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1. 发明授权

US4455415A Polymeric tertiary and secondary amines with a silica-type backbone, processes for their preparation, and use 失效
标题翻译：具有二氧化硅型主链的聚合叔胺和仲胺，其制备方法和用途
公开(公告)号：US4455415A
公开(公告)日：1984-06-19
申请号：US376882
申请日：1982-05-10
申请人： Peter Panster , Peter Kleinschmit , Wolfgang Buder
发明人： Peter Panster , Peter Kleinschmit , Wolfgang Buder
IPC分类号： B01J41/12 , B01F17/54 , B01J20/26 , B01J31/00 , C07F7/18 , C08G77/00 , C08G77/26 , C08G77/28 , C08G77/48 , C08G77/54 , C08G77/58 , C08G77/62
CPC分类号： C08G77/62 , C07F7/1836 , C08G77/26 , C08G77/54
摘要： Polymeric tertiary and secondary amines as described with a silica-type backbone, comprising units of the formula: ##STR1## in which R.sup.1 and R.sup.2 represent a group ##STR2## R.sup.4 is alkylene and the free valencies of the oxygen atoms are saturated by silicon atoms of further groups (2), if appropriate with incorporation of crosslinking agents, R.sup.3 has the same meaning as R.sup.1 and R.sup.2, or it represents hydrogen, alkyl, cycloalkyl or benzyl. Also disclosed are processes for preparing the polymeric tertiary and secondary amines and the use of these materials for removing acids from liquids and gases.
摘要翻译：（2）R4是亚烷基和氧的自由价，其中R 1和R 2代表一个基团，原子被另外的基团（2）的硅原子饱和，如果适当地加入交联剂，则R3具有与R 1和R 2相同的含义，或者它代表氢，烷基，环烷基或苄基。还公开了制备聚合叔胺和仲胺的方法以及这些材料用于从液体和气体中除去酸的用途。

2. 发明授权

US4287094A Monomeric, polymeric and carrier-fixed rhodium complex compounds, process for their production and their use as catalysts 失效
标题翻译：单体，聚合物和载体固定的铑络合物，其制备方法及其用作催化剂
公开(公告)号：US4287094A
公开(公告)日：1981-09-01
申请号：US63291
申请日：1979-08-02
申请人： Peter Panster , Wolfgang Buder , Peter Kleinschmit
发明人： Peter Panster , Wolfgang Buder , Peter Kleinschmit
IPC分类号： C07C45/50 , B01J31/00 , B01J31/16 , B01J31/20 , B01J31/22 , C07B31/00 , C07B35/02 , C07B61/00 , C07C45/00 , C07C67/00 , C07F15/00 , C08G83/00 , B01J31/12
CPC分类号： C07F15/008 , B01J31/1675 , B01J31/20 , B01J31/226 , B01J2231/321 , B01J2531/822
摘要： The invention relates to coordination compounds of rhodium with silicon-substitued dialkyl or diaryl sulfide groups as ligands in monomeric, polymeric or carrier-fixed forms. The substance can be used as catalysts.
摘要翻译：本发明涉及铑与硅取代的二烷基或二芳基硫醚基团作为配体的单体，聚合或载体固定形式的配位化合物。该物质可用作催化剂。

3. 发明授权

US4362885A Process for the manufacture of (iodoorganyl)alkoxysilanes 失效
标题翻译：（碘代有机基）烷氧基硅烷的制备方法
公开(公告)号：US4362885A
公开(公告)日：1982-12-07
申请号：US330355
申请日：1981-12-14
申请人： Peter Panster , Alfons Karl , Wolfgang Buder , Peter Kleinschmit
发明人： Peter Panster , Alfons Karl , Wolfgang Buder , Peter Kleinschmit
IPC分类号： C07F7/18 , C07F7/08
CPC分类号： C07F7/1888
摘要： The subject of the invention is a process for the manufacture of (iodoorganyl)alkoxysilanes of the general formula: ##STR1## in which R.sup.1 is an alkylene group, R.sup.2 is an alkoxy group and R.sup.3 and R.sup.4 an alkoxy group and/or an alkyl or aryl group, whereby the chlorine or bromine compound corresponding to that of formula (1) is caused to react with stoichiometric to double molar quantities of an inorganic iodine donor in the presence of 0.01-5 mol % of an organic substituted onium salt of nitrogen, phosphorus, arsenic or antimony or an organic substituted sulfonium salt or a crown ether as catalyst, in certain solubilizing agents.
摘要翻译：本发明的主题是制备通式如下的（碘代有机基）烷氧基硅烷的方法：其中R1是亚烷基，R2是烷氧基，R3和R4是烷氧基和/或烷基或芳基，其中使与对应于式（1）的氯或溴化合物在0.01-5mol％的有机取代鎓盐的存在下与化学计量比与双摩尔量的无机碘供体反应的氮，磷，砷或锑或有机取代的锍盐或冠醚作为催化剂，在某些增溶剂中。

