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1. 发明申请

US20090081454A1 Carbon Nanoparticles, Production and Use Thereof 审中-公开
标题翻译：碳纳米粒子，其生产和使用
公开(公告)号：US20090081454A1
公开(公告)日：2009-03-26
申请号：US11922753
申请日：2006-07-07
申请人： Peter Axmann , Margret Wohlfahrt-Mehrens , Ulrich Storr
发明人： Peter Axmann , Margret Wohlfahrt-Mehrens , Ulrich Storr
IPC分类号： D01F9/12 , C01B31/00 , B32B9/00 , B05D1/00 , B82B1/00 , B82B3/00
CPC分类号： D01F9/127 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , C01B2202/06 , C01B2202/36 , Y10T428/2918
摘要： The invention relates to carbon nanoparticles from fibers or tubes or combinations thereof, which have the morphology of macroscopic, spherical and/or spheroid secondary agglomerates, separated from each other. The invention also relates to a method for producing carbon nanoparticles by a CVD method using nanoporous catalyst particles having a spherical and/or spheroid secondary structure and comprising nanoparticulate metals and/or metal oxides or the precursors thereof as the catalytically active components. The inventive carbon nanoparticles are suitable for use in adsorbents, additives or active materials in energy accumulating systems, in supercapacitors, as filtering media, as catalysts or supports for catalysts, as sensors or as substrate for sensors, as additives for polymers, ceramics, metals and metal alloys, glasses, textiles and composite materials.
摘要翻译：本发明涉及具有彼此分离的宏观，球形和/或球状二次附聚物形态的来自纤维或管的碳纳米颗粒或其组合。本发明还涉及通过使用具有球形和/或球体二级结构并包含纳米颗粒金属和/或金属氧化物的纳米多孔催化剂颗粒或其前体作为催化活性组分的CVD方法制备碳纳米颗粒的方法。本发明的碳纳米颗粒适用于能量积聚系统中的吸附剂，添加剂或活性材料，超级电容器，过滤介质，催化剂催化剂或载体，传感器或传感器基质，聚合物，陶瓷，金属添加剂和金属合金，玻璃，纺织品和复合材料。

2. 发明申请

US20070275304A1 Method and Plasmatron for the Production of a Modified Material and Corresponding Modified Material 审中-公开
标题翻译：用于生产改性材料和相应改性材料的方法和Plasmatron
公开(公告)号：US20070275304A1
公开(公告)日：2007-11-29
申请号：US10576353
申请日：2004-10-14
申请人： Joerg Friedrich , Gerhard Kuhn , Reinhard Mach , Heinz-Eberhard Maneck , Walter Schutz , Ludwig Jorissen , Ulrich Storr , Margret Wohlfahrt-Mehrens
发明人： Joerg Friedrich , Gerhard Kuhn , Reinhard Mach , Heinz-Eberhard Maneck , Walter Schutz , Ludwig Jorissen , Ulrich Storr , Margret Wohlfahrt-Mehrens
IPC分类号： H01M4/58 , H05B6/02 , H05B7/00 , C01B31/00
CPC分类号： C04B41/80 , C04B41/0054 , C04B41/009 , C04B2111/00853 , H01M4/133 , H01M4/1393 , H01M10/0525 , C04B41/45 , C04B41/5346 , C04B35/522 , C04B35/52
摘要： Among other things, a method for the production of a modified material, for example, a carbon material, is described, having the following steps: Generation of a high-frequency field in a chamber (2) of a plasmatron (1); introduction of a plasma gas into chamber (2); generation of a plasma with the plasma gas by the high-frequency field; and introduction of initial material into the plasma. In addition a plasmatron (1) is described for the production of a modified material (M), having: a chamber (2), at least one high-frequency inductor (3) disposed in at least one region of chamber (2), a gas supply line (10, 11) for introducing a plasma gas into the region of a high-frequency field generated by high-frequency inductor (3), and a material supply line (4) for blowing in initial material with a transport gas into the plasma generated by high-frequency inductor (3) with the plasma gas. Finally, it also describes a modified carbon material which is correspondingly produced.
摘要翻译：其中，描述了用于生产改性材料例如碳材料的方法，具有以下步骤：在等离子体（1）的室（2）中产生高频场; 将等离子体气体引入室（2）中; 通过高频场产生具有等离子体气体的等离子体; 并将初始材料引入等离子体。此外，描述了用于生产改性材料（M）的等离子体（1），其具有：室（2），设置在室（2）的至少一个区域中的至少一个高频电感器（3）用于将等离子体气体引入到由高频电感器（3）产生的高频场的区域中的气体供给管线（10,11），以及用于将初始材料吹送到输送气体的材料供给管线（4）由等离子体气体由高频电感（3）产生的等离子体。最后，还描述了相应生产的改性碳材料。

