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1. 发明授权

US08431658B2 Process for feeding a catalyst in a polymerization reactor 有权
标题翻译：在聚合反应器中进料催化剂的方法
公开(公告)号：US08431658B2
公开(公告)日：2013-04-30
申请号：US13142444
申请日：2009-12-23
申请人： Pietro Baita , Rainer Karer , Gerhardus Meier , Guido Funk , Gabriele Mei
发明人： Pietro Baita , Rainer Karer , Gerhardus Meier , Guido Funk , Gabriele Mei
IPC分类号： C08F4/44 , B01J31/02
CPC分类号： B01J8/0015 , B01J8/1827 , B01J2208/00752 , B01J2208/00769 , C08F10/00 , C08F210/16 , C08F2/34 , C08F210/08 , C08F2500/12
摘要： A process for introducing a catalyst powder based on a titanium compound supported on magnesium halide into a gas-phase olefin polymerization reactor, characterized in that it comprises: (a) storing the catalyst powder under an atmosphere of a liquid C3-C12 alkane; (b) withdrawing from step (a) a measured amount of said catalyst powder by means of a rotary valve; (c) transferring said metered amount of catalyst powder to a catalyst activation section by a continuous pick-up flow of a liquid C3-C12 alkane; (d) contacting the catalyst powder with a liquid phase comprising an organo-aluminum compound and optionally an external donor compound, at a temperature ranging from −20° C. to 60° C.; (e) introducing the activated catalyst powder in one or more gas-phase olefin polymerization reactors, where a gaseous mixture comprising at least one alpha-olefin is subjected to polymerization.
摘要翻译：将基于负载在卤化镁上的钛化合物的催化剂粉末引入气相烯烃聚合反应器的方法，其特征在于，其包括：（a）将催化剂粉末在液体C 3 -C 12烷烃的气氛下储存; （b）通过旋转阀从步骤（a）中取出测量量的所述催化剂粉末; （c）通过液体C 3 -C 12烷烃的连续提取流将所述计量的催化剂粉末转移到催化剂活化部分; （d）在-20℃至60℃的温度下使催化剂粉末与包含有机铝化合物和任选的外部供体化合物的液相接触; （e）将活化的催化剂粉末引入一个或多个气相烯烃聚合反应器中，其中包含至少一种α-烯烃的气体混合物进行聚合。

2. 发明申请

US20110282013A1 Process for Feeding a Catalyst in a Polymerization Reactor 有权
标题翻译：在聚合反应器中加入催化剂的方法
公开(公告)号：US20110282013A1
公开(公告)日：2011-11-17
申请号：US13142444
申请日：2009-12-23
申请人： Pietro Baita , Rainer Karer , Gerhardus Meier , Guido Funk , Gabriele Mei
发明人： Pietro Baita , Rainer Karer , Gerhardus Meier , Guido Funk , Gabriele Mei
IPC分类号： C08F4/16
CPC分类号： B01J8/0015 , B01J8/1827 , B01J2208/00752 , B01J2208/00769 , C08F10/00 , C08F210/16 , C08F2/34 , C08F210/08 , C08F2500/12
摘要： A process for introducing a catalyst powder based on a titanium compound supported on magnesium halide into a gas-phase olefin polymerization reactor, characterized in that it comprises: (a) storing the catalyst powder under an atmosphere of a liquid C3-C12 alkane; (b) withdrawing from step (a) a measured amount of said catalyst powder by means of a rotary valve; (c) transferring said metered amount of catalyst powder to a catalyst activation section by a continuous pick-up flow of a liquid C3-C12 alkane; (d) contacting the catalyst powder with a liquid phase comprising an organo-aluminum compound and optionally an external donor compound, at a temperature ranging from −20° C. to 60° C.; (e) introducing the activated catalyst powder in one or more gas-phase olefin polymerization reactors, where a gaseous mixture comprising at least one alpha-olefin is subjected to polymerization.
摘要翻译：将基于负载在卤化镁上的钛化合物的催化剂粉末引入气相烯烃聚合反应器的方法，其特征在于，其包括：（a）将催化剂粉末在液体C 3 -C 12烷烃的气氛下储存; （b）通过旋转阀从步骤（a）中取出测量量的所述催化剂粉末; （c）通过液体C 3 -C 12烷烃的连续提取流将所述计量的催化剂粉末转移到催化剂活化部分; （d）在-20℃至60℃的温度下使催化剂粉末与包含有机铝化合物和任选的外部供体化合物的液相接触; （e）将活化的催化剂粉末引入一个或多个气相烯烃聚合反应器中，其中包含至少一种α-烯烃的气体混合物进行聚合。

