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1. 发明授权

US4340721B1 Polyesters for the packaging of comestibles 失效
标题翻译：聚酯包装食品
公开(公告)号：US4340721B1
公开(公告)日：1998-12-01
申请号：US26533581
申请日：1981-05-19
申请人： RHONE POULENC IND
发明人： BONNEBAT CLAUDE , ROULLETT GILBERT , VAGINAY YVES
IPC分类号： B65D65/02 , C08G63/00 , C08G63/02 , C08G63/16 , C08G63/18 , C08G63/181 , C08G63/183 , C08G63/199 , C08G63/66 , C08G63/78 , C08G63/80
CPC分类号： C08G63/80 , C08G63/16 , C08G63/183 , Y10T428/1352 , Y10T428/1355 , Y10T428/1397

2. 发明授权

KR840000468B1 폴리- 테레프탈레이트의 제조방법 失效
公开(公告)号：KR840000468B1
公开(公告)日：1984-04-09
申请号：KR810001706
申请日：1981-05-18
申请人： RHONE POULENC IND
发明人： BONNEBAT CLAUDE , ROLLE GILBERT , BAJINE EBO
IPC分类号： B65D65/02 , C08G63/00 , C08G63/02 , C08G63/16 , C08G63/18 , C08G63/181 , C08G63/183 , C08G63/199 , C08G63/66 , C08G63/78 , C08G63/80

3. 发明专利

FR2484324A1 未知
公开(公告)号：FR2484324A1
公开(公告)日：1981-12-18
申请号：FR8013158
申请日：1980-06-13
申请人： RHONE POULENC IND
发明人： BONNEBAT CLAUDE , MACABREY LOUIS
IPC分类号： B29C49/16 , B29D23/18 , B29D23/03 , B32B1/08 , B32B27/36 , B32B31/14 , C08L31/08
摘要： An elongate, rigid, tubular, biaxially oriented thermoplastic, hollow thin-walled shaped article is molded by (i) introducing into an elongate mold cavity, the internal configuration and dimensions thereof corresponding to the exterior surface area of the desired shaped article, and aligning along the longitudinal axis thereof, a hollow tubular thermoplastic preform heated to the biaxial orientation temperature of said thermoplastic; (ii) expanding under internal pressure said heated preform to simultaneously, both longitudinally and transversely, uniformly stretch same, at least to the natural biaxial drawing ratio thereof, but to a value in the transverse direction of less than 100% of that ultimately desired; (iii) next further expanding said heated preform, under increased internal pressure, completely against the internal walls of the mold cavity to thus completely shape said ultimately desired shaped article; and (iv) then cooling said desired shaped article and releasing all pressure therefrom.

4. 发明专利

CH621290A5 未知
公开(公告)号：CH621290A5
公开(公告)日：1981-01-30
申请号：CH483278
申请日：1978-05-03
申请人： RHONE POULENC IND
发明人： BONNEBAT CLAUDE , ROULLET GILBERT
IPC分类号： B29B11/08 , B29B11/10 , B29C35/16 , B29C49/04 , B29C49/06 , B29C49/12 , B29C49/18 , B29C49/22 , B29C49/48 , B29C49/58 , B29C49/64 , B29C49/66 , B29C49/68 , B29C51/42 , B29C65/00 , C08G63/02 , B29D23/03
摘要： A process for preparing biaxially oriented hollow shaped articles, in particular bottles of thermoplastic material, by biaxial draw- and blow-molding comprises blow-molding a preform and subsequently maintaining the thermoplastic material in close contact with the hot walls of the mold at a temperature which is in the range from about the minimum effective temperature for biaxial orientation of the thermoplastic material to about 40 DEG C. above this temperature for a period of time which is sufficient to partially reduce internal residual stresses in the hollow shaped articles. Following this partial thermo-stabilization, the hollow shaped article preferably is subjected to cooling, whereby the pressure within the article is at least partially maintained or the shaped article is cooled or allowed to shrink and subsequently subjected to a second blow-molding procedure.

