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1. 发明授权

US06908953B2 Polymerizable compositions based on epoxides 失效
标题翻译：基于环氧化物的可聚合组合物
公开(公告)号：US06908953B2
公开(公告)日：2005-06-21
申请号：US10389814
申请日：2003-03-18
申请人： Wolfgang Weinmann , Oswald Gasser , Rainer Guggenberger , Gunther Lechner , Wolfgang Soglowek , Joachim Zech
发明人： Wolfgang Weinmann , Oswald Gasser , Rainer Guggenberger , Gunther Lechner , Wolfgang Soglowek , Joachim Zech
IPC分类号： A61K6/087 , C07F7/08 , C07F7/21 , C08G59/20 , C08G59/22 , C08G59/24 , C08G59/30 , C08G59/32 , C08K3/00 , C08L63/00 , G03F7/038 , A61K6/093
CPC分类号： A61K6/0023 , A61K6/0017 , A61K6/087 , A61K6/09 , A61K6/093 , C07F7/0838 , C07F7/21 , C08G59/22 , C08G59/24 , C08G59/306 , C08G59/3218 , C08G59/3254 , C08L63/00 , G03F7/038 , C08L83/10 , C08L83/12
摘要： The present invention is directed to polymerizable dental compositions containing (a) 3 to 80 wt. % of cycloaliphatic epoxides; b) 0 to 80 wt. % of an epoxide or a mixture of epoxides which are different from a); c) 3 to 85 wt. % of a filler material; d) 0.01 to 25 wt. % of initiators, inhibitors and/or accelerators; e) 0 to 25 wt. % of auxiliary agents, the individual percentages of which are in relation to the total weight. The new polymerizable agents are particularly suited as dental material.
摘要翻译：本发明涉及可聚合牙科用组合物，其含有（a）3-80重量％％脂环族环氧化物; b）0至80wt。％的不同于a）的环氧化物或环氧化物的混合物; c）3-85重量％％的填料; d）0.01〜25重量％％的引发剂，抑制剂和/或促进剂; e）0-25重量％辅助剂的百分比，其各自的百分比与总重量有关。新的可聚合剂特别适用于牙科材料。

2. 发明授权

US06906117B2 Aziridinosilicones and the use thereof 有权
标题翻译：二氮杂环丁烷及其用途
公开(公告)号：US06906117B2
公开(公告)日：2005-06-14
申请号：US10296997
申请日：2001-05-30
申请人： Reinhold Nowak , Joachim Zech , Peter Bissinger , Erich Wanek , Gunther Eckhardt , Guenther Lechner
发明人： Reinhold Nowak , Joachim Zech , Peter Bissinger , Erich Wanek , Gunther Eckhardt , Guenther Lechner
IPC分类号： A61K6/093 , A61K6/10 , C08G77/388 , C08L83/08 , C08L83/00 , C08G77/26
CPC分类号： A61K6/093 , A61K6/0017 , A61K6/0023 , A61K6/10 , C08G77/388 , C08L83/08 , C08L83/12
摘要： Arizidinosilicones of the general formula (1), wherein R1 represents H, C1-C12 alkyl, C2-C12 alkenyl, C2-C12 alkinyl, C7-C15 alkaryl, C7-C15 aralkyl, C3-C12 cycloalkyl and these groups can be substituted with Cl or F partially, completely or in a mixed manner and/or may contain 0 to 5 heteroatoms selected from O, N, S, R2 represents a group of the selection of R1 and/or R4, and R3 represents SiRl3 or SiR12R4, and wherein R4 represents formula (2), and A represents an (n+1) radical saturated, unsaturated or aromatic, linear, branched or cyclic hydrocarbon group that may contain 0 to 5 heteroatoms selected from O, N, S and that includes 1 to 18 carbon atoms, B is selected from O, S, NR1, D is selected from C(O)O, C(O)NR1, C(O), C(O)C(O), C(O)(CH2)m(C(O), C(S)NR1, CH2, E represents a diradical saturated or unsaturated, linear, branched or cyclic hydrocarbon group that may contain 0 to 5 heteroatoms selected from O, N, S and that includes 0 to 18 carbon atoms, a is 0 or 1, f is an integer from 2 to 1000, n, m is an integer from 1 to 10, and x, y, z each represents 0 or an integer, the sum of which should range between 1 and 10000, with the proviso that, if x is larger 0, y or z is smaller or equal x, preferably smaller or equal 0.05 times x, and especially preferred 0.02 times x. The invention also relates to the use of arizidinosilicones.
摘要翻译：通式（1）的亚氮烷硅氧烷，其中R1表示H，C1-C12烷基，C2-C12烯基，C2-C12炔基，C7-C15烷芳基，C7-C15芳烷基，C3-C12环烷基，这些基团可以被 Cl或F部分，完全或以混合的方式和/或可以含有0至5个选自O，N，S的杂原子，R 2表示选自R 1和/或R 4的基团，R 3表示SiR 13或SiR 12 R 4，其中R 4表示式（2），A表示可以含有0至5个选自O，N，S的杂原子的（n + 1）基饱和，不饱和或芳族，直链，支链或环状的烃基，其包括1至 18个碳原子，B选自O，S，NR1，D选自C（O）O，C（O）NR1，C（O），C（O）C（O），C（O））m（C（O），C（S）NR1，CH2，E表示可以含有0至5个选自O，N，S的杂原子的二价饱和或不饱和的直链，支链或环状烃基， 18个碳原子，a为0或1，f为整数从2到1000，n，m是1至10的整数，x，y，z各自表示0或整数，其总和应在1和10000之间，条件是如果x大于0 ，y或z小于或等于x，优选小于或等于0.05倍×，特别优选0.02倍×。本发明还涉及三氮杂的使用。

