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1. 发明授权

US06677486B2 Hydrogenation of nitriles over Raney catalysts 失效
标题翻译：在阮内催化剂上氢化腈
公开(公告)号：US06677486B2
公开(公告)日：2004-01-13
申请号：US09985982
申请日：2001-11-07
申请人： Andreas Ansmann , Christoph Benisch , Frank Funke , Frank Ohlbach , Martin Merger
发明人： Andreas Ansmann , Christoph Benisch , Frank Funke , Frank Ohlbach , Martin Merger
IPC分类号： C07C2948
CPC分类号： C07D295/13 , B01J25/00 , B01J37/0018 , C07C209/48 , C07C211/14 , C07C211/36
摘要： Nitriles are hydrogenated to primary amines over an activated, alpha-Al2O3-containing, macroporous Raney catalyst based on an alloy of aluminum and at least one transition metal selected from the group consisting of iron, cobalt and nickel, and, if desired, one or more further transition metals selected from the group consisting of titanium, zirconium, chromium and manganese, which is obtainable by a process comprising the steps in the order (a)-(f): (a) preparing a kneadable composition comprising the alloy, a shaping aid, water and a pore former; (b) shaping the kneadable composition to form a shaped body; (c) calcining the shaped body; (d) activating the calcined shaped body by treatment with aqueous alkali metal hydroxide solution; (e) rinsing the shaped catalyst body with aqueous alkali metal hydroxide solution; (f) rinsing the shaped catalyst body with water.
摘要翻译：基于铝和至少一种选自铁，钴和镍的过渡金属的合金，并且如果需要，腈在一种活化的含α-Al 2 O 3的大孔阮内催化剂上氢化成伯胺，如果需要，（a） - （f）：（a）制备包含该合金的可捏合组合物的方法可以获得更多的选自钛，锆，铬和锰的过渡金属，成型助剂，水和成孔剂;（b）使捏合组合物成形以形成成形体;（c）煅烧成形体;（d）用碱金属氢氧化物水溶液处理活化煅烧成形体;（e）用碱金属氢氧化物水溶液冲洗成型的催化剂体;（f）用水冲洗成型的催化剂体。

2. 发明授权

US06469211B2 Hydrogenation of nitriles over Raney catalysts 失效
标题翻译：在阮内催化剂上氢化腈
公开(公告)号：US06469211B2
公开(公告)日：2002-10-22
申请号：US09987243
申请日：2001-11-14
申请人： Andreas Ansmann , Christoph Benisch , Frank Funke , Frank Ohlbach , Martin Merger
发明人： Andreas Ansmann , Christoph Benisch , Frank Funke , Frank Ohlbach , Martin Merger
IPC分类号： C07C20948
CPC分类号： C07C209/48 , C07C211/14
摘要： In a process for the continuous hydrogenation of nitrites to primary amines in the liquid phase over a suspended, activated Raney catalyst based on an alloy of aluminum and at least one transition metal selected from the group consisting of iron, cobalt and nickel, and, if desired, one or more further transition metals selected from the group consisting of titanium, zirconium, chromium and manganese, the hydrogenation is carried out in the absence of ammonia and basic alkali metal compounds or alkaline earth metal compounds.
摘要翻译：在一种基于铝合金和至少一种选自铁，钴和镍的过渡金属的悬浮活性阮内催化剂上，在液相中将亚硝酸盐连续氢化成伯胺的方法中，如果所需的一种或多种选自钛，锆，铬和锰的过渡金属，氢化在不存在氨和碱性碱金属化合物或碱土金属化合物的情况下进行。

