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    • 2. 发明申请
    • DEGRADABLE CASING SEAL CONSTRUCTION FOR DOWNHOLE APPLICATIONS
    • 适用于下水道应用的可降级铸件密封结构
    • US20160145964A1
    • 2016-05-26
    • US14552003
    • 2014-11-24
    • James DoaneWayne FurlanPing DuanSayantan RoyAnil Sadana
    • James DoaneWayne FurlanPing DuanSayantan RoyAnil Sadana
    • E21B33/128E21B23/06
    • E21B33/1208
    • In one aspect, a degradable apparatus is disclosed, including: an inner core with a first degradation rate in a downhole environment; an outer sheath disposed around an outer extent of the inner core with a second degradation rate less than the first degradation rate in the downhole environment. In another aspect, a method of temporarily sealing a downhole zone is disclosed, including: providing an inner core with a first degradation rate in a downhole environment; providing an outer sheath disposed around an outer extent of the inner core with a second degradation rate less than the first degradation rate in the downhole environment; sealing the downhole zone with the outer sheath; exposing the outer sheath to the downhole environment; and exposing the inner core to the downhole environment.
    • 一方面,公开了一种可降解装置,包括:在井下环境中具有第一降解速率的内核; 外护套,其设置在内芯的外部范围内,具有小于井下环境中的第一劣化率的第二降解率。 另一方面,公开了临时密封井下区域的方法,包括:在井下环境中提供具有第一降解速率的内核; 提供围绕所述内芯的外部范围设置的外护套,其具有小于所述井下环境中的所述第一降解速率的第二降解速率; 用外护套密封井下区域; 将外护套暴露于井下环境; 并将内芯暴露于井下环境中。
    • 5. 发明申请
    • DEGRADABLE MATERIAL FOR DOWNHOLE APPLICATIONS
    • 可降解材料用于井下应用
    • US20160145485A1
    • 2016-05-26
    • US14551976
    • 2014-11-24
    • James DoaneWayne FurlanPing DuanSayantan RoyAnil Sadana
    • James DoaneWayne FurlanPing DuanSayantan RoyAnil Sadana
    • C09K8/508E21B33/12
    • C09K8/5086C09K8/524E21B33/1208E21B33/134E21B43/26
    • In one aspect, degradable material is disclosed, including: a polyurethane component with a first degradation rate in a downhole environment; and a corrosive additive component with a second degradation rate that is higher than a first degradation rate in the downhole environment. In another aspect, a method of temporarily sealing a downhole zone is disclosed, including: providing a polyurethane component with a first degradation rate in a downhole environment; providing a corrosive additive component with a second degradation rate that is higher than a first degradation rate in the downhole environment; mixing the polyurethane component and the corrosive additive component to form a degradable material; sealing the downhole zone with the degradable material; exposing the degradable material to the downhole environment; and degrading the degradable material.
    • 一方面,公开了可降解材料,包括:在井下环境中具有第一降解速率的聚氨酯组分; 以及具有比井下环境中的第一降解速率高的第二降解速率的腐蚀性添加剂组分。 另一方面,公开了临时密封井下区域的方法,包括:在井下环境中提供具有第一降解速率的聚氨酯组分; 提供具有比井下环境中的第一降解速率高的第二降解速率的腐蚀性添加剂组分; 混合聚氨酯组分和腐蚀性添加剂组分以形成可降解材料; 用可降解材料密封井下区域; 将可降解材料暴露于井下环境; 并降解可降解材料。
    • 6. 发明申请
    • Silicone surfactants for rigid polyurethane foam made with hydrocarbon blowing agents
    • 用烃发泡剂制成的硬质聚氨酯泡沫硅胶表面活性剂
    • US20050131090A1
    • 2005-06-16
    • US10736042
    • 2003-12-15
    • Wayne FurlanMark ListemannJoan Sudbury-HoltschlagThomas MarkleyGary Andrew
    • Wayne FurlanMark ListemannJoan Sudbury-HoltschlagThomas MarkleyGary Andrew
    • C08G18/00C08G18/48C08G18/61C08G18/76C08G101/00C08J9/00C08J9/14
    • C08J9/141C08G18/7664C08G2101/0025C08G2101/005C08J9/0061C08J9/149C08J2203/14C08J2203/142C08J2205/10C08J2375/04C08J2483/00
    • A method for making a rigid polyurethane foam by reacting a polyisocyanate and a polyol in the presence of a urethane catalyst, a blowing agent and a silicone surfactant characterized by employing a blowing agent comprising a C4 or C5 hydrocarbon, or mixtures thereof, with an average molecular weight of ≦72 g/mole and a boiling point in the range of 27.8 to 50 ° C., and a silicone surfactant comprising a polyether-polysiloxane copolymer represented by the following formula: (CH3)3—Si—O—(Si(CH3)2—O)x—(Si(CH3)(R)O)y—Si(CH3)3 where R═(CH2)3—O—(—CH2—CH2—O)a—(CH2—CH(CH3)—O)b—R″, and where R″ is H, (CH2)ZCH3, or C(O)CH3; x+y+2 is 60-130; x/y is 5-14; z is 0-4; the total surfactant molecular weight, based on the formula, is 7000-30,000 g/mole, the wt % siloxane in the surfactant is 32-70 wt %, the blend average molecular weight (BAMW) of the polyether portion is 450-1000 g/mole, and the mole % of ethylene oxide in the polyether portion is 70-100 mole %.
    • 一种通过在聚氨酯催化剂,发泡剂和硅氧烷表面活性剂存在下使多异氰酸酯和多元醇反应制备硬质聚氨酯泡沫的方法,其特征在于使用包含C 4或C 5烃或其混合物的发泡剂, 分子量<= 72g / mol,沸点在27.8〜50℃的范围内,和含有下式表示的聚醚 - 聚硅氧烷共聚物的硅氧烷表面活性剂:&lt;线内配方说明=“ (CH 3 3)3 -Si-O-(Si(CH 3)3) (S(CH 3 O)O)y -S(CH 2)n - &lt; 3-in-line-formula description =“In-line formula”end =“tail”?>其中<?in-line-formula description =“In 线型式“end =”lead“?> R-(CH 2)3 -O - ( - CH 2)-CH (CH 2 CH 2) - (CH 2 CH 2) - (CH 2 CH 3)-O)b - SUB> -R“和<?in-line-formula description =”In-lin 其中R“为H,(CH 2)2 Z 3 CH 3或C(O) )CH 3 3; x + y + 2为60〜130; x / y为5-14; z为0-4; 表面活性剂的总表面活性剂分子量为7000-30,000g / mol,表面活性剂中的重量%硅氧烷为32-70重量%,聚醚部分的共混物平均分子量(BAMW)为450-1000g /摩尔,聚醚部分中环氧乙烷的摩尔%为70-100摩尔%。