3. 发明申请

US20110287319A1 MIXED OXIDE CONTAINING A LITHIUM MANGANESE SPINEL AND PROCESS FOR ITS PREPARATION 有权
标题翻译：含有锰锰矿的混合氧化物及其制备方法
公开(公告)号：US20110287319A1
公开(公告)日：2011-11-24
申请号：US12999376
申请日：2009-06-23
申请人： Christian Vogler , Gerhard Nuspl , Margret Wohlfahrt-Mehrens , Peter Axmann , Gisela Arnold
发明人： Christian Vogler , Gerhard Nuspl , Margret Wohlfahrt-Mehrens , Peter Axmann , Gisela Arnold
IPC分类号： H01M4/505
CPC分类号： H01M4/505 , C01B35/128 , C01G45/1242 , C01G51/54 , C01P2002/32 , C01P2002/52 , C01P2002/72 , C01P2004/03 , C01P2004/51 , C01P2004/52 , C01P2004/61 , C01P2006/11 , C01P2006/12 , C01P2006/13 , C01P2006/40 , C30B1/10 , C30B29/22 , H01M4/131 , H01M4/62 , H01M10/052 , H01M10/0525 , H01M2004/021 , H01M2004/028 , Y02E60/122
摘要： A mixed oxide containing a) a mixed-substituted lithium manganese spinel in which some of the manganese lattice sites are occupied by lithium ions and b) a boron-oxygen compound. Furthermore, a process for its preparation and the use of the mixed oxide as electrode material for lithium ion batteries.
摘要翻译：一种混合氧化物，其包含a）混合取代的锂锰尖晶石，其中一些锰晶格点由锂离子占据，b）硼 - 氧化合物。此外，其制备方法和使用混合氧化物作为锂离子电池的电极材料。