3. 发明授权

US07253322B2 Method for producing ethyldimethylamine and triethylamine 失效
标题翻译：乙基二甲基胺和三乙胺的制备方法
公开(公告)号：US07253322B2
公开(公告)日：2007-08-07
申请号：US10506514
申请日：2003-03-03
申请人： Ralf Böhling , Ulrich Steinbrenner , Frank Funke , Günter Müller , Günter Gaus , Christoph Benisch
发明人： Ralf Böhling , Ulrich Steinbrenner , Frank Funke , Günter Müller , Günter Gaus , Christoph Benisch
IPC分类号： C07C209/60
CPC分类号： C07C209/60 , C07C211/05 , C07C211/08
摘要： The present invention describes a process for the preparation of ethyldimethylamine and triethylamine with the following steps: (i) reaction of a mixture of diethylamine and dimethylamine with ethylene in the presence of a catalyst from the group of alkali metal dimethylamides, alkali metal diethylamides and alkali metal hydrides (ii) removal of the catalyst (iii) distillation separation of the resulting mixture in triethylamine and ethyldimethylamine and optionally diethylamine and dimethylamine (iv) optional return of the catalyst and of the starting amines to the reaction. The process according to the invention permits the coproduction of ethyldimethylamine and diethylamine in a simple process.
摘要翻译：本发明描述了一种用于制备乙基二甲基胺和三乙胺的方法，其步骤如下：（i）二乙胺和二甲胺的混合物与乙烯在催化剂存在下由碱金属二甲基酰胺，碱金属二乙基酰胺和碱金属氢化物（ii）除去催化剂（iii）将所得混合物蒸馏分离在三乙胺和乙基二甲胺和任选的二乙胺和二甲胺中（iv）任选地将催化剂和起始胺返回到反应中。根据本发明的方法允许以简单的方法共同生产乙基二甲胺和二乙胺。

4. 发明申请

US20050154235A1 Method for producing ethyldimethylamine and triethylamine 失效
标题翻译：乙基二甲基胺和三乙胺的制备方法
公开(公告)号：US20050154235A1
公开(公告)日：2005-07-14
申请号：US10506514
申请日：2003-03-03
申请人： Ralf Bohling , Ulrich Steinbrenner , Frank Funke , Gunter Muller , Gunter Gaus , Christoph Benisch
发明人： Ralf Bohling , Ulrich Steinbrenner , Frank Funke , Gunter Muller , Gunter Gaus , Christoph Benisch
IPC分类号： C07B61/00 , C07C209/60 , C07C211/05 , C07C211/08 , C07C29/08
CPC分类号： C07C209/60 , C07C211/05 , C07C211/08
摘要： The present invention describes a process for the preparation of ethyldimethylamine and triethylamine with the following steps: (i) reaction of a mixture of diethylamine and dimethylamine with ethylene in the presence of a catalyst from the group of alkali metal dimethylamides, alkali metal diethylamides and alkali metal hydrides (ii) removal of the catalyst (iii) distillation separation of the resulting mixture in triethylamine and ethyldimethylamine and optionally diethylamine and dimethylamine (iv) optional return of the catalyst and of the starting amines to the reaction. The process according to the invention permits the coproduction of ethyldimethylamine and diethylamine in a simple process.
摘要翻译：本发明描述了一种用于制备乙基二甲基胺和三乙胺的方法，其步骤如下：（i）二乙胺和二甲基胺的混合物与乙烯在催化剂存在下由碱金属二甲基酰胺，碱金属二乙基酰胺和碱金属氢化物（ii）除去催化剂（iii）将所得混合物蒸馏分离在三乙胺和乙基二甲胺和任选的二乙胺和二甲胺中（iv）任选地将催化剂和起始胺返回到反应中。根据本发明的方法允许以简单的方法共同生产乙基二甲胺和二乙胺。

5. 发明授权

US07053246B2 Preparation of a symmetrical secondary amine 失效
标题翻译：对称仲胺的制备
公开(公告)号：US07053246B2
公开(公告)日：2006-05-30
申请号：US10731095
申请日：2003-12-10
申请人： Till Gerlach , Frank Funke , Christoph Benisch , Johann-Peter Melder
发明人： Till Gerlach , Frank Funke , Christoph Benisch , Johann-Peter Melder
IPC分类号： C07C29/04
CPC分类号： C07C209/64 , C07C211/14
摘要： Process for preparing a symmetrical secondary amine by reaction of a primary amine in the presence of hydrogen and a catalyst whose preparation has involved precipitation of catalytically active components onto monoclinic, tetragonal or cubic zirconium dioxide.
摘要翻译：通过伯胺在氢气和催化剂的反应下制备对称仲胺的方法，其制备涉及将催化活性组分沉淀到单斜晶，四方晶或立方二氧化锆上。

