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1. 发明申请

US20100160579A1 PROCESS FOR PRODUCING BROADER MOLECULAR WEIGHT DISTRIBUTION POLYMERS WITH A REVERSE COMONOMER DISTRIBUTION AND LOW LEVELS OF LONG CHAIN BRANCHES 有权
标题翻译：用于生产广泛分子量分布聚合物的方法，具有反向共享分布和长链分支的低水平
公开(公告)号：US20100160579A1
公开(公告)日：2010-06-24
申请号：US12338225
申请日：2008-12-18
申请人： Qing Yang , Max P. McDaniel , Joel L. Martin , Tony R. Crain , Randy S. Muninger , Jerry T. Lanier , Jeff S. Fodor , Paul J. Deslauriers , Chung C. Tso , David C. Rohlfing
发明人： Qing Yang , Max P. McDaniel , Joel L. Martin , Tony R. Crain , Randy S. Muninger , Jerry T. Lanier , Jeff S. Fodor , Paul J. Deslauriers , Chung C. Tso , David C. Rohlfing
IPC分类号： C08F4/76 , C08F4/06 , C08F4/12 , C08F4/18 , C08F210/00
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , Y10S526/905 , Y10S526/943 , Y10T428/1352 , Y10T428/139 , Y10T428/2913 , Y10T428/2915 , C08F4/65927 , C08F210/14 , C08F2500/12 , C08F2500/04 , C08F2500/09 , C08F2500/10
摘要： The present invention provides a polymerization process which is conducted by contacting an olefin monomer and at least one olefin comonomer in the presence of hydrogen and a metallocene-based catalyst composition. Polymers produced from the polymerization process are also provided, and these polymers have a reverse comonomer distribution, low levels of long chain branches, and a ratio of Mw/Mn from about 3 to about 6.
摘要翻译：本发明提供聚合方法，其通过使烯烃单体和至少一种烯烃共聚单体在氢和茂金属基催化剂组合物的存在下接触进行。还提供了由聚合反应生成的聚合物，这些聚合物具有反相共聚单体分布，低水平的长支链，Mw / Mn约为3至6的比例。

2. 发明授权

US08475899B2 Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches 有权
标题翻译：制备具有反向共聚单体分布和低水平的长链分支的较宽分子量分布聚合物的方法
公开(公告)号：US08475899B2
公开(公告)日：2013-07-02
申请号：US13310841
申请日：2011-12-05
申请人： Qing Yang , Max P. McDaniel , Joel L. Martin , Tony R. Crain , Randy S. Muninger , Jerry T. Lanier , Jeff S. Fodor , Paul J. Deslauriers , Chung C. Tso , David C. Rohlfing
发明人： Qing Yang , Max P. McDaniel , Joel L. Martin , Tony R. Crain , Randy S. Muninger , Jerry T. Lanier , Jeff S. Fodor , Paul J. Deslauriers , Chung C. Tso , David C. Rohlfing
IPC分类号： C08F10/02 , C08F4/6592
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , Y10S526/905 , Y10S526/943 , Y10T428/1352 , Y10T428/139 , Y10T428/2913 , Y10T428/2915 , C08F4/65927 , C08F210/14 , C08F2500/12 , C08F2500/04 , C08F2500/09 , C08F2500/10
摘要： The present invention provides a polymerization process which is conducted by contacting an olefin monomer and at least one olefin comonomer in the presence of hydrogen and a metallocene-based catalyst composition. Polymers produced from the polymerization process are also provided, and these polymers have a reverse comonomer distribution, low levels of long chain branches, and a ratio of Mw/Mn from about 3 to about 6.
摘要翻译：本发明提供聚合方法，其通过使烯烃单体和至少一种烯烃共聚单体在氢和茂金属基催化剂组合物的存在下接触进行。还提供了由聚合反应生成的聚合物，这些聚合物具有反相共聚单体分布，低水平的长支链，Mw / Mn约为3至6的比例。

