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1. 发明申请

WO2019142017A1 OPTICAL FIBRE HAVING A CROSSLINKED POLYESTER COATING 审中-公开
公开(公告)号：WO2019142017A1
公开(公告)日：2019-07-25
申请号：PCT/IB2018/050345
申请日：2018-01-19
申请人： PRYSMIAN S.P.A. , POLITECNICO DI MILANO
发明人： TERRUZZI, Lidia , DE MARTINO, Pamela , CITTERIO, Attilio , GOLA, Massimo
IPC分类号： C03C25/323 , C03C25/50 , C09D167/08
CPC分类号： C03C25/323 , C03C25/50 , C09D167/08
摘要： An optical fibre comprising: an optical waveguide comprising a glass core surrounded by a glass cladding; a coating surrounding said optical waveguide comprising a polymer material comprising a cured polyester obtained by: (a) esterification of a reactant (A) selected from carboxylic acids, triglycerides, and mixtures thereof, having a C16-C24 aliphatic chain comprising at least two conjugated double bonds, with a reactant (B) selected from polyols having at least 3 hydroxyl groups, the polyols being thermally stable up to 300°C; (b) curing of the 10 so obtained polyester, in the presence of a transition metal salt, the transition metal being selected from Mn, Fe, Co, Cu, and Ni. Preferably, the step of curing is a thermal curing, preferably up to 300°C. The transition metal salt acts as curing accelerator, i.e. it increases the curing rate so as to match the optical fibre drawing speed, the temperature of the glass exiting the drawing step and the drawing tower height commonly used in industrial plants for optical fibre production.

2. 发明申请

WO2018046984A1 OPTICAL FIBRE COATED WITH A POLYESTER COATING 审中-公开
标题翻译：涂有聚酯涂层的光纤
公开(公告)号：WO2018046984A1
公开(公告)日：2018-03-15
申请号：PCT/IB2016/055389
申请日：2016-09-09
申请人： PRYSMIAN S.P.A. , POLITECNICO DI MILANO
发明人： TERRUZZI, Lidia , DE MARTINO, Pamela , CITTERIO, Attilio , GOLA, Massimo
IPC分类号： C03C25/32 , C03C25/50 , C08G63/48 , C09D167/08
CPC分类号： G02B6/02395 , C03C25/002 , C03C25/1065 , C03C25/12 , C03C25/325 , C03C25/50 , C08G63/48 , C09D167/08
摘要： The present invention concerns an optical fibre comprising: an optical waveguide comprising a glass core surrounded by a glass cladding; a coating surrounding said optical waveguide comprising a cured polymer material comprising a polyester obtained by polymerization of a monomer selected from an acid, a triglyceride, or a mixture of triglycerides having a C 16 -C 24 aliphatic chain comprising at least two conjugated double bonds. The present invention concerns also a method for coating an optical fibre with said polyester coating. The cured polymer material forming the coating can be prepared by curing the polyester of the invention either thermally or by radiation.
摘要翻译：本发明涉及一种光纤，其包括：光波导，其包括由玻璃包层围绕的玻璃芯; 围绕所述光波导的涂层包含固化的聚合物材料，所述固化的聚合物材料包含通过聚合选自酸，甘油三酯或具有C 16 -C 24的甘油三酯混合物的单体而获得的聚酯脂族链包含至少两个共轭双键。本发明还涉及用所述聚酯涂层涂覆光纤的方法。形成涂层的固化聚合物材料可以通过热固化或辐射固化本发明的聚酯来制备。

3. 发明申请

WO2017103655A1 OPTICAL FIBRE WITH ENHANCED HIGH TEMPERATURE RESISTANCE 审中-公开
标题翻译：具有增强的高温抗性的光纤
公开(公告)号：WO2017103655A1
公开(公告)日：2017-06-22
申请号：PCT/IB2015/059686
申请日：2015-12-16
申请人： PRYSMIAN S.P.A. , POLITECNICO DI MILANO
发明人： TERRUZZI, Lidia , DE MARTINO, Pamela , CITTERIO, Attilio
IPC分类号： G02B6/02 , C03C25/10 , C09D4/06 , C08G18/48 , C08G18/75 , C08F290/06 , C08G18/24 , C09D175/16 , G02B6/44
CPC分类号： G02B6/02395 , C03C25/1065 , C08F290/067 , C08G18/246 , C08G18/4854 , C08G18/758 , C09D4/00 , C09D175/16 , G02B6/443 , C08G18/672 , C08G18/48 , C08F2222/1013 , C08F2222/1086
摘要： An optical fibre comprising: an optical waveguide comprising a core surrounded by a cladding; a primary coating surrounding the optical waveguide; and a coating, surrounding the primary coating, comprising a polymer material obtained by radiation curing a polymerizable composition, the polymer material having a degree of crystallinity of at most 12. The coating of the optical fiber according to the present invention exhibits enhanced resistance upon exposure to high temperature, preferably a temperature over 250°C, while endowed with required features such as protective capability, elasticity, adhesion to underlying layer and simple manufacturing.
摘要翻译：一种光纤，包括：光波导，包括由包层围绕的芯; 围绕光波导的主涂层; 以及围绕所述主涂层的涂层，所述涂层包含通过辐射固化可聚合组合物获得的聚合物材料，所述聚合物材料具有至多12的结晶度。根据本发明的光纤涂层在暴露到高温，优选高于250℃的温度，同时赋予所需的特征，例如保护能力，弹性，对下层的粘附性和简单的制造。

