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1. 发明授权

US5270416A Thermosetting glycidyl modified acrylic powder coatings 失效
标题翻译：热固性缩水甘油基改性丙烯酸粉末涂料
公开(公告)号：US5270416A
公开(公告)日：1993-12-14
申请号：US941240
申请日：1992-09-04
申请人： Perry A. Toman , Andrew M. Rohn , Daniel Bode , Susan M. Miller
发明人： Perry A. Toman , Andrew M. Rohn , Daniel Bode , Susan M. Miller
IPC分类号： C08G59/20 , C08G59/32 , C09D5/03 , C09D5/46 , C09D125/00 , C09D125/14 , C09D133/04 , C09D133/06 , C09D133/14 , C09D163/00 , C08L63/00
CPC分类号： C09D133/068 , Y10S524/904
摘要： Thermosetting powder coating compositions are produced based on a low molecular weight glycidyl functional copolymer produced by solvent polymerization of ethylenic monomers in an organic solvent polymerization medium containing at least 15% by weight organic solvent based on the weight of solvent and monomers copolymerized, where the ethylenic monomers copolymerized comprise on a weight basis between about 15% and 35% glycidyl methacrylate, between about 5% and 60% methyl methacrylate, between about 2% and 15% butyl methacrylate, and between about 5% and 50% styrene, to produce glycidyl functional copolymer having a melt viscosity between 150 and 400 poise and a Tg between 80.degree. C. and 100.degree. C., where the copolymer is coreactive with carboxyl functional crosslinking compounds.
摘要翻译：基于通过在含有至少15重量％有机溶剂的有机溶剂聚合介质中的乙烯性单体的溶剂聚合制备的低分子量缩水甘油基官能共聚物来制备热固性粉末涂料组合物，所述有机溶剂基于溶剂和共聚单体的重量，其中烯属单体共聚包含约15％至35％甲基丙烯酸缩水甘油酯，约5％至60％甲基丙烯酸甲酯，约2％至15％甲基丙烯酸丁酯和约5％至50％苯乙烯之间，以产生缩水甘油基该共聚物的熔融粘度在150-400泊之间，Tg在80℃和100℃之间，其中共聚物与羧基官能交联化合物具有核心活性。

2. 发明授权

US5418292A Thermosetting acid functional crystalline polyester modified acrylic coatings 失效
标题翻译：热固性酸功能性结晶聚酯改性丙烯酸涂料
公开(公告)号：US5418292A
公开(公告)日：1995-05-23
申请号：US158655
申请日：1993-11-29
申请人： Daniel Bode , Perry A. Toman , Henry J. DeGraaf , Susan M. Miller
发明人： Daniel Bode , Perry A. Toman , Henry J. DeGraaf , Susan M. Miller
IPC分类号： C08L67/00 , C09D133/06 , C08L37/00
CPC分类号： C09D133/068 , C08L67/00 , Y10S525/934
摘要： Clear and pigmented powder paint coatings are based on a thermosetting polymeric binder comprising low molecular weight, carboxylic acid functional, crystalline polyester and a coreactive glycidyl functional addition copolymer, preferably and glycidyl functional acrylic copolymer.
摘要翻译：透明和着色的粉末涂料基于包含低分子量羧酸官能的结晶聚酯和核心缩水甘油基官能加成共聚物，优选和缩水甘油基官能丙烯酸共聚物的热固性聚合物粘合剂。

