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1. 发明授权

US6140447A Functionalized polyorganosiloxanes and one of the processes for the preparation thereof 失效
标题翻译：官能化聚有机硅氧烷及其制备方法之一
公开(公告)号：US6140447A
公开(公告)日：2000-10-31
申请号：US267927
申请日：1999-03-09
申请人： Michel Gay , Philippe Jost , Michel Peignier , Christian Priou
发明人： Michel Gay , Philippe Jost , Michel Peignier , Christian Priou
IPC分类号： C08L83/06 , C07F7/08 , C07F7/21 , C08G77/38 , C08G77/392 , C08L83/08 , C08G77/08 , C08G77/28 , C08G77/18
CPC分类号： C08G77/392 , C07F7/0859 , C07F7/21 , C08G77/38
摘要： The present invention relates to multifunctionalized alkoxy, the alkoxy functionality Y being introduced onto a suitable polyhydrooorganosiloxane by a dehydrogenation/condensation reaction from the alcohol from which Y derives and then the functionality W by a hydrosilylation reaction from the olefinic compound from which W derives. The multifunctionalized alkoxy polyorganosiloxanes can be used as antiadhesion modulators in silicone compositions and as silica covering agents in silicone compositions containing fillers.
摘要翻译：本发明涉及多官能化烷氧基，烷氧基官能团Y通过脱氢/缩合反应引入到合适的多羟基有机硅氧烷上，所述脱氢/缩合反应来自Y衍生的醇，然后通过来自W衍生的烯烃化合物的氢化硅烷化反应产生官能度W. 多官能烷氧基聚有机硅氧烷可用作硅氧烷组合物中的抗粘附调节剂，并且可用作含硅填料的硅氧烷组合物中的二氧化硅覆盖剂。

2. 发明授权

US06359097B1 Functionalized polyorganosiloxanes and one of the processes for the preparation thereof 失效
标题翻译：官能化聚有机硅氧烷及其制备方法之一
公开(公告)号：US06359097B1
公开(公告)日：2002-03-19
申请号：US09510801
申请日：2000-02-23
申请人： Philippe Jost , Michel Peignier , Christian Priou
发明人： Philippe Jost , Michel Peignier , Christian Priou
IPC分类号： C08G7708
CPC分类号： C08G77/50 , C07F7/0838 , C07F7/21 , C08G77/38 , C08G77/385
摘要： The present invention relates to multifunctionalized polyorganosiloxanes comprising, per molecule at least one functional siloxy unit Y having C1-C5 alkoxy radical and at least one other functional siloxy unit W having an halogenated or polyhalogenated alkyl, aralkyl or aryl; polyether ether; epoxidized alkyl; alkoxyalkyl; hydroxylated, carbonylated or esterified alkyl; phenol; and alkoxysilyl; and optionally at least one siloxy unit having a SiH group. The alkoxy functionality Y is introduced onto a suitable polyhydroorganosiloxane by a dehydrogenation/condensation reaction from the alcohol from which Y derives and then the non-hydrogen functionality W by a hydrosilylation reaction from the olefinic compound from which W derives. The multifunctionalized polyorganosiloxanes can be used as antiadhesion modulators in silicone compositions.
摘要翻译：本发明涉及多官能化聚有机硅氧烷，其包含每分子至少一个具有C 1 -C 5烷氧基的至少一个官能甲硅烷氧基单元Y和至少一个具有卤代或多卤代烷基，芳烷基或芳基的其它功能性甲硅烷氧基单元W; 聚醚醚; 环氧化烷基; 烷氧基烷基羟基化，羰基化或酯化烷基; 苯酚; 和烷氧基甲硅烷基; 和任选的具有SiH基团的至少一个甲硅烷氧基单元。将烷氧基官能团Y通过脱氢/缩合反应引入到合适的多羟基有机硅氧烷上，所述脱氢/缩合反应来自于Y衍生的醇，然后通过来自W衍生的烯烃化合物的氢化硅烷化反应产生非氢官能度W。多官能化聚有机硅氧烷可用作硅氧烷组合物中的抗粘附调节剂。