4. 发明申请

WO2018015790A1 OPTICAL FIBRE COATED WITH A POLYESTER COATING 审中-公开
标题翻译：涂有聚酯涂层的光纤
公开(公告)号：WO2018015790A1
公开(公告)日：2018-01-25
申请号：PCT/IB2016/054380
申请日：2016-07-22
申请人： PRYSMIAN S.P.A. , POLITECNICO DI MILANO
发明人： TERRUZZI, Lidia , DE MARTINO, Pamela , CITTERIO, Attilio , GOLA, Massimo
IPC分类号： C03C25/32 , C03C25/50 , C08G63/00 , C09D167/00
摘要： The present invention concerns an optical fibre comprising: an optical waveguide comprising a glass core surrounded by a glass cladding; a coating surrounding said optical waveguide comprising a cured polymer material comprising a polyester obtained by esterification of: a reactant A selected from an acid, a triglyceride, or a mixture of triglycerides having a C 16 -C 24 aliphatic chain comprising at least two conjugated double bonds; and a polyol made of at least one monomer comprising at least 3 hydroxyl groups, the polyol being thermally stable up to 300°C (reactant B). The present invention concerns also the above said polyester coating, a method for coating an optical fibre with said polyester coating and a method for obtaining predetermined mechanical properties of a coating for an optical fibre. The cured polymer forming the coating can be prepared by curing the polyester of the invention either thermally or by radiation.
摘要翻译：本发明涉及一种光纤，其包括：光波导，其包括由玻璃包层围绕的玻璃芯; 围绕所述光波导的涂层包含固化的聚合物材料，所述固化的聚合物材料包含通过酯化获得的聚酯：选自酸，甘油三酯或具有C 16 -C 18亚烷基的甘油三酯混合物的反应物A 包含至少两个共轭双键的24脂族链; 和由至少一种包含至少3个羟基的单体制成的多元醇，所述多元醇在高达300℃（反应物B）下是热稳定的。本发明还涉及上述聚酯涂层，用所述聚酯涂层涂覆光纤的方法和用于获得光纤涂层的预定机械性能的方法。形成涂层的固化聚合物可以通过热固化或辐射固化本发明的聚酯来制备。

5. 发明申请

WO2017050387A1 POWER CABLE OF ALUMINIUM COATED WITH A TETRAZOLE COMPOUND CORROSION INHIBITOR 审中-公开
标题翻译：用四唑化合物腐蚀抑制剂涂覆的铝的电源线
公开(公告)号：WO2017050387A1
公开(公告)日：2017-03-30
申请号：PCT/EP2015/072081
申请日：2015-09-25
申请人： PRYSMIAN S.P.A. , POLITECNICO DI MILANO
发明人： DE MARTINO, Pamela , FALLAHMOHAMMADI, Ehsan , CITTERIO, Attilio , TERRUZZI, Lidia
IPC分类号： C23F11/14 , H01B7/28 , H01B7/282 , H01B3/18 , H01B3/30 , H01B3/42
CPC分类号： C23F11/149 , C08K5/3472 , H01B3/185 , H01B3/305 , H01B3/421 , H01B7/2806 , H01B7/282 , H01B7/2825 , Y02A30/14
摘要： The present invention relates to a power cable comprising a metallic electric conductor surrounded by one or more semiconductive layer and one or more insulating layer, said cable having at least one metallic element made of aluminium, wherein a corrosion inhibitor is provided in direct contact with said at least one metallic element made of aluminium, and wherein said corrosion inhibitor is a corrosion inhibitor of formula (I).
摘要翻译：本发明涉及一种电力电缆，包括由一个或多个半导体层和一个或多个绝缘层围绕的金属导电体，所述电缆具有至少一个由铝制成的金属元件，其中提供腐蚀抑制剂以与所述绝缘层直接接触至少一种由铝制成的金属元件，其中所述腐蚀抑制剂是式（I）的腐蚀抑制剂。

