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1. 发明授权

US4331570A Carboamidoalkyl norbornanes and organoleptic use in perfumes 失效
标题翻译：卡波酰胺基烷基降冰片烷和感官用于香水
公开(公告)号：US4331570A
公开(公告)日：1982-05-25
申请号：US267844
申请日：1981-05-28
申请人： Philip T. Klemarczyk , Frederick L. Schmitt , Edward J. Granda , Domenick Luccarelli, Jr.
发明人： Philip T. Klemarczyk , Frederick L. Schmitt , Edward J. Granda , Domenick Luccarelli, Jr.
IPC分类号： A24B15/34 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , A61K7/22
CPC分类号： C11D3/50 , A24B15/345 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Described are compounds having the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond and wherein R.sub.2 is methyl or hydrogen; R.sub.6 is methyl or hydrogen; R.sub.1, R.sub.3 or R.sub.7 represent methyl or hydrogen, with the priviso that one of R.sub.1, R.sub.3 and R.sub.7 represents methyl and the other two of R.sub.1, R.sub.3 and R.sub.7 represent hydrogen; wherein R.sub.4 and R.sub.5 are the same or different and each represents hydrogen or C.sub.1 -C.sub.3 lower alkyl. In addition, organoleptic uses of such compounds are disclosed for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, toothpastes, medicinal products, chewing tobaccos, smoking tobaccos, smoking tobacco articles, perfumes, perfumed articles (such as liquid or solid anionic, cationic, nonionic or zwitterionic detergents, fabric softeners, dryer-added fabric softener articles, fabric brighteners and other perfumed articles and colognes). Also disclosed is a process for preparing such compounds according to the reaction scheme: ##STR2## wherein R" represents C.sub.1 -C.sub.3 alkyl; m+n=3 with the further proviso that m is 1 or 2 and n is 1 or 2; and wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are as defined above.
摘要翻译：描述了具有通用结构的化合物：其中虚线表示碳 - 碳单键或碳 - 碳双键，其中R2是甲基或氢; R6是甲基或氢; R 1，R 3或R 7表示甲基或氢，R 1，R 3和R 7中的一个表示甲基，R 1，R 3和R 7中的另外两个表示氢; 其中R 4和R 5相同或不同，各自表示氢或C 1 -C 3低级烷基。此外，公开了这种化合物的感官用途，用于增强或增强消费材料的香味或味道，包括食品，口香糖，牙膏，药用产品，咀嚼烟草，烟草烟草，烟草制品，香水，香水制品（如液体或固体阴离子，阳离子，非离子或两性离子洗涤剂，织物柔软剂，干燥剂添加的织物柔软剂制品，织物增白剂和其它香料制品和古龙水）。还公开了根据反应方案制备这些化合物的方法：其中R“表示C 1 -C 3烷基; m + n = 3，进一步的条件是m为1或2，n为1或2; 并且其中R 1，R 2，R 3，R 4，R 5，R 6和R 7如上所定义。

2. 发明授权

US4324912A Carboamidoalkyl norbornanes, organoleptic uses thereof and process for preparing same 失效
标题翻译：碳酰胺基烷基降冰片烷，感官用途及其制备方法
公开(公告)号：US4324912A
公开(公告)日：1982-04-13
申请号：US206632
申请日：1980-11-13
申请人： Philip T. Klemarczyk , Frederick L. Schmitt , Edward J. Granda , Domenick Luccarelli, Jr.
发明人： Philip T. Klemarczyk , Frederick L. Schmitt , Edward J. Granda , Domenick Luccarelli, Jr.
IPC分类号： A24B15/34 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , C07C103/19
CPC分类号： C11D3/50 , A24B15/345 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Described are compounds having the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond and wherein R.sub.2 is methyl or hydrogen; R.sub.6 is methyl or hydrogen; R.sub.1, R.sub.3 or R.sub.7 represent methyl or hydrogen, with the proviso that one of R.sub.1, R.sub.3 and R.sub.7 represents methyl and the other two of R.sub.1, R.sub.3 and R.sub.7 represent hydrogen; wherein R.sub.4 and R.sub.5 are the same or different and each represents hydrogen or C.sub.1 -C.sub.3 lower alkyl. In addition, organoleptic uses of such compounds are disclosed for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, toothpastes, medicinal products, chewing tobaccos, smoking tobaccos, smoking tobacco articles, perfumes, perfumed articles (such as liquid or solid anionic, cationic, nonionic or zwitterionic detergents, fabric softeners, dryer-added fabric softener articles, fabric brighteners and other perfumed articles and colognes). Also disclosed is a process for preparing such compounds according to the reaction scheme: ##STR2## wherein R" represents C.sub.1 -C.sub.3 alkyl; m+n=3 with the further proviso that m is 1 or 2 and n is 1 or 2; and wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are as defined above.
摘要翻译：描述了具有通用结构的化合物：其中虚线表示碳 - 碳单键或碳 - 碳双键，其中R2是甲基或氢; R6是甲基或氢; R 1，R 3或R 7表示甲基或氢，条件是R 1，R 3和R 7中的一个表示甲基，R 1，R 3和R 7中的另外两个表示氢; 其中R 4和R 5相同或不同，各自表示氢或C 1 -C 3低级烷基。此外，公开了这种化合物的感官用途，用于增强或增强消费材料的香味或味道，包括食品，口香糖，牙膏，药用产品，咀嚼烟草，烟草烟草，烟草制品，香水，香水制品（如液体或固体阴离子，阳离子，非离子或两性离子洗涤剂，织物柔软剂，干燥剂添加的织物柔软剂制品，织物增白剂和其它香料制品和古龙水）。还公开了根据反应方案制备这些化合物的方法：其中R“表示C 1 -C 3烷基; m + n = 3，进一步的条件是m为1或2，n为1或2; 并且其中R 1，R 2，R 3，R 4，R 5，R 6和R 7如上所定义。

