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1. 发明授权

US07491855B2 Integrated process for the production of bisphenol A from cumene hydroperoxide 有权
标题翻译：由氢过氧化枯烯生产双酚A的综合工艺
公开(公告)号：US07491855B2
公开(公告)日：2009-02-17
申请号：US10250114
申请日：2003-06-04
申请人： Pramod Shankar Kumbhar , Jegadeesh Thampi , Bharat Singh , John W. Fulmer , Prashant Anil Tatake
发明人： Pramod Shankar Kumbhar , Jegadeesh Thampi , Bharat Singh , John W. Fulmer , Prashant Anil Tatake
IPC分类号： C07C39/16
CPC分类号： C07C37/20 , C07C37/08 , Y02P20/125 , Y02P20/52 , C07C39/04 , C07C39/16
摘要： Use of a specific combination of catalysts for the first and second steps of the process for the conversion of CHP to BPA provides high yields of BPA and low impurity yields, without a requirement for the intermediate purification steps. In the first step, CHP is cleaved in the presence of an acid treated clay such as acid treated Montmorillonite clay to produce phenol and acetone. In the second step, the phenol and acetone produced is reacted, preferably without intermediate purification, in the presence of a cation exchange resin catalyst that includes a cation exchange resin and a mercaptan or mercaptoalkanoic acid promoter to produce BPA.
摘要翻译：用于将CHP转化为BPA的方法的第一和第二步骤的特定的催化剂组合的使用提供了高产率的BPA和低杂质产率，而不需要中间纯化步骤。在第一步中，CHP在酸处理的粘土如酸处理的蒙脱石粘土存在下裂解，以产生苯酚和丙酮。在第二步中，所生产的苯酚和丙酮优选不经中间纯化，在包含阳离子交换树脂和硫醇或巯基链烷酸促进剂以产生BPA的阳离子交换树脂催化剂的存在下反应。

2. 发明授权

US07154010B2 Integrated process for the production of bisphenol A from cumene hydroperoxide 有权
标题翻译：由氢过氧化枯烯生产双酚A的综合工艺
公开(公告)号：US07154010B2
公开(公告)日：2006-12-26
申请号：US10250107
申请日：2003-06-04
申请人： Pramod Shankar Kumbhar , Jegadeesh Thampi , Bharat Singh , John W. Fulmer , Prashant Anil Tatake
发明人： Pramod Shankar Kumbhar , Jegadeesh Thampi , Bharat Singh , John W. Fulmer , Prashant Anil Tatake
IPC分类号： C07C36/16
CPC分类号： C07C37/20 , C07C37/08 , C07C45/53 , Y02P20/125 , Y02P20/52 , C07C39/04 , C07C39/16 , C07C49/08
摘要： Use of a specific combination of catalysts for the first and second steps of the process for the conversion of CHP to BPA provides high yields of BPA and low impurity yields, without a requirement for the intermediate purification steps. In the first step, CHP is cleaved in the presence of a sulfated metal oxide catalyst such as sulfated Zirconia to produce phenol and acetone. In the second step, the phenol and acetone produced is reacted, preferably without intermediate purification, in the presence of a cation exchange resin catalyst that includes a cation exchange resin and a mercaptan or mercaptoalkanoic acid promoter to produce BPA.
摘要翻译：用于将CHP转化为BPA的方法的第一和第二步骤的特定的催化剂组合的使用提供了高产率的BPA和低杂质产率，而不需要中间纯化步骤。在第一步中，CHP在硫酸化金属氧化物催化剂如硫酸化氧化锆存在下裂解，生成苯酚和丙酮。在第二步中，所生产的苯酚和丙酮优选不经中间纯化，在包含阳离子交换树脂和硫醇或巯基链烷酸促进剂以产生BPA的阳离子交换树脂催化剂的存在下反应。

