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1. 发明授权

US5245040A Process for the preparation of nitroguanidine derivatives 失效
标题翻译：制备硝基胍衍生物的方法
公开(公告)号：US5245040A
公开(公告)日：1993-09-14
申请号：US777856
申请日：1991-10-16
申请人： Peter Maienfisch , Odd Kristiansen , Laurenz Gsell
发明人： Peter Maienfisch , Odd Kristiansen , Laurenz Gsell
IPC分类号： C07C277/00 , C07C279/32 , C07C279/36 , C07C323/44 , C07D213/36 , C07D213/40 , C07D213/61 , C07D213/89 , C07D233/64 , C07D239/26 , C07D251/08 , C07D261/08 , C07D263/32 , C07D265/06 , C07D265/30 , C07D265/32 , C07D271/04 , C07D271/06 , C07D271/08 , C07D273/00 , C07D273/04 , C07D277/20 , C07D277/32 , C07D279/06 , C07D279/12 , C07D285/00 , C07D285/18 , C07D285/34 , C07D307/52 , C07D333/20 , C07D401/06 , C07D401/14 , C07D417/06 , C07D471/04 , C07D498/04 , C07D513/04
CPC分类号： C07D213/40 , C07C279/36 , C07D213/61 , C07D213/89 , C07D251/08 , C07D277/32 , C07D401/06 , C07D401/14 , C07D417/06
摘要： A process for the preparation of 1,3-disubstituted 2-nitroguanidines of the formula I ##STR1## in which R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.2 is hydrogen, C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 cycloalkyl or a radical --CH.sub.2 B; A is an unsubstituted or mono- to tetrasubstituted aromatic or non-aromatic, monocyclic or bicyclic heterocyclic radical, which may contain one or two substituents from the group comprising C.sub.1 -C.sub.3 haloalkyl having 1 to 7 halogen atoms, cyclopropyl, halocyclopropyl having 1 to 3 halogen atoms, C.sub.2 -C.sub.3 alkenyl, C.sub.2 -C.sub.3 alkynyl, C.sub.2 -C.sub.3 haloalkenyl and C.sub.2 -C.sub.3 haloalkynyl having 1 to 4 halogen atoms, C.sub.1 -C.sub.3 haloalkoxy having 1 to 7 halogen atoms, C.sub.1 -C.sub.3 alkylthio, C.sub.1 -C.sub.3 haloalkylthio having 1 to 7 halogen atoms, allyloxy, propargyloxy, allylthio, propargylthio, haloallyloxy, haloallylthio, cyano and nitro and one to four substituents from the group comprising C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy and halogen; and B is optionally substituted phenyl or pyridyl, which comprises hydrolysing a compound of the formula II ##STR2## in which R.sub.3 is unsubstituted or substituted C.sub.1 -C.sub.10 alkyl, C.sub.3 -C.sub.6 cycloalkyl, phenyl or benzyl.The compounds of the formula I are suitable as intermediates for the preparation of pesticides.
摘要翻译：制备式I的1,3-二取代2-硝基胍的方法，其中R 1是氢或C 1 -C 4烷基，R 2是氢，C 1 -C 6烷基，C 3 -C 6环烷基或基团-CH 2 B ; A是未取代的或单取代或四取代的芳族或非芳族单环或双环杂环基团，其可以含有一个或两个取代基，该取代基包括具有1至7个卤素原子的C 1 -C 3卤代烷基，环丙基，具有1至3个卤素的卤代环丙基 C 1 -C 3烯基，C 2 -C 3炔基，C 2 -C 3卤代烯基和具有1至4个卤素原子的C 2 -C 3卤代炔基，具有1至7个卤素原子的C 1 -C 3卤代烷氧基，C 1 -C 3烷硫基，具有1至7个卤素原子的C 1 -C 3卤代烷硫基，烯丙氧基，炔丙氧基，烯丙硫基，炔丙硫基，卤代烯丙氧基，卤代烯硫基，氰基和硝基，以及一至四个取代基，包括C 1 -C 3烷基，C 1 -C 3烷氧基和卤素; 并且B是任选取代的苯基或吡啶基，其包括水解其中R 3为未取代或取代的C 1 -C 10烷基，C 3 -C 6环烷基，苯基或苄基的式II化合物（II）。式I的化合物适合作为制备农药的中间体。