3. 发明申请

US20110201769A1 Copolymers Of Ethylene And At Least One Other 1-Olefin, And Process For Their Preparation 审中-公开
标题翻译：乙烯和至少一种其他1-烯烃的共聚物及其制备方法
公开(公告)号：US20110201769A1
公开(公告)日：2011-08-18
申请号：US12223233
申请日：2007-01-24
申请人： Chistoph Kiener , Rainer Karer , Jens Wiesecke , Gerhardus Meier
发明人： Chistoph Kiener , Rainer Karer , Jens Wiesecke , Gerhardus Meier
IPC分类号： C08F210/16
CPC分类号： C08F210/16 , C08F4/24 , C08F2/34 , C08F210/14 , C08F2500/12 , C08F2500/17 , C08F2500/04 , C08F2500/07 , C08F2500/11 , C08F2500/13
摘要： Ethylene copolymers composed of ethylene units and units composed of at least one other 1-olefin whose density is from 0.940 to 0.955 g/cm3, whose vinyl end group content is at least 0.5 end groups, based on 1000 carbon atoms, whose tensile impact strength atn, measured to ISO 8256 (1997)/1A at −30° C., is greater than or equal to 145 kJ/m2, and whose content of comonomer side chains per 1000 carbon atoms Cx is above a value defined via equation I, Cx=128.7−134.62 d′ (I), where d′ is the density d of the copolymer in g/cm3, and a process for their preparation, and their use as blow-molded products.
摘要翻译：由乙烯单元构成的乙烯共聚物和由密度为0.940〜0.955g / cm 3的至少一种其它1-烯烃组成的单元，其乙烯基端基含量为至少0.5个端基，基于1000个碳原子，其拉伸冲击强度 atn根据ISO 8256（1997）/ 1A在-30℃测量，大于或等于145kJ / m 2，并且其每1000个碳原子C x的共聚单体侧链含量高于通过式I定义的值， Cx = 128.7-134.62d'（I），其中d'是共聚物的密度d，单位为g / cm 3，及其制备方法及其作为吹塑制品的用途。

4. 发明申请

US20110230629A1 Impact Resistant LLDPE Composition and Films Made Thereof 审中-公开
标题翻译：耐冲击LLDPE组合物及其制造的薄膜
公开(公告)号：US20110230629A1
公开(公告)日：2011-09-22
申请号：US13120399
申请日：2009-09-25
申请人： Shahram Mihan , Rainer Karer , Fabiana Fantinel , Manfred Hecker , Gerhardus Meier , Maclovio Herrera Salinas
发明人： Shahram Mihan , Rainer Karer , Fabiana Fantinel , Manfred Hecker , Gerhardus Meier , Maclovio Herrera Salinas
IPC分类号： C08F210/14 , C08F2/34 , C08F4/80
CPC分类号： C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/61925 , C08F10/00 , C08F4/61904 , C08F2/34 , C08F210/14 , C08F2500/17 , C08F2500/05 , C08F2500/20 , C08F2500/10 , C08F2500/12 , C08F2500/08 , C08F2500/26 , C08F4/7042
摘要： Method of polymerizing ethylene with C3-C20-olefine-comonomer, comprising the step of carrying out the olymerization in a single gas phase reactor with a mixed catalyst system herein the catalyst system has a catalyst mileage of higher than 6000 g polymer product/g catalyst.
摘要翻译：将乙烯与C 3 -C 20烯烃共聚单体聚合的方法包括在这种催化剂体系下用混合催化剂体系在单一气相反应器中进行低聚反应的步骤具有高于6000g聚合物产物/ g催化剂的催化剂里程。

5. 发明授权

US09284394B2 Polyethylene polymerisation in gas phase reactor 有权
标题翻译：气相反应器中聚乙烯聚合
公开(公告)号：US09284394B2
公开(公告)日：2016-03-15
申请号：US13989609
申请日：2011-11-24
申请人： Fabiana Fantinel , Shahram Mihan , Gerhardus Meier , Ulf Schueller , Maclovio Herrera Salinas , Giampaolo Pellegatti , Gerd Mannebach
发明人： Fabiana Fantinel , Shahram Mihan , Gerhardus Meier , Ulf Schueller , Maclovio Herrera Salinas , Giampaolo Pellegatti , Gerd Mannebach
IPC分类号： C08F210/16 , C08F4/659 , C08F4/6592
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F2410/02 , C08F2/34 , C08F210/08 , C08F2500/17 , C08F2500/20 , C08F2500/12 , C08F2500/08 , C08F2500/24 , C08F210/14 , C08F4/61904 , C08F4/7042
摘要： A novel gas phase polymerization method is devised, for polymerization of low and ultralow density polyethylene.
摘要翻译：设计了一种新型的气相聚合法，用于低和低密度聚乙烯的聚合。

