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1. 发明授权

US5408005A Process for the manufacture of an impact-resistant thermoplastic resin 失效
公开(公告)号：US5408005A
公开(公告)日：1995-04-18
申请号：US78859
申请日：1993-06-21
申请人： Philippe Heim , Gerard Riess
发明人： Philippe Heim , Gerard Riess
IPC分类号： C08L33/12 , C08F212/00 , C08F212/10 , C08F220/00 , C08F220/12 , C08F265/00 , C08F265/06 , C08F279/00 , C08F279/04 , C08F291/00 , C08F291/02 , C08L33/04 , C08L51/04 , C08F257/02
CPC分类号： C08F265/06 , C08F279/04 , C08F291/02 , Y10S524/923
摘要： A process for preparing a rubber modified thermoplastic resin, in which a latex in aqueous emulsion is prepared in the presence of an ionic surfactant; a vinyl monomer insoluble or substantially insoluble in water is added, and the particles of the latex are transferred to the monomer to form an organic phase using a transfer agent of opposite charge to the surfactant; and a polymerization of the organic phase is performed.

2. 发明授权

US4952635A Process for the manufacture of an impact resistant thermoplastic resin 失效
标题翻译：用于制造耐冲击热塑性树脂的方法
公开(公告)号：US4952635A
公开(公告)日：1990-08-28
申请号：US234055
申请日：1988-08-19
申请人： Philippe Heim , Gerard Riess
发明人： Philippe Heim , Gerard Riess
IPC分类号： C08F2/02 , C08F2/12 , C08F2/18 , C08F2/30 , C08F2/44 , C08F20/04 , C08F220/04 , C08F265/04 , C08F279/02 , C08F291/02 , C08L101/00
CPC分类号： C08F265/04 , C08F279/02 , C08F291/02
摘要： A process for preparing a rubber modified thermoplastic resin, in which a latex in aqueous emulsion is prepared in the presence of a non-ionic surfactant; a vinyl monomer insoluble or substantially insoluble water is added, and the particles of the latex are transferred to the monomer to form an organic phase using a polymer or copolymer based on carboxylic acid units capable of forming an interpolymeric complex with the non-ionic surfactant; and a suspension or bulk polymerization of the organic phase is performed.
摘要翻译：一种制备橡胶改性热塑性树脂的方法，其中在非离子表面活性剂存在下制备水乳液中的胶乳; 加入乙烯基单体不溶或基本上不溶的水，并且使用基于能够与非离子表面活性剂形成共聚物络合物的羧酸单元的聚合物或共聚物将胶乳颗粒转移到单体以形成有机相; 并进行有机相的悬浮或本体聚合。

3. 发明授权

US5115031A Process for the manufacture of an impact resistant thermoplastic resin 失效
标题翻译：制造耐冲击热塑性树脂的方法
公开(公告)号：US5115031A
公开(公告)日：1992-05-19
申请号：US505483
申请日：1990-04-06
申请人： Philippe Heim , Gerard Riess
发明人： Philippe Heim , Gerard Riess
IPC分类号： C08F2/02 , C08F2/12 , C08F2/18 , C08F2/30 , C08F2/44 , C08F20/04 , C08F220/04 , C08F265/04 , C08F279/02 , C08F291/02 , C08L101/00
CPC分类号： C08F265/04 , C08F279/02 , C08F291/02
摘要： A process for preparing a rubber modified thermoplastic resin, in which a latex in aqueous emulsion is prepared in the presence of a non-ionic surfactant; a vinyl monomer insoluble or substantially insoluble water is added, and the particles of the latex are transferred to the monomer to form an organic phase using a polymer or copolymer based on carboxylic acid units capable of forming an interpolymeric complex with the non-ionic surfactant; and a suspension or bulk polymerization of the organic phase is performed.

