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    • 9. 发明申请
    • CATHODE COATING
    • 阴极涂层
    • US20100289009A1
    • 2010-11-18
    • US12309575
    • 2007-07-26
    • Subramaniam GaneshamuruganPoopathy KathirgamanathanSivagnanasundram SurendrakumarSeenivasagam RavichandranYun Fu Chan
    • Subramaniam GaneshamuruganPoopathy KathirgamanathanSivagnanasundram SurendrakumarSeenivasagam RavichandranYun Fu Chan
    • H01L51/54H01L51/56B05D5/06
    • H01L51/5092H01L51/0077H01L51/009H01L51/5088
    • Embodiments of electroluminescent devices of the invention are preferably formed of a transparent anode; a layer of a hole transporting material; a layer of an electroluminescent material; a layer of an electron transporting material; a layer of lithium quinolate or of a substituted lithium quinolate e.g. of thickness less than 7 nm; and a metal cathode. The layer of the metal quinolate is preferably about 0.3-0.5 nm in thickness. In an embodiment there is provided an organic light-emitting diode having a cathode, an electron injection layer in contact with the cathode and an electron transport layer in contact with the electron injection layer and comprising aluminium, zirconium or hafnium quinolate or a mixture thereof or a mixture of any of them with a quinolate of a metal of group 1, 2, 3, 13 or 14 of the periodic table, wherein the electron injection layer comprises lithium quinolate or a substituted lithium quinolate having one or more substituents selected from C1-C4 alkyl, monocyclic aryl or aralk-(C1-C4)-yl, aryloxy or fluoro subject to the proviso that not more than one substituent is C2-C4 alkyl, aralkyl or aryloxy or an oligomer thereof, and wherein the electrode is of aluminium. Such devices may be made by a method including the steps of forming lithium quinolate or a substituted lithium quinolate having one or more substituents selected from C1-C4 alkyl, monocyclic aryl or aralk-(C1-C4)-yl, aryloxy or fluoro subject to the proviso that not more than one substituent is C2-C4 alkyl, aralkyl or aryloxy by reacting a lithium alkyl or alkoxide with 8-hydroxyquinoline or a derivative thereof in a solvent comprising acetonitrile, and depositing lithium quinolate or a substituted lithium quinolate formed as described above on a cathode of the device to provide an electron injection layer.
    • 本发明的电致发光器件的实施例优选由透明阳极形成; 一层空穴传输材料; 一层电致发光材料; 一层电子传输材料; 一层喹啉锂或一种取代的喹啉锂。 厚度小于7nm; 和金属阴极。 金属喹啉的层的厚度优选为约0.3-0.5nm。 在一个实施方案中,提供了一种有机发光二极管,其具有阴极,与阴极接触的电子注入层和与电子注入层接触并包含铝,锆或喹铪酸盐或其混合物的电子传输层,或 其中任何一种与周期表第1,2,3,13或14族金属的喹啉的混合物,其中电子注入层包含喹啉酸锂或具有一个或多个选自C1- C4烷基,单环芳基或芳 - (C1-C4) - 基,芳氧基或氟,条件是不多于一个取代基是C 2 -C 4烷基,芳烷基或芳氧基或其低聚物,其中电极是铝 。 这样的装置可以通过以下方法制备:包括以下步骤:形成喹诺酮酸锂或具有一个或多个选自C 1 -C 4烷基,单环芳基或芳烷基(C 1 -C 4) - 基,芳氧基或氟的取代的喹啉锂, 条件是通过使烷基或烷氧基化锂与8-羟基喹啉或其衍生物在包含乙腈的溶剂中反应而不是多于一个取代基是C 2 -C 4烷基,芳烷基或芳氧基,并沉积喹啉或取代的喹啉酸锂 在器件的阴极上方提供电子注入层。