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1. 发明授权

US4390464A Methyl substituted norbornane derivatives, organoleptic uses thereof and process for preparing same 失效
标题翻译：甲基取代的降冰片烷衍生物，其感官用途及其制备方法
公开(公告)号：US4390464A
公开(公告)日：1983-06-28
申请号：US366091
申请日：1982-04-06
申请人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
发明人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
IPC分类号： C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , A61K7/46
CPC分类号： C11D3/50 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Described are methyl substituted norbornane derivatives having the generic structure: ##STR1## wherein R represents the nitrile moiety having the structure: ##STR2## or the dimethoxymethyl moiety having the structure: ##STR3## and wherein one of R.sub.1, or R.sub.2 is methyl and the other of R.sub.1 or R.sub.2 is hydrogen.Also described are processes and compositions for augmenting or enhancing the flavor and/or aroma of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, perfumes, colognes and perfumed articles such as solid or liquid anionic, cationic, nonionic or zwitterionic detergents or fabric softeners or fabric softener articles using as the essential ingredient at least one of methyl substituted norbornane derivatives of our invention.
摘要翻译：描述了具有以下通用结构的甲基取代的降冰片烷衍生物：其中R表示具有以下结构的腈部分：[CN]或具有以下结构的二甲氧基甲基部分：其中R 1或R 2中的一个为甲基， R1或R2中的另一个是氢。还描述了用于增强或增强消耗材料的风味和/或香气的方法和组合物，包括食品，口香糖，药用产品，牙膏，咀嚼烟草，香水，古龙水和香料制品，例如固体或液体阴离子，阳离子，非离子或非离子的使用本发明的甲基取代的降冰片烷衍生物中的至少一种作为必需成分的两性离子洗涤剂或织物柔软剂或织物柔软剂制品。

2. 发明授权

US4388207A Process of augmenting the aroma of detergents using methyl substituted norbornane carboxaldehyde dimethyl acetals or norbornene carbonitriles 失效
标题翻译：使用甲基取代的降冰片烷甲醛二甲基缩醛或降冰片烯碳腈增加洗涤剂香气的方法
公开(公告)号：US4388207A
公开(公告)日：1983-06-14
申请号：US366081
申请日：1982-04-06
申请人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
发明人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
IPC分类号： A24B15/34 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , C11D9/44
CPC分类号： C11D3/50 , A24B15/345 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Described are methyl substituted norbornane derivatives having the generic structure: ##STR1## wherein R represents the nitrile moiety having the structure:[ C.tbd.N]or the dimethoxymethyl moiety having the structure: ##STR2## and wherein one of R.sub.1, or R.sub.2 is methyl and the other of R.sub.1 or R.sub.2 is hydrogen.Also described are processes and compositions for augmenting or enhancing the flavor and/or aroma of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, perfumes, colognes and perfumed articles such as solid or liquid anionic, cationic, nonionic or zwitterionic detergents or fabric softeners or fabric softener articles using as the essential ingredient at least one of methyl substituted norbornane derivatives of our invention.
摘要翻译：描述了具有以下通用结构的甲基取代的降冰片烷衍生物：其中R表示具有以下结构的腈部分：[C 3 N 3]或具有以下结构的二甲氧基甲基部分：其中R 1或R 2中的一个为甲基 R1或R2中的另一个为氢。还描述了用于增强或增强消耗材料的风味和/或香气的方法和组合物，包括食品，口香糖，药用产品，牙膏，咀嚼烟草，香水，古龙水和香料制品，例如固体或液体阴离子，阳离子，非离子或非离子的使用本发明的甲基取代的降冰片烷衍生物中的至少一种作为必需成分的两性离子洗涤剂或织物柔软剂或织物柔软剂制品。

3. 发明授权

US4386064A Flavoring with carbomethoxy methyl norbornanes 失效
标题翻译：用甲酯基甲基降冰片烷调味
公开(公告)号：US4386064A
公开(公告)日：1983-05-31
申请号：US380422
申请日：1982-05-20
申请人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
发明人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
IPC分类号： A24B15/34 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , A23L1/235
CPC分类号： C11D3/50 , A24B15/345 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Described are compounds defined according to the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; and one of R.sub.1 and R.sub.2 is methyl and the other of R.sub.1 and R.sub.2 is hydrogen. In addition, organoleptic uses of such compounds are disclosed for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, chewing tobaccos, medicinal products, toothpastes, perfumes, perfumed articles (such as liquid or solid, anionic, cationic, nonionic or zwitterionic detergents), fabric softeners and dryer-added fabric softener articles.
摘要翻译：描述了根据通用结构定义的化合物：其中虚线表示碳 - 碳单键或碳 - 碳双键; R1和R2之一是甲基，R1和R2中的另一个是氢。此外，公开了这种化合物的感官用途，用于增强或增强消费材料的香气或味道，包括食品，口香糖，咀嚼烟草，药用产品，牙膏，香料，加香制品（如液体或固体，阴离子，阳离子，非离子或两性离子洗涤剂），织物柔软剂和干燥剂添加的织物柔软剂制品。