4. 发明授权

US4927867A Process for the manufacture of an impact-resistant thermoplastic resin 失效
标题翻译：用于制造耐冲击热塑性树脂的方法
公开(公告)号：US4927867A
公开(公告)日：1990-05-22
申请号：US234052
申请日：1988-08-19
申请人： Philippe Heim , Gerard Riess
发明人： Philippe Heim , Gerard Riess
IPC分类号： C08L33/12 , C08F212/00 , C08F212/10 , C08F220/00 , C08F220/12 , C08F265/00 , C08F265/06 , C08F279/00 , C08F279/04 , C08F291/00 , C08F291/02 , C08L33/04 , C08L51/04
CPC分类号： C08F265/06 , C08F279/04 , C08F291/02 , Y10S524/923
摘要： A process for preparing a rubber modified thermoplastic resin, in which a latex in aqueous emulsion is prepared in the presence of an ionic surfactant; a vinyl monomer insoluble or substantially insoluble in water is added, and the particles of the latex are transferred to the monomer to form an organic phase using a transfer agent of opposite charge to the surfactant; and a polymerization of the organic phase is performed.
摘要翻译：一种制备橡胶改性热塑性树脂的方法，其中在离子表面活性剂存在下制备水乳液中的胶乳; 加入不溶于或基本不溶于水的乙烯基单体，并使用与表面活性剂相反电荷的转移剂将胶乳颗粒转移到单体以形成有机相; 进行有机相的聚合。

5. 发明授权

US08349944B2 Polymer dispersion in a reactive organic medium, preparation method and uses 失效
标题翻译：反应性有机介质中的聚合物分散体，制备方法和用途
公开(公告)号：US08349944B2
公开(公告)日：2013-01-08
申请号：US11915462
申请日：2006-05-24
申请人： Gerard Riess , Christelle Delaite , Kamal Hariri , Patrick Moireau
发明人： Gerard Riess , Christelle Delaite , Kamal Hariri , Patrick Moireau
IPC分类号： B05D3/12 , C04B24/26 , D02G3/00 , B32B9/00
CPC分类号： C03C25/26 , C03C25/28 , C08F2/14 , C08F218/08 , C08F226/10 , C08F283/12 , C08F2220/1825 , C08F2220/1858 , C09D151/003 , C09D151/085 , Y10T428/2913 , Y10T428/2933 , Y10T428/2962 , Y10T428/2964
摘要： The invention concerns a polymer dispersion free of water and volatile organic solvent for preparing a lubricating composition for glass yarns and for finishing glass yarns and assembling glass yarns, in particular for grids and fabrics. The dispersion comprises the product of polymerization of a vinyl monomer in the presence of a free radical initiator in a reactive organic dispersion medium.
摘要翻译：本发明涉及一种不含水和挥发性有机溶剂的聚合物分散体，用于制备用于玻璃纱线的润滑组合物和用于精整玻璃纱线并组装玻璃纱线，特别是用于网格和织物的玻璃纱线。分散体包括在反应性有机分散介质中在自由基引发剂存在下乙烯基单体聚合的产物。

6. 发明申请

US20050043429A1 Method for preparing films based on cross-linked poly(ethylene oxide) 审中-公开
标题翻译：基于交联聚（环氧乙烷）制备薄膜的方法
公开(公告)号：US20050043429A1
公开(公告)日：2005-02-24
申请号：US10498520
申请日：2002-12-20
申请人： Christo Tsvetanov , A Stamenov , Gerard Riess , Maria Ferrand , David Limal
发明人： Christo Tsvetanov , A Stamenov , Gerard Riess , Maria Ferrand , David Limal
IPC分类号： C08J7/00 , C08F283/06 , C08J3/28 , C08J5/18 , C08L1/00 , C08L71/02 , C08G2/00
CPC分类号： C08J3/28 , C08F283/06 , C08J5/18 , C08J2371/02 , C08L71/02 , C08F222/1006 , C08L2666/26 , C08L2666/04
摘要： The present invention relates to a novel method of preparing films based on cross-linked poly(ethylene oxide). This method comprises the steps consisting in: a) dissolving said polymer or copolymer of ethylene oxide, alone or in a mixture, with a water-soluble polymer, in a solvent system made up of water, an organic solvent, or a mixture in any proportion. of water and of organic solvent, in the presence of an effective amount of a photo-initiating agent or of a cross-linking agent; b1) either drying the solution thus obtained until the solvent system has evaporated, when this solvent system is made up exclusively of an organic solvent, to thus obtain a dry film, and treating the film thus obtained under conditions enabling an amount of water to be absorbed of between 10 and 100% by weight with respect to the weight of the polymer; b2) or drying the solution thus obtained until the solvent system has evaporated, when this solvent system is made up of water or a water-organic solvent mixture, to thus obtain a film containing between 10 and 100% by weight of water with respect to the weight of the polymer; c) irradiating the film thus obtained by means of ultraviolet rays of a wavelength of between 200 and 400 nm, for a period of time sufficient to enable the cross-linking.
摘要翻译：本发明涉及一种基于交联聚（环氧乙烷）制备薄膜的新方法。该方法包括以下步骤：a）将单独或混合物中的环氧乙烷的聚合物或共聚物与水溶性聚合物溶解在由水，有机溶剂或任何混合物中混合的溶剂体系中比例。的水和有机溶剂，在有效量的光引发剂或交联剂的存在下; b1）干燥所得到的溶液直到溶剂体系蒸发，当该溶剂体系仅由有机溶剂组成时，从而得到干膜，并且在使得一定量的水的条件下处理由此获得的膜相对于聚合物的重量吸收10至100重量％; b2）或干燥所得到的溶液直到溶剂体系蒸发，当该溶剂系统由水或水 - 有机溶剂混合物组成时，从而获得含有10至100重量％水的膜相对于聚合物的重量; c）通过波长在200和400nm之间的紫外线照射由此获得的膜足以实现交联的时间。