6. 发明授权

US06790995B2 Preparation of primary and secondary amines from nitriles 失效
标题翻译：从腈制备伯胺和仲胺
公开(公告)号：US06790995B2
公开(公告)日：2004-09-14
申请号：US10033912
申请日：2002-01-03
申请人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
发明人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
IPC分类号： C07C20948
CPC分类号： C07C213/02 , C07C209/48 , C07C211/11 , C07C215/08
摘要： Mixtures of primary amines of the formula (I) X—CH2—NH2 (I) and secondary amines of the formula (II) (X—CH2—)2NH (II) where X is C1-20-alkyl, C2-20-alkenyl or C3-8-cycloalkyl which may be unsubstituted or substituted by C1-20-alkyl, C3-8-cycloalkyl, C4-20-alkylcycloalkyl, C4-20-cycloalkylalkyl, C2-20-alkoxyalkyl, C6-14-aryl, C7-20-alkylaryl, C7-20-aralkyl, C1-20-alkoxy, hydroxy, C1-20-hydroxyalkyl, amino, C1-20-alkylamino, C2-20-dialkylamino, C2-12-alkenylamino. C3-8-cycloalkylamino, arylamino, diarylamino, aryl-C1-8-alkylamino, halogen, mercapto, C2-20-alkenyloxy, C3-8-cycloalkoxy, aryloxy and/or C2-8-alkoxycarbonyl are prepared by reacting nitriles of the formula (III) X—CN (III) with hydrogen at from 50 to 250° C. and pressures of from 5 to 350 bar in the presence of a Pd-containing catalyst comprising, based on the total weight of the catalyst, from 0.1 to 10% by weight of Pd on a support.
摘要翻译：式（I）的伯胺和式（II）的仲胺的混合物，其中X是可以未被取代或被C 1-20烷基取代的C 1-20 - 烷基，C 2-20 - 烯基或C 3-8 - 环烷基，C 3-8 - 环烷基，C 4-20 - 烷基环烷基，C 4-20 - 环烷基烷基，C 2-20烷氧基烷基，C 6-14 - 芳基，C 7-20 - 烷基芳基，C 7-20 - 芳烷基，C 1-20 - 烷氧基，羟基，C 1-20羟烷基，氨基，C 1-20烷基氨基，C 2-20 - 二烷基氨基，C 2-12 - 烯基氨基。 C 3-8 - 环烷基氨基，芳基氨基，二芳基氨基，芳基-C 1-8 - 烷基氨基，卤素，巯基，C 2-20 - 烯氧基，C 3-8 - 环烷氧基，芳氧基和/或C 2-8烷氧基羰基，（III）与氢气在50-250℃下反应，压力为5-350巴，在含Pd催化剂的存在下，基于催化剂的总重量计，为0.1-10重量％的Pd 在支持上。

