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    • 1. 发明申请
    • NANOCOMPOSITE POSITIVE PHOTOSENSITIVE COMPOSITION AND USE THEREOF
    • NANOCOMPOSITE POSITIVE PHOSOSTIC COMPOSITION及其用途
    • US20130108956A1
    • 2013-05-02
    • US13286712
    • 2011-11-01
    • Ping-Hung LUChunwei CHENStephen MEYER
    • Ping-Hung LUChunwei CHENStephen MEYER
    • G03F7/20G03F7/004B82Y30/00
    • G03F7/0047G03F7/039G03F7/0392G03F7/405
    • The present invention relates to a positive photosensitive composition suitable for image-wise exposure and development as a positive photoresist comprising a positive photoresist composition and an inorganic particle material having an average particle size equal or greater than 10 nanometers, wherein the thickness of the photoresist coating film is less than 5 microns. The positive photoresist composition can be selected from (1) a composition comprising (i) a film-forming resin having acid labile groups, and (ii) a photoacid generator, or (2) a composition comprising (i) a film-forming novolak resin, and (ii) a photoactive compound, or (3) a composition comprising (i) a film-forming resin, (ii) a photoacid generator, and (iii) a dissolution inhibitor. The invention also relates to a process of forming an image using the novel photosensitive composition.
    • 本发明涉及适用于作为正性光致抗蚀剂的成像曝光和显影的正型光敏组合物,其包含正性光致抗蚀剂组合物和平均粒度等于或大于10纳米的无机颗粒材料,其中光致抗蚀剂涂层的厚度 薄膜小于5微米。 正光致抗蚀剂组合物可以选自(1)包含(i)具有酸不稳定基团的成膜树脂和(ii)光酸产生剂的组合物的组合物,或(2)包含(i)成膜酚醛清漆 树脂,和(ii)光活性化合物,或(3)包含(i)成膜树脂,(ii)光致酸发生剂和(iii)溶解抑制剂的组合物。 本发明还涉及使用新颖的光敏组合物形成图像的方法。
    • 2. 发明申请
    • NANOCOMPOSITE NEGATIVE PHOTOSENSITIVE COMPOSITION AND USE THEREOF
    • NANOCOMPOSITE NEGATIVE PHOSOSTIVE COMPOSITION及其用途
    • US20130105440A1
    • 2013-05-02
    • US13286755
    • 2011-11-01
    • Ping-Hung LUChunwei CHENStephen MEYER
    • Ping-Hung LUChunwei CHENStephen MEYER
    • C23F1/02G03F7/075G03F7/09G03F7/032B82Y30/00
    • G03F7/0047G03F7/027G03F7/038G03F7/405
    • The present invention relates to a negative photosensitive composition suitable for image-wise exposure and development as a negative photoresist comprising a negative photoresist composition and an inorganic particle material having an average particle size equal or greater than 10 nanometers, wherein the thickness of the photoresist coating film is less than 5 microns. The negative photoresist composition is selected from (1) a composition comprising (i) a resin binder, (ii) a photoacid generator, and (iii) a cross-linking agent; or (2) a composition comprising (i) a resin binder, (ii) optionally, addition-polymerizeable, ethylenically unsaturated compound(s) and (iii) a photoinitiator; or (3) a composition comprising (i) a photopolymerizable compound containing at least two pendant unsaturated groups; (ii) ethylenically unsaturated photopolymerizable polyalkylene oxide hydrophilic compound(s); and (iii) a photoinitiator. The invention also relates to a process of forming an image using the novel photosensitive composition.
    • 本发明涉及适用于作为负性光致抗蚀剂的成像曝光和显影的负型感光性组合物,其包含负性光致抗蚀剂组合物和平均粒度等于或大于10纳米的无机颗粒材料,其中光致抗蚀剂涂层的厚度 薄膜小于5微米。 负光致抗蚀剂组合物选自(1)包含(i)树脂粘合剂,(ii)光致酸产生剂和(iii)交联剂)的组合物; 或(2)组合物,其包含(i)树脂粘合剂,(ii)任选的可加成聚合的烯属不饱和化合物和(iii)光引发剂; 或(3)包含(i)含有至少两个侧链不饱和基团的光聚合化合物的组合物; (ii)烯属不饱和光聚合聚环氧烷亲水化合物; 和(iii)光引发剂。 本发明还涉及使用新颖的光敏组合物形成图像的方法。
    • 3. 发明申请
    • POSITIVE PHOTOSENSITIVE MATERIAL
    • 积极的感光材料
    • US20130337380A1
    • 2013-12-19
    • US13524790
    • 2012-06-15
    • Weihong LIUPingHung LUChunwei CHENStephen MEYERMedhat TOUKHYSookMee LAI
    • Weihong LIUPingHung LUChunwei CHENStephen MEYERMedhat TOUKHYSookMee LAI
    • G03F7/004
    • G03F7/004G03F7/0392G03F7/0397
    • The invention relates to a novel positive working photosensitive composition having: at least one photoacid generator; at least one novolak polymer; at least one polymer, having a polymer backbone, said polymer comprising a structure of the following formula: wherein R1-R5 are, independently, —H or —CH3, A is a linear or branched C1-C10 alkylene group, B is a C1-C12 alkyl or alicyclic group, D is a linking group that may be a chemical bond, a carboxylate group, wherein the carbonyl carbon is bonded to the polymer backbone, or a —COOCH2— group, wherein the carbonyl carbon is bonded to the polymer backbone, Ar is a substituted or unsubstituted aromatic group or heteroaromatic group, E is a linear or branched C2-C10 alkylene group, G is an acid cleavable group. The invention further relates to a process for using the novel composition for forming an image.
    • 本发明涉及一种新型的正性光敏组合物,其具有:至少一种光致酸发生剂; 至少一种酚醛清漆聚合物; 至少一种具有聚合物主链的聚合物,所述聚合物包含下式的结构:其中R 1 -R 5独立地是-H或-CH 3,A是直链或支链C 1 -C 10亚烷基,B是C1 -C 12烷基或脂环基,D是可以是化学键的连接基团,其中羰基碳键合到聚合物主链上的羧酸酯基团或-COOCH 2 - 基团,其中羰基碳键合到聚合物上 骨架,Ar是取代或未取代的芳基或杂芳基,E是直链或支链C 2 -C 10亚烷基,G是酸可裂解基团。 本发明还涉及使用该组合物形成图像的方法。