7. 发明申请

US20090214864A1 POLYMER DISPERSION IN A REACTIVE ORGANIC MEDIUM, PREPARATION METHOD AND USES 失效
标题翻译：反应有机介质中的聚合物分散体，制备方法和用途
公开(公告)号：US20090214864A1
公开(公告)日：2009-08-27
申请号：US11915462
申请日：2006-05-24
申请人： Gerard Riess , Christelle Delaite , Kamal Hariri , Patrick Moireau
发明人： Gerard Riess , Christelle Delaite , Kamal Hariri , Patrick Moireau
IPC分类号： B32B17/02 , C08L31/04 , C08L39/06 , C08K5/1515
CPC分类号： C03C25/26 , C03C25/28 , C08F2/14 , C08F218/08 , C08F226/10 , C08F283/12 , C08F2220/1825 , C08F2220/1858 , C09D151/003 , C09D151/085 , Y10T428/2913 , Y10T428/2933 , Y10T428/2962 , Y10T428/2964
摘要： The present invention relates to a polymer dispersion devoid of water and of volatile organic solvent intended for the preparation of sizing compositions for glass strands and of coating compositions for glass strands and assemblages of such strands, in particular grids or woven fabrics.The dispersion comprises the product from the polymerization of at least one vinyl monomer in the presence of a radical initiator in a reactive organic dispersing medium.The dispersion includes 20 to 70% by weight of polymer in the form of fine substantially spherical particles with a size of less than 40 μm. It is stable under the normal storage conditions.
摘要翻译：本发明涉及一种不含水和挥发性有机溶剂的聚合物分散体，其用于制备玻璃丝的上胶组合物和用于玻璃丝的涂料组合物和这种丝束，特别是网格或机织织物的组合物。分散体包括在反应性有机分散介质中在自由基引发剂存在下由至少一种乙烯基单体聚合的产物。分散体包含20至70重量％的具有小于40μm的尺寸的细小的基本上为球形的颗粒形式的聚合物。在正常储存条件下稳定。

8. 发明授权

US5696183A Elastomer-coated mineral particles 失效
标题翻译：弹性体涂覆的矿物颗粒
公开(公告)号：US5696183A
公开(公告)日：1997-12-09
申请号：US324947
申请日：1994-10-18
申请人： Tarek Sarraf , Frederic Hoehn , Gerard Riess
发明人： Tarek Sarraf , Frederic Hoehn , Gerard Riess
IPC分类号： C08K9/04 , C08K9/10 , C09C3/10 , C08K9/02
CPC分类号： C08K9/10
摘要： Disclosed are elastomer-coated mineral particles which are characterized by being in the form of individual granules. The disclosure also relates to a process for preparing the said particles, the said process being characterized in that it consists of the following: a) Causing the mineral particles to react with at least one binding agent which includes at least one polyoxyethylenic sequence, and with at least one elastomer latex; b) Separation of the liquid phase from the particles; c) Drying of the said particles. The utilization of the said particles for the reinforcement of thermoplastic polymers and thermoplastic polymers reinforced with the mineral particles according to this invention are likewise disclosed.
摘要翻译：公开了以弹性体涂覆的矿物颗粒为特征的单颗粒形式。本公开还涉及制备所述颗粒的方法，所述方法的特征在于其由以下组成：a）使矿物颗粒与至少一种包含至少一个聚氧乙烯序列的结合剂反应，并且与至少一种弹性体胶乳; b）液相与颗粒的分离; c）干燥所述颗粒。同样公开了利用所述颗粒加强根据本发明的矿物颗粒的热塑性聚合物和热塑性聚合物。