4. 发明申请

US20090035208A1 Nanoporous Catalyst Particles, the Production Thereof and Their Use 审中-公开
标题翻译：纳米催化剂颗粒及其制备及其用途
公开(公告)号：US20090035208A1
公开(公告)日：2009-02-05
申请号：US11922775
申请日：2006-07-07
申请人： Peter Axmann , Margret Wohlfahrt-Mehrens , Michael Kasper , Wolfgang Weirather
发明人： Peter Axmann , Margret Wohlfahrt-Mehrens , Michael Kasper , Wolfgang Weirather
IPC分类号： B01J21/18 , B01J23/32 , B01J23/755 , C04B35/00 , D01F9/12 , B01J23/75 , B01J23/745
CPC分类号： B82Y30/00 , B01J23/8892 , B01J35/0013 , B01J35/002 , B01J35/006 , B01J35/08 , B01J37/03 , B82Y40/00 , C01B32/162 , C01B2202/06
摘要： The invention relates to nanoporous catalyst particles having a spherical and/or spheroidal secondary structure, which contain, as catalytically active constituents, transition metals and/or oxides or precursors thereof. The invention also relates to a method for producing the nanoporous catalyst particles, during which, by means of a precipitation process, precursors with a spherical and/or spheroidal preliminary shape are produced from soluble compounds of the active constituents, and these morphologically pre-shaped precursors are, in a thermal activation step, transformed into nanoporous catalyst particles having a spherical and/or spheroidal secondary structure. The inventive catalyst particles can be used in the production of ceramic materials, as electrode materials in electrochemical cells or in fuel cells, as storage materials for chemical species and, in particular, in the production of carbon nanoparticles in the form of small tubes or fibers.
摘要翻译：本发明涉及具有球形和/或球形二级结构的纳米多孔催化剂颗粒，其包含作为催化活性组分的过渡金属和/或氧化物或其前体。本发明还涉及一种用于制备纳米多孔催化剂颗粒的方法，其中通过沉淀方法，由活性组分的可溶性化合物产生具有球形和/或球形初步形状的前体，并且这些形态上预成形在热活化步骤中，前体转变成具有球形和/或球形二级结构的纳米多孔催化剂颗粒。本发明的催化剂颗粒可用于制造陶瓷材料，作为电化学电池或燃料电池中的电极材料，用作化学物质的储存材料，特别是以小管或纤维的形式生产碳纳米颗粒。

5. 发明申请

US20120183855A1 Positive active electrode material for lithium secondary battery, process for preparing the same and lithium secondary battery 审中-公开
标题翻译：锂二次电池正极活性电极材料及其制备方法以及锂二次电池
公开(公告)号：US20120183855A1
公开(公告)日：2012-07-19
申请号：US13498790
申请日：2010-09-27
申请人： Margret Wohlfahrt-Mehrens , Peter Axmann , Wolfgang Weirather , Karl Kohler
发明人： Margret Wohlfahrt-Mehrens , Peter Axmann , Wolfgang Weirather , Karl Kohler
IPC分类号： H01M10/05 , H01M4/525 , H01M4/505 , H01M4/485 , H01M4/131
CPC分类号： H01M4/485 , H01M4/505 , H01M4/525 , H01M10/0525
摘要： Positive active electrode material for lithium secondary batteries comprising a mixed oxide represented by the general formula LivNiwMnxCoyAlzO2 wherein 0.9≦v≦1.2, 0.34≦w≦0.49, 0.34≦x≦0.42, 0.08≦y≦0.20, 0.03≦z≦0.05, 0.8≦w/x≦1.8, −0.08≦w−x≦0.22, 0.12≦y+z≦0.25 and w+x+y+z=1.
摘要翻译：包含由通式LivNiwMnxCoyAlzO2表示的混合氧化物的锂二次电池的正极活性电极材料，其中0.9和nlE; v和nlE; 1.2,0.34和nlE; w和nlE; 0.49,0.34和n1E; x和nlE; 0.42,0.08和n1E; y和n1E; 0.20,0.03＆ z + nlE; 0.05,0.8＆nlE; w / x和nlE; 1.8,0.08＆nlE; w-x和nlE; 0.22,0.12＆nlE; y + z＆nlE; 0.25和w + x + y + z = 1。