3. 发明申请

US20130281574A1 LATEX EMULSIONS AND COATING COMPOSITIONS FORMED FROM LATEX EMULSIONS 有权
标题翻译： LATEX乳液和涂料组合物由LATEX EMULSIONS形成
公开(公告)号：US20130281574A1
公开(公告)日：2013-10-24
申请号：US13996600
申请日：2011-12-28
申请人： Cathy Li , Tiffany Weidendorf , Timothy I. Memmer , Daniel Bode
发明人： Cathy Li , Tiffany Weidendorf , Timothy I. Memmer , Daniel Bode
IPC分类号： C09D133/04
CPC分类号： C09D133/04 , B65D25/14 , C08F2/001 , C08F2/22 , C08F265/06 , C09D5/20 , C09D133/062 , C09D133/068 , C09D151/003 , C08F220/18 , C08F220/32 , C08F220/28
摘要： Latex emulsions are disclosed which can be used in the formation of coating compositions that are not water sensitive have good blush resistance and retortability. In some embodiments, the coating compositions are used to coat substrates such as cans and packaging materials for the storage of food and beverages. Coating compositions of the invention may be prepared by polymerizing at least one ethylenically unsaturated monomer component, a stabilizer comprising a strong acid and an initiator in a carrier to form an emulsion, polymerizing the emulsion with at least one different ethylenically unsaturated monomer component to prepare the composite latex emulsion, and reacting the composite latex emulsion with a neutralizer to form the coating composition. Methods of coating substrates with the coating compositions, and substrates coated with the coating compositions are also disclosed.
摘要翻译：公开了可用于形成不具有水敏性的涂料组合物的乳胶乳液，其具有良好的抗沾红和耐蒸煮性能。在一些实施方案中，涂料组合物用于涂覆底物例如罐和包装材料以储存食品和饮料。本发明的涂料组合物可以通过在载体中聚合至少一种烯键式不饱和单体组分，包含强酸和引发剂的稳定剂以形成乳液，使乳液与至少一种不同的烯属不饱和单体组分聚合以制备复合胶乳乳液，并使复合胶乳乳液与中和剂反应形成涂料组合物。还公开了用涂料组合物涂布基材的方法和涂覆有涂料组合物的基材。

4. 发明授权

US4609706A High solids coatings using unsaturated monoisocyanate adducts of alkyd resins 失效
标题翻译：使用醇酸树脂的不饱和单异氰酸酯加合物的高固含量涂料
公开(公告)号：US4609706A
公开(公告)日：1986-09-02
申请号：US716699
申请日：1985-03-27
申请人： Daniel Bode , Henry J. DeGraaf
发明人： Daniel Bode , Henry J. DeGraaf
IPC分类号： C08G18/42 , C08G18/81 , C08L33/06 , C08L67/08 , C09D133/06 , C09D167/08 , C08L33/08
CPC分类号： C09D133/062 , C08G18/4288 , C08G18/8108 , C09D167/08 , C08L2205/02 , C08L33/062 , C08L67/08
摘要： High solids alkyd resin coatings are prepared by reacting at least a portion of the available hydroxyl groups on a resin with an ethylenically unsaturated monoisocyanate monomer. The new products, useful both as the major vehicle resin in high solids coatings and as a cure modifier for oxidatively curable alkyd, polyester and acrylic resins, impart improved drying and weathering properties to coatings while maintaining low paint viscosity.
摘要翻译：通过使树脂上的至少一部分可用的羟基与烯属不饱和单异氰酸酯单体反应来制备高固含量的醇酸树脂涂料。作为高固含量涂料中的主要载体树脂和用于氧化可固化的醇酸树脂，聚酯和丙烯酸树脂的固化改性剂的新产品在保持低涂料粘度的同时赋予涂料更好的干燥和耐候性能。

5. 发明授权

US07341762B2 Coating composition having improved release properties and the process for making the same 失效
标题翻译：具有改善的脱模性能的涂料组合物及其制备方法
公开(公告)号：US07341762B2
公开(公告)日：2008-03-11
申请号：US10338520
申请日：2003-01-08
申请人： Daniel Bode , Timothy I. Memmer , Deborah L. Howard
发明人： Daniel Bode , Timothy I. Memmer , Deborah L. Howard
IPC分类号： B05D7/14
CPC分类号： C09D5/00 , C08L23/00 , C08L23/06 , C08L91/06 , C08L91/08 , C09D7/65 , C09D163/00 , C08L2666/02 , C08L2666/04
摘要： A protective coating composition and a method for coating a metal substrate are provided. The composition and method are particularly suitable for coating can ends. The coating composition includes a film-forming polymer that includes an epoxy-based resin, a lubricant system, and a solvent or water component or mixture of solvent and water. The lubricant system includes a first surface modifier that reduces the coefficient of friction and a second surface modifier that reduces the abrasion of the cured coating.
摘要翻译：提供保护涂料组合物和涂覆金属基材的方法。组合物和方法特别适用于涂覆罐端。涂料组合物包括包含环氧基树脂，润滑剂体系和溶剂或水组分或溶剂和水的混合物的成膜聚合物。润滑剂系统包括减少摩擦系数的第一表面改性剂和减少固化涂层的磨损的第二表面改性剂。