3. 发明授权

US06271331B1 Functionalized polyorganosiloxanes and one of the processes for the preparation thereof 失效
标题翻译：官能化聚有机硅氧烷及其制备方法之一
公开(公告)号：US06271331B1
公开(公告)日：2001-08-07
申请号：US09454879
申请日：1999-12-03
申请人： Michel Gay , Philippe Jost , Michel Peignier , Christian Priou
发明人： Michel Gay , Philippe Jost , Michel Peignier , Christian Priou
IPC分类号： C08G7708
CPC分类号： C08G77/392 , C07F7/0838 , C07F7/21 , C08G77/38
摘要： The present invention relates to multifunctionalized alkoxy, the alkoxy functionality Y being introduced onto a suitable polyhydroorganosiloxane by a dehydrogenation/condensation reaction from the alcohol from which Y derives and then the functionality W by a hydrosilylation reaction from the olefinic compound form which W derives. The multifunctionalized alkoxy polyorganosiloxanes can be used as antiadhesion modulators in silicone compositions and as silica covering agents in silicone compositions containing fillers.
摘要翻译：本发明涉及多官能化烷氧基，烷氧基官能团Y通过脱氢/缩合反应从Y衍生出的醇引入到合适的聚有机硅氧烷上，然后通过来自W衍生的烯烃化合物形式的氢化硅烷化反应引入官能度W. 多官能烷氧基聚有机硅氧烷可用作硅氧烷组合物中的抗粘附调节剂，并且可用作含硅填料的硅氧烷组合物中的二氧化硅覆盖剂。

4. 发明授权

US5703137A Initiators for the cationic crosslinking of polymers containing organofunctional groups 失效
标题翻译：用于阳离子交联含有有机官能团的聚合物的引发剂
公开(公告)号：US5703137A
公开(公告)日：1997-12-30
申请号：US616170
申请日：1996-03-14
申请人： Christian Priou , Stuart Kerr, III
发明人： Christian Priou , Stuart Kerr, III
IPC分类号： C08F2/50 , C08G59/32 , C08G59/68 , C08K5/00 , C09D183/06 , D21H27/00 , G03F7/004 , C08L83/06
CPC分类号： G03F7/0045 , C08G59/3254 , C08G59/68 , C08K5/0025 , C09D183/06 , D21H27/001
摘要： The present invention relates to initiators for the polymerization and/or crosslinking, cationically and under photochemical and/or thermal activation and/or activation by a beam of electrons, of monomers and/or polymers containing organofunctional groups. The said initiators are of the type comprising an onium salt of an element from groups 15 to 17 of the Periodic Table (Chem & Eng News, Vol 63, N5, 26, of 4 Feb. 1985) and they are characterized in that they contain at least one polymerization and/or crosslinking accelerator chosen from .alpha.-hydroxylated carboxylic acid esters such as, for example, lactic acid esters. Another subject of the invention is compositions based on at least one cationically crosslinkable polyorganosiloxane and on at least one initiator.
摘要翻译：本发明涉及用于聚合和/或交联的阳离子和光活化和/或热活化和/或通过电子束，含有有机官能团的单体和/或聚合物进行激活的引发剂。所述引发剂的类型包括元素周期表第15-17族元素的鎓盐（Chem＆Eng News，Vol 63，N5,26，1985年2月4日），它们的特征在于它们含有选自α-羟基化羧酸酯的至少一种聚合和/或交联促进剂，例如乳酸酯。本发明的另一主题是基于至少一种阳离子交联聚有机硅氧烷和至少一种引发剂的组合物。

5. 发明授权

US5340898A Cationically crosslinkable polyorganosiloxanes and antiadhesive coatings produced therefrom 失效
标题翻译：阳离子交联的聚有机硅氧烷和由其制备的防粘涂层
公开(公告)号：US5340898A
公开(公告)日：1994-08-23
申请号：US35603
申请日：1993-03-23
申请人： Jacques Cavezzan , Christian Priou
发明人： Jacques Cavezzan , Christian Priou
IPC分类号： C08J3/28 , C07F5/02 , C08K5/55 , C08L83/04 , C09D183/04 , C09D183/06 , C08G77/06
CPC分类号： C08K5/55 , C07F5/027 , C09D183/06 , Y10T428/31663
摘要： Cationically crosslinkable polyorganosiloxane compositions, well suited for providing antiadhesive coatings on a wide variety of shaped substrates via the photochemical/electron beam crosslinking thereof, include a catalytically effective amount of an onium borate of an element of Groups 15 to 17 of the Periodic Table, the anionic borate moiety of which onium borate having the formula:[BX.sub.a R.sub.b ].sup.-in which a and b are integers ranging from 0 to 4 and a+b=4; the symbols X are each a halogen atom when a ranges up to 3 and an OH functional group when a ranges up to 2; and the symbols R, which may be identical or different, are each a phenyl radical substituted by at least one electron-withdrawing substituent or by at least two halogen atoms, or an aryl radical containing at least two aromatic ring members, or such aryl radical bearing at least one electron-withdrawing substituent.
摘要翻译：非常适合通过其光化学/电子束交联在各种成形基材上提供抗粘附涂层的阳离子交联性聚有机硅氧烷组合物包括催化有效量的元素周期表第15-17族元素的硼酸镧，其中硼和硼酸盐的阴离子硼酸盐部分具有下式：[BXaRb] - 其中a和b是0-4和a + b = 4的整数; 当范围高达3时，符号X各自为卤素原子，当范围达到2时，符号X为OH官能团; 并且可以相同或不同的符号R各自为被至少一个吸电子取代基或至少两个卤素原子取代的苯基，或含有至少两个芳族环成员的芳基或这样的芳基带有至少一个吸电子取代基。

