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1. 发明申请

US20120283369A1 Polymerization process in the presence of an antistatic agent 审中-公开
标题翻译：在抗静电剂存在下的聚合过程
公开(公告)号：US20120283369A1
公开(公告)日：2012-11-08
申请号：US13514968
申请日：2010-12-16
申请人： Lars Koelling , Shahram Mihan , Gerhardus Meier
发明人： Lars Koelling , Shahram Mihan , Gerhardus Meier
IPC分类号： C08L81/06 , C08K5/42
CPC分类号： C08F10/00 , C08F110/02 , C08F2/005 , C08F2500/12 , C08F2500/04
摘要： Process for the polymerization of olefins at temperatures of from −20 to 200° C. and pressures of from 0.1 to 20 MPa in the presence of a polymerization catalyst and an antistatic agent, wherein the antistatic agent is an antistatically acting composition comprising a polysulfone copolymer, a polymeric compound comprising basic nitrogen atoms, an oil-soluble sulfonic acid and optionally a solvent and the polysulfone copolymer, the polymeric compound comprising basic nitrogen atoms and the oil-soluble sulfonic acid constitute together at least 1 wt. % of the antistatically acting composition, and wherein the antistatically acting composition, when contacted as solution or suspension in heptane, wherein the solution or suspension has a concentration of about 80 g of the antistatically acting composition per liter of heptane, with a 2 M solution of triethylaluminum in heptane at 0° C., generates less than 5 cm3, measured at 23° C. and atmospheric pressure, of ethane per gram of the antistatically acting composition and use of an antistatically acting composition as antistatic agent for the polymerization of olefins at temperatures of from −20 to 200° C. and pressures of from 0.1 to 20 MPa in the presence of a polymerization catalyst.
摘要翻译：在聚合催化剂和抗静电剂存在下，在-20至200℃的温度和0.1至20MPa的压力下烯烃的聚合方法，其中抗静电剂是包含聚砜共聚物，包含碱性氮原子的聚合化合物，油溶性磺酸和任选的溶剂和聚砜共聚物，包含碱性氮原子的聚合化合物和油溶性磺酸一起构成至少1重量％％的抗静电作用组合物，并且其中所述抗静电作用组合物当作为溶液或悬浮液在庚烷中接触时，其中所述溶液或悬浮液的浓度为每升庚烷约80g抗静电作用组合物，与2M溶液的三乙基铝在庚烷中在0℃下产生小于5cm 3，在23℃和大气压下测量每克抗静电作用组合物的乙烷和抗静电作用组合物的用作抗静电剂用于烯烃聚合在-20至200℃的温度和0.1至20MPa的压力下，在聚合催化剂存在下进行。

2. 发明授权

US09284394B2 Polyethylene polymerisation in gas phase reactor 有权
标题翻译：气相反应器中聚乙烯聚合
公开(公告)号：US09284394B2
公开(公告)日：2016-03-15
申请号：US13989609
申请日：2011-11-24
申请人： Fabiana Fantinel , Shahram Mihan , Gerhardus Meier , Ulf Schueller , Maclovio Herrera Salinas , Giampaolo Pellegatti , Gerd Mannebach
发明人： Fabiana Fantinel , Shahram Mihan , Gerhardus Meier , Ulf Schueller , Maclovio Herrera Salinas , Giampaolo Pellegatti , Gerd Mannebach
IPC分类号： C08F210/16 , C08F4/659 , C08F4/6592
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F2410/02 , C08F2/34 , C08F210/08 , C08F2500/17 , C08F2500/20 , C08F2500/12 , C08F2500/08 , C08F2500/24 , C08F210/14 , C08F4/61904 , C08F4/7042
摘要： A novel gas phase polymerization method is devised, for polymerization of low and ultralow density polyethylene.
摘要翻译：设计了一种新型的气相聚合法，用于低和低密度聚乙烯的聚合。