6. 发明授权

US4683273A Polyester and epoxy resin coating 失效
标题翻译：聚酯和环氧树脂涂料
公开(公告)号：US4683273A
公开(公告)日：1987-07-28
申请号：US867050
申请日：1986-05-27
申请人： Daniel Bode
发明人： Daniel Bode
IPC分类号： C09D151/08 , C09D163/00 , C08L63/10
CPC分类号： C09D151/08 , C09D163/00
摘要： Polymer composition particularly useful as protective surface coatings comprise an aqueous mixture of epoxy-acrylic graft copolymers combined with a functional low molecular weight polyester and minor amounts of an amine derivative crosslinking resin. The low molecular weight polyester contains reactive hydroxyl or carboxyl functional groups and a molecular weight less than about 2,000.
摘要翻译：特别可用作保护性表面涂层的聚合物组合物包含与功能性低分子量聚酯和少量胺衍生物交联树脂结合的环氧 - 丙烯酸接枝共聚物的水性混合物。低分子量聚酯含有反应性羟基或羧基官能团，分子量小于约2,000。

7. 发明授权

US06306934B1 Aqueous coating composition 失效
标题翻译：水性涂料组合物
公开(公告)号：US06306934B1
公开(公告)日：2001-10-23
申请号：US09280639
申请日：1999-03-29
申请人： Daniel Bode , Deborah Howard , Christopher Bradley , Martin Belton
发明人： Daniel Bode , Deborah Howard , Christopher Bradley , Martin Belton
IPC分类号： C08K318
CPC分类号： C08F290/144 , C09D151/003 , C08L2666/02
摘要： A protective coating composition for coating interior surfaces of beer, beverage, and food containers, as well as interior and exterior surfaces of can ends, comprises a polymeric binder of emulsion copolymerized ethylenic monomers in the presence of an unsaturated polyester dispersed into water with an aqueous dispersed epoxy-acrylic graft copolymer dispersant. The preferred polymeric binder comprises by weight between 0.1% and 40% unsaturated polyester, between 20% and 80% emulsion copolymerized ethylenic unsaturated monomers, and at least 20% dispersant, where the emulsion copolymerized monomers crosslink with the water dispersed unsaturated polyester.
摘要翻译：用于涂覆啤酒，饮料和食品容器的内表面以及罐端部的内表面和外表面的保护性涂料组合物包含在分散于水中的不饱和聚酯与水分散的乳液共聚乙烯类单体的聚合物粘合剂分散环氧丙烯酸接枝共聚物分散剂。优选的聚合物粘合剂包含重量百分比为0.1％至40％的不饱和聚酯，20％至80％的乳液共聚的烯属不饱和单体和至少20％的分散剂，其中乳液共聚单体与水分散的不饱和聚酯交联。

8. 发明授权

US5342864A Low VOC, high molecular weight epoxy emulsion coatings 失效
标题翻译：低VOC，高分子量环氧乳液涂料
公开(公告)号：US5342864A
公开(公告)日：1994-08-30
申请号：US64632
申请日：1993-05-20
申请人： Gary P. Craun , Daniel Bode
发明人： Gary P. Craun , Daniel Bode
IPC分类号： C08F283/10 , C08G59/06 , C09D151/08 , C08K3/20 , C08L63/02
CPC分类号： C08G59/066 , C08F283/10 , C09D151/08
摘要： Coating compositions containing aqueous dispersion of higher molecular weight epoxy resin are produced by advancing the molecular weight of an aqueous dispersion of a low molecular weight epoxy resin having a number average molecular weight between about 360 and 2,000. The water dispersed low molecular weight epoxy resins are advanced in molecular weight by coreaction with diphenol at temperatures above about 105.degree. C. and at pressures above about 5 psig to produce the aqueous dispersed high molecular weight epoxy resin. The aqueous dispersed high molecular weight epoxy resin can be further copolymerized with ethylenic monomers, if desired, to produce an acrylic epoxy emulsion binder useful protective coatings.
摘要翻译：含有较高分子量环氧树脂的水性分散体的涂料组合物是通过使数均分子量在约360和2,000之间的低分子量环氧树脂的水性分散体的分子量提高而得到的。水分散的低分子量环氧树脂通过在高于约105℃的温度和高于约5psig的压力下与二酚共核化而分子量提高以产生水分散的高分子量环氧树脂。如果需要，水性分散的高分子量环氧树脂可以进一步与烯属单体共聚，以生产丙烯酸环氧乳液粘合剂有用的保护涂层。

