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1. 发明授权

US5210320A Preparation of 2,5-dimethylhexane-2,5-dihydroperoxide and derivatives thereof 失效
标题翻译： 2,5-二甲基己烷-2,5-二氢过氧化物及其衍生物的制备
公开(公告)号：US5210320A
公开(公告)日：1993-05-11
申请号：US930588
申请日：1992-08-17
申请人： Chung C. Tso , Joe W. Ryker
发明人： Chung C. Tso , Joe W. Ryker
IPC分类号： C07C409/04 , C07C409/16
CPC分类号： C07C409/04 , C07C407/00 , C07C409/16
摘要： A one-step process for preparing 2,5-dimethylhexane-2,5-dihydroperoxide and its alkyl derivatives comprises: (1) adding sulfuric acid to a 60-70% hydrogen peroxide solution to form a first reaction mixture where the first mixture is controlled at a temperature in the range of from about -10.degree. C. to about 10.degree. C.; (2) adding 2,5-dimethyl-2,5-dihydroxy hexane to the mixture held at a temperature in the range of from about -10.degree. C. to about 10.degree. C. or lower to form a second reaction mixture and maintaining the second mixture at a temperature in the range of from about 20.degree. C. to about 50.degree. C. for about 5 minutes to about 5 hours to form a slurry containing the solid product of 2,5-dimethylhexane-2,5-dihydroperoxide, unreacted reactants and impurities; (3) lowering the temperature of the slurry to the range of from about -10.degree. C. to about 10.degree. C.; (4) removing unreacted reactants and impurities from the solid product and optionally, washing the solid product; and (5) adding sulfated alkyl alcohol, which is prepared by adding the alkyl alcohol to sulfuric acid, to the solid product to form a third reaction mixture and maintaining the third mixture at about 30.degree. C. to about 60.degree. C. for about 1 to about 5 hours to prepare the alkyl derivatives.
摘要翻译：制备2,5-二甲基己烷-2,5-二氢过氧化物及其烷基衍生物的一步法包括：（1）向60-70％过氧化氢溶液中加入硫酸以形成第一反应混合物，其中第一混合物为控制在约-10℃至约10℃的温度范围内。（2）向保持在约-10℃至约10℃或更低温度范围的混合物中加入2,5-二甲基-2,5-二羟基己烷以形成第二反应混合物并保持第二混合物在约20℃至约50℃的温度下进行约5分钟至约5小时，以形成含有2,5-二甲基己烷-2,5-二氢过氧化物的固体产物的浆液，未反应的反应物和杂质; （3）将浆料的温度降低至约-10℃至约10℃的范围。（4）从固体产物中除去未反应的反应物和杂质，任选地洗涤固体产物; 和（5）将通过将烷基醇加入硫酸制备的硫酸化烷基醇加入到固体产物中以形成第三反应混合物并将第三混合物保持在约30℃至约60℃约约 1至约5小时以制备烷基衍生物。

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