2. 发明授权

US5223520A Pyridine compounds which are useful as pesticides 失效
标题翻译：可用作杀虫剂的吡啶化合物
公开(公告)号：US5223520A
公开(公告)日：1993-06-29
申请号：US858910
申请日：1992-03-27
申请人： Odd Kristiansen , Laurenz Gsell , Peter Maienfisch
发明人： Odd Kristiansen , Laurenz Gsell , Peter Maienfisch
IPC分类号： A01N43/40 , A01N43/78 , A01N47/44 , A01N51/00 , C07D213/36 , C07D213/40 , C07D213/61 , C07D213/89 , C07D277/20 , C07D277/32
CPC分类号： C07D213/40 , A01N43/40 , A01N43/78 , A01N47/44 , A01N51/00 , C07D213/61 , C07D213/89 , C07D277/32
摘要： Compounds of formula ##STR1## wherein R.sub.1 is hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.3 -C.sub.6 cycloalkyl, R.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.3 is hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.3 -C.sub.6 cycloalkyl and R.sub.4 is C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.6 cycloalkyl or --CH.sub.2 CH.sub.2 COOR.sub.7, or R.sub.3 and R.sub.4 together are --(CH.sub.2).sub.4 -- or --(CH.sub.2).sub.5 --, R.sub.5 is hydrogen, C.sub.1 -C.sub.4 alkyl, ##STR2## --CH.sub.2 OCH.sub.3, --CN, --COOR.sub.7 or ##STR3## R.sub.6 is hydrogen, chlorine, methyl or nitro, R.sub.7 and R.sub.8 are each methyl or ethyl, A is an unsubstituted or mono- to tetra-substituted, aromatic or non-aromatic, monocyclic or bicyclic, heterocyclic radical, one or two substituents being selected from the group consisting of C.sub.1 -C.sub.3 haloalkyl, cyclopropyl, halocyclopropy, C.sub.2 -C.sub.3 alkenyl, C.sub.2 -C.sub.3 alkynyl, C.sub.2 -C.sub.3 haloalkenyl, C.sub.2 -C.sub.3 haloalkynyl, C.sub.1 -C.sub.3 haloalkoxy, C.sub.1 -C.sub.3 alkylthio, C.sub.1 -C.sub.3 haloalkylthio, allyloxy, propargyloxy, allylthio, propargylthio, haloallyloxy, haloallylthio, cyano and nitro, and from one to four substituents being selected from the group consisting of C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy and halogen, and .dbd.X is .dbd.N--NO.sub.2, .dbd.CH--NO.sub.2, .dbd.N--CN or .dbd.CH--CO--CF.sub.3, in free form or in the form of acid addition salts, can be used as agrochemical active ingredients and can be prepared in a manner known per se.
摘要翻译：式（I）的化合物其中R 1是氢，C 1 -C 4烷基或C 3 -C 6环烷基，R 2是氢或C 1 -C 4烷基，R 3是氢，C 1 -C 4烷基或C 3 -C 6环烷基，R 4是C 1 -C 4烷基， C 6环烷基或-CH 2 CH 2 COOR 7，或者R 3和R 4一起是 - （CH 2）4 - 或 - （CH 2）5 - ，R 5是氢，C 1 -C 4烷基，-CH 2 OCH 3，-CN，-COOR 7或者R 6是氢，氯，甲基或硝基，R 7和R 8各自为甲基或乙基，A为未取代或单取代或四取代的芳族或非芳族单环或双环杂环基，一个或两个选自由C 1 -C 3卤代烷基，环丙基，卤代环丙基，C 2 -C 3烯基，C 2 -C 3炔基，C 2 -C 3卤代烯基，C 2 -C 3卤代炔基，C 1 -C 3卤代烷氧基，C 1 -C 3烷硫基，C 1 -C 3卤代烷硫基，烯丙氧基，炔丙氧基，烯丙硫基，炔丙基硫代，卤代烯氧基，卤代烯硫基氰基和硝基，以及一至四个选自C 1 -C 3烷基，C 1 -C 3烷氧基和卤素的取代基，X = N-NO 2 = 游离形式或以酸加成盐形式的CH-NO 2，= N-CN或= CH-CO-CF 3可用作农业化学活性成分，并且可以以本身已知的方式制备。

