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1. 发明授权

US06624236B1 Cyclosiloxane-based cross-linkable monomers, production thereof and use thereof in polymerizable materials 有权
标题翻译：环氧硅氧烷类可交联单体，其制造方法及其在可聚合材料中的应用
公开(公告)号：US06624236B1
公开(公告)日：2003-09-23
申请号：US09868450
申请日：2001-09-19
申请人： Peter Bissinger , Oswald Gasser , Rainer Guggenberger , Wolfgang Soglowek , Gunther Eckhardt
发明人： Peter Bissinger , Oswald Gasser , Rainer Guggenberger , Wolfgang Soglowek , Gunther Eckhardt
IPC分类号： C08L8304
CPC分类号： C07F7/21
摘要： The invention relates to polysiloxanes from cross-linkable monomers based on cyclosiloxanes and their use in polymerizable compositions. The invention relates in particular to polysiloxanes from sol-gel-condensable cyclosiloxane(meth)acrylates as well as resinous compositions, obtainable by hydrolytic condensation of one or more hydrolyzable and condensable cyclosiloxane(meth)acrylates.
摘要翻译：本发明涉及基于环硅氧烷的可交联单体的聚硅氧烷及其在可聚合组合物中的用途。本发明特别涉及溶胶 - 凝胶 - 可冷凝的环状硅氧烷（甲基）丙烯酸酯的聚硅氧烷以及通过一种或多种可水解和可缩合的环硅氧烷（甲基）丙烯酸酯的水解缩合获得的树脂组合物。

2. 发明授权

US06566413B1 Polymerisable materials which are based on hardenable siloxane compounds 有权
公开(公告)号：US06566413B1
公开(公告)日：2003-05-20
申请号：US09868525
申请日：2001-09-19
申请人： Wolfgang Weinmann , Joachim Zech , Oswald Gasser , Rainer Guggenberger , Gunther Eckhardt , Peter Bissinger , Wolfgang Soglowek
发明人： Wolfgang Weinmann , Joachim Zech , Oswald Gasser , Rainer Guggenberger , Gunther Eckhardt , Peter Bissinger , Wolfgang Soglowek
IPC分类号： C08F246
CPC分类号： A61K6/083 , C07F7/21 , C08L51/085
摘要： The invention relates to novel cyclic siloxane compounds of the following general formula (I): in which: n=0, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10 preferably 1, 2, 3, 4, 5; A=H or C1-C15 alk(en)yl, C3-C15 cycloalk(en)yl, C6-C12 aryl, C8-C18 alkaryl, where, in the said radicals, in each case one or more C atoms can be replaced by O, C═O, O(C═O), SiR2 and/or NR, R being an aliphatic radical with 1 to 7 C atoms, in which one or more C atoms can be replaced by O, C═O, and/or O(C═O); B=E or a linear, branched or polycyclic aliphatic- or aromatic-groups-containing hydrocarbon radical which links 2 to 10 of the cyclosiloxane radicals defined above, less B, to one another and contains 2 to 50 C atoms and additionally 0 to 30 other atoms from the group O, N, S, P, Si, Cl, F, Br, I and from which correspondingly 1 to 9, preferably 1 to 4 of the above defined cyclosiloxane radicals, less B, are pending; E=A or a polymerizable group G—Q—L, where on average up to 50% or less of the groups E correspond to representatives of A; G=C1-10 alk(en)ylene; Q=O, N—A or a di- or polyvalent linear, branched or cyclic alcohol, amine or aminoalcohol radical with 2 to 10 C atoms; L=an organic radical, containing a C═C double bond, with 2 to 10 C atoms; and with the proviso that no annelated siloxane ring systems can occur in (I), and also dental compositions which contain the compounds of formula (I) and/or compounds of formula (II): in which: T=independently of each other H or C1-C10 alk(en)yl, C3-C10 cycloalk(en)yl, C6-C12 aryl or C8-C8 alkaryl; N=a polymerizable group R1—R2—R3; b=0 to 500, where the proportion b may be at most 50% of the repeat units (b+c); c=1 to 1000; R1=C1-C10 alk(en)ylene; R2=O, N—T or a di- or polyvalent linear, branched or cyclic alcohol, amine or aminoalcohol radical with 2 to 10 C atoms; R3=an organic radical, containing a C═C double bond, with 3 to 10 C atoms; V=SiMe2T, SiEt2T, SiMePhT, SiPh2T.