3. 发明授权

US06677393B1 Silicon-based impression compounds with improved non-sag properties 有权
标题翻译：具有改善的非凹陷性能的硅基印模化合物
公开(公告)号：US06677393B1
公开(公告)日：2004-01-13
申请号：US09937911
申请日：2001-10-01
申请人： Joachim Zech , Erich Wanek
发明人： Joachim Zech , Erich Wanek
IPC分类号： C08K506
CPC分类号： A61K6/10
摘要： The invention relates to silicone-based addition-crosslinking impression material, containing (a) organopolysiloxanes with at least two unsaturated groups in the molecule, (b) organohydrogen polysiloxanes with at least three Si—H groups in the molecule, (c) optionally, organopolysiloxanes without reactive groups, (d) platinum catalyst, (e) optionally, hydrophilizing agent, (f) filler, (g) optionally, further customary additives, auxiliaries and dyes, characterized in that it contains, as component (h), polyalkylene oxide and/or its derivatives with an average molar mass of Mw>1000 at the rate of 0.001 to 1.0 wt.-% relative to the total mass of the cured material.
摘要翻译：本发明涉及基于硅氧烷的加成交联印模材料，其包含（a）在分子中具有至少两个不饱和基团的有机聚硅氧烷，（b）分子中具有至少三个Si-H基团的有机氢聚硅氧烷，（c）没有反应性基团的有机聚硅氧烷，（d）铂催化剂，（e）任选的亲水剂，（f）填料，（g）任选的另外的常规添加剂，助剂和染料，其特征在于，其作为组分（h）含有聚亚烷基氧化物和/或其衍生物，其平均摩尔质量Mw> 1000，相对于固化材料的总质量为0.001至1.0重量％。

4. 发明授权

US06566413B1 Polymerisable materials which are based on hardenable siloxane compounds 有权
公开(公告)号：US06566413B1
公开(公告)日：2003-05-20
申请号：US09868525
申请日：2001-09-19
申请人： Wolfgang Weinmann , Joachim Zech , Oswald Gasser , Rainer Guggenberger , Gunther Eckhardt , Peter Bissinger , Wolfgang Soglowek
发明人： Wolfgang Weinmann , Joachim Zech , Oswald Gasser , Rainer Guggenberger , Gunther Eckhardt , Peter Bissinger , Wolfgang Soglowek
IPC分类号： C08F246
CPC分类号： A61K6/083 , C07F7/21 , C08L51/085
摘要： The invention relates to novel cyclic siloxane compounds of the following general formula (I): in which: n=0, 1, 2, 3, 4, 5, 6, 7, 8, 9, 10 preferably 1, 2, 3, 4, 5; A=H or C1-C15 alk(en)yl, C3-C15 cycloalk(en)yl, C6-C12 aryl, C8-C18 alkaryl, where, in the said radicals, in each case one or more C atoms can be replaced by O, C═O, O(C═O), SiR2 and/or NR, R being an aliphatic radical with 1 to 7 C atoms, in which one or more C atoms can be replaced by O, C═O, and/or O(C═O); B=E or a linear, branched or polycyclic aliphatic- or aromatic-groups-containing hydrocarbon radical which links 2 to 10 of the cyclosiloxane radicals defined above, less B, to one another and contains 2 to 50 C atoms and additionally 0 to 30 other atoms from the group O, N, S, P, Si, Cl, F, Br, I and from which correspondingly 1 to 9, preferably 1 to 4 of the above defined cyclosiloxane radicals, less B, are pending; E=A or a polymerizable group G—Q—L, where on average up to 50% or less of the groups E correspond to representatives of A; G=C1-10 alk(en)ylene; Q=O, N—A or a di- or polyvalent linear, branched or cyclic alcohol, amine or aminoalcohol radical with 2 to 10 C atoms; L=an organic radical, containing a C═C double bond, with 2 to 10 C atoms; and with the proviso that no annelated siloxane ring systems can occur in (I), and also dental compositions which contain the compounds of formula (I) and/or compounds of formula (II): in which: T=independently of each other H or C1-C10 alk(en)yl, C3-C10 cycloalk(en)yl, C6-C12 aryl or C8-C8 alkaryl; N=a polymerizable group R1—R2—R3; b=0 to 500, where the proportion b may be at most 50% of the repeat units (b+c); c=1 to 1000; R1=C1-C10 alk(en)ylene; R2=O, N—T or a di- or polyvalent linear, branched or cyclic alcohol, amine or aminoalcohol radical with 2 to 10 C atoms; R3=an organic radical, containing a C═C double bond, with 3 to 10 C atoms; V=SiMe2T, SiEt2T, SiMePhT, SiPh2T.