4. 发明授权

US4335152A Methyl substituted norbornane carboxaldehydes, organoleptic uses thereof and process for preparing same 失效
标题翻译：甲基取代的降冰片烷甲醛，其感官用途及其制备方法
公开(公告)号：US4335152A
公开(公告)日：1982-06-15
申请号：US220646
申请日：1980-12-29
申请人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
发明人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
IPC分类号： C07C45/69 , C07C47/347 , C11B9/00 , A23L2/26
CPC分类号： C11B9/0046 , C07C45/69 , C07C47/347
摘要： Described are methyl-substituted norbornane carboxaldehyde having the generic structure: ##STR1## wherein the dashed line is a carbon-carbon single bond, or a carbon-carbon double bond, and R.sub.1 R.sub.2 and R.sub.3 each represent methyl or hydrogen with the proviso that (i) R.sub.1 is hydrogen when R.sub.3 is methyl and (ii) R.sub.1 is methyl when R.sub.3 is hydrogen.Also described are processes and compositions for augmenting or enhancing the flavor and/or aroma of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, perfumes, colognes and perfumed articles such as solid or liquid anionic, cationic, nonionic or zwitterionic detergents or fabric softeners or fabric softener articles using as the essential ingredient at least one of the methyl substituted norbornane carboxaldehydes of our invention.
摘要翻译：描述了具有以下通用结构的甲基取代的降冰片烷甲醛：其中虚线是碳 - 碳单键或碳 - 碳双键，R1R2和R3各自表示甲基或氢，条件是（ i）当R3为甲基时，R 1为氢，（ii）当R 3为氢时，R 1为甲基。还描述了用于增强或增强消耗材料的风味和/或香气的方法和组合物，包括食品，口香糖，药用产品，牙膏，咀嚼烟草，香水，古龙水和香料制品，例如固体或液体阴离子，阳离子，非离子或非离子的使用本发明的至少一种甲基取代的降冰片烷甲醛作为必需成分的两性离子洗涤剂或织物柔软剂或织物柔软剂制品。

5. 发明授权

US4374054A Use in perfumery of carboalkoxy alkyl norbornanes 失效
标题翻译：用于香料中的烷氧基烷基降冰片烷烃
公开(公告)号：US4374054A
公开(公告)日：1983-02-15
申请号：US303163
申请日：1981-09-17
申请人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
发明人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
IPC分类号： A24B15/34 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , A61K7/46
CPC分类号： C11D3/50 , A24B15/345 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Use in perfumery are compounds both separately and in admixture having the generic structure: ##STR1## wherein the dashed line is either a carbon-carbon single bond or a carbon-carbon double bond and each of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.6 and R.sub.7 represents hydrogen or methyl with the proviso that one of R.sub.1, R.sub.2, R.sub.6 and R.sub.7 is methyl and each of the other of R.sub.1, Rhd 2, R.sub.6 and R.sub.7 is hydrogen and R.sub.3 and R.sub.4 are not both methyl; wherein R.sub.5 represents C.sub.1 -C.sub.4 alkyl are disclosed.
摘要翻译：在香料中使用的化合物分别是具有通用结构的化合物：其中虚线是碳 - 碳单键或碳 - 碳双键，R1，R2，R3，R4，R6和 R 7表示氢或甲基，条件是R 1，R 2，R 6和R 7中的一个为甲基，R 1，R 2d，R 6和R 7中的每一个为氢，且R 3和R 4不为甲基; 其中R5代表C1-C4烷基。

6. 发明授权

US4350823A Carbomethoxy methyl norbornanes 失效
标题翻译：甲氧基甲基降冰片烷
公开(公告)号：US4350823A
公开(公告)日：1982-09-21
申请号：US284107
申请日：1981-07-16
申请人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
发明人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
IPC分类号： A24B15/34 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , C07C69/753
CPC分类号： C11D3/50 , A24B15/345 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Described are compounds defined according to the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; and one of R.sub.1 and R.sub.2 is methyl and the other of R.sub.1 and R.sub.2 is hydrogen. In addition, organoleptic uses of such compounds are disclosed for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, chewing tobaccos, medicinal products, toothpastes, perfumes, perfumed articles (such as liquid or solid, anionic, cationic, nonionic or zwitterionic detergents), fabric softeners and dryer-added fabric softener articles.
摘要翻译：描述了根据通用结构定义的化合物：其中虚线表示碳 - 碳单键或碳 - 碳双键; R1和R2之一是甲基，R1和R2中的另一个是氢。此外，公开了这种化合物的感官用途，用于增强或增强消费材料的香气或味道，包括食品，口香糖，咀嚼烟草，药用产品，牙膏，香料，加香制品（如液体或固体，阴离子，阳离子，非离子或两性离子洗涤剂），织物柔软剂和干燥剂添加的织物柔软剂制品。