3. 发明授权

US06908953B2 Polymerizable compositions based on epoxides 失效
标题翻译：基于环氧化物的可聚合组合物
公开(公告)号：US06908953B2
公开(公告)日：2005-06-21
申请号：US10389814
申请日：2003-03-18
申请人： Wolfgang Weinmann , Oswald Gasser , Rainer Guggenberger , Gunther Lechner , Wolfgang Soglowek , Joachim Zech
发明人： Wolfgang Weinmann , Oswald Gasser , Rainer Guggenberger , Gunther Lechner , Wolfgang Soglowek , Joachim Zech
IPC分类号： A61K6/087 , C07F7/08 , C07F7/21 , C08G59/20 , C08G59/22 , C08G59/24 , C08G59/30 , C08G59/32 , C08K3/00 , C08L63/00 , G03F7/038 , A61K6/093
CPC分类号： A61K6/0023 , A61K6/0017 , A61K6/087 , A61K6/09 , A61K6/093 , C07F7/0838 , C07F7/21 , C08G59/22 , C08G59/24 , C08G59/306 , C08G59/3218 , C08G59/3254 , C08L63/00 , G03F7/038 , C08L83/10 , C08L83/12
摘要： The present invention is directed to polymerizable dental compositions containing (a) 3 to 80 wt. % of cycloaliphatic epoxides; b) 0 to 80 wt. % of an epoxide or a mixture of epoxides which are different from a); c) 3 to 85 wt. % of a filler material; d) 0.01 to 25 wt. % of initiators, inhibitors and/or accelerators; e) 0 to 25 wt. % of auxiliary agents, the individual percentages of which are in relation to the total weight. The new polymerizable agents are particularly suited as dental material.
摘要翻译：本发明涉及可聚合牙科用组合物，其含有（a）3-80重量％％脂环族环氧化物; b）0至80wt。％的不同于a）的环氧化物或环氧化物的混合物; c）3-85重量％％的填料; d）0.01〜25重量％％的引发剂，抑制剂和/或促进剂; e）0-25重量％辅助剂的百分比，其各自的百分比与总重量有关。新的可聚合剂特别适用于牙科材料。

4. 发明授权

US06852822B1 Hydrolyzable silanes and polymerizable silanes with low viscosity and use thereof 有权
标题翻译：可水解硅烷和可聚合硅烷，具有低粘度和可用硅烷
公开(公告)号：US06852822B1
公开(公告)日：2005-02-08
申请号：US10031612
申请日：2000-07-12
申请人： Peter Bissigner , Oswald Gasser , Rainer Guggenberger , Wolfgang Soglowek
发明人： Peter Bissigner , Oswald Gasser , Rainer Guggenberger , Wolfgang Soglowek
IPC分类号： A61K6/027 , A61K6/00 , A61K6/02 , A61K6/04 , A61K6/083 , A61K6/093 , C07F7/18 , C08G77/20 , C08G77/48 , C09D183/04 , C09K3/10
CPC分类号： A61K6/0017 , A61K6/0023 , A61K6/083 , A61K6/093 , C07F7/1804 , C08L51/085
摘要： The invention provides processes for making low viscosity condensates, condensates per se, and processes for making polymers from these condensates. The invention also encompasses the polymer products of these processes, especially articles for dental use. The condensates per se of the invention are of hydrolyzable silanes. The condensates can contain one or more elements selected from the group consisting of B, AI, P, Sn, Pb, the transition metals, the lanthanides and the actinides. Processes of the invention for making polymers from the condensates optionally include use of compounds that can be polymerized ionically or by radical reactions in addition to the hydrolyzable silanes. Curing of the polymers is optionally performed by photochemical, thermal or by redox-induction methods.
摘要翻译：本发明提供了制备低粘度缩合物，缩合物本身以及由这些缩合物制备聚合物的方法。本发明还包括这些方法的聚合物产品，特别是用于牙科用途的制品。本发明本身的缩合物是可水解的硅烷。缩合物可以含有选自B，Al，P，Sn，Pb，过渡金属，镧系元素和锕系元素中的一种或多种元素。用于从冷凝物制备聚合物的本发明的方法任选地包括除了可水解硅烷之外还可以使用可以离子化或通过自由基反应聚合的化合物。聚合物的固化任选地通过光化学，热或氧化还原诱导方法进行。

5. 发明授权

US06245828B1 Polymerizable compositions based on epoxides 有权
标题翻译：基于环氧化物的可聚合组合物
公开(公告)号：US06245828B1
公开(公告)日：2001-06-12
申请号：US09101867
申请日：1998-09-21
申请人： Wolfgang Weinmann , Oswald Gasser , Rainer Guggenberger , Gunther Lechner , Wolfgang Soglowek , Joachim Zech
发明人： Wolfgang Weinmann , Oswald Gasser , Rainer Guggenberger , Gunther Lechner , Wolfgang Soglowek , Joachim Zech
IPC分类号： A61K6087
CPC分类号： A61K6/0023 , A61K6/0017 , A61K6/087 , A61K6/09 , A61K6/093 , C07F7/0838 , C07F7/21 , C08G59/22 , C08G59/24 , C08G59/306 , C08G59/3218 , C08G59/3254 , C08L63/00 , G03F7/038 , C08L83/10 , C08L83/12
摘要： The present invention is directed to polymerizable dental compositions containing a) 3 to 80 wt. % of cycloaliphatic epoxides; b) 0 to 80 wt. % of an epoxide or a mixture of epoxides which are different from a); c) 3 to 85 wt. % of a filer material; d) 0.01 to 25 wt. % of initiators, inhibitors and/or accelerators; e) 0 to 25 wt. % of auxiliary agents, the individual percentages of which are in relation to the total weight. The new polymerizable agents are particularly suited as dental material.
摘要翻译：本发明涉及可聚合牙科组合物，其含有a）3-80wt。％脂环族环氧化物; b）0至80wt。％的不同于a）的环氧化物或环氧化物的混合物; c）3-85重量％％的档案资料; d）0.01〜25重量％％的引发剂，抑制剂和/或促进剂; e）0-25重量％辅助剂的百分比，其各自的百分比与总重量有关。新的可聚合剂特别适用于牙科材料。