3. 发明授权

US5302605A Picoline oxides 失效
标题翻译：吡啶氧化物
公开(公告)号：US5302605A
公开(公告)日：1994-04-12
申请号：US758932
申请日：1991-09-11
申请人： Odd Kristiansen , Laurenz Gsell , Peter Maienfisch
发明人： Odd Kristiansen , Laurenz Gsell , Peter Maienfisch
IPC分类号： A01N43/50 , A01N43/54 , A01N51/00 , C07D213/89 , C07D401/06 , A61K31/44
CPC分类号： C07D401/06 , A01N43/50 , A01N43/54 , A01N51/00
摘要： Novel 3-picoline-N-oxides of formula I ##STR1## wherein R.sub.1 and R.sub.2 independently of each other are hydrogen or halogen, R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl, n is the number two or three, and Y is nitrogen or the methine group, can be used as pesticides. Especially insects are controlled.
摘要翻译：式I的新型3-甲基吡啶-N-氧化物其中R 1和R 2彼此独立地为氢或卤素，R 3为氢或C 1 -C 4烷基，n为二或三，Y为氮或次甲基，可用作农药。特别是昆虫受到控制。

4. 发明授权

US07655650B2 Oxadiazine derivatives 失效
标题翻译：恶二嗪衍生物
公开(公告)号：US07655650B2
公开(公告)日：2010-02-02
申请号：US11745550
申请日：2007-05-08
申请人： Peter Maienfisch , Laurenz Gsell
发明人： Peter Maienfisch , Laurenz Gsell
IPC分类号： A61K31/54 , C07D273/04
CPC分类号： C07D413/06 , A01N47/40 , A01N51/00 , C07D273/00 , C07D273/04 , C07D417/06
摘要： Compounds of the formula in which A is an unsubstituted or mono- to tetrasubstituted, aromatic or non-aromatic, monocyclic or bicyclic heterocyclic radical, where one to two of the substituents of A can be selected from the group consisting of halo-C1-C3alkyl, cyclopropyl, halocyclopropyl, C2-C3alkenyl, C2-C3alkynyl, halo-C2-C3alkenyl, halo-C2-C3alkynyl, halo-C1-C3alkoxy, C1-C3alkylthio, halo-C1-C3alkylthio, allyloxy, propargyloxy, allylthio, propargylthio, haloallyloxy, haloallylthio, cyano and nitro, and one to four of the substituents of A can be selected from the group consisting of C1-C3alkyl, C1-C3alkoxy and halogen; R is hydrogen, C1-C6alkyl, phenyl-C1-C4alkyl, C3-C6cycloalkyl, C2-C6alkenyl or C2-C6alkynyl; and X is N—NO2 or N—CN, and, if appropriate, tautomers thereof, in each case in free form or in salt form, can be used as agrochemical active ingredients and can be prepared in a manner known per se.
摘要翻译：下式的化合物，其中A是未取代或单取代，四取代的，芳族的或非芳香的单环或双环杂环基，其中一至两个A的取代基可以选自卤代-C 1 -C 3烷基环丙基，卤代环丙基，C 2 -C 3烯基，C 2 -C 3炔基，卤代-C 2 -C 3烯基，卤代-C 2 -C 3炔基，卤代-C 1 -C 3烷氧基，C 1 -C 3烷硫基，卤代C 1 -C 3烷硫基，烯丙氧基，炔丙氧基，烯丙硫基，炔丙硫基，，卤代烯硫基，氰基和硝基，A至1-4个取代基可以选自C 1 -C 3烷基，C 1 -C 3烷氧基和卤素; R是氢，C 1 -C 6烷基，苯基-C 1 -C 4烷基，C 3 -C 6环烷基，C 2 -C 6烯基或C 2 -C 6炔基; 且X为N-NO 2或N-CN，并且如果合适，其互变异构体（以每种形式为游离形式或盐形式）可用作农业化学活性成分，并且可以以本身已知的方式制备。