6. 发明授权

US06849208B1 Nickel mixed hydroxide, method for the producing the same, and the use thereof as a cathode material in alkaline batteries 失效
标题翻译：镍混合氢氧化物，其制造方法及其在碱性电池中作为阴极材料的用途
公开(公告)号：US06849208B1
公开(公告)日：2005-02-01
申请号：US09868995
申请日：1999-12-14
申请人： Viktor Stoller , Armin Olbrich , Juliane Meese-Marktscheffel , Margret Wohlfahrt-Mehrens , Peter Axmann , Herbert Dittrich , Sandra Ströbele
发明人： Viktor Stoller , Armin Olbrich , Juliane Meese-Marktscheffel , Margret Wohlfahrt-Mehrens , Peter Axmann , Herbert Dittrich , Sandra Ströbele
IPC分类号： C01G53/00 , C01G53/04 , H01M4/52
CPC分类号： C01G53/006 , C01G53/04 , C01P2002/52 , C01P2002/72 , C01P2004/03 , C01P2004/51 , C01P2004/61 , C01P2006/10 , C01P2006/11 , C01P2006/12 , C01P2006/40 , C01P2006/80 , H01M4/32 , H01M4/38 , H01M10/30
摘要： The invention relates to a nickel mixed hydroxide with Ni as the main element and with a layer structure, comprising at least one element Ma from the group comprising Fe, Cr, Co, Ti, Zr and Cu which is present in two different oxidation states which differ by one electron in terms of the number of outer electrons; at least one element Mb from the group comprising B, Al, Ga, In and RE (rare earth metals) present in the trivalent oxidation state; optionally at least one element Mc from the group comprising Mg, Ca, Sr, Ba and Zn present in the divalent oxidation state; apart from the hydroxide, at least one additional anion from the group comprising halides, carbonate, sulfate, oxalate, acetate, borate and phosphate in a quantity sufficient to preserve the electroneutrality of the mixed hydroxide; and water of hydration in a quantity which stabilizes the relevant structure of the mixed hydroxide.
摘要翻译：本发明涉及以Ni为主要元素并具有层结构的镍混合氢氧化物，其包含至少一种元素Ma，所述组分包含Fe，Cr，Co，Ti，Zr和Cu，其以两种不同的氧化态存在，在外电子数方面相差一电子; 来自包含以三价氧化态存在的B，Al，Ga，In和RE（稀土金属）的组中的至少一种元素Mb; 任选地，存在二价氧化态的包含Mg，Ca，Sr，Ba和Zn的组中的至少一种元素Mc; 除了氢氧化物外，还含有足以保持混合氢氧化物的电中性的量的卤代烃，碳酸盐，硫酸盐，草酸盐，乙酸盐，硼酸盐和磷酸盐的至少一种另外的阴离子; 和水合水，其量稳定了混合氢氧化物的相关结构。

7. 发明授权

US09281522B2 Mixed oxide containing a lithium manganese spinel and process for its preparation 有权
标题翻译：含有锂锰尖晶石的混合氧化物及其制备方法
公开(公告)号：US09281522B2
公开(公告)日：2016-03-08
申请号：US12999376
申请日：2009-06-23
申请人： Christian Vogler , Gerhard Nuspl , Margret Wohlfahrt-Mehrens , Peter Axmann , Gisela Arnold
发明人： Christian Vogler , Gerhard Nuspl , Margret Wohlfahrt-Mehrens , Peter Axmann , Gisela Arnold
IPC分类号： H01M4/131 , H01M4/62 , C01G45/12 , C01G51/00 , H01M4/505 , H01M10/052
CPC分类号： H01M4/505 , C01B35/128 , C01G45/1242 , C01G51/54 , C01P2002/32 , C01P2002/52 , C01P2002/72 , C01P2004/03 , C01P2004/51 , C01P2004/52 , C01P2004/61 , C01P2006/11 , C01P2006/12 , C01P2006/13 , C01P2006/40 , C30B1/10 , C30B29/22 , H01M4/131 , H01M4/62 , H01M10/052 , H01M10/0525 , H01M2004/021 , H01M2004/028 , Y02E60/122
摘要： A mixed oxide containing a) a mixed-substituted lithium manganese spinel in which some of the manganese lattice sites are occupied by lithium ions and b) a boron-oxygen compound. Furthermore, a process for its preparation and the use of the mixed oxide as electrode material for lithium ion batteries.
摘要翻译：一种混合氧化物，其包含a）混合取代的锂锰尖晶石，其中一些锰晶格点由锂离子占据，b）硼 - 氧化合物。此外，其制备方法和使用混合氧化物作为锂离子电池的电极材料。