9. 发明授权

US5244940A Process for agglomerating a latex, agglomerated latex obtained and its application to the modification of thermoplastic matrices to make them impact-resistant 失效
标题翻译：聚合胶乳的方法，所获得的聚集胶乳及其在热塑性基质改性中的应用，使其具有抗冲击性
公开(公告)号：US5244940A
公开(公告)日：1993-09-14
申请号：US595674
申请日：1990-10-11
申请人： Gerard Riess , Herve Thyebault
发明人： Gerard Riess , Herve Thyebault
IPC分类号： C08C1/07 , C08F6/18
CPC分类号： C08C1/07 , C08F6/18
摘要： The agglomeration of a latex of a polymer chosen from elastomers and thermoplastic resins is performed by mixing the latex to be agglomerated with an agglomerating latex consisting of:(A) a polymer chosen from elastomers and thermoplastic resins; and(B) a nonionic surface-active agent consisting of a block polymer containing at least one polyoxyethylene block and at least one block of a polymer chosen from vinyl, diene and acrylic and methacrylic ester polymers,the said agglomerating latex being produced by the synthesis of the polymer defined under (A) during which (B) has been employed as a surfactant. The polyoxyethylene-polystyrene-polyoxyethylene triblock polymer may be mentioned among the surface-active agents (B).
摘要翻译：选自弹性体和热塑性树脂的聚合物胶乳的聚集是通过将待凝聚的胶乳与由以下组成的聚集胶乳混合进行的：（A）选自弹性体和热塑性树脂的聚合物; 和（B）由含有至少一个聚氧乙烯嵌段和至少一个选自乙烯基，二烯和丙烯酸和甲基丙烯酸酯聚合物的聚合物的至少一个嵌段的嵌段聚合物组成的非离子表面活性剂，所述附聚胶乳通过合成的（A）中定义的聚合物，其中（B）已经用作表面活性剂。表面活性剂（B）中可以提及聚氧乙烯 - 聚苯乙烯 - 聚氧乙烯三嵌段聚合物。

10. 发明授权

US06362274B1 Graft copolymers, method for preparing same, compositions containing said copolymers, and use thereof for preparing pigment dispersions in aqueous and/or organic media 有权
标题翻译：接枝共聚物，其制备方法，含有所述共聚物的组合物及其在水性和/或有机介质中制备颜料分散体的用途
公开(公告)号：US06362274B1
公开(公告)日：2002-03-26
申请号：US09117306
申请日：1999-02-23
申请人： Pierre Legrand , Gerard Riess , Jean-Phillipe Lerch , Daniel Lefevre
发明人： Pierre Legrand , Gerard Riess , Jean-Phillipe Lerch , Daniel Lefevre
IPC分类号： C08J300
CPC分类号： C09D17/00 , C08F290/04 , C09D7/45 , C09D151/00
摘要： The invention relates to grafted copolymers comprising at least three sequences of distinct chemical nature, among which one or more sequence(s) for anchoring on solid particles, one or more sequence(s) of hydrophobic character and one or more sequence(s) of hydrophilic character. The invention also concerns their process of preparation, the compositions containing them, their use as agent for dispersing, stabilizing solid particles and/or emulsifying in an aqueous and/or organic medium, as well as use thereof for preparing pigmentary dispersions in aqueous and/or organic medium.
摘要翻译：本发明涉及包含至少三种具有不同化学性质的序列的接枝共聚物，其中一个或多个锚定在固体颗粒上的序列，一个或多个疏水性序列和一个或多个序列亲水性本发明还涉及它们的制备方法，含有它们的组合物，它们作为用于分散，稳定固体颗粒和/或在水性和/或有机介质中乳化的试剂的用途，以及其用于在水性和/或有机介质中制备颜料分散体的用途，或有机介质。

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