7. 发明授权

US4347858A Use of carboalkoxy alkyl norbornanes for augmenting or enhancing the aroma or taste of a smoking tobacco composition or at least a portion of a smoking tobacco article 失效
标题翻译：用于增加或增强吸烟烟草组合物或吸烟烟草制品的至少一部分的香烟或味道的使用烷氧基烷基降冰片烷
公开(公告)号：US4347858A
公开(公告)日：1982-09-07
申请号：US303032
申请日：1981-09-17
申请人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
发明人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
IPC分类号： A24B15/34 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , A24B3/10 , A24B15/30
CPC分类号： C11D3/50 , A24B15/345 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Described is a process for augmenting or enhancing the aroma or taste of a smoking tobacco composition or at least a portion of a smoking tobacco article comprising the step of intimately admixing with a smoking tobacco composition or at least a portion of a smoking tobacco article, an aroma or taste augmenting or enhancing quantity of at least one compound defined according to the generic structure: ##STR1## wherein the dashed line represents a carbon-carbon single bond or a carbon-carbon double bond; R.sub.1 ', R.sub.2 ', R.sub.3 ', R.sub.4 ', R.sub.6 ' and R.sub.7 ' are each selected from the group consisting of hydrogen and methyl and R.sub.5 ' is C.sub.1 -C.sub.4 alkyl with the provisos that;1. one of R.sub.1 ', R.sub.2 ', R.sub.6 ' and R.sub.7 ' is methyl and the other of R.sub.1 ', R.sub.2 ', R.sub.6 ' and R.sub.7 ' represents hydrogen;2. R.sub.3 ' and R.sub.4 ' are not both methyl;3. when the dashed line is a carbon-carbon double bond, R.sub.1 ', R.sub.3 ' and R.sub.4 ' are not all hydrogen when R.sub.2 ' is methyl.
摘要翻译：描述了用于增强或增强吸烟烟草组合物或吸烟烟草制品的至少一部分的香味或味道的方法，其包括与吸烟烟草组合物或吸烟烟草制品的至少一部分密切混合的步骤，根据通用结构定义的至少一种化合物的芳香或味道增加或增加量：其中虚线表示碳 - 碳单键或碳 - 碳双键; R 1'，R 2'，R 3'，R 4'，R 6'和R 7'各自选自氢和甲基，R 5'为C 1 -C 4烷基，条件是： R1'，R2'，R6'和R7'之一是甲基，R1'，R2'，R6'和R7'中的另一个表示氢; R3'和R4'都不是甲基; 3.当虚线为碳 - 碳双键时，当R2'为甲基时，R1'，R3'和R4'不全为氢。