3. 发明授权

US4357949A Carboamidoalkyl norbornanes, organoleptic uses thereof and process for preparing same 失效
标题翻译：碳酰胺基烷基降冰片烷，感官用途及其制备方法
公开(公告)号：US4357949A
公开(公告)日：1982-11-09
申请号：US268144
申请日：1981-05-28
申请人： Philip T. Klemarczyk , Frederick L. Schmitt , Edward J. Granda , Domenick Luccarelli, Jr.
发明人： Philip T. Klemarczyk , Frederick L. Schmitt , Edward J. Granda , Domenick Luccarelli, Jr.
IPC分类号： A24B15/34 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , A24B3/12 , A24B15/30
CPC分类号： C11D3/50 , A24B15/345 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Described are compounds having the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond and wherein R.sub.2 is methyl or hydrogen; R.sub.6 is methyl or hydrogen; R.sub.1, R.sub.3 or R.sub.7 represent methyl or hydrogen, with the proviso that one of R.sub.1, R.sub.3 and R.sub.7 represents methyl and the other two of R.sub.1, R.sub.3 and R.sub.7 represent hydrogen; wherein R.sub.4 and R.sub.5 are the same or different and each represents hydrogen or C.sub.1 -C.sub.3 lower alkyl. In addition, organoleptic uses of such compounds are disclosed for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, toothpastes, medicinal products, chewing tobaccos, smoking tobaccos, smoking tobacco articles, perfumes, perfumed articles (such as liquid or solid anionic, cationic, nonionic or zwitterionic detergents, fabric softeners, dryer-added fabric softener articles, fabric brighteners and other perfumed articles and colognes). Also disclosed is a process for preparing such compounds according to the reaction scheme: ##STR2## wherein R" represents C.sub.1 C.sub.3 alkyl; m+n=3 with the further proviso that m is 1 or 2 and n is 1 or 2; and wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are as defined above.
摘要翻译：描述了具有通用结构的化合物：其中虚线表示碳 - 碳单键或碳 - 碳双键，其中R2是甲基或氢; R6是甲基或氢; R 1，R 3或R 7表示甲基或氢，条件是R 1，R 3和R 7中的一个表示甲基，R 1，R 3和R 7中的另外两个表示氢; 其中R 4和R 5相同或不同，各自表示氢或C 1 -C 3低级烷基。此外，公开了这种化合物的感官用途，用于增强或增强消费材料的香味或味道，包括食品，口香糖，牙膏，药用产品，咀嚼烟草，烟草烟草，烟草制品，香水，香水制品（如液体或固体阴离子，阳离子，非离子或两性离子洗涤剂，织物柔软剂，干燥剂添加的织物柔软剂制品，织物增白剂和其它香料制品和古龙水）。还公开了根据反应方案制备这些化合物的方法：其中R“表示C 1 -C 3烷基; m + n = 3，进一步的条件是m为1或2，n为1或2; 并且其中R 1，R 2，R 3，R 4，R 5，R 6和R 7如上所定义。