3. 发明授权

US06486365B1 Production and purification of phenol: hydroxyacetone removal by hydrotalcite 有权
标题翻译：苯酚的生产和纯化：通过水滑石除去羟基丙酮
公开(公告)号：US06486365B1
公开(公告)日：2002-11-26
申请号：US10063258
申请日：2002-04-04
申请人： John W. Fulmer , Bharat Singh , Pramod Kumbhar , Prashant Anil Tatake , Umesh Hasyagar
发明人： John W. Fulmer , Bharat Singh , Pramod Kumbhar , Prashant Anil Tatake , Umesh Hasyagar
IPC分类号： C07C3708
CPC分类号： C07C37/86 , C07C2521/10 , C07C39/04
摘要： A process for converting carbonyl-type impurities contained in a phenolic solvent to high-boiling derivatives is provided by contacting the phenolic solvent with a hydrotalcite-type material (HTM). The phenol can be separated from the high-boiling derivatives using conventional separation techniques, such as distillation, so the invention also provides a process for separating carbonyl-type impurities, such as hydroxyacetone (HA), from a phenolic solvent. The process can be applied in the conventional industrial process for converting cumene to phenol to remove carbonyl-type impurities from the phenol product. A process and a facility for producing purified phenol by converting cumene to phenol are provided. In the conversion of cumene to phenol, the phenol often contains carbonyl-type impurities. The phenol and carbonyl-type impurities are reacted in the presence of an HTM to produce phenol and high-boiling derivatives. The phenol may be further purified using conventional separation techniques, such as distillation, to remove the high-boiling derivatives.
摘要翻译：通过使酚类溶剂与水滑石类材料（HTM）接触来提供将酚类溶剂中所含的羰基型杂质转化成高沸点衍生物的方法。苯酚可以使用常规的分离技术如蒸馏从高沸点衍生物中分离，因此本发明还提供了从酚类溶剂中分离羰基型杂质如羟基丙酮（HA）的方法。该方法可用于将异丙基苯转化为苯酚以从苯酚产物中除去羰基型杂质的常规工业方法。提供了通过将异丙基苯转化成苯酚来生产纯化苯酚的方法和设备。在异丙苯转化为苯酚时，苯酚常含有羰基型杂质。苯酚和羰基型杂质在HTM存在下反应生成苯酚和高沸点衍生物。可以使用常规分离技术如蒸馏进一步纯化苯酚，以除去高沸点衍生物。

4. 发明授权

US06635789B2 Production and purification of phenol 失效
标题翻译：苯酚的生产和纯化
公开(公告)号：US06635789B2
公开(公告)日：2003-10-21
申请号：US09683956
申请日：2002-03-06
申请人： John W. Fulmer , Nitin Vaish , Pramod Kumbhar , Jacob L. Oberholtzer , R. Jothi Mahalingam
发明人： John W. Fulmer , Nitin Vaish , Pramod Kumbhar , Jacob L. Oberholtzer , R. Jothi Mahalingam
IPC分类号： C07C3768
CPC分类号： C07C37/82 , B01J41/02 , B01J41/10 , C07C39/04
摘要： A process for separating sulfonic acid compounds from a phenolic solvent is provided by contacting the phenolic solvent with a hydrotalcite-type material (HTM). The process can be applied in the conventional industrial process for converting cumene to phenol to remove sulfonic acid compounds from the phenol product. A process and a facility for producing purified phenol by converting cumene to phenol are provided. In the conversion of cumene to phenol, the phenol often contains carbonyl-type impurities. The phenol and carbonyl-type impurities are reacted in the presence of a sulfonic acid cation exchange resin catalyst (IER) to produce a reaction product that may contain sulfonic acid compounds. The reaction product is contacted with an HTM to reduce the amount of sulfonic acid compounds which may be present and to produce a purified phenol-containing stream. The purified phenol-containing stream may be further purified using conventional separation techniques, such as distillation.
摘要翻译：通过使酚类溶剂与水滑石型材料（HTM）接触来提供从酚类溶剂中分离磺酸化合物的方法。该方法可用于将异丙基苯转化为苯酚以从苯酚产物中除去磺酸化合物的常规工业过程。提供了通过将异丙基苯转化成苯酚来生产纯化苯酚的方法和设备。在异丙苯转化为苯酚时，苯酚常含有羰基型杂质。苯酚和羰基型杂质在磺酸阳离子交换树脂催化剂（IER）的存在下反应，生成可能含有磺酸化合物的反应产物。使反应产物与HTM接触，以减少可能存在的磺酸化合物的量并产生纯化的含苯酚流。可以使用常规分离技术例如蒸馏进一步纯化纯化的含苯酚流。