8. 发明授权

US4357253A Process of enhancing or augmenting the aroma of detergents using norbornyl esters 失效
标题翻译：使用降冰片烯酯增强或增加洗涤剂香气的方法
公开(公告)号：US4357253A
公开(公告)日：1982-11-02
申请号：US303161
申请日：1981-09-17
申请人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
发明人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
IPC分类号： C07C45/62 , C07C61/13 , C11B9/00 , C11D3/50
CPC分类号： C11D3/50 , C07C45/62 , C07C61/13 , C11B9/0046
摘要： Described are compounds both separately and in admixture having the generic structure: ##STR1## wherein the dashed line is either a carbon-carbon single bond or a carbon-carbon double bond and each of R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.6 and R.sub.7 represents hydrogen or methyl with the proviso that one of R.sub.1, R.sub.2, R.sub.6 and R.sub.7 is methyl and each of the other of R.sub.1, R.sub.2, R.sub.6 and R.sub.7 is hydrogen and R.sub.3 and R.sub.4 are not both methyl; wherein R.sub.5 represents C.sub.1 -C.sub.4 alkyl are disclosed. In addition organoleptic uses of such compounds are disclosed for augmenting or enhancing the aroma or taste of consumable materials including foodstuffs, chewing gums, chewing tobaccos, medicinal products, toothpastes, perfumes, perfumed articles (such as liquid or solid anionic, cationic, nonionic or zwitterionic detergents) fabric softeners, dryer-added fabric softener articles and smoking tobaccos. Also disclosed is a process for preparing such compounds according to one of the reaction schemes: ##STR2## wherein R' represents C.sub.1 -C.sub.3 alkyl; m+n equals 3 with the proviso that m is one or two and n is one or two; and wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are defined as above; or ##STR3## wherein R.sub.1 -R.sub.7 are defined as above.
摘要翻译：描述的是具有通用结构的单独和混合的化合物：其中虚线是碳 - 碳单键或碳 - 碳双键，R1，R2，R3，R4，R6和R7各自表示氢或甲基，条件是R 1，R 2，R 6和R 7中的一个为甲基，R 1，R 2，R 6和R 7中的每一个为氢，且R 3和R 4不为甲基; 其中R5代表C1-C4烷基。此外，公开了这种化合物的感官用途，用于增强或增强消费材料的香气或味道，包括食品，口香糖，咀嚼烟草，医药产品，牙膏，香料，香料制品（如液体或固体阴离子，阳离子，非离子或非离子的两性离子洗涤剂）织物柔软剂，干燥剂添加织物柔软剂制品和吸烟烟草。还公开了根据以下反应方案之一制备这种化合物的方法：其中R'表示C 1 -C 3烷基; m + n等于3，条件是m为1或2，n为1或2; 并且其中R 1，R 2，R 3，R 4和R 5如上定义; 或 dbb HR2COOR5 R3HR7R4 + dbb R1R4R3COOR5R6HH + RE其中R1-R7如上定义。

9. 发明授权

US4357246A Carboalkoxy alkyl norbornanes, organoleptic uses thereof and process for preparing same 失效
标题翻译：羧甲烷基烷基降冰片烷，其感官用途及其制备方法
公开(公告)号：US4357246A
公开(公告)日：1982-11-02
申请号：US303162
申请日：1981-09-17
申请人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
发明人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
IPC分类号： A24B15/34 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , D06M13/18
CPC分类号： C11D3/50 , A24B15/345 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Described is a process for augmenting or enhancing the aroma or taste of a foodstuff or chewing gum comprising the step of adding to a foodstuff or chewing gum an aroma augmenting or enhancing quantity of a product comprising a major proportion of compounds defined according to the structure: ##STR1##
摘要翻译：描述了一种用于增强或增强食品或口香糖的香味或味道的方法，其包括向食品或口香糖中加入香味增加或增加量的包含主要比例的根据以下结构定义的化合物的产品的步骤：

10. 发明授权

US4346243A Methyl substituted norbornane carboxaldehyde dimethyl acetals 失效
标题翻译：甲基取代的降冰片烷甲醛二甲基缩醛
公开(公告)号：US4346243A
公开(公告)日：1982-08-24
申请号：US284108
申请日：1981-07-16
申请人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
发明人： Philip T. Klemarczyk , James M. Sanders , Manfred H. Vock , Joaquin F. Vinals , Frederick L. Schmitt , Edward J. Granda
IPC分类号： A24B15/34 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/00 , C11D3/50 , C07C43/162
CPC分类号： C11D3/50 , A24B15/345 , C07C45/62 , C07C45/69 , C07C47/347 , C07C47/445 , C07C61/13 , C11B9/0046
摘要： Described are methyl substituted norbornane derivatives having the generic structure: ##STR1## wherein R represents the nitrile moiety having the structure:--C.tbd.N]or the dimethoxymethyl moiety having the structure: ##STR2## and wherein one of R.sub.1, or R.sub.2 is methyl and the other of R.sub.1 or R.sub.2 is hydrogen.Also described are processes and compositions for augmenting or enhancing the flavor and/or aroma of consumable materials including foodstuffs, chewing gums, medicinal products, toothpastes, chewing tobaccos, perfumes, colognes and perfumed articles such as solid or liquid anionic, cationic, nonionic or zwitterionic detergents or fabric softeners or fabric softener articles using as the essential ingredient at least one of methyl substituted norbornane derivatives of our invention.
摘要翻译：描述了具有以下通用结构的甲基取代的降冰片烷衍生物：其中R表示具有以下结构的腈部分：-C 3 N N]或具有以下结构的二甲氧基甲基部分：其中R 1或R 2中的一个为甲基 R1或R2中的另一个为氢。还描述了用于增强或增强消耗材料的风味和/或香气的方法和组合物，包括食品，口香糖，药用产品，牙膏，咀嚼烟草，香水，古龙水和香料制品，例如固体或液体阴离子，阳离子，非离子或非离子的使用本发明的甲基取代的降冰片烷衍生物中的至少一种作为必需成分的两性离子洗涤剂或织物柔软剂或织物柔软剂制品。

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