4. 发明授权

US4331550A Carboamidoalkyl norbornanes and organoleptic use in detergents 失效
标题翻译：卡波酰胺基烷基降冰片烷和感官用于洗涤剂
公开(公告)号：US4331550A
公开(公告)日：1982-05-25
申请号：US268117
申请日：1981-05-28
申请人： Philip T. Klemarczyk , Frederick L. Schmitt , Edward J. Granda , Domenick Luccarelli, Jr.
发明人： Philip T. Klemarczyk , Frederick L. Schmitt , Edward J. Granda , Domenick Luccarelli, Jr.
IPC分类号： A24B15/34 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , A61K7/46
CPC分类号： C11D3/50 , A24B15/345 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Described are compounds having the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond and wherein R.sub.2 is methyl or hydrogen; R.sub.6 is methyl or hydrogen; R.sub.1, R.sub.3 or R.sub.7 represent methyl or hydrogen, with the proviso that one of R.sub.1, R.sub.3 and R.sub.7 represents methyl and the other two of R.sub.1, R.sub.3 and R.sub.7 represent hydrogen; wherein R.sub.4 and R.sub.5 are the same or different and each represents hydrogen or C.sub.1 -C.sub.3 lower alkyl. In addition, organoleptic uses of such compounds are disclosed for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, toothpastes, medicinal products, chewing tobaccos, smoking tobaccos, smoking tobacco articles, perfumes, perfumed articles (such as liquid or solid anionic, cationic, nonionic or zwitterionic detergents, fabric softeners, dryer-added fabric softener articles, fabric brighteners and other perfumed articles and colognes). Also disclosed is a process for preparing such compounds according to the reaction scheme: ##STR2## wherein R" represents C.sub.1 -C.sub.3 alkyl; m+n=3 with the further proviso that m is 1 or 2 and n is 1 or 2; and wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are as defined above.
摘要翻译：描述了具有通用结构的化合物：其中虚线表示碳 - 碳单键或碳 - 碳双键，其中R2是甲基或氢; R6是甲基或氢; R 1，R 3或R 7表示甲基或氢，条件是R 1，R 3和R 7中的一个表示甲基，R 1，R 3和R 7中的另外两个表示氢; 其中R 4和R 5相同或不同，各自表示氢或C 1 -C 3低级烷基。此外，公开了这种化合物的感官用途，用于增强或增强消费材料的香味或味道，包括食品，口香糖，牙膏，药用产品，咀嚼烟草，烟草烟草，烟草制品，香水，香水制品（如液体或固体阴离子，阳离子，非离子或两性离子洗涤剂，织物柔软剂，干燥剂添加的织物柔软剂制品，织物增白剂和其它香料制品和古龙水）。还公开了根据反应方案制备这些化合物的方法：其中R“表示C 1 -C 3烷基; m + n = 3，进一步的条件是m为1或2，n为1或2; 并且其中R 1，R 2，R 3，R 4，R 5，R 6和R 7如上所定义。

5. 发明授权

US4329373A Use of carboamidoalkyl norbornanes for augmenting or enhancing the aroma or taste of a foodstuff 失效
标题翻译：使用碳酰氨基烷基降冰片烷来增强或增强食品的香气或味道
公开(公告)号：US4329373A
公开(公告)日：1982-05-11
申请号：US268112
申请日：1981-05-28
申请人： Philip T. Klemarczyk , Frederick L. Schmitt , Edward J. Granda , Domenick Luccarelli, Jr.
发明人： Philip T. Klemarczyk , Frederick L. Schmitt , Edward J. Granda , Domenick Luccarelli, Jr.
IPC分类号： A24B15/34 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , A23L1/235
CPC分类号： C11D3/50 , A24B15/345 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Described is a process for augmenting or enhancing the grapefruit aroma or taste of a foodstuff which comprises adding to a foodstuff at least one norbornane derivative defined according to the structure ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond and wherein R.sub.2 is methyl or hydrogen; R.sub.6 is methyl or hydrogen; R.sub.1, R.sub.3, or R.sub.7 represent methyl or hydrogen, with the proviso that one of R.sub.1, R.sub.3 and R.sub.7 represents methyl and the other two of R.sub.1, R.sub.3 and R.sub.7 represent hydrogen; wherein R.sub.4 and R.sub.5 are the same or different and each represents hydrogen or C.sub.1 -C.sub.3 lower alkyl.
摘要翻译：描述了用于增加或增强食品的葡萄柚香气或味道的方法，其包括向食品中加入至少一种根据结构定义的降冰片烷衍生物，其中虚线表示碳 - 碳单键或碳 - 碳双键，其中R2是甲基或氢; R6是甲基或氢; R 1，R 3或R 7表示甲基或氢，条件是R 1，R 3和R 7中的一个表示甲基，R 1，R 3和R 7中的另外两个表示氢; 其中R 4和R 5相同或不同，各自表示氢或C 1 -C 3低级烷基。