3. 发明申请

US20120141710A1 Process for Producing Broader Molecular Weight Distribution Polymers with a Reverse Comonomer Distribution and Low Levels of Long Chain Branches 有权
标题翻译：用于生产具有反向共聚单体分布和低水平的长链分支的更宽分子量分布聚合物的方法
公开(公告)号：US20120141710A1
公开(公告)日：2012-06-07
申请号：US13310841
申请日：2011-12-05
申请人： Qing Yang , Max P. McDaniel , Joel L. Martin , Tony R. Crain , Randy S. Muninger , Jerry T. Lanier , Jeff S. Fodor , Paul J. Deslauriers , Chung C. Tso , David C. Rohlfing
发明人： Qing Yang , Max P. McDaniel , Joel L. Martin , Tony R. Crain , Randy S. Muninger , Jerry T. Lanier , Jeff S. Fodor , Paul J. Deslauriers , Chung C. Tso , David C. Rohlfing
IPC分类号： C08F210/02 , B32B1/02 , B32B1/08
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , Y10S526/905 , Y10S526/943 , Y10T428/1352 , Y10T428/139 , Y10T428/2913 , Y10T428/2915 , C08F4/65927 , C08F210/14 , C08F2500/12 , C08F2500/04 , C08F2500/09 , C08F2500/10
摘要： The present invention provides a polymerization process which is conducted by contacting an olefin monomer and at least one olefin comonomer in the presence of hydrogen and a metallocene-based catalyst composition. Polymers produced from the polymerization process are also provided, and these polymers have a reverse comonomer distribution, low levels of long chain branches, and a ratio of Mw/Mn from about 3 to about 6.
摘要翻译：本发明提供聚合方法，其通过使烯烃单体和至少一种烯烃共聚单体在氢和茂金属基催化剂组合物的存在下接触进行。还提供了由聚合反应生成的聚合物，这些聚合物具有反相共聚单体分布，低水平的长支链，Mw / Mn约为3至6的比例。

4. 发明授权

US08114946B2 Process for producing broader molecular weight distribution polymers with a reverse comonomer distribution and low levels of long chain branches 有权
标题翻译：制备具有反向共聚单体分布和低水平的长链分支的较宽分子量分布聚合物的方法
公开(公告)号：US08114946B2
公开(公告)日：2012-02-14
申请号：US12338225
申请日：2008-12-18
申请人： Qing Yang , Max P. McDaniel , Joel L. Martin , Tony R. Crain , Randy S. Muninger , Jerry T. Lanier , Jeff S. Fodor , Paul J. Deslauriers , Chung C. Tso , David C. Rohlfing
发明人： Qing Yang , Max P. McDaniel , Joel L. Martin , Tony R. Crain , Randy S. Muninger , Jerry T. Lanier , Jeff S. Fodor , Paul J. Deslauriers , Chung C. Tso , David C. Rohlfing
IPC分类号： C08F4/6592
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , Y10S526/905 , Y10S526/943 , Y10T428/1352 , Y10T428/139 , Y10T428/2913 , Y10T428/2915 , C08F4/65927 , C08F210/14 , C08F2500/12 , C08F2500/04 , C08F2500/09 , C08F2500/10
摘要： The present invention provides a polymerization process which is conducted by contacting an olefin monomer and at least one olefin comonomer in the presence of hydrogen and a metallocene-based catalyst composition. Polymers produced from the polymerization process are also provided, and these polymers have a reverse comonomer distribution, low levels of long chain branches, and a ratio of Mw/Mn from about 3 to about 6.
摘要翻译：本发明提供聚合方法，其通过使烯烃单体和至少一种烯烃共聚单体在氢和茂金属基催化剂组合物的存在下接触进行。还提供了由聚合反应生成的聚合物，这些聚合物具有反相共聚单体分布，低水平的长支链，Mw / Mn约为3至6的比例。