5. 发明授权

US06457973B1 Dental impression tray 有权
标题翻译：牙齿印模托盘
公开(公告)号：US06457973B1
公开(公告)日：2002-10-01
申请号：US09714517
申请日：2000-11-17
申请人： Johann Fetz , Ingo Wagner , Joachim Zech
发明人： Johann Fetz , Ingo Wagner , Joachim Zech
IPC分类号： A61C900
CPC分类号： A61C9/0006
摘要： A dental impression tray has a wall member which, in the working position of the tray, is disposed on the inner surface facing the jaw, is opposite the dental arch which faces the palate or tongue, respectively, and forms a flow surface for directing impression material into the region between a tooth or stub and the gingiva to prevent voids in the solidified impression.
摘要翻译：牙齿印模托盘具有壁构件，其在托盘的工作位置设置在面向颚部的内表面上，分别与面向腭或舌的牙弓相对，并形成用于引导印象的流动面材料进入牙齿或短枝与牙龈之间的区域以防止固化印模中的空隙。

6. 发明授权

US06245828B1 Polymerizable compositions based on epoxides 有权
标题翻译：基于环氧化物的可聚合组合物
公开(公告)号：US06245828B1
公开(公告)日：2001-06-12
申请号：US09101867
申请日：1998-09-21
申请人： Wolfgang Weinmann , Oswald Gasser , Rainer Guggenberger , Gunther Lechner , Wolfgang Soglowek , Joachim Zech
发明人： Wolfgang Weinmann , Oswald Gasser , Rainer Guggenberger , Gunther Lechner , Wolfgang Soglowek , Joachim Zech
IPC分类号： A61K6087
CPC分类号： A61K6/0023 , A61K6/0017 , A61K6/087 , A61K6/09 , A61K6/093 , C07F7/0838 , C07F7/21 , C08G59/22 , C08G59/24 , C08G59/306 , C08G59/3218 , C08G59/3254 , C08L63/00 , G03F7/038 , C08L83/10 , C08L83/12
摘要： The present invention is directed to polymerizable dental compositions containing a) 3 to 80 wt. % of cycloaliphatic epoxides; b) 0 to 80 wt. % of an epoxide or a mixture of epoxides which are different from a); c) 3 to 85 wt. % of a filer material; d) 0.01 to 25 wt. % of initiators, inhibitors and/or accelerators; e) 0 to 25 wt. % of auxiliary agents, the individual percentages of which are in relation to the total weight. The new polymerizable agents are particularly suited as dental material.
摘要翻译：本发明涉及可聚合牙科组合物，其含有a）3-80wt。％脂环族环氧化物; b）0至80wt。％的不同于a）的环氧化物或环氧化物的混合物; c）3-85重量％％的档案资料; d）0.01〜25重量％％的引发剂，抑制剂和/或促进剂; e）0-25重量％辅助剂的百分比，其各自的百分比与总重量有关。新的可聚合剂特别适用于牙科材料。