6. 发明授权

US4390464A Methyl substituted norbornane derivatives, organoleptic uses thereof and process for preparing same 失效
标题翻译：甲基取代的降冰片烷衍生物，其感官用途及其制备方法
公开(公告)号：US4390464A
公开(公告)日：1983-06-28
申请号：US366091
申请日：1982-04-06
申请人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
发明人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
IPC分类号： C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , A61K7/46
CPC分类号： C11D3/50 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Described are methyl substituted norbornane derivatives having the generic structure: ##STR1## wherein R represents the nitrile moiety having the structure: ##STR2## or the dimethoxymethyl moiety having the structure: ##STR3## and wherein one of R.sub.1, or R.sub.2 is methyl and the other of R.sub.1 or R.sub.2 is hydrogen.Also described are processes and compositions for augmenting or enhancing the flavor and/or aroma of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, perfumes, colognes and perfumed articles such as solid or liquid anionic, cationic, nonionic or zwitterionic detergents or fabric softeners or fabric softener articles using as the essential ingredient at least one of methyl substituted norbornane derivatives of our invention.
摘要翻译：描述了具有以下通用结构的甲基取代的降冰片烷衍生物：其中R表示具有以下结构的腈部分：[CN]或具有以下结构的二甲氧基甲基部分：其中R 1或R 2中的一个为甲基， R1或R2中的另一个是氢。还描述了用于增强或增强消耗材料的风味和/或香气的方法和组合物，包括食品，口香糖，药用产品，牙膏，咀嚼烟草，香水，古龙水和香料制品，例如固体或液体阴离子，阳离子，非离子或非离子的使用本发明的甲基取代的降冰片烷衍生物中的至少一种作为必需成分的两性离子洗涤剂或织物柔软剂或织物柔软剂制品。

7. 发明授权

US4388207A Process of augmenting the aroma of detergents using methyl substituted norbornane carboxaldehyde dimethyl acetals or norbornene carbonitriles 失效
标题翻译：使用甲基取代的降冰片烷甲醛二甲基缩醛或降冰片烯碳腈增加洗涤剂香气的方法
公开(公告)号：US4388207A
公开(公告)日：1983-06-14
申请号：US366081
申请日：1982-04-06
申请人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
发明人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
IPC分类号： A24B15/34 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , C11D9/44
CPC分类号： C11D3/50 , A24B15/345 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Described are methyl substituted norbornane derivatives having the generic structure: ##STR1## wherein R represents the nitrile moiety having the structure:[ C.tbd.N]or the dimethoxymethyl moiety having the structure: ##STR2## and wherein one of R.sub.1, or R.sub.2 is methyl and the other of R.sub.1 or R.sub.2 is hydrogen.Also described are processes and compositions for augmenting or enhancing the flavor and/or aroma of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, perfumes, colognes and perfumed articles such as solid or liquid anionic, cationic, nonionic or zwitterionic detergents or fabric softeners or fabric softener articles using as the essential ingredient at least one of methyl substituted norbornane derivatives of our invention.
摘要翻译：描述了具有以下通用结构的甲基取代的降冰片烷衍生物：其中R表示具有以下结构的腈部分：[C 3 N 3]或具有以下结构的二甲氧基甲基部分：其中R 1或R 2中的一个为甲基 R1或R2中的另一个为氢。还描述了用于增强或增强消耗材料的风味和/或香气的方法和组合物，包括食品，口香糖，药用产品，牙膏，咀嚼烟草，香水，古龙水和香料制品，例如固体或液体阴离子，阳离子，非离子或非离子的使用本发明的甲基取代的降冰片烷衍生物中的至少一种作为必需成分的两性离子洗涤剂或织物柔软剂或织物柔软剂制品。