6. 发明授权

US08802795B2 Process for the preparation of a polyolefin polymer with improved wax deposition 有权
标题翻译：用于制备具有改进的蜡沉积的聚烯烃聚合物的方法
公开(公告)号：US08802795B2
公开(公告)日：2014-08-12
申请号：US13818845
申请日：2011-08-30
申请人： Gerhardus Meier , Reinhard Kuehl , Harald Prang , Michael Aulbach
发明人： Gerhardus Meier , Reinhard Kuehl , Harald Prang , Michael Aulbach
IPC分类号： C08F2/12 , C08F6/24 , C08F210/08
CPC分类号： C08F2/04 , C08F210/16 , C08F2/001 , C08F2/14 , C08F210/14
摘要： Process for the preparation of a polyolefin polymer by continuously polymerizing one or more olefin monomers in suspension at temperatures of from 40° C. to 120° C. and pressures of from 0.1 to 10 MPa in the presence of a polymerization catalyst in at least one polymerization reactor, comprising a) withdrawing a suspension of solid polyolefin particles in a suspension medium from the polymerization reactor, wherein the suspension has a temperature of from 65° C. to 120° C.; b) feeding the suspension withdrawn from the polymerization reactor to a moderating vessel; c) keeping the suspension in the moderating vessel at a temperature of from 60° C. to 85° C. for a time sufficiently long that the mean residence time of the suspension in the moderating vessel is at least 5 min; d) withdrawing suspension from the moderating vessel; e) cooling the suspension withdrawn from the moderating vessel to a temperature of from 20° C. to 55° C.; and f) mechanically separating the solid polyolefin particles from the liquid suspension medium, and method for controlling the content of hydrocarbons with from 14 to 300 carbon atoms in a polyolefin polymer prepared by polymerizing one or more olefin monomers in suspension.
摘要翻译：在聚合催化剂存在下，在至少一种聚合催化剂的存在下，通过在40℃至120℃的温度和0.1至10MPa的温度下将悬浮液中的一种或多种烯烃单体连续聚合来制备聚烯烃聚合物的方法聚合反应器，包括a）从聚合反应器中取出固体聚烯烃颗粒在悬浮介质中的悬浮液，其中悬浮液的温度为65℃至120℃; b）将从聚合反应器中取出的悬浮液送入调节容器; c）将悬浮液在调节容器中保持在60℃至85℃的温度下足够长的时间，使得悬浮液在调节容器中的平均停留时间为至少5分钟; d）从缓和容器中取出悬浮液; e）将从调节容器中取出的悬浮液冷却至20℃至55℃的温度; 和f）从液体悬浮介质中机械分离固体聚烯烃颗粒，以及通过在悬浮液中聚合一种或多种烯烃单体制备的聚烯烃聚合物中控制含有14至300个碳原子的烃的含量的方法。

7. 发明申请

US20130317185A1 POLYETHYLENE POLYMERISATION IN GAS PHASE REACTOR 有权
标题翻译：气相反应器中的聚乙烯聚合
公开(公告)号：US20130317185A1
公开(公告)日：2013-11-28
申请号：US13989609
申请日：2011-11-24
申请人： Fabiana Fantinel , Shahram Mihan , Gerhardus Meier , Ulf Schueller , Maclovio Herrera Salinas , Giampaolo Pellegatti , Gerd Mannebach
发明人： Fabiana Fantinel , Shahram Mihan , Gerhardus Meier , Ulf Schueller , Maclovio Herrera Salinas , Giampaolo Pellegatti , Gerd Mannebach
IPC分类号： C08F210/16
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F2410/02 , C08F2/34 , C08F210/08 , C08F2500/17 , C08F2500/20 , C08F2500/12 , C08F2500/08 , C08F2500/24 , C08F210/14 , C08F4/61904 , C08F4/7042
摘要： A novel gas phase polymerisation method is devised, for polymerisation of low and ultralow density polyethylene.
摘要翻译：设计了一种新型的气相聚合方法，用于低和低密度聚乙烯的聚合。