6. 发明公开

EP3626688A1 OPTICAL FIBRE HAVING A CROSSLINKED SECONDARY COATING 有权
公开(公告)号：EP3626688A1
公开(公告)日：2020-03-25
申请号：EP19197937.6
申请日：2019-09-18
申请人： Prysmian S.p.A. , Politecnico di Milano
发明人： TERRUZZI, Lidia , DE MARTINO, Pamela , CITTERIO, Attilio , GOLA, Massimo
IPC分类号： C03C25/323 , C03C25/36 , C09D163/00 , C09D167/06
摘要： An optical fibre comprising: an optical waveguide comprising a glass core surrounded by a glass cladding; a primary coating surrounding the optical waveguide; a secondary coating, surrounding the primary coating, comprising a cured polymer material obtained by curing a curable coating composition comprising: (a) a polyester obtained by esterification of a reactant A selected from carboxylic acids, triglycerides, and mixtures thereof, having a C 16 -C 24 aliphatic chain comprising at least two double bonds spaced by one carbon atom at most, with a reactant B selected from polyols having at least 3 hydroxyl groups, the polyols being thermally stable up to 300°C; (b) an aromatic glycidyl epoxy resin; (c) an aliphatic polyether hardener containing from 8 to 64 hydroxy groups and/or from 2 to 4 epoxy groups; and (d) a secondary amine compound as curing agent. Preferably, the step of curing is a thermal curing, preferably up to 300°C. When cured by heat, the coating material can be applied during the drawing process of the fibre so as to exploit the heat of the just drawn glass fibre as heat source for curing.

7. 发明公开

EP3353334A1 POWER CABLE OF ALUMINIUM COATED WITH A TETRAZOLE COMPOUND CORROSION INHIBITOR 有权
公开(公告)号：EP3353334A1
公开(公告)日：2018-08-01
申请号：EP15771568.1
申请日：2015-09-25
申请人： Prysmian S.p.A. , Politecnico di Milano
发明人： DE MARTINO, Pamela , FALLAHMOHAMMADI, Ehsan , CITTERIO, Attilio , TERRUZZI, Lidia
IPC分类号： C23F11/14 , H01B7/28 , H01B7/282 , H01B3/18 , H01B3/30 , H01B3/42
摘要： A power cable having a metallic electrical conductor surrounded by one or more semiconductive layer and more or more insulating layer, wherein the cable has at least one metallic element made of aluminum, having a corrosion inhibitor provided in direct contact with the at least one metallic element made of aluminum.

8. 发明公开

EP3740461A1 OPTICAL FIBRE HAVING A CROSSLINKED POLYESTER COATING 有权
公开(公告)号：EP3740461A1
公开(公告)日：2020-11-25
申请号：EP18703365.9
申请日：2018-01-19
申请人： Prysmian S.p.A. , Politecnico di Milano
发明人： TERRUZZI, Lidia , DE MARTINO, Pamela , CITTERIO, Attilio , GOLA, Massimo
IPC分类号： C03C25/323 , C03C25/50 , C09D167/08

9. 发明公开

EP3510004A1 OPTICAL FIBRE COATED WITH A POLYESTER COATING 有权
公开(公告)号：EP3510004A1
公开(公告)日：2019-07-17
申请号：EP16766642.9
申请日：2016-09-09
申请人： Prysmian S.p.A. , Politecnico di Milano
发明人： TERRUZZI, Lidia , DE MARTINO, Pamela , CITTERIO, Attilio , GOLA, Massimo
IPC分类号： C03C25/32 , C03C25/50 , C08G63/48 , C09D167/08

10. 发明公开

EP3391107A1 OPTICAL FIBRE WITH ENHANCED HIGH TEMPERATURE RESISTANCE 有权
公开(公告)号：EP3391107A1
公开(公告)日：2018-10-24
申请号：EP15817575.2
申请日：2015-12-16
申请人： Prysmian S.p.A. , Politecnico di Milano
发明人： TERRUZZI, Lidia , DE MARTINO, Pamela , CITTERIO, Attilio
IPC分类号： G02B6/02 , C03C25/10 , C09D4/06 , C08G18/48 , C08G18/75 , C08F290/06 , C08G18/24 , C09D175/16 , G02B6/44
CPC分类号： G02B6/02395 , C03C25/1065 , C08F290/067 , C08G18/246 , C08G18/4854 , C08G18/758 , C09D4/00 , C09D175/16 , G02B6/443 , C08G18/672 , C08G18/48 , C08F2222/1013 , C08F2222/1086
摘要： An optical fibre comprising: an optical waveguide comprising a core surrounded by a cladding; a primary coating surrounding the optical waveguide; and a coating, surrounding the primary coating, comprising a polymer material obtained by radiation curing a polymerizable composition, the polymer material having a degree of crystallinity of at most 12. The coating of the optical fiber according to the present invention exhibits enhanced resistance upon exposure to high temperature, preferably a temperature over 250°C, while endowed with required features such as protective capability, elasticity, adhesion to underlying layer and simple manufacturing.

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