3. 发明申请

US20130317185A1 POLYETHYLENE POLYMERISATION IN GAS PHASE REACTOR 有权
标题翻译：气相反应器中的聚乙烯聚合
公开(公告)号：US20130317185A1
公开(公告)日：2013-11-28
申请号：US13989609
申请日：2011-11-24
申请人： Fabiana Fantinel , Shahram Mihan , Gerhardus Meier , Ulf Schueller , Maclovio Herrera Salinas , Giampaolo Pellegatti , Gerd Mannebach
发明人： Fabiana Fantinel , Shahram Mihan , Gerhardus Meier , Ulf Schueller , Maclovio Herrera Salinas , Giampaolo Pellegatti , Gerd Mannebach
IPC分类号： C08F210/16
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F2410/02 , C08F2/34 , C08F210/08 , C08F2500/17 , C08F2500/20 , C08F2500/12 , C08F2500/08 , C08F2500/24 , C08F210/14 , C08F4/61904 , C08F4/7042
摘要： A novel gas phase polymerisation method is devised, for polymerisation of low and ultralow density polyethylene.
摘要翻译：设计了一种新型的气相聚合方法，用于低和低密度聚乙烯的聚合。

4. 发明申请

US20120148777A1 Polyethylene for Rotomoulding 有权
标题翻译：聚乙烯为Rotomoulding
公开(公告)号：US20120148777A1
公开(公告)日：2012-06-14
申请号：US13390924
申请日：2010-08-20
申请人： Gerd Mannebach , Heinz Vogt , Fabiana Fantinel , Shahram Mihan , Peter Bisson , Cees Besems , Gerhardus Meier , Ulf Schüller , Barbara Gall , Iakovos Vittorias , Manfred Hecker , Michael Olmscheid
发明人： Gerd Mannebach , Heinz Vogt , Fabiana Fantinel , Shahram Mihan , Peter Bisson , Cees Besems , Gerhardus Meier , Ulf Schüller , Barbara Gall , Iakovos Vittorias , Manfred Hecker , Michael Olmscheid
IPC分类号： B32B1/02 , C08L23/20 , C08F210/16
CPC分类号： B29C41/04 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F210/16 , C08F4/61904 , C08F4/7042 , C08F210/14 , C08F2500/04 , C08F2500/12 , C08F2500/10 , C08F2500/17
摘要： A novel polyethylene is devised which polyethylene is particularyl advantageous for manufacturing rotomoulded articles.
摘要翻译：设计出一种新颖的聚乙烯，其聚乙烯是有利于制造滚塑制品的特殊的。

5. 发明申请

US20110294957A1 Method for Transitioning Between Incompatible Olefin Polymerization Catalyst Systems 有权
标题翻译：不相容的烯烃聚合催化剂体系的转化方法
公开(公告)号：US20110294957A1
公开(公告)日：2011-12-01
申请号：US13133803
申请日：2009-12-17
申请人： Gerhardus Meier , Shahram Mihan
发明人： Gerhardus Meier , Shahram Mihan
IPC分类号： C08F255/00 , C08F4/64 , C08F2/34 , C08F4/24
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F2410/05 , C08F4/69 , C08F4/642 , C08F2/34 , C08F2/42 , C08F210/08 , C08F210/14 , C08F2500/12 , C08F2500/18 , C08F2500/07 , C08F4/7042 , C08F4/61904
摘要： A method for transitioning from a Ziegler-Natta to a Phillips catalyst system for the olefin polymerization reaction in one reactor, preferably a gas phase reactor, is described. The method comprises the steps of a) discontinuing a first olefin polymerization reaction performed in the presence of the Ziegler-Natta catalyst system; b) performing a second olefin polymerization reaction in the presence of a further catalyst system comprising catalyst components (A) and (B) producing, respectively, a first and a second polyolefin fraction, wherein the Mw of the first polyolefin fraction is less than the Mw of the second polyolefin fraction and the initial activity of catalyst component (A) exceeds the initial activity of catalyst component (B); and c) performing a third olefin polymerization reaction the presence of the Phillips catalyst system. Thanks to this method, there is no need to empty the reactor after each olefin polymerization reaction, and the transitioning time needed to attain the desired quality of the polyolefin obtained in each olefin polymerization reaction subsequent to the first one is sufficiently short to permit a quick and reliable change of production.
摘要翻译：描述了在一个反应器，优选气相反应器中从齐格勒 - 纳塔过渡到用于烯烃聚合反应的菲利普斯催化剂体系的方法。该方法包括以下步骤：a）停止在齐格勒 - 纳塔催化剂体系存在下进行的第一种烯烃聚合反应; b）在另外的催化剂体系存在下进行第二烯烃聚合反应，所述催化剂体系包含分别产生第一和第二聚烯烃部分的催化剂组分（A）和（B），其中第一聚烯烃部分的Mw小于第二聚烯烃级分的Mw和催化剂组分（A）的初始活性超过催化剂组分（B）的初始活性; 和c）进行第三烯烃聚合反应的存在的菲利浦催化剂体系。由于这种方法，在每个烯烃聚合反应之后不需要清空反应器，并且在第一个烯烃聚合反应之后获得的每个烯烃聚合反应中获得的聚烯烃所需的质量所需的转化时间足够短，以使快速可靠的生产变更。