6. 发明授权

US07259192B2 Molecular weight reduction of polysaccharides by electron beams 有权
标题翻译：通过电子束分子量减少多糖
公开(公告)号：US07259192B2
公开(公告)日：2007-08-21
申请号：US10606256
申请日：2003-06-24
申请人： Leo Zhaoqing Liu , Christian Priou
发明人： Leo Zhaoqing Liu , Christian Priou
IPC分类号： C08F2/46 , C09K3/32
CPC分类号： C08B37/0087 , C08B37/00 , C08B37/0033 , C08B37/0096 , C09K8/68 , C09K8/90
摘要： A method of depolymerizing galactomannan-type polysaccharide polymers and xanthan, preferably galactomannans, to a pre-selected lower molecular weight by irradiation with high energy electron beams. The preferred galactomannans for treatment according to this method are guar gum, guar splits and hydroxypropyl guar. In a preferred embodiment the guar gum is depolymerized preferably to a molecular weight of about 150,000 Daltons to about 200,000 Daltons. The depolymerized guar has a polydispersity of less than about 3.0 and is useful in oil well fracturing to enhance oil production.
摘要翻译：通过用高能电子束照射，将半乳甘露聚糖型多糖聚合物和黄原胶，优选半乳甘露聚糖解聚为预选的较低分子量的方法。根据该方法治疗的优选的半乳甘露聚糖是瓜尔胶，瓜尔胶和羟丙基瓜尔胶。在优选的实施方案中，瓜耳胶优选解聚至约150,000道尔顿至约200,000道尔顿的分子量。解聚瓜尔胶具有小于约3.0的多分散性，并且可用于油井压裂以增强油的生产。

7. 发明授权

US06700019B2 Process for the preparation of tetrakis (pentafluorophenyl) borate derivatives 有权
标题翻译：四（五氟苯基）硼酸盐衍生物的制备方法
公开(公告)号：US06700019B2
公开(公告)日：2004-03-02
申请号：US10310503
申请日：2002-12-05
申请人： Michel Dury , Christian Priou , Jacques Richard
发明人： Michel Dury , Christian Priou , Jacques Richard
IPC分类号： C07F502
CPC分类号： C07F5/027
摘要： The invention concerns a novel method for preparing tetrakis(pentafluorophenyl)borate derivatives of general formula MB(C6F5)4, M being selected among Na+, Li+, or K+, wherein: (a) a C6F5X solution, X being selected among H, Cl, Br or I, in anhydrous butylic ether is contacted with an alkyllithium, the mol ratio of C6F5X/alkyllithium being 1 to 1.1, and the alkyl radical, linear or branched comprising 1 to 10 carbon atoms; (b) the resulting product is contacted with previously non-dissolved BR3, R, identical or different being selected among a chlorine atom, a fluorine atom, a bromine atom, an alkoxy radical comprising between 1 and 4 carbon atoms.
摘要翻译：本发明涉及制备通式MB（C6F5）4的四（五氟苯基）硼酸盐衍生物的新方法，M选自Na +，Li +或K +，其中：（a）C 6 F 5 X 溶液中，选自H，Cl，Br或I的无水丁基醚中的X与烷基锂接触，C 6 F 5 X /烷基锂的摩尔比为1〜1.1，直链或支链的碳原子数为1〜10的烷基 ; （b）将所得产物与之前未溶解的BR 3，R 3相同或不同，选自氯原子，氟原子，溴原子，含有1至4个碳原子的烷氧基。