4. 发明授权

US4584395A Method for preparation of 3-chloropropyl-trichlorosilane 失效
标题翻译： 3-氯丙基三氯硅烷的制备方法
公开(公告)号：US4584395A
公开(公告)日：1986-04-22
申请号：US699696
申请日：1985-02-08
申请人： Peter Panster , Rudolf Michel , Wolfgang Buder , Peter Kleinschmit
发明人： Peter Panster , Rudolf Michel , Wolfgang Buder , Peter Kleinschmit
IPC分类号： C07F7/12 , B01J31/00 , C07B61/00 , C07F7/14 , C07F7/08
CPC分类号： C07F7/14
摘要： A method for the preparation of 3-chloropropyltrichlorosilane is carried out by conversion of trichlorosilane with allylchloride in the presence of a platinum containing polymeric organosiloxane-ammonium compound containing units represented by the structural formula: ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 represent a group of the formula:R.sup.5 --SiO.sub.3/2 (2)wherein R.sup.5 denotes an alkylene group and the free valences of the oxygen atoms are saturated by silicon atoms of further groups of the formula (2), optionally with incorporation of crosslinking agents, R.sup.4 has the same meaning as R.sup.1, R.sup.2 and R.sup.3 or hydrogen, alkyl, cycloalkyl or benzyl, Y.sup.x- represents PtX.sub.4.sup.2- or PtX.sub.6.sup.2- (X is Cl or Br) and can also be an inorganic 1 to 3 functional anion of a protonic acid which yields stable salts with amine bases or the hydroxy group, and x is a number from 1 to 3.
摘要翻译：制备3-氯丙基三氯硅烷的方法是通过在含有由下列结构式表示的含有单元的含铂聚合物有机硅氧烷 - 铵化合物存在下，将三氯硅烷与烯丙基氯反应进行的：其中R1，R2和R3 代表式为R5-SiO3 / 2（2）的基团，其中R5表示亚烷基并且氧原子的游离价被另外的式（2）的基团的硅原子饱和，任选地加入交联剂，R4与R1，R2和R3或氢，烷基，环烷基或苄基具有相同的含义，Yx-表示PtX42-或PtX62-（X是Cl或Br），也可以是质子的无机1至3官能阴离子其与胺碱或羟基产生稳定的盐，x为1至3的数。

5. 发明授权

US4623740A N,N'- and N,N',N'-substituted silylureas and process for their production 失效
标题翻译： N，N'-和N，N'，N'-取代的甲硅烷基脲及其制备方法
公开(公告)号：US4623740A
公开(公告)日：1986-11-18
申请号：US750272
申请日：1985-07-01
申请人： Ulrich Deschler , Wolfgang Buder , Peter Kleinschmit , Rudolf Michel
发明人： Ulrich Deschler , Wolfgang Buder , Peter Kleinschmit , Rudolf Michel
IPC分类号： C07F7/18 , C07F7/10
CPC分类号： C07F7/182
摘要： The invention is directed to N,N' and N,N',N'-substituted silylureas and a process for their production in which in a single step process there are reacted a halogenoalkylsilane or a halogenbenzylsilane with a primary or secondary amine and an alkali cyanate in equimolar amounts.
摘要翻译：本发明涉及N，N'和N，N'，N'-取代的甲硅烷基脲及其制备方法，其中在单步骤中使卤代烷基硅烷或卤代苄基硅烷与伯胺或仲胺和碱反应氰酸酯等摩尔量。