7. 发明授权

US06867246B2 N-alkyl aziridine block copolymers and the uses thereof 有权
标题翻译： N-烷基氮丙啶嵌段共聚物及其用途
公开(公告)号：US06867246B2
公开(公告)日：2005-03-15
申请号：US10296996
申请日：2001-05-30
申请人： Reinhold Nowak , Joachim Zech , Peter Bissinger , Erich Wanek , Gunther Eckhardt , Guenther Lechner
发明人： Reinhold Nowak , Joachim Zech , Peter Bissinger , Erich Wanek , Gunther Eckhardt , Guenther Lechner
IPC分类号： A61C13/34 , A61K6/093 , A61K6/10 , C08G77/388 , C08G77/46 , C08L83/12
CPC分类号： A61K6/093 , A61K6/0017 , A61K6/0023 , A61K6/10 , C08G77/388 , C08G77/46 , C08L83/12
摘要： N-alkyl aziridine block copolymers of the general structure (1), wherein R1 represents H, C1-C12 alkyl, C2-C12 alkenyl, C2-C12 alkinyl, C7-C15 aralkyl C7-C15 aralkyl, or C3-C12 cycloalkyl and these groups can be substituted with C1 or F partially, completely or in a mixed manner and/or may contain 0 to 5 heteroatoms selected from O, N, S; R2 represents a group selected from R1 and/or R4; R3 represents SiR13 or SiR12R4, wherein R4 represents a group of the general formula (2), wherein A represents an (n+1) radical saturated, unsaturated or aromatic, linear, branched or cyclic hydrocarbon group that may contain 0 to 5 heteroatoms selected from O, N, S and that comprises 1 to 18 carbon atoms; B is selected from O, S, NR1; D is selected from C(O)O, C(O)NR1, C(O), C(S)NR1, CH2; E represents a diradical saturated or unsaturated, linear, branched or cyclic hydrocarbon group that may contain 0 to 5 heteroatoms selected from O, N, S, and that comprises 0 to 18 carbon atoms; Q represents and α, ω-radical polyether chain of the general formula (3): —[O—CgH2g]h—, wherein g is 2 to 20; h is 1 to 1000; a is 0 or 1; f is an integer from 2 to 1000; n is an integer from 1 to 10; and x, y, z each represents 0 or an integer, the sum of which should range between 1 and 10000, with the proviso that if x is larger 0, y or z is smaller or equal x. There are many uses of these copolymers.
摘要翻译：通式（1）的N-烷基氮丙啶嵌段共聚物，其中R1表示H，C1-C12烷基，C2-C12烯基，C2-C12炔基，C7-C15芳烷基C7-C15烷芳基或C3-C12环烷基，基团可以部分，完全或以混合方式被C1或F取代和/或可以含有0至5个选自O，N，S的杂原子; R2表示选自R1和/或R4的基团; R3表示SiR13或SiR12R4，其中R4表示通式（2）的基团，其中A表示可以含有0至5个选自杂原子的（n + 1）基饱和，不饱和或芳族，直链，支链或环状烃基来自O，N，S并且包含1至18个碳原子; B选自O，S，NR1; D选自C（O）O，C（O）NR1，C（O），C（S）NR1，CH2; E表示可以含有0至5个选自O，N，S的杂原子并且包含0至18个碳原子的二价饱和或不饱和的直链，支链或环状烃基; Q表示和通式（3）的α，ω-自由基聚醚链： - [O-CgH2g] h-，其中g为2至20; h为1〜1000; a是0或1; f为2〜1000的整数; n是1至10的整数; 并且x，y，z各自表示0或整数，其总和应在1和10000之间，条件是如果x大于0，则y或z小于或等于x。这些共聚物有许多用途。

8. 发明授权

US06302690B1 Dental impression tray 失效
标题翻译：牙印版托盘
公开(公告)号：US06302690B1
公开(公告)日：2001-10-16
申请号：US09656024
申请日：2000-09-06
申请人： Gerd Brandhorst , Johann Fetz , Ingo Wagner , Joachim Zech
发明人： Gerd Brandhorst , Johann Fetz , Ingo Wagner , Joachim Zech
IPC分类号： A61C900
CPC分类号： A61C9/0006
摘要： A dental impression tray comprises a mold shell made of synthetic material and having an inner space for receiving the impression material, and a support shell made of metal and surrounding the exterior of the mold shell in order to provide the overall impression tray with the rigidity and dimensional stability required for taking precisely fitting impressions. The support shell may be detachably connected to the mold shell by positive or non-positive engagement. While the mold shell including the impression material is passed on to the technician who will produce a model of the teeth from which the impression was taken and who may subsequently dispose of the mold shell including the impression material, the support shell will remain with the dentist, immediately ready for reuse upon sterilization.
摘要翻译：牙科印模托盘包括由合成材料制成并具有用于接收印模材料的内部空间的模具外壳和由金属制成并围绕模具外壳的支撑壳体，以便为整个印模托盘提供刚性和采取精确贴合印象所需的尺寸稳定性。支撑壳可以通过正或非正接合而可拆卸地连接到模壳。当包括印模材料的模具壳体被传递给技术人员时，该技术人员将产生印模的牙齿模型，并且谁可以随后处理包括印模材料的模具壳，支撑壳体将保留在牙医立即准备在灭菌后再次使用。

