ohlbach , Martin Merger
IPC分类号： C07C2948
CPC分类号： C07D295/13 , B01J25/00 , B01J37/0018 , C07C209/48 , C07C211/14 , C07C211/36
摘要： Nitriles are hydrogenated to primary amines over an activated, alpha-Al2O3-containing, macroporous Raney catalyst based on an alloy of aluminum and at least one transition metal selected from the group consisting of iron, cobalt and nickel, and, if desired, one or more further transition metals selected from the group consisting of titanium, zirconium, chromium and manganese, which is obtainable by a process comprising the steps in the order (a)-(f): (a) preparing a kneadable composition comprising the alloy, a shaping aid, water and a pore former; (b) shaping the kneadable composition to form a shaped body; (c) calcining the shaped body; (d) activating the calcined shaped body by treatment with aqueous alkali metal hydroxide solution; (e) rinsing the shaped catalyst body with aqueous alkali metal hydroxide solution; (f) rinsing the shaped catalyst body with water.
摘要翻译：基于铝和至少一种选自铁，钴和镍的过渡金属的合金，并且如果需要，腈在一种活化的含α-Al 2 O 3的大孔阮内催化剂上氢化成伯胺，如果需要，（a） - （f）：（a）制备包含该合金的可捏合组合物的方法可以获得更多的选自钛，锆，铬和锰的过渡金属，成型助剂，水和成孔剂;（b）使捏合组合物成形以形成成形体;（c）煅烧成形体;（d）用碱金属氢氧化物水溶液处理活化煅烧成形体;（e）用碱金属氢氧化物水溶液冲洗成型的催化剂体;（f）用水冲洗成型的催化剂体。

4. 发明授权

US07053246B2 Preparation of a symmetrical secondary amine 失效
标题翻译：对称仲胺的制备
公开(公告)号：US07053246B2
公开(公告)日：2006-05-30
申请号：US10731095
申请日：2003-12-10
申请人： Till Gerlach , Frank Funke , Christoph Benisch , Johann-Peter Melder
发明人： Till Gerlach , Frank Funke , Christoph Benisch , Johann-Peter Melder
IPC分类号： C07C29/04
CPC分类号： C07C209/64 , C07C211/14
摘要： Process for preparing a symmetrical secondary amine by reaction of a primary amine in the presence of hydrogen and a catalyst whose preparation has involved precipitation of catalytically active components onto monoclinic, tetragonal or cubic zirconium dioxide.
摘要翻译：通过伯胺在氢气和催化剂的反应下制备对称仲胺的方法，其制备涉及将催化活性组分沉淀到单斜晶，四方晶或立方二氧化锆上。

5. 发明授权

US06469211B2 Hydrogenation of nitriles over Raney catalysts 失效
标题翻译：在阮内催化剂上氢化腈
公开(公告)号：US06469211B2
公开(公告)日：2002-10-22
申请号：US09987243
申请日：2001-11-14
申请人： Andreas Ansmann , Christoph Benisch , Frank Funke , Frank Ohlbach , Martin Merger
发明人： Andreas Ansmann , Christoph Benisch , Frank Funke , Frank Ohlbach , Martin Merger
IPC分类号： C07C20948
CPC分类号： C07C209/48 , C07C211/14
摘要： In a process for the continuous hydrogenation of nitrites to primary amines in the liquid phase over a suspended, activated Raney catalyst based on an alloy of aluminum and at least one transition metal selected from the group consisting of iron, cobalt and nickel, and, if desired, one or more further transition metals selected from the group consisting of titanium, zirconium, chromium and manganese, the hydrogenation is carried out in the absence of ammonia and basic alkali metal compounds or alkaline earth metal compounds.
摘要翻译：在一种基于铝合金和至少一种选自铁，钴和镍的过渡金属的悬浮活性阮内催化剂上，在液相中将亚硝酸盐连续氢化成伯胺的方法中，如果所需的一种或多种选自钛，锆，铬和锰的过渡金属，氢化在不存在氨和碱性碱金属化合物或碱土金属化合物的情况下进行。

6. 发明授权

US07217818B2 Purification of caprolactam 有权
标题翻译：己内酰胺的纯化
公开(公告)号：US07217818B2
公开(公告)日：2007-05-15
申请号：US10534802
申请日：2003-11-11
申请人： Rolf-Hartmuth Fischer , Hermann Luyken , Andreas Ansmann , Peter Bassler , Christoph Benisch , Stefan Maixner , Johann-Peter Melder
发明人： Rolf-Hartmuth Fischer , Hermann Luyken , Andreas Ansmann , Peter Bassler , Christoph Benisch , Stefan Maixner , Johann-Peter Melder
IPC分类号： C07D201/16
CPC分类号： C07D201/16 , C07D201/08
摘要： A process for removing high boilers from crude caprolactam which comprises high boilers, caprolactam and in some cases low boilers, and which has been obtained by a) reacting 6-aminocapronitrile with water to give a reaction mixture b) removing ammonia and unconverted water from the reaction mixture to obtain crude caprolactam, which comprises c) feeding the crude caprolactam to a distillation apparatus to obtain a first substream via the top as a product and a second substream via the bottom, by setting the pressure in the distillation in such a way that the bottom temperature does not go below 170° C., and adjusting the second substream in such a way that the caprolactam content of the second substream is not less than 10% by weight, based on the entire second substream.
摘要翻译：一种从粗己内酰胺中除去高锅炉的方法，其包括高锅炉，己内酰胺，在某些情况下是低锅炉，并且通过以下方法获得：a）使6-氨基己腈与水反应得到反应混合物; b）除去氨和未转化的水反应混合物以获得粗己内酰胺，其包括c）将粗己内酰胺加入到蒸馏装置中，通过顶部获得第一子流作为产物，通过底部通过设置第二子流，通过将蒸馏中的压力设定为使得底部温度不低于170℃，并且调节第二子流，使得第二子流的己内酰胺含量基于整个第二子流不小于10重量％。