8. 发明授权

US08168150B2 Binary, ternary and quaternary lithium phosphates, method for the production thereof and use of the same 有权
标题翻译：二元，三元和四元磷酸锂，其制备方法和用途
公开(公告)号：US08168150B2
公开(公告)日：2012-05-01
申请号：US10474555
申请日：2002-04-10
申请人： Reinhard P. Hemmer , Giesela Arnold , Christian Vogler , Margret Wohlfahrt-Mehrens
发明人： Reinhard P. Hemmer , Giesela Arnold , Christian Vogler , Margret Wohlfahrt-Mehrens
IPC分类号： H01M4/58 , C01B25/30
CPC分类号： H01M4/136 , C01B25/45 , H01M4/5825 , H01M10/052
摘要： The invention relates to binary, ternary and quaternary lithium phosphates of general formula Li(FexM1yM2z)PO4 wherein M1 represents at least one element of the group comprising Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Be, Mg, Ca, Sr, Ba, Al, Zr, and La; M2 represents at least one element of the group comprising Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Be, Mg, Ca, Sr, Ba, Al, Zr, and La; x=between 0.5 and 1, y=between 0 and 0.5, z=between 0 and 0.5, provided that x+y+z=1, or x=0, y=1 and z=0. The said lithium phosphates can be obtained according to a method whereby precursor compounds of elements Li, Fe, M1 and/or M2 are precipitated from aqueous solutions and the precipitation product is dried in an inert gas atmosphere or a reducing atmosphere at a temperature which is between room temperature and approximately 200° C. and tempered at a temperature of between 300° C. and 1000° C. The inventive lithium phosphates have a very high capacity when used as cathode material in lithium accumulators.
摘要翻译：本发明涉及通式为Li（FexM1yM2z）PO4的二元，三元和四价磷酸锂，其中M1代表包括Sc，Ti，V，Cr，Mn，Co，Ni，Cu，Zn，Be， Mg，Ca，Sr，Ba，Al，Zr和La; M2表示包括Sc，Ti，V，Cr，Mn，Co，Ni，Cu，Zn，Be，Mg，Ca，Sr，Ba，Al，Zr和La中的至少一种元素; x = 0.5和1之间，y = 0和0.5之间，z = 0和0.5之间，条件是x + y + z = 1或x = 0，y = 1和z = 0。所述磷酸锂可以按照以下方法获得，其中元素Li，Fe，M1和/或M2的前体化合物从水溶液中沉淀出来，沉淀产物在惰性气体气氛或还原气氛中在温度为在室温和约200℃之间，并在300℃和1000℃之间的温度下回火。当用作锂蓄电池中的阴极材料时，本发明的磷酸锂具有非常高的容量。

9. 发明授权

US06511639B1 Process for recycling negative-electrode materials from spent lithium batteries 失效
标题翻译：从废旧锂电池回收负极材料的方法
公开(公告)号：US06511639B1
公开(公告)日：2003-01-28
申请号：US09584059
申请日：2000-05-30
申请人： Michael Schmidt , Reinhard P. Hemmer , Margret Wohlfahrt-Mehrens , Giesela Arnold , Christian Vogler
发明人： Michael Schmidt , Reinhard P. Hemmer , Margret Wohlfahrt-Mehrens , Giesela Arnold , Christian Vogler
IPC分类号： C22B700
CPC分类号： H01M10/54 , H01M6/52 , H01M10/052 , Y02W30/84
摘要： A process for recycling electrode materials from spent lithium batteries in which negative-electrode materials from the lithium/transition-metal mixed oxide class of compounds from discharged, spent lithium batteries can, after comminution of the electrode constituents, be re-synthesized into chemically identical products as employed for the production of the batteries comprising mechanical and extractive processing of these constituents with the aim of removing positive-electrode constituents and other secondary constituents, such as binders and other processing auxiliaries, followed by controlled high-temperature treatment without leaving thermal decomposition products behind.
摘要翻译：从废锂电池回收电极材料的方法，其中来自排出的废弃锂电池的锂/过渡金属混合氧化物类化合物的负极材料可以在电极组分粉碎之后再次合成为化学相同的用于生产电池的产品包括这些成分的机械和萃取处理，目的是除去正极成分和其它二次成分，例如粘合剂和其它加工助剂，然后进行受控的高温处理而不留下热分解产品背后。

