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1. 发明授权

US06218445B1 Stable polyorganosiloxane based compositions with cross-linkable functional groups and their use for producing antiadhesive coating 有权
标题翻译：具有可交联官能团的稳定的聚有机硅氧烷基组合物及其用于生产防粘涂层的用途
公开(公告)号：US06218445B1
公开(公告)日：2001-04-17
申请号：US09242713
申请日：2000-01-10
申请人： Christian Priou , Andre Soldat , Stuart R. Kerr, III , Reeshemah Beaty
发明人： Christian Priou , Andre Soldat , Stuart R. Kerr, III , Reeshemah Beaty
IPC分类号： C08F250
CPC分类号： C08K5/0008 , C09D183/06 , C08L83/06 , C08L2666/28
摘要： The invention concerns a composition cross-linkable under radiation. The composition includes at least one polyorganosiloxane with cross-linkable functional groups, a stabilizing amino agent, and an initiator system for hardening under radiation. The composition is stable for use and storage.
摘要翻译：本发明涉及在辐射下可交联的组合物。该组合物包括至少一种具有可交联官能团的聚有机硅氧烷，稳定化氨基剂和用于在辐射下硬化的引发剂体系。组合物使用和储存稳定。

2. 发明授权

US5721291A Crosslinkable polyorganosiloxane composition 失效
标题翻译：可交联聚有机硅氧烷组合物
公开(公告)号：US5721291A
公开(公告)日：1998-02-24
申请号：US602518
申请日：1996-02-20
申请人： Eric Gaulle , Christian Priou , Andre Soldat
发明人： Eric Gaulle , Christian Priou , Andre Soldat
IPC分类号： C08L83/05 , C08F2/46 , C08L83/04 , C08L83/06 , C09D183/06 , C09J7/02
CPC分类号： C08L83/06 , C09D183/06
摘要： The invention relates to a composition based on crosslinkable epoxy-functional organopolysiloxanes. This composition comprises: A. at least 10% by weight of a linear polyorganosiloxane A (POS) of average general formula (II): ##STR1## in which: R.sub.1 is CH.sub.3, R' is an alkylene containing 2 to 50 C, R is an alkyl having from 6 to 26 C, X is R.sub.1, H, --R'-epoxy or hydroxyl, x=40-150, t=3-9, z=0-5 and y=0, B. at least one second crosslinkable epoxy-functional POS (B), B being present in the proportion of at most 90% by weight and corresponding to: B(a) with x=160-1000, t=1-15, z=0-5 and y=0, B(b) with x=0-120, t=10-30, z=0-5 and y=0, or B(c) with x=0-200, t=0-5, z=0-5 and y=10-90, C. and at least one photoinitiator. This composition can be used in the manufacture of protectors for adhesive bodies ("release liners"), papers or plastics or of liner-free self-adhesive labels.
摘要翻译：本发明涉及一种基于交联性环氧官能的有机聚硅氧烷的组合物。该组合物包含：A.至少10重量％的平均通式（II）的线性聚有机硅氧烷A（POS）：其中：R 1是CH 3，R'是含有2至50个的亚烷基 C，R为6至26个碳原子的烷基，X为R1，H，-R'-环氧或羟基，x = 40-150，t = 3-9，z = 0-5，y = 0，B 至少一个第二可交联环氧官能POS（B），B以至多90重量％的比例存在，并且对应于：B（a），其中x = 160-1000，t = 1-15，z = 0-5和y = 0，B（b）其中x = 0-120，t = 10-30，z = 0-5和y = 0，或B（c），x = 0-200，t = 0 -5，z = 0-5和y = 10-90，C和至少一种光引发剂。该组合物可用于制造用于粘合体（“脱模衬垫”），纸张或塑料或无衬垫的自粘标签的保护件。

3. 发明授权

US5795947A Olefinically functional polyorganosiloxanes and curable silicone compositions comprised thereof 失效
标题翻译：由其组成的烯属功能性聚有机硅氧烷和可固化的有机硅组合物
公开(公告)号：US5795947A
公开(公告)日：1998-08-18
申请号：US678174
申请日：1996-07-11
申请人： Jean-Marc Frances , Andre Soldat
发明人： Jean-Marc Frances , Andre Soldat
IPC分类号： C08G77/20 , C08G77/38 , C09D183/04 , C08G77/08
CPC分类号： C08G77/38 , C08G77/20 , C09D183/04
摘要： Functional mixed polyorganosiloxanes, well suited for formulation into curable release compositions, notably for paper, comprise the same or different recurring structural units of the formula (I): R.sub.a Y.sub.b X.sub.c SiO.sub.(4-a-b-c)/2 (I) in which the radicals R are each an alkyl, vinyl, aryl or aralkyl radical, at least 80% of the radicals R being methyl radicals, the radicals X are each H or a reactive polar functional group devoid of the heteroatoms nitrogen and sulfur, the radicals Y are at least C.sub.4 alkenyl or alkenyloxy radical containing at least one site of ethylenic unsaturation at a polymer chain end or along the polymer chain, a, b and c are equal to 0, 1, 2 or 3, and a+b+c=0, 1, 2 or 3, with the proviso that the number of SiO.sub.4/2 units is less than 30 mol %, and are prepared from the corresponding organohydropolysiloxanes devoid of the X functional groups and the Y radicals, from the corresponding alkenes from which the alkenyl or alkenyloxy radicals Y are derived and from the corresponding ethylenically or hydroxylated organic compounds from which the X functional groups are derived, whether via simultaneous or successive addition reactions, or via simultaneous dehydrocondensation and addition reactions, or via successive dehydrocondensation and then addition reactions.
摘要翻译：功能性混合聚有机硅氧烷，非常适合配制成可固化脱模组合物，特别是用于纸的组合物包含相同或不同的式（I）的重复结构单元：其中基团R各自独立地为R ybXcSiO（4-abc）/ 2（I）烷基，乙烯基，芳基或芳烷基，至少80％的基团R是甲基，基团X各自为H或没有杂原子氮和硫的反应性极性官能团，基团Y至少为C4链烯基或在聚合物链端或沿着聚合物链的至少一个含有烯属不饱和位点的烯氧基，a，b和c等于0,1,2或3，a + b + c = 0,1,2 或3，条件是SiO 4/2单元的数量小于30摩尔％，并且由相应的烯烃或烯氧基自由基的烯烃由相应的烯烃或链烯基氧基组成的相应的没有X官能团和Y基团的有机氢聚硅氧烷制备 Y是衍生的，来自相应的eth 不管是通过同时还是连续的加成反应，或通过同时脱氢缩合和加成反应，或通过连续脱氢缩合，然后加成反应，衍生出X官能团的烯属或羟基化有机化合物。