7. 发明申请

US20070100168A1 Method for producing tricyclodecandialdehyde 失效
标题翻译：三环癸二醛生产方法
公开(公告)号：US20070100168A1
公开(公告)日：2007-05-03
申请号：US10581802
申请日：2004-12-14
申请人： Rainer Papp , Rocco Paciello , Christoph Benisch
发明人： Rainer Papp , Rocco Paciello , Christoph Benisch
IPC分类号： C07C45/49
CPC分类号： C07C209/26 , C07C29/141 , C07C47/347 , C07C2603/68 , C07C211/19 , C07C31/278
摘要： Process for preparing tricyclodecanedialdehyde by hydroformylation of dicyclopentadiene by means of a CO/H2 mixture at elevated temperature and under superatmospheric pressure in the presence of a rhodium catalyst which has not been modified by means of a ligand and is homogeneously dissolved in the hydroformylation medium, wherein the hydroformylation is carried out at a pressure of from 200 to 350 bar in at least two reaction zones, with a reaction temperature of from 80 to 120° C. being set in a first reaction zone and a reaction temperature of from 120 to 150° C. being set in a reaction zone following this reaction zone, with the proviso that the reaction temperature in the subsequent reaction zone is at least 5° C. higher than in the preceding reaction zone.
摘要翻译：在高温和超大气压下，在没有通过配体修饰的铑催化剂存在下，通过二环戊二烯加氢甲酰化二环戊二烯制备三环癸二醛的方法，均匀地溶解在加氢甲酰基化介质中，其中加氢甲酰化在至少两个反应区中在200-350巴的压力下进行，反应温度为80-120℃设定在第一反应区和在该反应区之后的反应区中设置120至150℃的反应温度，条件是后续反应区中的反应温度比前述反应区高至少5℃。

8. 发明申请

US20060041122A1 Method for purifying caprolactam 有权
标题翻译：己内酰胺纯化方法
公开(公告)号：US20060041122A1
公开(公告)日：2006-02-23
申请号：US10534802
申请日：2003-11-11
申请人： Rolf-Hartmuth Fischer , Hermann Luyken , Andreas Ansmann , Peter Babler , Christoph Benisch , Stefan Maixner , Johann-Peter Melder
发明人： Rolf-Hartmuth Fischer , Hermann Luyken , Andreas Ansmann , Peter Babler , Christoph Benisch , Stefan Maixner , Johann-Peter Melder
IPC分类号： C07D201/16
CPC分类号： C07D201/16 , C07D201/08
摘要： A process for removing high boilers from crude caprolactam which comprises high boilers, caprolactam and in some cases low boilers, and which has been obtained by a) reacting 6-aminocapronitrile with water to give a reaction mixture b) removing ammonia and unconverted water from the reaction mixture to obtain crude caprolactam, which comprises c) feeding the crude caprolactam to a distillation apparatus to obtain a first substream via the top as a product and a second substream via the bottom, by setting the pressure in the distillation in such a way that the bottom temperature does not go below 170° C., and adjusting the second substream in such a way that the caprolactam content of the second substream is not less than 10% by weight, based on the entire second substream.
摘要翻译：一种从粗己内酰胺中除去高锅炉的方法，其包括高锅炉，己内酰胺，在某些情况下是低锅炉，并且通过以下方法获得：a）使6-氨基己腈与水反应得到反应混合物; b）除去氨和未转化的水反应混合物以获得粗己内酰胺，其包括c）将粗己内酰胺加入到蒸馏装置中，通过顶部获得第一子流作为产物，通过底部通过设置第二子流，通过将蒸馏中的压力设定为使得底部温度不低于170℃，并且调节第二子流，使得第二子流的己内酰胺含量基于整个第二子流不小于10重量％。