5. 发明申请

US20070219188A1 Oxadiazine Derivatives 失效
标题翻译：恶二嗪衍生物
公开(公告)号：US20070219188A1
公开(公告)日：2007-09-20
申请号：US11745550
申请日：2007-05-08
申请人： Peter Maienfisch , Laurenz Gsell
发明人： Peter Maienfisch , Laurenz Gsell
IPC分类号： A61K31/5395 , C07D273/04
CPC分类号： C07D413/06 , A01N47/40 , A01N51/00 , C07D273/00 , C07D273/04 , C07D417/06
摘要： Compounds of the formula in which A is an unsubstituted or mono- to tetrasubstituted, aromatic or non-aromatic, monocyclic or bicyclic heterocyclic radical, where one to two of the substituents of A can be selected from the group consisting of halo-C1-C3alkyl, cyclopropyl, halocyclopropyl, C2-C3alkenyl, C2-C3alkynyl, halo-C2-C3alkenyl, halo-C2-C3alkynyl, halo-C1-C3alkoxy, C1-C3alkylthio, halo-C1-C3alkylthio, allyloxy, propargyloxy, allylthio, propargylthio, haloallyloxy, haloallylthio, cyano and nitro, and one to four of the substituents of A can be selected from the group consisting of C1-C3alkyl, C1-C3alkoxy and halogen; R is hydrogen, C1-C6alkyl, phenyl-C1-C4alkyl, C3-C6cycloalkyl, C2-C6alkenyl or C2-C6alkynyl; and X is N—NO2 or N—CN, and, if appropriate, tautomers thereof, in each case in free form or in salt form, can be used as agrochemical active ingredients and can be prepared in a manner known per se.
摘要翻译：其中A是未取代或单 - 四取代的芳族或非芳族单环或双环杂环基的式的化合物，其中A的一个至两个取代基可以选自卤代-C C 1 -C 3烷基，环丙基，卤代环丙基，C 2 -C 3链烯基，C 2 - C 1 -C 3炔基，卤代-C 2 -C 3烯基，卤代-C 2 -C 3 - 炔基，炔基，卤代C 1 -C 3烷氧基，C 1 -C 3烷基，C 1 -C 3烷基，烷硫基，卤代-C 1 -C 3烷硫基，烯丙氧基，炔丙氧基，烯丙硫基，炔丙硫基，卤代烯丙氧基，卤代烯硫基，氰基和硝基，以及一至四个取代基的A可以选自C 1 -C 3 -C 3烷基，C 1 -C 3 - 烷基，C 1 -C 3 - 烷氧基和卤素; R是氢，C 1 -C 6烷基，苯基-C 1 -C 4烷基，C 1 -C 6烷基， C 3 -C 6环烷基，C 2 -C 6链烯基或C 2 - C 6炔基; 并且X为N-NO 2 N或N-CN，并且如果合适，其互变异构体（在每种情况下为游离形式或盐形式）均可用作农业化学活性成分，并且可以制备为本身已知的方式。