9. 发明授权

US5252637A Low VOC, high molecular weight epoxy emulsion coatings 失效
标题翻译：低VOC，高分子量环氧乳液涂料
公开(公告)号：US5252637A
公开(公告)日：1993-10-12
申请号：US900924
申请日：1992-06-12
申请人： Gary P. Craun , Daniel Bode
发明人： Gary P. Craun , Daniel Bode
IPC分类号： C08F283/10 , C08G59/06 , C09D151/08 , C08K3/20
CPC分类号： C08G59/066 , C08F283/10 , C09D151/08
摘要： Coating compositions containing aqueous dispersions of higher molecular weight epoxy resin are produced by advancing the molecular weight of an aqueous dispersion of a low molecular weight epoxy resin having a number average molecular weight between about 360 and 2,000. The water dispersed low molecular weight epoxy resins are advanced in molecular weight by coreaction with diphenol at temperatures above about 105.degree. C. and at pressures above about 5 psig to produce the aqueous dispersed high molecular weight epoxy resin. The aqueous dispersed high molecular weight epoxy resin can be further copolymerized with ethylenic monomers, if desired, to produce an acrylic epoxy emulsion binder useful in protective coatings.

10. 发明授权

US08247051B2 Curable polymeric water based coating compositions and resulting coatings with barrier properties for gases and laminate structures 有权
标题翻译：可固化聚合物水基涂料组合物和具有气体和层压结构阻隔性能的所得涂料
公开(公告)号：US08247051B2
公开(公告)日：2012-08-21
申请号：US11497003
申请日：2006-08-01
申请人： Daniel Bode , Cathy Li , Kenneth J. Gardner
发明人： Daniel Bode , Cathy Li , Kenneth J. Gardner
IPC分类号： B32B27/08 , B32B27/32 , B32B27/34 , B32B27/36 , B32B27/38
CPC分类号： C09D163/00 , C08L61/20 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383 , Y10T428/24802 , Y10T428/24851 , Y10T428/24893 , Y10T428/24901 , Y10T428/31504 , Y10T428/31511 , Y10T428/31515 , Y10T428/31522 , Y10T428/31529 , Y10T428/31681 , Y10T428/31692 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855 , Y10T428/31938 , C08L2666/16
摘要： A coating composition is provided for use in laminate substrates useful in packaging of liquids and solids where the coating provides and increased resistance to the permeability of gases such as oxygen and carbon dioxide. In one embodiment the coating composition is a dispersion or a solution that comprises at least one hydroxyl functional polyetheramine, phosphoric acid and a defoamer. The backbone of the polyetheramine has diglycidyl ether linkages that comprise about 5 to about 70 mole percent resorcinol diglycidyl ether. The coating composition can be applied to substrates by coating applications such as spraying, rolling reverse and direct, rolling direct and reverse gravure, kiss coat, flow coating, brushing, dipping and curtain-wall coating, for example.
摘要翻译：提供涂料组合物用于层压基材，其可用于包装液体和固体，其中涂层提供并增加对诸如氧气和二氧化碳的气体的渗透性的抵抗性。在一个实施方案中，涂料组合物是包含至少一种羟基官能聚醚胺，磷酸和消泡剂的分散体或溶液。聚醚胺的主链具有包含约5至约70摩尔％间苯二酚二缩水甘油醚的二缩水甘油醚键。涂料组合物可以通过例如喷涂，滚轧，直接轧制，直接和逆向凹版，接触涂层，流涂，刷涂，浸涂和幕墙涂覆等涂布应用于基材。

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