5. 发明授权

US08933175B2 Hyperbranched polymers and methods of making and using same 有权
标题翻译：超支化聚合物及其制备和使用方法
公开(公告)号：US08933175B2
公开(公告)日：2015-01-13
申请号：US13599290
申请日：2012-08-30
申请人： Youlu Yu , Chung C. Tso , David C. Rohlfing , Paul J. Deslauriers , Melvin Hildebrand , Max P. McDaniel , Qing Yang
发明人： Youlu Yu , Chung C. Tso , David C. Rohlfing , Paul J. Deslauriers , Melvin Hildebrand , Max P. McDaniel , Qing Yang
IPC分类号： C08F10/02 , C08F110/02 , C08F6/04 , C08L23/06
CPC分类号： C08L23/06 , C08F6/04 , C08L2205/025 , C08L2207/07 , C08L2308/00 , C08L2314/02 , C08F110/02 , C08F2500/04 , C08F2500/09
摘要： A composition comprising a polyethylene wherein the composition is enriched in polymer molecules having topological variations by an enrichment factor ω and wherein the composition displays a long chain branching frequency of greater than about 0.5 long chain branches per 1000 total carbon atoms. A composition comprising an isolated Ziegler-catalyzed polyethylene having a long chain branching frequency of greater than about 0.5 long chain branches per 1000 total carbon atoms at the high molecular weight end.
摘要翻译：一种包含聚乙烯的组合物，其中所述组合物富集具有通过富集因子ω的拓扑变化的聚合物分子，并且其中所述组合物显示每1000个总碳原子大于约0.5个长链分支的长链支化频率。包含分子齐格勒催化的聚乙烯的组合物，其在高分子量末端的每1000个总碳原子具有大于约0.5个长链支链的长链支化频率。

6. 发明授权

US08722416B2 Integrated on-line two-dimensional method and device for synchroned analytical temperature rising elution fractionation and gel permeation chromatography 有权
$Integrated on-line two-dimensional method and device for synchroned analytical temperature rising elution fractionation and gel permeation chromatography$
标题翻译：集成在线二维方法和装置，用于同步分析升温洗脱分级和凝胶渗透色谱
公开(公告)号：US08722416B2
公开(公告)日：2014-05-13
申请号：US11439646
申请日：2006-05-24
申请人： Youlu Yu , Chung C. Tso , Paul J. DesLauriers
发明人： Youlu Yu , Chung C. Tso , Paul J. DesLauriers
IPC分类号： B01D15/08
CPC分类号： G01N30/88 , G01N25/147 , G01N30/02 , G01N30/24 , G01N30/30 , G01N30/463 , G01N30/52 , G01N33/442 , G01N2030/008 , G01N2030/885 , Y10T436/255 , B01D15/34 , G01N30/44 , B01D15/361 , B01D15/327
摘要： An analytical method comprising performing a first fractionation of a polymer sample based on differences in crystallizability to provide a first set of sample fractions, performing a first analysis on the first set of sample fractions, performing a second fractionation of the first set of sample fractions to produce a second set of sample fractions, performing a second analysis on the second set of sample fractions, and synchronizing the first fractionation and second fractionation to provide about concurrent analysis of the polymer sample.
摘要翻译：一种分析方法，包括基于可结晶性的差异进行聚合物样品的第一次分级，以提供第一组样品级分，对第一组样品级分进行第一分析，对第一组样品级分进行第二次分级，产生第二组样品级分，对第二组样品级分进行第二次分析，并使第一分馏和第二分馏同步以提供聚合物样品的大约同时分析。