5. 发明授权

US4626600A Process for purifying acetone 失效
标题翻译：丙酮纯化方法
公开(公告)号：US4626600A
公开(公告)日：1986-12-02
申请号：US703990
申请日：1985-02-21
申请人： John W. Fulmer , William D. Kight
发明人： John W. Fulmer , William D. Kight
IPC分类号： C07C45/53 , C07C45/80 , C07C45/81 , C07C45/82
CPC分类号： C07C45/81 , C07C45/53 , C07C45/80 , C07C45/82
摘要： In accordance with the invention there is a process for reducing the water content of acetone prepared from cumene which includes the steps ofa. adding cleaving effective catalytic quantities of sulfuric acid to a mixture comprising cumene hydroperoxide and cumene, the cumene hydroperoxide making up about 81 to 83 weight percent of the said mixture, thereby producing a mixture comprising phenol, acetone, cumene and sulfuric acid;b. neutralizing the said sulfuric acid with an aqueous alkali hydroxide and separating the alkali metal sulfate from the mixture comprising phenol, acetone, water and cumene, the water being from about 40 to 60 weight percent of the total weight of water and cumene, the cumene being present in sufficient quantities to cause the formation of two liquid phases upon condensing the acetone fraction distillate;c. separating by distillation the acetone fraction from the phenol fraction, said acetone fraction containing acetone, water, aldehyde, and other organics including cumene;d. condensing the said acetone fraction, the said acetone fraction separating into two phases, the bottom phase having a substantial portion of the water and aldehyde present in the said acetone fraction, the upper phase having a substantial portion of the cumene of the said acetone fraction, the acetone being partitioned between the bottom phase and the upper phase;e. recycling at least a portion of the bottom phase to the vessel in which the sulfuric acid is neutralized andf. processing the upper phase to achieve a separation of the acetone and water.
摘要翻译：根据本发明，存在一种降低由枯烯制备的丙酮的水含量的方法，其包括以下步骤：a。向包含氢过氧化异丙苯和异丙基苯的混合物中加入有效催化量的硫酸，氢过氧化异丙苯占所述混合物的约81-83％（重量），从而产生包含苯酚，丙酮，异丙基苯和硫酸的混合物; b。用碱金属氢氧化物中和所述硫酸，并从包括苯酚，丙酮，水和枯烯的混合物中分离出碱金属硫酸盐，水为水和异丙基苯的总重量的约40至60重量％，枯烯为存在足够的量以在冷凝丙酮馏分馏出物时形成两个液相; C。通过蒸馏从苯酚馏分中蒸馏出丙酮馏分，所述丙酮馏分含有丙酮，水，醛和其它有机物，包括枯烯; d。将所述丙酮馏分冷凝，将所述丙酮馏分分离成两相，底相具有存在于所述丙酮馏分中的大部分水和醛，上部相具有所述丙酮馏分的枯烯的相当大部分，丙酮被分配在底相和上相之间; e。将至少一部分底部相转移到其中硫酸中和的容器中。加工上相以实现丙酮和水的分离。

6. 发明授权

US5504251A Co-cracking of BPA and phenol process tars 失效
标题翻译： BPA和苯酚过程焦油的共裂化
公开(公告)号：US5504251A
公开(公告)日：1996-04-02
申请号：US401732
申请日：1995-03-09
申请人： Arkady S. Dyckman , Andrey V. Zinenkov , Boris I. Gorovits , Valentina Y. Shefter , John W. Fulmer , William D. Kight
发明人： Arkady S. Dyckman , Andrey V. Zinenkov , Boris I. Gorovits , Valentina Y. Shefter , John W. Fulmer , William D. Kight
IPC分类号： C07B63/02 , C07C7/148 , C07C15/085 , C07C15/44 , C07C37/00 , C07C37/52 , C07C37/86 , C07C39/04 , C07C37/68
CPC分类号： C07C7/148 , C07C37/52 , Y02P20/127
摘要： This invention relates to processing of a mixture of tars produced in phenol manufacture and in bisphenol manufacture. The heating of a bottom liquid from a bisphenol-A process together with phenol tar from in a cumene-to-phenol process in a distillation column-type thermal cracking reactor at 290.degree.-360.degree. C. at a mass ratio of 1:(1-10) is employed. The process is carried out by feed entering into the middle of the column and valuable products removed as overhead.
摘要翻译：本发明涉及在酚制造和双酚制造中生产的焦油混合物的加工。在蒸馏塔型热裂解反应器中，在290℃-360℃以1：3的质量比将来自双酚A工艺的底部液体与苯酚焦油一起从异丙苯到苯酚方法加热 1-10）。该过程由进入塔中部的饲料进行，有价值的产物作为塔顶除去。