9. 发明申请

US20070004858A1 Allylsilane containing composition 有权
标题翻译：含烯丙基硅烷的组合物
公开(公告)号：US20070004858A1
公开(公告)日：2007-01-04
申请号：US10570415
申请日：2004-09-03
申请人： Joachim Zech , Henning Hoffmann , Peter Bissinger , Wolf Steiger
发明人： Joachim Zech , Henning Hoffmann , Peter Bissinger , Wolf Steiger
IPC分类号： C08L83/04 , B32B27/00
CPC分类号： A61K6/10 , C08G77/12 , C08G77/18 , C08G77/20 , C08G77/70 , C08K5/5425 , C08L83/04 , C08L83/00
摘要： The invention provides a method to reduce evolution of hydrogen gas especially during pouring gypsum models from addition cured silicones. In this respect the invention relates to an addition curable silicone composition, comprising an addition-curable siloxane compound, a siloxane crosslinker, a catalyst and an unsaturated silane compound with at least one methylene group directly attached to the unsaturation in an amount effective to reduce the amount of hydrogen gas evolved in the reaction of said composition.
摘要翻译：本发明提供了一种减少氢气进化的方法，特别是在从加入的固化硅氧烷浇注石膏模型期间。在这方面，本发明涉及一种可加成固化的硅氧烷组合物，其包含可加成固化的硅氧烷化合物，硅氧烷交联剂，催化剂和不饱和硅烷化合物，其中至少一个亚甲基直接连接到不饱和基团上，在所述组合物的反应中释放的氢气量。

10. 发明授权

US06894144B1 Two-constituent elastomer materials based on alkyl aziridine comprising a catalyst constituent that contains a boric acid complex 失效
标题翻译：基于烷基氮丙啶的双组分弹性体材料，其包含含有硼酸络合物的催化剂成分
公开(公告)号：US06894144B1
公开(公告)日：2005-05-17
申请号：US10070376
申请日：2000-09-01
申请人： Joachim Zech , Gunther Eckhardt , Cornelia Führer , Bernd Gangnus , Andreas Rombach , Oswald Gasser , Thomas Klettke , Erich Wanek
发明人： Joachim Zech , Gunther Eckhardt , Cornelia Führer , Bernd Gangnus , Andreas Rombach , Oswald Gasser , Thomas Klettke , Erich Wanek
IPC分类号： A61C11/00 , A61K6/00 , A61K6/087 , A61K6/10 , C08G73/02 , C08G73/04 , C08K5/55 , C08L71/02 , C08G79/38
CPC分类号： C08G73/0213 , A61K6/10 , C08L71/00
摘要： The invention relates to elastomer materials based on N-alkylaziridino compounds with a base component which contains the aziridino compounds and with a catalyst component which contains at least one acid-acting compound, both components being mixed before use, characterized in that, as acid-acting compound of the catalyst component, one or more boric acid complexes are used which can be obtained by reaction of boric acid and/or a boric acid derivative with at least one OH-functional compound, the OH functions being able to be present wholly or partly protected, and this reaction being carried out either as an upstream reaction between boric acid and/or a boric acid derivative and at least one such OH-functional compound or during or after the preparation of the catalyst component or by mixing the catalyst component with the base component which then contains at least one OH-functional compound. The elastomer materials are preferably used as dental impression materials, bite-registration materials and doubling materials.
摘要翻译：本发明涉及基于N-烷基氮丙啶基化合物的弹性体材料，其基质成分含有氮丙啶基化合物，以及含有至少一种酸作用化合物的催化剂组分，两种组分在使用前混合，其特征在于，使用催化剂组分的一种或多种硼酸络合物，其可以通过使硼酸和/或硼酸衍生物与至少一种OH官能化合物反应而获得，OH官能团可以全部存在部分保护，并且该反应作为硼酸和/或硼酸衍生物与至少一种这样的OH官能化合物之间的上游反应进行，或者在制备催化剂组分期间或之后进行，或者通过将催化剂组分与该基础组分然后含有至少一种OH官能化合物。弹性体材料优选用作牙科印模材料，咬合配准材料和加倍材料。

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