7. 发明授权

US07241620B2 Ultra high molecular weight polyethylene fractions having narrow molecular weight distributions and methods of making and using the same 有权
$Ultra high molecular weight polyethylene fractions having narrow molecular weight distributions and methods of making and using the same$
标题翻译：具有窄分子量分布的超高分子量聚乙烯级分及其制备和使用方法
公开(公告)号：US07241620B2
公开(公告)日：2007-07-10
申请号：US10754373
申请日：2004-01-09
申请人： Chung C. Tso , Melvin Hildebrand , Paul J. DesLauriers , Youlu Yu
发明人： Chung C. Tso , Melvin Hildebrand , Paul J. DesLauriers , Youlu Yu
IPC分类号： G01N30/02 , C08F6/12
CPC分类号： C08F6/04 , C08F110/02 , Y10T436/10 , C08L23/04 , C08F2500/01 , C08F2500/03
摘要： Polymer fractions such as polyethylene fractions can be produced that have a PDI less than about 2.3 and a Mw greater than about 1,000,000 g/mol, 3,000,000 g/mol, or 6,000,000 g/mol. Such polyethylene fractions are separated from a UHMWPE parent polymer by first dissolving the parent polymer in a relatively good solvent. The conditions employed for such dissolution are selected to reduce the degradation of the parent polymer. The resulting parent solution is transported into a fractionation column in which a support is disposed. The fractionation column is thereafter operated at conditions effective to form a precipitate on the support comprising the desired polyethylene fraction. The polyethylene fraction may then be recovered from the fractionation column by repeatedly displacing a solvent/non-solvent mixture into the column to dissolve the polyethylene fraction. The relative concentrations of the solvent and the non-solvent are based on a solvent gradient profile of the polyethylene parent polymer.
摘要翻译：可以制备聚合物级分例如聚乙烯级分，其具有小于约2.3的PDI和大于约1,000,000g / mol，3,000,000g / mol或6,000,000g / mol的M max。通过首先将母体聚合物溶解在相对良好的溶剂中，将这样的聚乙烯部分与UHMWPE母体聚合物分离。选择用于这种溶解的条件以降低母体聚合物的降解。将所得的母体溶液输送到其中设置有支持物的分馏塔。然后分馏塔在有效地在包含所需聚乙烯部分的载体上形成沉淀物的条件下操作。然后可以通过将溶剂/非溶剂混合物重复置换到柱中以溶解聚乙烯部分，从分馏塔中回收聚乙烯部分。溶剂和非溶剂的相对浓度基于聚乙烯母体聚合物的溶剂梯度分布。

8. 发明授权

US07691633B2 Ultra high molecular weight polyethylene fractions having narrow molecular weight distributions and methods of making and using the same 有权
$Ultra high molecular weight polyethylene fractions having narrow molecular weight distributions and methods of making and using the same$
标题翻译：具有窄分子量分布的超高分子量聚乙烯级分及其制备和使用方法
公开(公告)号：US07691633B2
公开(公告)日：2010-04-06
申请号：US11766518
申请日：2007-06-21
申请人： Chung C. Tso , Melvin Hildebrand , Paul J. DesLauriers , Youlu Yu
发明人： Chung C. Tso , Melvin Hildebrand , Paul J. DesLauriers , Youlu Yu
IPC分类号： C08F210/02 , G01N30/02 , C08F6/12
CPC分类号： C08F6/04 , C08F110/02 , Y10T436/10 , C08L23/04 , C08F2500/01 , C08F2500/03
摘要： Polymer fractions such as polyethylene fractions can be produced that have a PDI less than about 2.3 and a Mw greater than about 1,000,000 g/mol, 3,000,000 g/mol, or 6,000,000 g/mol. Such polyethylene fractions are separated from a UHMWPE parent polymer by first dissolving the parent polymer in a relatively good solvent. The conditions employed for such dissolution are selected to reduce the degradation of the parent polymer. The resulting parent solution is transported into a fractionation column in which a support is disposed. The fractionation column is thereafter operated at conditions effective to form a precipitate on the support comprising the desired polyethylene fraction. The polyethylene fraction may then be recovered from the fractionation column by repeatedly displacing a solvent/non-solvent mixture into the column to dissolve the polyethylene fraction. The relative concentrations of the solvent and the non-solvent are based on a solvent gradient profile of the polyethylene parent polymer.
摘要翻译：可以制备聚合物级分，例如具有小于约2.3的PDI和大于约1,000,000g / mol的Mw，3,000,000g / mol或6,000,000g / mol的聚乙烯级分。通过首先将母体聚合物溶解在相对良好的溶剂中，将这样的聚乙烯部分与UHMWPE母体聚合物分离。选择用于这种溶解的条件以降低母体聚合物的降解。将所得的母体溶液输送到其中设置有支持物的分馏塔。然后分馏塔在有效地在包含所需聚乙烯部分的载体上形成沉淀物的条件下操作。然后可以通过将溶剂/非溶剂混合物重复置换到柱中以溶解聚乙烯部分，从分馏塔中回收聚乙烯部分。溶剂和非溶剂的相对浓度基于聚乙烯母体聚合物的溶剂梯度分布。