6. 发明授权

US4337205A Nitrogen containing alkoxysilane and process for its production 失效
标题翻译：含氮烷氧基硅烷及其生产方法
公开(公告)号：US4337205A
公开(公告)日：1982-06-29
申请号：US182313
申请日：1980-08-28
申请人： Wolfgang Buder , Siegfried Wolff , Peter Kleinschmit
发明人： Wolfgang Buder , Siegfried Wolff , Peter Kleinschmit
IPC分类号： C07F7/18 , C07C117/04 , C07C118/04
CPC分类号： C07F7/182
摘要： There are prepared nitrogen containing alkoxysilanes of the formula (RO).sub.3-n (CH.sub.3).sub.n Si(CH.sub.2).sub.m NHCON.sub.3 in which R is an alkyl group having 1 to 3 carbon atoms, n is 0, 1 or 2 and m is 1, 2 or 3 by a process comprising dissolving in an inert solvent an isocyanate group containing silane of the formula (RO).sub.3-n (CH.sub.3).sub.n Si(CH.sub.2).sub.m N.dbd.C.dbd.O in which R, n and m are as defined above and reacting the silane with a water free hydrogen nitride or with hydrogen halide and an alkali metal-alkaline earth metal-, or ammonium azide at a temperature between 0.degree. C. and the boiling point of the inert solvent. The compounds are useful in making phosphinimines.
摘要翻译：制备式（RO）3-n（CH3）nSi（CH2）mNHCON3的含氮烷氧基硅烷，其中R是具有1至3个碳原子的烷基，n是0,1或2，m是1,2 或通过包括在惰性溶剂中溶解含有式（RO）3-n（CH 3）n Si（CH 2）m N = C = O的硅烷的异氰酸酯基团的方法，其中R，n和m如上所定义，并使该硅烷与无水氮化氢或与卤化氢和碱金属 - 碱土金属或叠氮化铵在0℃至惰性溶剂的沸点之间的温度下进行。该化合物可用于制备次膦酰亚胺。

7. 发明授权

US4390712A Aqueous solution of cationic organosilicon compounds and process for the production of the solutions 失效
标题翻译：阳离子有机硅化合物的水溶液及其制备方法
公开(公告)号：US4390712A
公开(公告)日：1983-06-28
申请号：US298251
申请日：1981-08-31
申请人： Alfons Karl , Wolfgang Buder , Peter Kleinschmit
发明人： Alfons Karl , Wolfgang Buder , Peter Kleinschmit
IPC分类号： B03D1/01 , C07F7/18 , C07F7/10
CPC分类号： C07F7/1892 , B03D1/0046 , B03D1/01
摘要： There are prepared aqueous solutions of cationic organosilicon compounds which are produced by reacting an alkoxysilylalkyl halide of the formula (RO).sub.3-n R.sub.n.sup.1 --Si--R.sup.2 --X (I) where R is C.sub.1 to C.sub.5 alkyl, methoxy, ethoxy, phenyl, or C.sub.5 to C.sub.8 cycloalkyl; R.sup.1 is C.sub.1 to C.sub.5 alkyl, phenyl, tolyl, benzyl, or C.sub.5 to C.sub.8 cycloalkyl; R.sup.2 is a divalent ethylenic double bond free hydrocarbon group having 3 to 8 carbon atoms, n is zero, 1 or 2 and X is chlorine, bromine, or iodine with a tertiary amine of the formula R.sup.3 NR.sup.4 R.sup.5 (II) where R.sup.3, R.sup.4, and R.sup.5 are the same or different and each is an alkyl group or benzyl in which the number of carbon atoms of the alkyl group or the alkyl groups together is up to 30 or R.sup.4 and .sup.5 together with the nitrogen atom, as well as in a given case a further hetero atom selected from the group consisting of oxygen, nitrogen, and sulfur is a univalent five to eight membered heterocyclic ring having three to seven --CH.sub.2 -- groups in the heterocyclic ring, or R.sup.5 is a C.sub.3 to C.sub.12 cycloalkyl group in aqueous medium at a temperature from room temperature (e.g. about 20.degree. C.) to 300.degree. C. at a mole ratio of (I) to (II) between 1:0.8 to 1:1,2 and in a given case under pressure.
摘要翻译：制备阳离子有机硅化合物的水溶液，其通过使式（RO）3-nRn1-Si-R2-X（I）的烷氧基甲硅烷基烷基卤化物反应制备，其中R是C1至C5烷基，甲氧基，乙氧基，苯基或 C5至C8环烷基; R 1是C 1至C 5烷基，苯基，甲苯基，苄基或C 5至C 8环烷基; R2是具有3-8个碳原子的二价烯键式双键无键烃基，n为0,1或2，X为氯，溴或碘，与式R3NR4R5（Ⅱ）的叔胺反应，其中R3，R4和 R5相同或不同，并且各自为烷基或苄基，其中烷基或烷基的碳原子数一起为至多30或R4和5以及氮原子以及在给定的在另一个选自氧，氮和硫的杂原子的情况下，杂环中具有三至七个-CH 2 - 基的一价五元至八元杂环，或者R5是水性中的C3至C12环烷基介质在室温（例如约20℃）至300℃的温度下以（I）至（II）的摩尔比为1:0.8至1:1.2，在给定情况下在压力下。

