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    • 1. 发明授权
    • Silver halide multilayer color photographic material
    • 卤化银多层彩色照相材料
    • US06518005B2
    • 2003-02-11
    • US09877467
    • 2001-06-08
    • Piero CavalleriRaffaella BiavascoStefano Parodi
    • Piero CavalleriRaffaella BiavascoStefano Parodi
    • G03C146
    • G03C1/832G03C7/3029G03C2007/3039G03C2200/23G03C2200/25
    • The present invention refers to photographic elements having, coated on a support base, at least one silver halide emulsion layer sensitized to a radiation different from the blue one in addition to its intrinsic sensitivity to the blue region, and a yellow filter layer positioned between said at least one silver halide emulsion layer and the exposure source, where such yellow filter layer contains a yellow filtering dye represented by the formula (1): wherein R and R1 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkylene group, a substituted or unsubstituted heterocyclic group or a substituted or unsubstituted aryl group; R2, R3 and R4 each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group and R3 and R4 may be combined to form a 6-membered ring.
    • 本发明涉及具有涂覆在支撑基底上的至少一种卤化银乳剂层的照相元件,除了对蓝色区域的固有敏感性以外,对与蓝色不同的辐射敏感的卤化银乳剂层和位于所述蓝色区域之间的黄色滤光层 至少一个卤化银乳剂层和曝光源,其中这种黄色过滤层含有由式(1)表示的黄色过滤染料:其中R和R 1各自独立地表示氢原子,取代或未取代的烷基,取代的 或未取代的亚烷基,取代或未取代的杂环基或取代或未取代的芳基; R2,R3和R4各自独立地表示氢原子,取代或未取代的烷基,取代或未取代的芳基,R3和R4可以组合形成6元环。
    • 3. 发明授权
    • Yellow and magenta chromogenic leuco dyes for photothermographic elements
    • 用于光热敏成像元件的黄色和品红色显色无色染料
    • US5432041A
    • 1995-07-11
    • US161900
    • 1993-12-03
    • Raffaella BiavascoStefano ParodiSharon M. SimpsonKim M. Vogel
    • Raffaella BiavascoStefano ParodiSharon M. SimpsonKim M. Vogel
    • G03C8/40G03C1/498
    • G03C1/49827G03C1/49854
    • Photothermographic elements capable of producing a high density yellow or magenta image upon image-wise exposure and thermal development at a relatively low temperature and for a short period of time are described. The photothermographic elements of the invention comprise coated on a support base at least one light-sensitive emulsion layer comprising (a) a leuco dye reducing reducing agent, (b) a photosensitive silver halide, (c) an organic silver compound capable of being reduced by the leuco dye reducing agent, and (d) a binder; wherein the leuco dye reducing agent thereto comprises a chromogenic yellow or magenta leuco dye compound.The photothermographic elements of the invention may be used to obtain yellow and magenta images of suitable density in single color or multicolor photothermographic articles. At the same time the chromogenic leuco dye is stable enough not to be oxidized by oxygen of the air or by simple heating and to limit the fog formation after development.
    • 描述了能够在相对低的温度和短时间内在成像曝光和热显影时产生高密度黄色或品红色图像的光热敏成像元件。 本发明的光热敏成像元件包括在支撑基底上涂覆至少一种感光乳剂层,其包含(a)无色染料还原还原剂,(b)光敏卤化银,(c)能够还原的有机银化合物 通过无色染料还原剂,和(d)粘合剂; 其中所述无色染料还原剂包含显色黄色或品红色无色染料化合物。 本发明的光热敏成像元件可用于获得单色或多色光热成像制品中适合密度的黄色和品红色图像。 同时,显色无色染料足够稳定,不会被空气的氧气或简单的加热氧化,并且限制了显影后的雾形成。
    • 4. 发明授权
    • Cyan chromogenic leuco dyes for photothermographic materials
    • 用于光热照相材料的青色发色无色染料
    • US5330864A
    • 1994-07-19
    • US939093
    • 1992-09-02
    • Raffaella BiavascoCristina Soncini
    • Raffaella BiavascoCristina Soncini
    • G03C1/498
    • G03C1/49854
    • Phothermographic material capable of producing a high density cyan image upon image-wise exposure and thermal development at a relatively low temperature and for a short period of time. The photothermographic material of the invention comprise coated on a support base at least one light-sensitive emulsion layer containing: (a) a binder; (b) a silver source material; (c) a light sensitive silver halide in catalytic proximity to said silver source material, wherein said emulsion layer or an adjacent layer thereto comprises a chromogenic cyan leuco dye.The photothermographic material of the invention may be used to obtain good cyan image of suitable density in single color or multicolor photothermographic articles. At the same time the chromogenic leuco dye is stable enough not to be oxidized by oxygen of the air or by simple heating and to limit the fog formation after development.