9. 发明授权

US5280001A Benzylic oxidation and catalyst therefor 失效
标题翻译：苄氧化及其催化剂
公开(公告)号：US5280001A
公开(公告)日：1994-01-18
申请号：US956925
申请日：1992-10-05
申请人： Chung C. Tso , Robert L. Wynn
发明人： Chung C. Tso , Robert L. Wynn
IPC分类号： C07C67/00 , B01J31/04
CPC分类号： C07C67/00
摘要： Oxidation of alkylaromatics having a benzylic hydrogen atom is catalyzed by a catalyst comprising a palladium salt, a metal persulfate, a third metal salt, and a tin salt in a carboxylic acid for a period of time sufficient to convert the alkylaromatics to their corresponding oxidized derivatives. The catalyst is prepared by preheating the palladium salt and the metal persulfate at a temperature sufficient to provide the desired catalytic activity followed by addition of the third metal salt and the tin salt.
摘要翻译：具有苄基氢原子的烷基芳族化合物的氧化通过包含钯盐，金属过硫酸盐，第三金属盐和锡盐的催化剂在羧酸中催化足以将烷基芳族化合物转化成其相应的氧化衍生物的时间。通过在足以提供所需催化活性的温度下预热钯盐和金属过硫酸盐，然后加入第三金属盐和锡盐来制备催化剂。

10. 发明授权

US5210320A Preparation of 2,5-dimethylhexane-2,5-dihydroperoxide and derivatives thereof 失效
标题翻译： 2,5-二甲基己烷-2,5-二氢过氧化物及其衍生物的制备
公开(公告)号：US5210320A
公开(公告)日：1993-05-11
申请号：US930588
申请日：1992-08-17
申请人： Chung C. Tso , Joe W. Ryker
发明人： Chung C. Tso , Joe W. Ryker
IPC分类号： C07C409/04 , C07C409/16
CPC分类号： C07C409/04 , C07C407/00 , C07C409/16
摘要： A one-step process for preparing 2,5-dimethylhexane-2,5-dihydroperoxide and its alkyl derivatives comprises: (1) adding sulfuric acid to a 60-70% hydrogen peroxide solution to form a first reaction mixture where the first mixture is controlled at a temperature in the range of from about -10.degree. C. to about 10.degree. C.; (2) adding 2,5-dimethyl-2,5-dihydroxy hexane to the mixture held at a temperature in the range of from about -10.degree. C. to about 10.degree. C. or lower to form a second reaction mixture and maintaining the second mixture at a temperature in the range of from about 20.degree. C. to about 50.degree. C. for about 5 minutes to about 5 hours to form a slurry containing the solid product of 2,5-dimethylhexane-2,5-dihydroperoxide, unreacted reactants and impurities; (3) lowering the temperature of the slurry to the range of from about -10.degree. C. to about 10.degree. C.; (4) removing unreacted reactants and impurities from the solid product and optionally, washing the solid product; and (5) adding sulfated alkyl alcohol, which is prepared by adding the alkyl alcohol to sulfuric acid, to the solid product to form a third reaction mixture and maintaining the third mixture at about 30.degree. C. to about 60.degree. C. for about 1 to about 5 hours to prepare the alkyl derivatives.
摘要翻译：制备2,5-二甲基己烷-2,5-二氢过氧化物及其烷基衍生物的一步法包括：（1）向60-70％过氧化氢溶液中加入硫酸以形成第一反应混合物，其中第一混合物为控制在约-10℃至约10℃的温度范围内。（2）向保持在约-10℃至约10℃或更低温度范围的混合物中加入2,5-二甲基-2,5-二羟基己烷以形成第二反应混合物并保持第二混合物在约20℃至约50℃的温度下进行约5分钟至约5小时，以形成含有2,5-二甲基己烷-2,5-二氢过氧化物的固体产物的浆液，未反应的反应物和杂质; （3）将浆料的温度降低至约-10℃至约10℃的范围。（4）从固体产物中除去未反应的反应物和杂质，任选地洗涤固体产物; 和（5）将通过将烷基醇加入硫酸制备的硫酸化烷基醇加入到固体产物中以形成第三反应混合物并将第三混合物保持在约30℃至约60℃约约 1至约5小时以制备烷基衍生物。

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