8. 发明申请

US20120148777A1 Polyethylene for Rotomoulding 有权
标题翻译：聚乙烯为Rotomoulding
公开(公告)号：US20120148777A1
公开(公告)日：2012-06-14
申请号：US13390924
申请日：2010-08-20
申请人： Gerd Mannebach , Heinz Vogt , Fabiana Fantinel , Shahram Mihan , Peter Bisson , Cees Besems , Gerhardus Meier , Ulf Schüller , Barbara Gall , Iakovos Vittorias , Manfred Hecker , Michael Olmscheid
发明人： Gerd Mannebach , Heinz Vogt , Fabiana Fantinel , Shahram Mihan , Peter Bisson , Cees Besems , Gerhardus Meier , Ulf Schüller , Barbara Gall , Iakovos Vittorias , Manfred Hecker , Michael Olmscheid
IPC分类号： B32B1/02 , C08L23/20 , C08F210/16
CPC分类号： B29C41/04 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F210/16 , C08F4/61904 , C08F4/7042 , C08F210/14 , C08F2500/04 , C08F2500/12 , C08F2500/10 , C08F2500/17
摘要： A novel polyethylene is devised which polyethylene is particularyl advantageous for manufacturing rotomoulded articles.
摘要翻译：设计出一种新颖的聚乙烯，其聚乙烯是有利于制造滚塑制品的特殊的。

9. 发明申请

US20110294957A1 Method for Transitioning Between Incompatible Olefin Polymerization Catalyst Systems 有权
标题翻译：不相容的烯烃聚合催化剂体系的转化方法
公开(公告)号：US20110294957A1
公开(公告)日：2011-12-01
申请号：US13133803
申请日：2009-12-17
申请人： Gerhardus Meier , Shahram Mihan
发明人： Gerhardus Meier , Shahram Mihan
IPC分类号： C08F255/00 , C08F4/64 , C08F2/34 , C08F4/24
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F2410/05 , C08F4/69 , C08F4/642 , C08F2/34 , C08F2/42 , C08F210/08 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/07 , C08F4/7042 , C08F4/61904
摘要： A method for transitioning from a Ziegler-Natta to a Phillips catalyst system for the olefin polymerization reaction in one reactor, preferably a gas phase reactor, is described. The method comprises the steps of a) discontinuing a first olefin polymerization reaction performed in the presence of the Ziegler-Natta catalyst system; b) performing a second olefin polymerization reaction in the presence of a further catalyst system comprising catalyst components (A) and (B) producing, respectively, a first and a second polyolefin fraction, wherein the Mw of the first polyolefin fraction is less than the Mw of the second polyolefin fraction and the initial activity of catalyst component (A) exceeds the initial activity of catalyst component (B); and c) performing a third olefin polymerization reaction the presence of the Phillips catalyst system. Thanks to this method, there is no need to empty the reactor after each olefin polymerization reaction, and the transitioning time needed to attain the desired quality of the polyolefin obtained in each olefin polymerization reaction subsequent to the first one is sufficiently short to permit a quick and reliable change of production.
摘要翻译：描述了在一个反应器，优选气相反应器中从齐格勒 - 纳塔过渡到用于烯烃聚合反应的菲利普斯催化剂体系的方法。该方法包括以下步骤：a）停止在齐格勒 - 纳塔催化剂体系存在下进行的第一种烯烃聚合反应; b）在另外的催化剂体系存在下进行第二烯烃聚合反应，所述催化剂体系包含分别产生第一和第二聚烯烃部分的催化剂组分（A）和（B），其中第一聚烯烃部分的Mw小于第二聚烯烃级分的Mw和催化剂组分（A）的初始活性超过催化剂组分（B）的初始活性; 和c）进行第三烯烃聚合反应的存在的菲利浦催化剂体系。由于这种方法，在每个烯烃聚合反应之后不需要清空反应器，并且在第一个烯烃聚合反应之后获得的每个烯烃聚合反应中获得的聚烯烃所需的质量所需的转化时间足够短，以使快速可靠的生产变更。

10. 发明申请

US20110223406A1 Impact Resistant LLDPE Composition and Films Made Thereof 有权
公开(公告)号：US20110223406A1
公开(公告)日：2011-09-15
申请号：US13119655
申请日：2009-09-22
申请人： Fabiana Fantinel , Gerd Mannebach , Shahram Mihan , Gerhardus Meier , Iakovos Vittorias
发明人： Fabiana Fantinel , Gerd Mannebach , Shahram Mihan , Gerhardus Meier , Iakovos Vittorias
IPC分类号： B32B3/00 , C08F210/14 , C08F4/72 , C08L23/20 , C08F4/80 , B01J31/12
CPC分类号： C08J5/18 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F210/16 , C08J2323/06 , C08F4/61904 , C08F210/14 , C08F2500/08 , C08F2500/05 , C08F2500/12 , C08F2500/10 , C08F2500/19 , C08F2500/20 , C08F2500/17 , C08F2500/26 , C08F4/7042
摘要： A novel PE material is devised showing excellent mechanical/optical properties and process ability, e.g. for film extrusion. The polyethylene of the invention is produced in one single e.g. gas phase reactor.

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