    • 能够在相对低的温度和短时间内在成像曝光和热显影时产生高密度青色图像的热成像材料。 本发明的光热敏成像材料包括在支撑基底上涂覆至少一种感光乳剂层,其包含:(a)粘合剂; (b)银源材料; (c)催化接近所述银源材料的感光卤化银,其中所述乳剂层或其相邻层包含显色青色无色染料。 本发明的光热敏成像材料可以用于在单色或多色光热敏成像制品中获得合适密度的良好的青色图像。 同时,显色无色染料足够稳定,不会被空气的氧气或简单的加热氧化,并且限制了显影后的雾形成。
    • 9. 发明授权
    • Silver halide color photographic light-sensitive elements having improved image quality
    • 卤化银彩色照相感光元件具有改善的图像质量
    • US06242168B1
    • 2001-06-05
    • US09576528
    • 2000-05-23
    • Mauro AvidanoRaffaella BiavascoDiego BrignoneGiuseppe RoccaLuisa Tavella
    • Mauro AvidanoRaffaella BiavascoDiego BrignoneGiuseppe RoccaLuisa Tavella
    • G03C146
    • G03C7/3003G03C7/3022G03C7/3029G03C7/30558G03C7/30594G03C2001/03535G03C2001/03558G03C2007/3037Y10S430/158
    • The present invention relates to a light-sensitive silver halide color multilayer photographic material which comprises a support base having coated thereon at least three red-sensitive emulsion layers having different sensitivity, at least three green-sensitive emulsion layers having different sensitivity, and at least two yellow-sensitive emulsion layers having different sensitivity, wherein (a) a core-shell silver halide emulsion having an average silver iodide content lower than 10% mol is present in at least one of the lowest sensitive red-, green- and yellow layers, (b) a yellow dye forming malonodiamide DIR coupler having in the coupling position thereof a 4,7-dihalogen-2-benzotriazolyl group is present in both the medium sensitive red- and green-sensitive layers, and (c) a yellow dye forming DIR coupler having a 1,2,4-triazolyl group attached to the coupling position, such 1,2,4-triazolyl group comprising a hydrolizable alkoxy- or aryloxy-carbonyl group attached to a benzytlthio substituent on the 1,2,4-triazolyl group is present in at least one of the highest sensitive red- and green-sensitive layers.
    • 本发明涉及一种感光卤化银彩色多层照相材料,其包括其上涂覆有至少三种具有不同灵敏度的感红乳剂层的支持基质,至少三种具有不同灵敏度的感绿乳剂层,至少 两个具有不同灵敏度的黄敏感乳剂层,其中(a)平均碘化银含量低于10%摩尔的核 - 壳卤化银乳剂存在于至少一个最低敏感的红,绿和黄层中 ,(b)具有4,7-二卤代-2-苯并三唑基的偶联位置的黄色染料形成丙二酰胺DIR成色剂存在于中敏感红和绿敏感层中,和(c)黄色染料 形成具有连接到偶联位置上的1,2,4-三唑基的DIR成色剂,所述1,2,4-三唑基包含连接到苯甲硫基的可水解烷氧基 - 或芳氧基 - 羰基 1,2,4-三唑基中的取代基存在于最敏感的红敏感层和绿敏感层中的至少一个中。