6. 发明申请

US20110223406A1 Impact Resistant LLDPE Composition and Films Made Thereof 有权
公开(公告)号：US20110223406A1
公开(公告)日：2011-09-15
申请号：US13119655
申请日：2009-09-22
申请人： Fabiana Fantinel , Gerd Mannebach , Shahram Mihan , Gerhardus Meier , Iakovos Vittorias
发明人： Fabiana Fantinel , Gerd Mannebach , Shahram Mihan , Gerhardus Meier , Iakovos Vittorias
IPC分类号： B32B3/00 , C08F210/14 , C08F4/72 , C08L23/20 , C08F4/80 , B01J31/12
CPC分类号： C08J5/18 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F210/16 , C08J2323/06 , C08F4/61904 , C08F210/14 , C08F2500/08 , C08F2500/05 , C08F2500/12 , C08F2500/10 , C08F2500/19 , C08F2500/20 , C08F2500/17 , C08F2500/26 , C08F4/7042
摘要： A novel PE material is devised showing excellent mechanical/optical properties and process ability, e.g. for film extrusion. The polyethylene of the invention is produced in one single e.g. gas phase reactor.

7. 发明授权

US08865834B2 Adhesive polymer composition 有权
标题翻译：粘合剂聚合物组成
公开(公告)号：US08865834B2
公开(公告)日：2014-10-21
申请号：US12735689
申请日：2009-02-18
申请人： Heinz Vogt , Shahram Mihan , Gerd Mannebach , Gerhardus Meier , Joachim Berthold , Manfred Hecker
发明人： Heinz Vogt , Shahram Mihan , Gerd Mannebach , Gerhardus Meier , Joachim Berthold , Manfred Hecker
IPC分类号： C08L51/06 , C08L23/08 , C09J151/06 , C09J123/08 , B32B7/12 , C08J5/18 , B29C41/04 , B32B1/08 , C08F255/02 , B32B15/08 , C08F10/00 , H01B3/44 , B29C41/00 , C08F4/659 , C08F210/02 , C08F210/16 , C08F4/6592 , C08L23/04
CPC分类号： C08F255/02 , B29C41/003 , B29C41/04 , B29K2023/06 , B29K2995/0088 , B32B1/08 , B32B7/10 , B32B7/12 , B32B15/02 , B32B15/08 , B32B15/18 , B32B27/08 , B32B27/18 , B32B27/308 , B32B27/32 , B32B27/38 , B32B2270/00 , B32B2307/30 , B32B2307/50 , B32B2307/554 , B32B2307/7246 , B32B2597/00 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F210/02 , C08F210/16 , C08J5/18 , C08J2323/08 , C08L23/04 , C08L23/0869 , C08L51/06 , C08L2666/02 , C08L2666/04 , C08L2666/24 , C09J123/0869 , C09J151/06 , H01B3/441 , Y10T428/2933 , C08F4/61904 , C08F220/06 , C08F220/10 , C08F210/14 , C08F2500/04 , C08F2500/19 , C08F2500/12 , C08F4/7042 , C08F210/06 , C08F210/10
摘要： A novel adhesive composition suitable for composing multilayered coatings onto large, industrial equipment such as pipeline tubes is devised. The composition is a blend based on a polyethylene which determines the blend's favorable properties, which polyethylene itself can be used further in coating cables and for producing moldings, especially rotomoulded articles.
摘要翻译：设计出适合于在诸如管道管的大型工业设备上组成多层涂层的新型粘合剂组合物。组合物是基于聚乙烯的共混物，其确定共混物的有利性质，聚乙烯本身可以进一步用于涂覆电缆和用于生产模制品，特别是滚塑制品。