8. 发明授权

US06218445B1 Stable polyorganosiloxane based compositions with cross-linkable functional groups and their use for producing antiadhesive coating 有权
标题翻译：具有可交联官能团的稳定的聚有机硅氧烷基组合物及其用于生产防粘涂层的用途
公开(公告)号：US06218445B1
公开(公告)日：2001-04-17
申请号：US09242713
申请日：2000-01-10
申请人： Christian Priou , Andre Soldat , Stuart R. Kerr, III , Reeshemah Beaty
发明人： Christian Priou , Andre Soldat , Stuart R. Kerr, III , Reeshemah Beaty
IPC分类号： C08F250
CPC分类号： C08K5/0008 , C09D183/06 , C08L83/06 , C08L2666/28
摘要： The invention concerns a composition cross-linkable under radiation. The composition includes at least one polyorganosiloxane with cross-linkable functional groups, a stabilizing amino agent, and an initiator system for hardening under radiation. The composition is stable for use and storage.
摘要翻译：本发明涉及在辐射下可交联的组合物。该组合物包括至少一种具有可交联官能团的聚有机硅氧烷，稳定化氨基剂和用于在辐射下硬化的引发剂体系。组合物使用和储存稳定。

9. 发明授权

US06153661A Onium borates/borates of organometallic complexes and cationic initiation of polymerization therewith 失效
公开(公告)号：US06153661A
公开(公告)日：2000-11-28
申请号：US851713
申请日：1997-05-06
申请人： Frederic Castellanos , Jacques Cavezzan , Jean-Pierre Fouassier , Christian Priou
发明人： Frederic Castellanos , Jacques Cavezzan , Jean-Pierre Fouassier , Christian Priou
IPC分类号： C07F5/02 , C07F9/50 , C07F19/00 , C08F2/46 , C08F2/50 , C08F4/00 , C08F4/52 , C08G59/24 , C08G59/68 , C08G59/72 , G03F7/004 , G03F7/029 , G03F7/038
CPC分类号： C08G59/72 , C07F5/022 , C08F2/50 , C08F4/52 , C08G59/24 , C08G59/68 , G03F7/0042 , G03F7/0045 , G03F7/029 , G03F7/038
摘要： Novel onium borates of an element of Groups 15 to 17 of the Periodic Table, or borates of an organometallic complex of an element of Groups 4 to 10 of the Periodic Table, well suited for the photochemical/electron beam cationic initiation of polymerization/crosslinking, the anionic borate moiety of which having the formula:[BX.sub.a R.sub.b ].sup.-in which a and b are integers ranging from 0 to 4 and a+b=4; the symbols X are each a halogen atom when a ranges up to 3 and an OH functional group when a ranges up to 2; and the symbols R, which may be identical or different, are each a phenyl radical substituted by at least one element or electron-withdrawing substituent or by at least two halogen atoms, or an aryl radical containing at least two aromatic ring members, or such aryl radical bearing at least one electron-withdrawing substituent.

10. 发明授权

US5693688A Initators for the cationic crosslinking of polymers containing organofunctional groups, crosslinkable polyorganosiloxane-based compositions containing these initiators and application of said compositions in anti-adhesion 失效
标题翻译：含有有机官能团的聚合物阳离子交联的起始剂，含有这些引发剂的可交联聚有机硅氧烷基组合物和所述组合物在抗粘连中的应用
公开(公告)号：US5693688A
公开(公告)日：1997-12-02
申请号：US528926
申请日：1995-09-15
申请人： Christian Priou
发明人： Christian Priou
IPC分类号： C08F4/00 , C07F5/02 , C08F2/46 , C08G59/68 , C08G77/06 , C08G77/22 , C09D183/06
CPC分类号： C08G59/68 , C07F5/027 , C09D183/06
摘要： The present invention relates to initiators of cationic polymerization and/or crosslinking, under photochemical and/or thermal activation and/or activation by a beam of electrons, of monomers and/or polymers containing organofunctional groups. These initiators give good performance with the majority of monomers/polymers, including in particular functional polyorganosiloxanes, which are crosslinkable cationically and under UV. The subject of the invention is also compositions based on at least one cationically crosslinkable polyorganosiloxane and on at least one initiator, as defined above. Application: paper anti-adhesion.
摘要翻译：本发明涉及在含有有机官能团的单体和/或聚合物的电子束的光化学和/或热活化和/或活化下阳离子聚合和/或交联的引发剂。这些引发剂与大多数单体/聚合物（包括特别是功能性聚有机硅氧烷）具有良好的性能，其可阳离子交联和在UV下。本发明的主题还是基于至少一种可阳离子交联的聚有机硅氧烷和至少一种如上所定义的引发剂的组合物。适用范围：纸张防粘。

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