8. 发明授权

US4386064A Flavoring with carbomethoxy methyl norbornanes 失效
标题翻译：用甲酯基甲基降冰片烷调味
公开(公告)号：US4386064A
公开(公告)日：1983-05-31
申请号：US380422
申请日：1982-05-20
申请人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
发明人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
IPC分类号： A24B15/34 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , A23L1/235
CPC分类号： C11D3/50 , A24B15/345 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Described are compounds defined according to the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; and one of R.sub.1 and R.sub.2 is methyl and the other of R.sub.1 and R.sub.2 is hydrogen. In addition, organoleptic uses of such compounds are disclosed for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, chewing tobaccos, medicinal products, toothpastes, perfumes, perfumed articles (such as liquid or solid, anionic, cationic, nonionic or zwitterionic detergents), fabric softeners and dryer-added fabric softener articles.
摘要翻译：描述了根据通用结构定义的化合物：其中虚线表示碳 - 碳单键或碳 - 碳双键; R1和R2之一是甲基，R1和R2中的另一个是氢。此外，公开了这种化合物的感官用途，用于增强或增强消费材料的香气或味道，包括食品，口香糖，咀嚼烟草，药用产品，牙膏，香料，加香制品（如液体或固体，阴离子，阳离子，非离子或两性离子洗涤剂），织物柔软剂和干燥剂添加的织物柔软剂制品。

9. 发明授权

US4335152A Methyl substituted norbornane carboxaldehydes, organoleptic uses thereof and process for preparing same 失效
标题翻译：甲基取代的降冰片烷甲醛，其感官用途及其制备方法
公开(公告)号：US4335152A
公开(公告)日：1982-06-15
申请号：US220646
申请日：1980-12-29
申请人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
发明人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
IPC分类号： C07C45/69 , C07C47/347 , C11B9/00 , A23L2/26
CPC分类号： C11B9/0046 , C07C45/69 , C07C47/347
摘要： Described are methyl-substituted norbornane carboxaldehyde having the generic structure: ##STR1## wherein the dashed line is a carbon-carbon single bond, or a carbon-carbon double bond, and R.sub.1 R.sub.2 and R.sub.3 each represent methyl or hydrogen with the proviso that (i) R.sub.1 is hydrogen when R.sub.3 is methyl and (ii) R.sub.1 is methyl when R.sub.3 is hydrogen.Also described are processes and compositions for augmenting or enhancing the flavor and/or aroma of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, perfumes, colognes and perfumed articles such as solid or liquid anionic, cationic, nonionic or zwitterionic detergents or fabric softeners or fabric softener articles using as the essential ingredient at least one of the methyl substituted norbornane carboxaldehydes of our invention.
摘要翻译：描述了具有以下通用结构的甲基取代的降冰片烷甲醛：其中虚线是碳 - 碳单键或碳 - 碳双键，R1R2和R3各自表示甲基或氢，条件是（ i）当R3为甲基时，R 1为氢，（ii）当R 3为氢时，R 1为甲基。还描述了用于增强或增强消耗材料的风味和/或香气的方法和组合物，包括食品，口香糖，药用产品，牙膏，咀嚼烟草，香水，古龙水和香料制品，例如固体或液体阴离子，阳离子，非离子或非离子的使用本发明的至少一种甲基取代的降冰片烷甲醛作为必需成分的两性离子洗涤剂或织物柔软剂或织物柔软剂制品。

10. 发明授权

US4346243A Methyl substituted norbornane carboxaldehyde dimethyl acetals 失效
标题翻译：甲基取代的降冰片烷甲醛二甲基缩醛
公开(公告)号：US4346243A
公开(公告)日：1982-08-24
申请号：US284108
申请日：1981-07-16
申请人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
发明人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
IPC分类号： A24B15/34 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , C07C43/162
CPC分类号： C11D3/50 , A24B15/345 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Described are methyl substituted norbornane derivatives having the generic structure: ##STR1## wherein R represents the nitrile moiety having the structure:--C.tbd.N]or the dimethoxymethyl moiety having the structure: ##STR2## and wherein one of R.sub.1, or R.sub.2 is methyl and the other of R.sub.1 or R.sub.2 is hydrogen.Also described are processes and compositions for augmenting or enhancing the flavor and/or aroma of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, perfumes, colognes and perfumed articles such as solid or liquid anionic, cationic, nonionic or zwitterionic detergents or fabric softeners or fabric softener articles using as the essential ingredient at least one of methyl substituted norbornane derivatives of our invention.
摘要翻译：描述了具有以下通用结构的甲基取代的降冰片烷衍生物：其中R表示具有以下结构的腈部分：-C 3 N N]或具有以下结构的二甲氧基甲基部分：其中R 1或R 2中的一个为甲基 R1或R2中的另一个为氢。还描述了用于增强或增强消耗材料的风味和/或香气的方法和组合物，包括食品，口香糖，药用产品，牙膏，咀嚼烟草，香水，古龙水和香料制品，例如固体或液体阴离子，阳离子，非离子或非离子的使用本发明的甲基取代的降冰片烷衍生物中的至少一种作为必需成分的两性离子洗涤剂或织物柔软剂或织物柔软剂制品。

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