10. 发明授权

US6080510A Ternary mixed lithium oxides, process for preparing the same, and secondary lithium battery formed therefrom 失效
标题翻译：三元混合氧化锂，其制备方法和由其形成的二次锂电池
公开(公告)号：US6080510A
公开(公告)日：2000-06-27
申请号：US817339
申请日：1997-06-30
申请人： Reinhard P. Hemmer , Rudiger Oesten , Margret Wohlfahrt-Mehrens , Gisela Arnold
发明人： Reinhard P. Hemmer , Rudiger Oesten , Margret Wohlfahrt-Mehrens , Gisela Arnold
IPC分类号： C01B13/18 , C01B13/36 , C01G45/00 , C01G49/00 , C01G51/00 , C01G53/00 , H01M4/48 , H01M4/485 , H01M4/50 , H01M4/505 , H01M4/52 , H01M4/525 , H01M10/052 , H01M10/36 , H01M4/58 , C01G45/12 , C01F13/14
CPC分类号： H01M4/505 , C01B13/185 , C01G45/1242 , C01G49/0072 , C01G49/009 , C01G51/54 , C01G53/54 , H01M4/525 , C01P2002/32 , C01P2002/50 , C01P2002/52 , C01P2002/72 , C01P2004/51 , C01P2004/61 , C01P2004/62 , C01P2006/40 , C01P2006/60 , H01M10/052 , H01M4/485 , Y02P70/54
摘要： Ternary lithium mixed oxides having a spinel-type crystal structure and the general formula (I) Li.sub.y Me.sub.x Mn.sub.2-x O.sub.4 are disclosed. In this formula (I), Me represents a metal cation from groups IIa, IIIa, Iva, IIb, IIIb, IVb, IVb, VIIb, and VIII of the Periodic Table of Elements, x is in a range between 0 and 1, and y is in a range of greater than zero and not more than 1.2. The ternary mixed lithium oxide is obtainable by reacting reaction components in the form of hydroxides and/or water-soluble metal salts dissolved in a basic aqueous medium to form a homogenous suspension of the hydroxylic reaction products, removing water and optionally further solvents from the suspension, and subjecting the dried reaction products to heat treatment by heating them to temperatures between 500.degree. C. and 900.degree. C. at a heating speed of between 1 K/min and 20 K/min. The respective mixed oxides obtained are in a form which has no phase having a radiographic effect. These mixed oxides are suitable, in particular, as cathode materials in lithium secondary batteries.
摘要翻译： PCT No.PCT / EP95 / 03842 Sec。 371日期：1997年6月30日 102（e）日期1997年6月30日PCT提交1995年9月28日PCT公布。公开号WO96 / 10538 日期：1996年04月11日公开了具有尖晶石型晶体结构和通式（I）LiyMexMn2-xO4的三元锂混合氧化物。在该式（I）中，Me表示元素周期表IIa，IIIa，Iva，IIb，IIIb，IVb，IVb，VIIb和VIII族的金属阳离子，x在0和1之间， y在大于零且不大于1.2的范围内。三元混合氧化锂可以通过使溶解在碱性水介质中的氢氧化物和/或水溶性金属盐形式的反应组分反应以形成羟基反应产物的均匀悬浮液，从悬浮液中除去水和任选的其它溶剂通过将干燥的反应产物以1K / min至20K / min的加热速度加热至500℃至900℃的温度进行热处理。所得到的各混合氧化物为不具有放射线照相效果的相的形式。这些混合氧化物特别适用于锂二次电池中的阴极材料。

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