6. 发明授权

US5852012A Oxadiazine derivatives 失效
标题翻译：恶二嗪衍生物
公开(公告)号：US5852012A
公开(公告)日：1998-12-22
申请号：US464931
申请日：1995-06-05
申请人： Peter Maienfisch , Laurenz Gsell
发明人： Peter Maienfisch , Laurenz Gsell
IPC分类号： A01N43/88 , A01N43/72 , A01N43/84 , A01N47/40 , A01N47/44 , A01N51/00 , A01P7/04 , C07D20060101 , C07D273/04 , C07D413/06 , C07D417/06 , C07D471/04 , C07D487/04 , C07D498/04 , C07D513/04
CPC分类号： C07D413/06 , A01N47/40 , A01N51/00 , C07D273/00 , C07D273/04 , C07D417/06
摘要： Compounds of the formula ##STR1## in which A is an unsubstituted or mono- to tetrasubstituted, aromatic or non-aromatic, monocyclic or bicyclic heterocyclic radical, where one to two of the substituents of A can be selected from the group consisting of halo-C.sub.1 -C.sub.3 alkyl, cyclopropyl, halocyclopropyl, C.sub.2 -C.sub.3 alkenyl, C.sub.2 -C.sub.3 alkynyl, halo-C.sub.2 -C.sub.3 alkenyl, halo-C.sub.2 -C.sub.3 alkynyl, halo-C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 alkylthio, halo-C.sub.1 -C.sub.3 alkylthio, allyloxy, propargyloxy, allylthio, propargylthio, haloallyloxy, haloallylthio, cyano and nitro, and one to four of the substituents of A can be selected from the group consisting of C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy and halogen; R is hydrogen, C.sub.1 -C.sub.6 alkyl, phenyl-C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.2 -C.sub.6 alkenyl or C.sub.2 -C.sub.6 alkynyl; and X is N--NO.sub.2 or N--CN, and, if appropriate, tautomers thereof, in each case in free form or in salt form, can be used as insecticidal active ingredients and can be prepared in a manner known per se.
摘要翻译：式（I）的化合物，其中A是未取代或单取代或单取代的，芳香族或非芳族的单环或双环杂环基，其中A的一至两个取代基可以选自卤代C 1 -C 3烷基，环丙基，卤代环丙基，C 2 -C 3烯基，C 2 -C 3炔基，卤代-C 2 -C 3烯基，卤代-C 2 -C 3炔基，卤代-C 1 -C 3烷氧基，C 1 -C 3烷硫基，卤代C 1 -C 3烷硫基，烯丙氧基，炔丙氧基，烯丙硫基，炔丙硫基，卤代烯丙氧基，卤代烯硫基，氰基和硝基，A至1-4个取代基可以选自C 1 -C 3烷基，C 1 -C 3烷氧基和卤素; R是氢，C 1 -C 6烷基，苯基-C 1 -C 4烷基，C 3 -C 6环烷基，C 2 -C 6烯基或C 2 -C 6炔基; 且X为N-NO 2或N-CN，并且如果合适，其互变异构体在各种情况下以游离形式或盐形式可用作杀虫活性成分，并且可以以本身已知的方式制备。

7. 发明授权

US06627753B1 Oxadiazine derivatives 失效
标题翻译：恶二嗪衍生物
公开(公告)号：US06627753B1
公开(公告)日：2003-09-30
申请号：US09669209
申请日：2000-09-25
申请人： Peter Maienfisch , Laurenz Gsell
发明人： Peter Maienfisch , Laurenz Gsell
IPC分类号： C07D27304
CPC分类号： C07D413/06 , A01N47/40 , A01N51/00 , C07D273/00 , C07D273/04 , C07D417/06
摘要： Compounds of the formula in which A is an unsubstituted or mono- to tetrasubstituted, aromatic or non-aromatic, monocyclic or bicyclic heterocyclic radical, where one to two of the substituents of A can be selected from the group consisting of halo-C1-C3alkyl, cyclopropyl, halocyclopropyl, C2-C3alkenyl, C2-C3alkynyl, halo-C2-C3alkenyl, halo-C2-C3alkynyl, halo-C1-C3alkoxy, C1-C3alkylthio, halo-C1-C3alkylthio, allyloxy, propargyloxy, allylthio, propargylthio, haloallyloxy, haloallylthio, cyano and nitro, and one to four of the substituents of A can be selected from the group consisting of C1-C3alkyl, C1-C3alkoxy and halogen; R is hydrogen, C1-C6alkyl, phenyl-C1-C4alkyl, C3-C6cycloalkyl, C2-C6alkenyl or C2-C6alkynyl; and X is N—NO2 or N—CN, and, if appropriate, tautomers thereof, in each case in free form or in salt form, can be used as agrochemical active ingredients and can be prepared in a manner known per se.
摘要翻译：其中A是未取代或单取代或单取代的芳香族或非芳香族单环或双环杂环基的化合物，其中A的一个至两个取代基可以选自卤代-C 1 -C 3烷基，环丙基卤代环丙基，C 2 -C 3烯基，C 2 -C 3炔基，卤代-C 2 -C 3烯基，卤代-C 2 -C 3炔基，卤代-C 1 -C 3烷氧基，C 1 -C 3烷硫基，卤代C 1 -C 3烷硫基，烯丙氧基，炔丙氧基，烯丙硫基，炔丙硫基，卤代烯氧基，卤代烯硫基氰基和硝基，A至1-4个取代基可以选自C 1 -C 3烷基，C 1 -C 3烷氧基和卤素; R 2是氢，C 1 -C 6烷基，苯基-C 1 -C 4烷基，C 3 -C 6环烷基， C 2 -C 6烯基或C 2 -C 6炔基; 且X是N-NO 2或N-CN，并且如果合适，其互变异构体在各种情况下以游离形式或盐形式可用作农业化学活性成分，并且可以以本身已知的方式制备。