5. 发明专利

CA1115472A PROCEDE D'EXTRUSION POUR LA FABRICATION DE CORPS CREUX 未知
公开(公告)号：CA1115472A
公开(公告)日：1982-01-05
申请号：CA292650
申请日：1977-12-08
申请人： RHONE POULENC IND
发明人： BONNEBAT CLAUDE , HALNA DU FRETAY GERARD
IPC分类号： B65D1/00 , B29B11/10 , B29C47/36 , B29C47/80 , B29C48/32 , B29C48/395 , B29C49/00 , B29C49/04 , B29C49/68 , B29C49/78 , B29C65/00 , B29D23/03
摘要： Procédé de fabrication de corps creux en matière thermoplastique comprenant la formation d'un extrudat fondu, le passage de la matière fondue au travers d'une filière de calibrage de forme appropriée suivie de la mise en forme conventionnelle à l'aide d'un dispositif de conformation et/ou de soufflage. Ce procédé est caractérisé en ce que la matière thermoplastique fondue à une température To supérieure à sa température de fusion TFF est refroidie avant son entrée dans la filière de calibrage à une température T1 comprise entre TFF et la température de début de cristallisation TDC, le refroidissement étant effectué de façon homogène et dans des conditions contrôlées de manière à ce que la matière reste totalement exempte de germes cristallins jusqu'au dispositif de conformation ou de soufflage. Le procédé selon l'invention permet d'extruder des polymères de faibles viscosités dans des conditions de stabilité améliorées.

6. 发明专利

FR2462254A1 Biaxial orientation of freshly extruded polyester tubing - to make stiff tough packaging tubes, involves chilling surface to amorphous state 未知
公开(公告)号：FR2462254A1
公开(公告)日：1981-02-13
申请号：FR7919144
申请日：1979-07-25
申请人： RHONE POULENC IND
发明人： ROULLET GILBERT , MACABREY LOUIS , BONNEBAT CLAUDE
IPC分类号： B29C47/00 , B29C47/88 , B29C49/00 , B29C49/10 , B29C49/64 , B29C55/26 , B29C17/07 , B29D23/04 , B65D65/38 , F16L9/12
摘要： Hollow thermoplastic profiles are from freshly extruded tubing which passes through a calibration die where at least one surface is chilled to an amorphous state, the body of the tubing is adjusted to a temp. above the glass transition temp. of the material, and the tubing is then stretched radially and longitudinally to a diameter controlled by an extension of the calibration chamber. Claimed for making tubular containers, pref. from polyethylene terephthalate (PET) of intrinsic viscosity 0.50-1.10 dl/g in orthochlorophenol, so that when the container is lying horizontal, the radial sag under its own wt. is less than 2%. The material used may be pigmented or filled, opt. is reinforced by incorporation of ground glass fibres or lamellae of mica, graphite or talc. Suitable for tough containers with a high strength/wt. ratio for holding e.g. fluoroescent light tubes, or for packaging liquids or edible pastes.

7. 发明专利

DE2819495A1 未知
公开(公告)号：DE2819495A1
公开(公告)日：1978-11-09
申请号：DE2819495
申请日：1978-05-03
申请人： RHONE POULENC IND
发明人： BONNEBAT CLAUDE , ROULLET GILBERT
IPC分类号： B29B11/08 , B29B11/10 , B29C35/16 , B29C49/04 , B29C49/06 , B29C49/12 , B29C49/18 , B29C49/22 , B29C49/48 , B29C49/58 , B29C49/64 , B29C49/66 , B29C49/68 , B29C51/42 , B29C65/00 , C08G63/02 , B29C17/07
摘要： A process for preparing biaxially oriented hollow shaped articles, in particular bottles of thermoplastic material, by biaxial draw- and blow-molding comprises blow-molding a preform and subsequently maintaining the thermoplastic material in close contact with the hot walls of the mold at a temperature which is in the range from about the minimum effective temperature for biaxial orientation of the thermoplastic material to about 40 DEG C. above this temperature for a period of time which is sufficient to partially reduce internal residual stresses in the hollow shaped articles. Following this partial thermo-stabilization, the hollow shaped article preferably is subjected to cooling, whereby the pressure within the article is at least partially maintained or the shaped article is cooled or allowed to shrink and subsequently subjected to a second blow-molding procedure.