7. 发明授权

US06525223B2 Preparation of secondary amines from nitriles 失效
标题翻译：从腈制备仲胺
公开(公告)号：US06525223B2
公开(公告)日：2003-02-25
申请号：US10026900
申请日：2001-12-27
申请人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
发明人： Joachim Pfeffinger , Michael Hüllmann , Arthur Höhn , Frank Funke , Frank Ohlbach , Till Gerlach
IPC分类号： C07C20948
CPC分类号： C07C209/48 , C07C211/11
摘要： Secondary amines of the formula (II) (X—CH2—)2NH (II) where X is a C1-20-alkyl, C2-20-alkenyl or C3-8-cycloalkyl group which may be unsubstituted or substituted by C1-20-alkyl, C3-8-cycloalkyl, C4-20-alkylcycloalkyl, C4-20-cycoalkylalkyl, C2-20-alkoxyalkyl, C6-14-aryl, C7-20-alkylaryl, C7-20-aralkyl, C1-20-alkoxy, hydroxy, C1-20-hydroxyalkyl, amino, C1-20-alkylamino, C2-20-dialkylamino, C2-12-alkenylamino, C3-8-cycloalkylamino, arylamino, diarylamino, aryl-C1-8-alkylamino, halogen, mercapto, C2-20-alkenyloxy, C3-8-cycloalkoxy, aryloxy and/or C2-8-alkoxycarbonyl, are prepared by reacting nitriles of the formula (III) X—CN (III) with hydrogen at from 20 to 250° C. and pressures of from 60 to 350 bar in the presence of an Rh-containing catalyst comprising from 0.1 to 5% by weight, based on the total weight of the catalyst, of Rh on a support to give mixtures of primary amines of the formula (I) X—CH2—NH2 (I) and secondary amines of the formula (II) (X—CH2—)2NH (II) and returning at least part of the primary amines separated from the mixtures obtained to the reaction.
摘要翻译：式（II）的仲胺，其中X是可以是未取代的或被C 1-20 - 烷基，C 3-8 - 环烷基，C 4 -C 18环烷基，C 3-8 - C 20-20烷基烷基，C 2-20 - 烷氧基烷基，C 6-14 - 芳基，C 7-20 - 烷基芳基，C 7-20 - 芳烷基，C 1-20 - 烷氧基，羟基，C 1-20 - 羟基烷基，氨基， C 1-20 - 烷基氨基，C 2-20 - 二烷基氨基，C 2-12 - 烯基氨基，C 3-8 - 环烷基氨基，芳基氨基，二芳基氨基，芳基-C 1-8 - 烷基氨基，卤素，巯基，C 2-20 - 烯氧基，环烷氧基，芳氧基和/或C 2-8 - 烷氧基羰基，通过在含Rh的催化剂存在下，使式（III）的腈与20至250℃的压力和60至350巴的压力反应来制备包含基于催化剂总重量的0.1至5重量％的Rh在载体上以得到式（I）的伯胺和式（II）的仲胺的混合物，并使至少部分从获得的混合物中分离出伯胺反应。

8. 发明授权

US07183438B2 Catalysts and method for the production of amines 有权
标题翻译：用于生产胺的催化剂和方法
公开(公告)号：US07183438B2
公开(公告)日：2007-02-27
申请号：US10507602
申请日：2003-03-07
申请人： Till Gerlach , Frank Funke , Johann-Peter Melder , Stefan Iselborn , Martin Rudloff , Michael Hüllmann
发明人： Till Gerlach , Frank Funke , Johann-Peter Melder , Stefan Iselborn , Martin Rudloff , Michael Hüllmann
IPC分类号： C07C209/16 , C07C209/18 , C07C209/29 , B01J23/40 , B01J23/42
CPC分类号： C07C213/02 , B01J23/70 , B01J23/755 , B01J37/03 , B01J37/06 , C07C209/16 , C07C209/26 , C07D295/023 , C07C211/03 , C07C217/08
摘要： Disclosed are catalysts, the catalytically active mass of which contains 22 to 40 percent by weight of oxygen-containing compounds of zirconium, calculated as ZrO2, 1 to 30 percent by weight of oxygen-containing compounds of copper, calculated as CuO, 15 to 50 percent by weight of oxygen-containing compounds of nickel, calculated as NiO, the molar ratio between nickel and copper being greater than 1, 15 to 50 percent by weight of oxygen-containing compounds of cobalt, calculated as CoO, and less than 1 percent by weight of an alkali metal, calculated as alkali metal oxide, prior to being treated with hydrogen. Also disclosed is a method for the production of amines by reacting primary and secondary alcohols, aldehydes, or ketones with hydrogen and nitrogen compounds selected from the group ammonia, primary and secondary amines, in the presence of said catalysts at an elevated temperature and an elevated pressure.
摘要翻译：公开了催化剂，其催化活性物质含有22至40重量％的以ZrO 2计算的含氧化合物的锆，1至30重量％的含氧化合物的铜，以CuO计，15至50重量％的含氧化合物的镍，以NiO计算，镍和铜之间的摩尔比大于15重量％，含氧化合物的化合物为15至50重量％作为CoO，并且在用氢处理之前少于1重量％的碱金属（以碱金属氧化物计）。还公开了一种通过使伯醇和仲醇，醛或酮与选自氨，伯胺和仲胺的氢和氮化合物在所述催化剂存在下在升高的温度和升高的温度下生产胺的方法压力。