8. 发明授权

US6022871A Oxadiazine derivatives 有权
公开(公告)号：US6022871A
公开(公告)日：2000-02-08
申请号：US252541
申请日：1999-02-18
申请人： Peter Maienfisch , Laurenz Gsell
发明人： Peter Maienfisch , Laurenz Gsell
IPC分类号： A01N43/88 , C07D273/04 , C07D417/06
CPC分类号： A01N51/00 , A01N47/40 , C07D273/04 , C07D413/06 , C07D417/06
摘要： Compounds of the formula ##STR1## in which A is an unsubstituted or mono- to tetrasubstituted, aromatic or non-aromatic, monocyclic or bicyclic heterocyclic radical, where one to two of the substituents of A can be selected from the group consisting of halo-C.sub.1 -C.sub.3 alkyl, cyclopropyl, halocyclopropyl, C.sub.2 -C.sub.3 alkenyl, C.sub.2 -C.sub.3 alkynyl, halo-C.sub.2 -C.sub.3 alkenyl, halo-C.sub.2 -C.sub.3 alkynyl, halo-C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 alkylthio, halo-C.sub.1 -C.sub.3 alkylthio, allyloxy, propargyloxy, allylthio, propargylthio, haloallyloxy, haloallylthio, cyano and nitro, and one to four of the substituents of A can be selected from the group consisting of C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 alkoxy and halogen;R is hydrogen, C.sub.1 -C.sub.6 alkyl, phenyl-C.sub.1 -C.sub.4 alkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.2 -C.sub.6 alkenyl or C.sub.2 -C.sub.6 alkynyl; andX is N--NO.sub.2 or N--CN,and, if appropriate, tautomers thereof, in each case in free form or in salt form, can be used as agrochemical active ingredients and can be prepared in a manner known per se.