8. 发明授权

US5126473A Process for the hydriding of halogen-substituted compounds 失效
标题翻译：氢化取代的化合物的方法
公开(公告)号：US5126473A
公开(公告)日：1992-06-30
申请号：US565433
申请日：1990-08-10
申请人： Hans-Juergen Klockner , Ralf Schmoll , Peter Panster , Peter Kleinschmit
发明人： Hans-Juergen Klockner , Ralf Schmoll , Peter Panster , Peter Kleinschmit
IPC分类号： C01B6/00 , C01B33/04 , C01B33/107 , C07F7/08
CPC分类号： C07F7/0801 , C01B33/043 , C01B33/107 , C01B6/00 , C07F7/0896
摘要： A process is described for the hydrided of halogen-substituted compounds of the second to fourth period of Groups III to V of the periodic system, with the exception of gallium, aluminum, carbon, or nitrogen. A finely-granulated aluminum is added to a molten salt melt that consists of 50-67 molar % AlCl.sub.3 (anhydrous) and 50 to 33 molar % of sodium chloride. Then to the stirred, or by some other means dispersed suspension, hydrogen is introduced to hydrided the finely-dispersed aluminum. Thereafter the mixture is reacted with the halogen-substituted compound and the resulting hydrided compound is renewed.
摘要翻译：描述了除了镓，铝，碳或氮之外，周期性系的第III至V族的第二至第四周期的卤素取代的化合物的氢化方法。将细粒状的铝加入由50-67摩尔％AlCl 3（无水）和50-33摩尔％氯化钠组成的熔融盐熔体中。然后通过搅拌或通过其它方式分散悬浮液，引入氢气使细分散的铝水合。然后将混合物与卤素取代的化合物反应，并且更新所得的氢化化合物。

9. 发明授权

US4704428A Silyl substituted cyclopentadiene, process for its production and synthetic resin and rubber mixtures containing it 失效
标题翻译：甲硅烷基取代的环戊二烯，其生产方法和含有它的合成树脂和橡胶混合物
公开(公告)号：US4704428A
公开(公告)日：1987-11-03
申请号：US933136
申请日：1986-11-21
申请人： Ulrich Deschler , Peter Panster , Peter Kleinschmit , Siegfried Wolff , Ewe-Hong Tan
发明人： Ulrich Deschler , Peter Panster , Peter Kleinschmit , Siegfried Wolff , Ewe-Hong Tan
IPC分类号： C08L21/00 , C07F7/18 , C08K5/00 , C08K5/5419 , C08K5/5425 , C08K9/06 , C08L1/00 , C08L7/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L101/00 , C08K3/36
CPC分类号： C07F7/1836 , C08K5/5419 , C08K9/06
摘要： The invention is directed to silylalkyl and silylaralkyl substituted cyclopentadienes which have a hydrolyzable group attached to the silicone atom, a process for their production and peroxide cross-linkable synthetic resin and rubber mixtures containing them.
摘要翻译：本发明涉及具有连接到硅氧烷原子的可水解基团的甲硅烷基烷基和甲硅烷基烷基取代的环戊二烯，其生产方法和可过氧化物可交联的合成树脂和含有它们的橡胶混合物。

10. 发明授权

US5438111A Formed, polymeric transition-metal complex catalysts with organosiloxane diphenylphosphine ligands 失效
标题翻译：形成的聚合物过渡金属络合物催化剂与有机硅氧烷二苯基膦配体
公开(公告)号：US5438111A
公开(公告)日：1995-08-01
申请号：US227529
申请日：1994-04-14
申请人： Peter Panster , Robert Gradl , Peter Kleinschmit
发明人： Peter Panster , Robert Gradl , Peter Kleinschmit
IPC分类号： C08G77/26 , B01J31/16 , B01J31/18 , B01J31/24 , B01J31/28 , C07C45/50 , C08G77/22 , C08G77/28 , C08G77/30 , C08G77/54 , C08G77/58 , C08G77/06
CPC分类号： C08G77/58 , B01J31/1608 , B01J31/1675 , B01J31/18 , B01J31/1805 , B01J31/2404 , C07C45/50 , C08G77/22 , C08G77/54 , B01J2231/20 , B01J2231/321 , B01J2231/323 , B01J2231/52 , B01J2231/645 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/827 , B01J2531/828 , B01J2531/842 , B01J2531/845 , B01J2531/847
摘要： Several method is of preparing formed spherical polymeric complexes of metals of the 8th subgroup of the periodic system with ligands of an organosiloxane copolycondensate optionally cross-linked by means of cross-linking agents containing Si, Ti, Zr and/or Al (statistical, block-shaped or mixed) with special posttreatment stages are described.
摘要翻译：几种方法是制备周期性系统的第8族的金属的形成的球形聚合物络合物与有机硅氧烷共缩聚物的配体，任选地通过含有Si，Ti，Zr和/或Al的交联剂交联（统计，嵌段形状或混合），具有特殊的后处理阶段。

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