9. 发明申请

US20070004849A1 Method for the preliminary treatment of cellulose-containing textile 审中-公开
标题翻译：纤维素纤维素预处理方法
公开(公告)号：US20070004849A1
公开(公告)日：2007-01-04
申请号：US10573808
申请日：2004-09-24
申请人： Karl Siemensmeyer , Steffen Gibs , Frank Funke , Andreas Bastian , Michael Gotsche , Heinz Heissler , James Carnahan , Tanja Schneider , Holger Schopke , Stefan Frenzel
发明人： Karl Siemensmeyer , Steffen Gibs , Frank Funke , Andreas Bastian , Michael Gotsche , Heinz Heissler , James Carnahan , Tanja Schneider , Holger Schopke , Stefan Frenzel
IPC分类号： C08F8/30
CPC分类号： D06P1/5257 , C08F8/12 , D06P1/22 , D06P1/38 , D06P1/5221 , D06P1/5242 , D06P3/6025 , D06P3/62 , D06P3/66 , D06P5/225 , C08F126/02 , C08F226/02 , C08F226/06 , C08F226/10
摘要： A process for pretreating cellulosic textile, which comprises the steps of: (a) treating cellulosic textile with a solution of polymer or copolymer obtainable by (a1) polymerization or copolymerization of N-vinylamide of the general formula I where R is selected from hydrogen and C1-C10-alkyl, and (a2) partial hydrolysis if appropriate, (b) optionally drying the treated textile, and (c) optionally saponifying all or some of the amide groups, wherein at least one of the steps (a2) and (c) is carried out.
摘要翻译：一种用于预处理纤维素织物的方法，其包括以下步骤：（a）用聚合物或共聚物溶液处理纤维素织物，所述聚合物或共聚物可通过（a1）通式I的N-乙烯基酰胺的聚合或共聚获得，其中R选自氢和 C 1 -C 10 - 烷基，和（a2）适当的部分水解，（b）任选地干燥经处理的织物，和（c）任选地皂化全部或一些酰胺基，其中进行步骤（a2）和（c）中的至少一个。

10. 发明申请

US20060116311A1 Use of copolymers as auxiliaries for dyeing and printing textiles 审中-公开
标题翻译：使用共聚物作为染色和印花纺织品的助剂
公开(公告)号：US20060116311A1
公开(公告)日：2006-06-01
申请号：US10537268
申请日：2003-11-28
申请人： Pia Baum , Nicola Kulzer , Frank Funke , Andreas Bastian , Markus Ringelsbacher , Heinz Heissler , Gerhard Reuther , Rouven Konrad , James Carnahan , Karl Siemensmeyer , Birgit Potthoff-Karl , Tarja Schneider , Johann Muller
发明人： Pia Baum , Nicola Kulzer , Frank Funke , Andreas Bastian , Markus Ringelsbacher , Heinz Heissler , Gerhard Reuther , Rouven Konrad , James Carnahan , Karl Siemensmeyer , Birgit Potthoff-Karl , Tarja Schneider , Johann Muller
IPC分类号： C11D3/37
CPC分类号： D06P5/137 , D06P1/52 , D06P1/5242 , D06P1/60 , D06P5/08
摘要： The use of copolymers containing units derived from at least 2 monoethylenically unsaturated monomers B1 and B2 which each contain at least one nitrogenous heterocycle, as auxiliaries for textile dyeing and textile printing.
摘要翻译：使用含有至少2个单烯属不饱和单体B1和B2的单元的共聚物，每个含有至少一个含氮杂环的单烯属不饱和单体作为织物染色和织物印刷的助剂。

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