9. 发明申请

US20050256340A1 Method for producing aminoalkoxy benzylamines and aminoalkoxy benzonitriles as intermediates 有权
标题翻译：制备氨基烷氧基苄胺和氨基烷氧基苯甲腈作为中间体的方法
公开(公告)号：US20050256340A1
公开(公告)日：2005-11-17
申请号：US10522614
申请日：2003-07-18
申请人： Oliver Lober , Christoph Benisch , Klaus Ebel , Johann-Peter Melder
发明人： Oliver Lober , Christoph Benisch , Klaus Ebel , Johann-Peter Melder
IPC分类号： C07B61/00 , C07C213/02 , C07C217/58 , C07C253/30 , C07C255/54 , C07C29/48
CPC分类号： C07C213/02 , C07C253/30 , C07C217/58 , C07C255/54
摘要： The invention relates to a process for preparing 4-[aminoalkoxy]benzylamines of the general formula (I) by catalytically hydrogenating 4-[aminoalkoxy]benzonitriles of the general formula (II) where, in the compounds of the general formulae I and II, R1 is C1-C8-alkylene, R2 and R3 are each independently C1-C8-alkyl or are joined to give a ring which may additionally contain a heteroatom, which comprises carrying out the hydrogenation at elevated pressure and elevated temperatures. The invention further relates to a process for preparing the intermediate (II).
摘要翻译：本发明涉及通过催化氢化通式（II）的4- [氨基烷氧基]苯甲腈制备通式（I）的4- [氨基烷氧基]苄胺的方法，其中在通式I和II的化合物中， R 1是C 1 -C 8 - 亚烷基，R 2和R 3 O 3 各自独立地为C 1 -C 8 - 烷基或连接，得到可另外含有杂原子的环，其包括在升高的压力下进行氢化并升高温度。本发明还涉及制备中间体（II）的方法。

10. 发明申请

US20050222449A1 Method for reducing the content of an unsaturated amine in a mixture containing an amino nitrile, a diamine, a dinitrile or mixtures thereof 有权
标题翻译：降低含氨基腈，二胺，二腈或其混合物的混合物中不饱和胺含量的方法
公开(公告)号：US20050222449A1
公开(公告)日：2005-10-06
申请号：US10515281
申请日：2003-05-21
申请人： Stefan Maixner , Christoph Benisch , Hermann Luyken , Peter Bassler , Rolf-Hartmuth Fischer , Johann-Peter Melder , Andreas Ansmann
发明人： Stefan Maixner , Christoph Benisch , Hermann Luyken , Peter Bassler , Rolf-Hartmuth Fischer , Johann-Peter Melder , Andreas Ansmann
IPC分类号： C07C209/84 , C07C211/09 , C07C211/12 , C07C253/34 , C07C255/09 , C07C255/24
CPC分类号： C07C253/34 , C07C255/24
摘要： A process for reducing the level of an aliphatic monounsaturated amine (IV) in a mixture (V) containing an aminonitrile (I) or a diamine (II) or a dinitrile (III) or mixtures thereof as well as said amine (IV) by a) reacting said mixture (V) with an anionic nucleophile (VI) which contains a nucleophilic atom selected from the group consisting of oxygen, nitrogen and sulfur, which is capable of taking up an H+ ion to form an acid having a pKa value in the range from 7 to 11, as measured in water at 25° C., and which has a relative nucleophilicity, as measured in methyl perchlorate/methanol at 25° C., in the range from 3.4 to 4.7 when said nucleophilic atom is oxygen, in the range from 4.5 to 5.8 when said nucleophilic atom is nitrogen, and in the range from 5.5 to 6.8 when said nucleophilic atom is sulfur, in an amount in the range from 0.01 to 10 mol per mole of said amine (IV) in said mixture (V) at a temperature in the range from 50 to 200° C. to obtain a mixture (VII), b) distilling said aminonitrile (I) or said diamine (II) or said dinitrile (III) or mixtures thereof from said mixture (VII) at a temperature in the range from 50 to 200° C. and at a pressure in the range from 0.1 to 100 kPa to obtain a bottom product (VIII), which comprises c) distilling an aminonitrile (I) or diamine (II) or dinitrile (III) or mixtures thereof from said bottom product (VIII) at a temperature which is lower than that chosen in step b).
摘要翻译：含有氨基腈（I）或二胺（II）或二腈（III）或其混合物以及所述胺（IV）的混合物（V）中的脂肪族单不饱和胺（IV）的水平以及所述胺（IV） a）使所述混合物（V）与含有选自氧，氮和硫的亲核原子的阴离子亲核试剂（VI）反应，其能够吸收H + 形成在25℃下在水中测量的具有7至11的pK值的酸，其在25℃下在高氯酸甲酯/甲醇中测得的具有相对亲核性当所述亲核原子为氧时，在3.4至4.7的范围内，当所述亲核原子为氮时，在4.5至5.8的范围内，当所述亲核原子为硫时在5.5至6.8的范围内，其量为在所述混合物（V）中，在50至200℃的温度范围内每摩尔所述胺（IV）为0.01至10摩尔的范围，以获得混合物（VII）中，b）在50至200℃的温度下，从所述混合物（VII）中蒸馏所述氨基腈（I）或所述二胺（II）或所述二腈（III）或其混合物，压力为0.1至100kPa，以获得底部产物（VIII），其包括c）在所述底部产物（VIII）中蒸馏氨基腈（I）或二胺（II）或二腈（III）或其混合物，温度低于步骤b）中选择的温度。

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