7. 发明授权

US4567304A Process for preparing acetone and phenol 失效
标题翻译：制备丙酮和苯酚的方法
公开(公告)号：US4567304A
公开(公告)日：1986-01-28
申请号：US614124
申请日：1984-05-24
申请人： John W. Fulmer
发明人： John W. Fulmer
IPC分类号： C07C27/00 , C07C27/26 , C07C29/132 , C07C37/08 , C07C37/74 , C07C39/04 , C07C45/00 , C07C45/53 , C07C49/08 , C07C67/00
CPC分类号： C07C45/53 , C07C37/74
摘要： Benzene, toluene and ethylbenzene is removed from the heavy residues of a phenol distillation in a phenol and acetone from cumene process.
摘要翻译：从苯酚和丙酮中的苯酚蒸馏的重残余物中除去苯，甲苯和乙苯。

8. 发明授权

US4480134A Process for preparing phenol and acetone from cumene 失效
标题翻译：从异丙苯制备苯酚和丙酮的方法
公开(公告)号：US4480134A
公开(公告)日：1984-10-30
申请号：US482298
申请日：1983-04-05
申请人： John W. Fulmer
发明人： John W. Fulmer
IPC分类号： C07C39/04 , C07C45/53 , C07C45/82
CPC分类号： C07C45/53 , C07C39/04 , C07C45/82
摘要： Benzene is removed from the heavy residues of a phenol distillation in a phenol and acetone from cumene process.
摘要翻译：在苯酚和丙酮的苯酚蒸馏的重残渣中从异丙苯法除去苯。

9. 发明授权

US6025530A Phenol tar cracking process 失效
标题翻译：苯酚焦油开裂过程
公开(公告)号：US6025530A
公开(公告)日：2000-02-15
申请号：US18662
申请日：1998-02-04
申请人： Arkady Samuilovich Dyckman , Andrey Zinenkov , Boris Issakovich Gorovits , John W. Fulmer
发明人： Arkady Samuilovich Dyckman , Andrey Zinenkov , Boris Issakovich Gorovits , John W. Fulmer
IPC分类号： C07C37/52 , C07C37/72 , C07C37/86 , C07C39/06 , C10C1/19 , C07C37/68 , C07C45/00
CPC分类号： C07C37/86 , C07C37/72 , C10C1/19
摘要： The present invention relates generally to a method for treating phenol tar, and, more particularly to a method for separating valuable products from phenol tar by treating the tar with steam.
摘要翻译：本发明一般涉及一种处理苯酚焦油的方法，更具体地说，涉及通过用蒸汽处理焦油来分离有价值的产物与苯酚焦油的方法。

10. 发明授权

US5510543A Removal and neutralization of acid catalyst from products of cumene hydroperoxide cleavage 失效
标题翻译：从氢过氧化枯烯裂解产物中除去和中和酸催化剂
公开(公告)号：US5510543A
公开(公告)日：1996-04-23
申请号：US353004
申请日：1994-12-09
申请人： John W. Fulmer , Andrei K. Griaznov , William D. Kight , Vladimir M. Zakoshansky
发明人： John W. Fulmer , Andrei K. Griaznov , William D. Kight , Vladimir M. Zakoshansky
IPC分类号： C07C37/08 , C07C37/68 , C07C37/72 , C07C39/04 , C10C1/00
CPC分类号： C07C37/72 , C07C37/86 , Y02P20/52
摘要： The present invention is an improved method for the recovery of phenol from a cleavage mass resulting from the sulfuric acid cleavage of cumene hydroperoxide comprising neutralizing the cleavage mass, forming an aqueous phase and an organic phase, separating the organic phase into an acetone-rich stream and a phenol-rich stream, removing phenol tars from the phenol-rich stream and cracking the phenol tars wherein the improvement comprises maintaining the pH of the cleavage mass during neutralization between 4.0 and about 4.9 whereby the sulfuric acid is converted to the bisulfate salt and substantially no free sulfuric acid remains in the cleavage mass and corrosion of process equipment is reduced.As a result of this improved process, a phenol tar waste stream containing less than about 4 parts per million by weight of chromium is obtained.
摘要翻译：本发明是一种改进的方法，用于从由氢过氧化枯烯的硫酸裂解产生的裂解物质中回收苯酚，包括中和裂解物质，形成水相和有机相，将有机相分离成富含丙酮的物流和富酚的物流，从富酚流中除去酚焦油并裂解苯酚焦碳，其中改进包括在中和期间保持裂解物质的pH在4.0至约4.9之间，由此将硫酸转化为硫酸氢盐，并且在裂解物质中基本上不残留游离硫酸，并减少了工艺设备的腐蚀。作为这种改进方法的结果，获得了含有小于约4重量％的铬的酚焦油废液流。

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