6. 发明授权

US06852775B1 Polymerizable dental compositions 有权
标题翻译：可聚合牙科组合物
公开(公告)号：US06852775B1
公开(公告)日：2005-02-08
申请号：US10018660
申请日：2000-06-21
申请人： Wolfgang Soglowek , Keith O'Connell
发明人： Wolfgang Soglowek , Keith O'Connell
IPC分类号： A61K6/083 , C08F2/44 , A61K6/10 , C08F4/40
CPC分类号： A61K6/083 , A61K6/0023 , A61K6/005 , C08L33/00
摘要： The invention relates to polymerizable dental compositions which contain (a) 10 to 98.999 wt.-% of at least one bi- or higher-functional ethylenically unsaturated monomer, (b) 0 to 88.999 wt.-% of at least one monofunctional ethylenically unsaturated monomer, (c) 0 to 5 wt.-% of an accelerator, (d) 0.001 to 5 wt.-% of a redox initiator system which can trigger the radical polymerisation and (e) 0 to 88.999 wt.-% fillers, thixotropic auxiliaries, retarders and other auxiliaries (f) 1 to 30 wt.-% of a customary plasticizer and are characterized in that the redox initiator system comprises (i) a barbituric acid derivative and/or a malonyl sulfamide and (ii) an organic peroxide, selected from the group of the mono- or multifunctional carboxylic acid peroxyesters, and the constituents (a) to (f) are present in two pastes spatially separated from each other. The dental compositions are suitable as filling material, stump build-up material, fixing cement, temporary crown and bridge material, dental material or for the preparation of inlays, onlays, facing shells, modelling materials.
摘要翻译：本发明涉及可聚合牙科组合物，其含有（a）10至98.999重量％的至少一种双官能或更高官能的烯属不饱和单体，（b）0至88.999重量％的至少一个单官能烯属不饱和单体单体，（c）0至5重量％的促进剂，（d）0.001至5重量％的可引发自由基聚合的氧化还原引发剂体系，和（e）0至88.999重量％的填料，触变助剂，缓凝剂和其它助剂（f）占常规增塑剂的1至30重量％，其特征在于氧化还原引发剂体系包含（i）巴比妥酸衍生物和/或丙二酰基磺酰胺和（ii）有机过氧化物选自单官能或多官能羧酸过氧酯的组，和（a）至（f）组分存在于彼此空间分离的两个糊料中。牙科用组合物适用于填充材料，树桩堆积材料，固定水泥，临时牙冠和桥梁材料，牙科材料或用于制备嵌体，镶嵌，面罩，造型材料。

7. 发明授权

US06936642B2 Dental materials 有权
标题翻译：牙科材料
公开(公告)号：US06936642B2
公开(公告)日：2005-08-30
申请号：US10168092
申请日：2000-12-15
申请人： Thomas Lehmann , Wolfgang Soglowek , Reinhold Hecht
发明人： Thomas Lehmann , Wolfgang Soglowek , Reinhold Hecht
IPC分类号： A61C13/003 , A61K6/09 , A61K6/08 , C08L75/04
CPC分类号： A61K6/083 , A61K6/09 , C08L75/16 , C08L33/00
摘要： The invention relates to compositions containing: (a) 14 to 55 wt.-% fillers, (b) 3 to 35 wt.-% of at least one mono- or polyethylenically unsaturated compound which is not a urethane (meth)acrylate, (c) 0.1 to 5 wt.-% of at least one initiator system which is capable of starting a radical reaction, (d) 1 to 40 wt.-% plasticizers, (e) 0 to 10 wt.-% auxiliaries such as dyes, pigments, stabilizers, solvents, rheological additives such as flow-improvers and/or retarders, and (f) 30 to 81.9 wt.-% of at least two urethane (meth)acrylates with different molecular weights, these being present in a molecular weight ratio of 1.5:1 to 50:1.
摘要翻译：本发明涉及包含：（a）14至55重量％的填料，（b）3至35重量％的至少一种不是聚氨酯（甲基）丙烯酸酯的单或多烯属不饱和化合物（ c）0.1至5重量％的至少一种能够开始自由基反应的引发剂体系，（d）1至40重量％的增塑剂，（e）0至10重量％的助剂如染料，颜料，稳定剂，溶剂，流变添加剂如流动改进剂和/或缓凝剂，和（f）30至81.9重量％的至少两种具有不同分子量的氨基甲酸酯（甲基）丙烯酸酯，它们分子重量比为1.5：1至50：1。

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