9. 发明授权

US06664248B2 2-nitromethylidene/2-cyanimino/2-nitro-imino-pyrrolidines and piperidines, intermediates, and their use as pesticides 失效
标题翻译： 2-硝基亚甲基/ 2-氰基亚氨基/ 2-硝基 - 亚氨基 - 吡咯烷酮和哌啶，中间体及其作为农药的用途
公开(公告)号：US06664248B2
公开(公告)日：2003-12-16
申请号：US10341555
申请日：2003-01-13
申请人： Peter Maienfisch , Jozef Gonda , Olivier Jacob , Laurenz Gsell
发明人： Peter Maienfisch , Jozef Gonda , Olivier Jacob , Laurenz Gsell
IPC分类号： A61K3133
CPC分类号： C07D401/06 , A01N43/40 , A01N47/38 , A01N51/00 , C07D417/06
摘要： Compounds of formula wherein A is an unsubstituted or substituted aromatic or non-aromatic, monocyclic or bicyclic heterocyclic radical wherein a ring nitrogen atom may have been replaced by a group R1 is hydrogen or C1-C3alkyl; R2 is hydrogen or C1-C3alkyl; R3 is hydrogen an unsubstituted or substituted C1-C6alkyl, C3-C6cycloalkyl, C2-C6alkenyl or C2-C6alkynyl group, or C(═O)—R5, R5 is C1-C4alkyl, C1-C4alkoxy, an unsubstituted or substituted phenyl, phenoxy or benzyloxy group, or N(R6)2, each R6, independently of the other, is hydrogen, C1-C4alkyl or unsubstituted or substituted phenyl, X is CH—NO2, N—CN or N—NO2 and n is from 1 to 3, in free form or in salt form, and, where appropriate, tautomers of those compounds and the salts thereof, can be used as agrochemical active ingredients and can be prepared in a manner known per se
摘要翻译：马来酰亚胺A的化合物是未取代或取代的芳族或非芳族单环或双环杂环基，其中环氮原子可以被基团R 1取代为氢或C 1 -C 3烷基; R 2是氢或C 1 -C 3烷基; R 3是氢未取代或取代的C 1 -C 6烷基，C 3 -C 6环烷基，C 2 -C 6烯基或C 2 -C 6炔基，或C（= O）-R 5，R 5是C 1 -C 4烷基，C 1 -C 4烷氧基，未取代或取代的苯基，苯氧基或苄氧基，或N（R 6）2，每个R 6彼此独立地为氢，C 1 -C 4烷基或未取代或取代的苯基，X为CH-NO 2，N-CN或N-NO 2，n为1至3，为游离形式或盐形式，并且在适当的情况下，这些化合物及其盐的互变异构体可用作农业化学活性成分，并且可以以本身已知的方式制备

10. 发明授权

US06506743B2 2-nitromethylidene/2-cyanimino/2-nitro-imino-pyrrolidines and piperidines, intermediates, and their use as pesticides 失效
标题翻译： 2-硝基亚甲基/ 2-氰基亚氨基/ 2-硝基 - 亚氨基 - 吡咯烷酮和哌啶，中间体及其作为农药的用途
公开(公告)号：US06506743B2
公开(公告)日：2003-01-14
申请号：US10013778
申请日：2001-12-11
申请人： Peter Maienfisch , Jozef Gonda , Olivier Jacob , Laurenz Gsell
发明人： Peter Maienfisch , Jozef Gonda , Olivier Jacob , Laurenz Gsell
IPC分类号： C07D4006
CPC分类号： C07D401/06 , A01N43/40 , A01N47/38 , A01N51/00 , C07D417/06
摘要： Compounds of formula wherein A is an unsubstituted or substituted aromatic or non-aromatic, monocyclic or bicyclic heterocyclic radical wherein a ring nitrogen atom may have been replaced by a group R1 is hydrogen or C1-C3alkyl; R2 is hydrogen or C1-C3alkyl; R3 is hydrogen, an unsubstituted or substituted C1-C3-C6alkyl, C6cycloalkyl, C2-C6alkenyl or C2-C6alkynyl group, or C(═O)—R5, R5 is C1-C4alkyl, C1-C4alkoxy, an unsubstituted or substituted phenyl, phenoxy or benzyloxy group, or N(R6)2, each R6, independently of the other, is hydrogen, C1-C4alkyl or unsubstituted or substituted phenyl, X is CH—NO2, N—CN or N—NO2 and n is from 1 to 3, in free form or in salt form, and, where appropriate, tautomers of those compounds and the salts thereof, can be used as agrochemical active ingredients and can be prepared in a manner known per se.
摘要翻译：马来酰亚胺碱A的化合物是未取代或取代的芳族或非芳族单环或双环杂环基，其中环氮原子可以被基团R 1取代为氢或C 1 -C 3烷基; R 2是氢或C 1 -C 3烷基; R 3是氢，未取代或取代的C1-C3-C6烷基，C6环烷基，C2-C6链烯基或C2-C6炔基，或C（= O）-R5，R5是C1-C4烷基，C1-C4烷氧基，未取代或取代的苯基，苯氧基或苄氧基，或N（R 6）2，每个R 6彼此独立地是氢，C 1 -C 4烷基或未取代或取代的苯基，X是CH-NO 2，N-CN或N-NO 2，并且n为1至3，形式或盐形式，并且在适当的情况下，这些化合物及其盐的互变异构体可以用作农业化学活性成分，并且可以以本身已知的方式制备。

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