4. 发明授权

US5629387A Silicone compositions comprising long chain .alpha.-acetylenic alcohol hydrosilylation inhibitors 失效
标题翻译：含有长链α-乙炔醇氢化硅烷化抑制剂的硅酮组合物
公开(公告)号：US5629387A
公开(公告)日：1997-05-13
申请号：US526780
申请日：1995-09-11
申请人： Jean-Marc Frances , Robert S. Dordick , Andre Soldat
发明人： Jean-Marc Frances , Robert S. Dordick , Andre Soldat
IPC分类号： C07C33/042 , C07C33/24 , C08G77/06 , C08K5/05 , C08L83/04 , C08L83/07 , C09D7/12 , C09D183/04 , C09J7/02 , C08F283/00
CPC分类号： C08K5/05 , C08L83/04 , C08G77/12 , C08G77/14 , C08G77/16 , C08G77/20 , C08G77/70 , C08G77/80
摘要： Stable curable silicone compositions, well suited for the deposition of release coatings onto a wide variety of substrates, for example paper or plastic films, comprise a hydrosilylation-curable polyorganosiloxane oil and/or at least one Si alkenylated organopolysiloxane resin and, optionally, at least one organohydrosiloxane resin, an SiH crosslinking agent therefor, a hydrosilylation-inhibiting amount of a long chain acetylenic alcohol, advantageously having a boiling point higher than 250.degree. C., and a catalytically effective amount of a hydrosilylation catalyst, e.g., platinum or a platinum compound/complex.
摘要翻译：非常适合于将剥离涂层沉积在各种基材上，例如纸或塑料膜的稳定的可固化的硅氧烷组合物包含氢化硅烷化可固化的聚有机硅氧烷油和/或至少一种Si烯基化的有机聚硅氧烷树脂，并且任选地至少一种有机氢硅氧烷树脂，其SiH交联剂，有利于沸点高于250℃的长链炔醇的氢化硅烷化抑制量和催化有效量的氢化硅烷化催化剂，例如铂或铂化合物/复合物。

5. 发明授权

US5446087A Curable release compositions comprising novel silicone adhesion modifier 失效
标题翻译：包含新型硅氧烷粘合改性剂的可固化释放组合物
公开(公告)号：US5446087A
公开(公告)日：1995-08-29
申请号：US161467
申请日：1993-12-06
申请人： Francois Chizat , Andre Soldat
发明人： Francois Chizat , Andre Soldat
IPC分类号： C08L83/04 , C09D183/04 , C09J7/02
CPC分类号： C09D183/04 , C08L83/04 , C08G77/12 , C08G77/16 , C08G77/20 , C08G77/80
摘要： Unique silicone adhesion modifiers well suited for formulation into curable release compositions containing a linear polydiorganosiloxane, comprise an organopolysiloxane resin (A) containing at least 0.1 mol % of alkenyl or alkenyloxyalkylene radicals directly bonded to silicon atoms, an organopolysiloxane resin (B) containing at least 0.5 mol % of hydrogen atoms directly bonded to silicon atoms, and a solvent/diluent (C) for the resins (A) and (B).
摘要翻译：非常适合配制成含有线性聚二有机硅氧烷的可固化脱模组合物的独特的硅氧烷粘合改性剂包括含有至少0.1mol％直接键合到硅原子上的链烯基或烯氧基亚烷基的有机聚硅氧烷树脂（A），至少含有直接键合到硅原子上的0.5mol％的氢原子和用于树脂（A）和（B）的溶剂/稀释剂（C）。

6. 发明授权

US4405590A Dismutation/redistribution of halogenosilanes into silane 失效
标题翻译：卤代硅烷转化为硅烷的重新分配
公开(公告)号：US4405590A
公开(公告)日：1983-09-20
申请号：US358387
申请日：1982-03-15
申请人： Gerard Simon , Andre Soldat
发明人： Gerard Simon , Andre Soldat
IPC分类号： C01B33/04
CPC分类号： C01B33/043
摘要： The dismutation/redistribution of halogenosilanes into silane is carried out by contacting at least one halogenosilane comprising at least one Si-H function with a compound comprising at least one .alpha.-oxoamine group, then by contacting the products of such reaction with a compound also comprising at least one .alpha.-oxoamine group, to selectively dissolve all products of reaction except for the silane therein, and then separating the desired silane therefrom.
摘要翻译：卤代硅烷对硅烷的歧化/重新分配是通过使包含至少一种Si-H官能团的至少一种卤代硅烷与包含至少一个α-氧代胺基团的化合物接触来进行的，然后通过使这种反应产物与还包含至少一个α-氧代胺基团，以选择性地溶解除硅烷之外的所有反应产物，然后从其中分离所需的硅烷。

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