8. 发明专利

MX166409B 未知
公开(公告)号：MX166409B
公开(公告)日：1993-01-07
申请号：MX848281
申请日：1981-05-19
申请人： RHONE POULENC IND
发明人： BONNEBAT CLAUDE , ROULLET GILBERT , VAGINAYC YVES
IPC分类号： B65D65/02 , C08G63/00 , C08G63/02 , C08G63/16 , C08G63/18 , C08G63/181 , C08G63/183 , C08G63/199 , C08G63/66 , C08G63/78 , C08G63/80
摘要： Novel polyester for the packaging of perishable comestibles, e.g., as bottles for still or carbonated mineral waters, is a poly(ethylene glycol)terephthalate (PET) having an intrinsic viscosity ranging from 0.65 to 1.05 dl/g and a density of more than 1.38, comprising 92.5 to 98.5% of ethylene terephthalate recurring units and 1.5 to 7.5 mol % of recurring units of at least one polybasic acid and/or polyhydric alcohol comonomeric crystallization retardant, the di- and/or triethylene glycol content thereof being less than about 3.5 mol % per mol of diacid radicals present in the polymer chain, said PET also having a residual acetaldehyde concentration of less than 1.25 ppm, with acetaldehyde being reformed therefrom at a rate of less than 5 ppm/hour, at 220 DEG C., and said PET being devoid of visible crystallization in an at least 4 mm thick test plate shaped in a mold cavity from a melt thereof.

9. 发明专利

DE2755028A1 未知
公开(公告)号：DE2755028A1
公开(公告)日：1978-06-22
申请号：DE2755028
申请日：1977-12-09
申请人： RHONE POULENC IND
发明人： BONNEBAT CLAUDE , HALNA DU FRETAY GERARD
IPC分类号： B65D1/00 , B29B11/10 , B29C47/36 , B29C47/80 , B29C48/32 , B29C48/395 , B29C49/00 , B29C49/04 , B29C49/68 , B29C49/78 , B29C65/00 , B29D23/04
摘要： Hollow shaped articles are extruded, advantageously continuously extruded, from molten thermoplastics by controlled cooling of the molten charge prior to entry into an extrusion die.

10. 发明专利

AU540702B2 NEW POLYESTERS 未知
公开(公告)号：AU540702B2
公开(公告)日：1984-11-29
申请号：AU7065681
申请日：1981-05-18
申请人： RHONE POULENC IND
发明人： BONNEBAT CLAUDE , ROULLET GILBERT , VAGINAY YVES
IPC分类号： B65D65/02 , C08G63/00 , C08G63/02 , C08G63/16 , C08G63/18 , C08G63/181 , C08G63/183 , C08G63/199 , C08G63/66 , C08G63/78 , C08G63/80 , C08G63/36
摘要： Novel polyester for the packaging of perishable comestibles, e.g., as bottles for still or carbonated mineral waters, is a poly(ethylene glycol)terephthalate (PET) having an intrinsic viscosity ranging from 0.65 to 1.05 dl/g and a density of more than 1.38, comprising 92.5 to 98.5% of ethylene terephthalate recurring units and 1.5 to 7.5 mol % of recurring units of at least one polybasic acid and/or polyhydric alcohol comonomeric crystallization retardant, the di- and/or triethylene glycol content thereof being less than about 3.5 mol % per mol of diacid radicals present in the polymer chain, said PET also having a residual acetaldehyde concentration of less than 1.25 ppm, with acetaldehyde being reformed therefrom at a rate of less than 5 ppm/hour, at 220 DEG C., and said PET being devoid of visible crystallization in an at least 4 mm thick test plate shaped in a mold cavity from a melt thereof.

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