8. 发明授权

US08846188B2 Impact resistant LLDPE composition and films made thereof 有权
标题翻译：耐冲击LLDPE组合物及其制成的薄膜
公开(公告)号：US08846188B2
公开(公告)日：2014-09-30
申请号：US13119655
申请日：2009-09-22
申请人： Fabiana Fantinel , Gerd Mannebach , Shahram Mihan , Gerhardus Meier , Iakovos Vittorias
发明人： Fabiana Fantinel , Gerd Mannebach , Shahram Mihan , Gerhardus Meier , Iakovos Vittorias
IPC分类号： B32B3/00 , C08F210/14 , C08F4/72 , C08F4/80 , C08L23/20 , B01J31/12
CPC分类号： C08J5/18 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F210/16 , C08J2323/06 , C08F4/61904 , C08F210/14 , C08F2500/08 , C08F2500/05 , C08F2500/12 , C08F2500/10 , C08F2500/19 , C08F2500/20 , C08F2500/17 , C08F2500/26 , C08F4/7042
摘要： A novel PE material is devised showing excellent mechanical/optical properties and process ability, e.g. for film extrusion. The polyethylene of the invention is produced in one single e.g. gas phase reactor.
摘要翻译：设计了一种新颖的PE材料，其显示出优异的机械/光学性能和加工能力，例如用于膜挤出。本发明的聚乙烯在一个单一的例子中生产。气相反应器。

9. 发明申请

US20130116392A1 Polyethylene Composition And Method For Obtaining Same 有权
标题翻译：聚乙烯组合物及其制备方法
公开(公告)号：US20130116392A1
公开(公告)日：2013-05-09
申请号：US13700120
申请日：2011-05-26
申请人： Fabiana Fantinel , Shahram Mihan , Gerhardus Meier , Ulf Schueller , Maclovio Salinas Herrera , Giampaolo Pellegatti , Gerd Mannebach
发明人： Fabiana Fantinel , Shahram Mihan , Gerhardus Meier , Ulf Schueller , Maclovio Salinas Herrera , Giampaolo Pellegatti , Gerd Mannebach
IPC分类号： C08F210/16
CPC分类号： C08F210/16 , C08F4/61912 , C08F4/61916 , C08F4/61925 , C08F2410/02 , C08L23/0815 , C08F4/025 , C08F4/61904 , C08L2666/06 , C08F210/08 , C08F210/14 , C08F2500/08 , C08F2500/17 , C08F2500/12 , C08F2500/20 , C08F4/7042
摘要： New plastomer material for use in automotive parts such as bumpers is devised here, which is a novel polyethylene produced by a gas phase process.
摘要翻译：这里设计了用于汽车部件如保险杠的新的塑性体材料，其是通过气相法生产的新型聚乙烯。

10. 发明申请

US20120148776A1 Polyethylene for Rotomoulding 有权
标题翻译：聚乙烯为Rotomoulding
公开(公告)号：US20120148776A1
公开(公告)日：2012-06-14
申请号：US13390919
申请日：2010-08-20
申请人： Gerd Mannebach , Heinz Vogt , Fabiana Fantinel , Shahram Mihan , Peter Bisson , Cees Besems , Gerhardus Meier , Ulf Schüller , Barbara Gall , Iakovos Vittorias , Manfred Hecker , Michael Olmscheid
发明人： Gerd Mannebach , Heinz Vogt , Fabiana Fantinel , Shahram Mihan , Peter Bisson , Cees Besems , Gerhardus Meier , Ulf Schüller , Barbara Gall , Iakovos Vittorias , Manfred Hecker , Michael Olmscheid
IPC分类号： B32B1/02 , C08L23/20 , C08F210/16
CPC分类号： C08F210/16 , B29C41/04 , B29K2023/06 , B29K2023/0641 , B29K2105/0094 , B29K2995/0088 , C08F4/61904 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F4/7042 , C08F210/14 , C08F2500/04 , C08F2500/10 , C08F2500/12 , C08F2500/17 , Y10T428/1397
摘要： A novel polyethylene is devised which polyethylene is particularly advantageous for manufacturing rotomoulded articles.
摘要翻译：设计出一种新型聚乙烯，其中聚乙烯特别有利于制造滚塑制品。

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