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1. 发明授权

US5418292A Thermosetting acid functional crystalline polyester modified acrylic coatings 失效
标题翻译：热固性酸功能性结晶聚酯改性丙烯酸涂料
公开(公告)号：US5418292A
公开(公告)日：1995-05-23
申请号：US158655
申请日：1993-11-29
申请人： Daniel Bode , Perry A. Toman , Henry J. DeGraaf , Susan M. Miller
发明人： Daniel Bode , Perry A. Toman , Henry J. DeGraaf , Susan M. Miller
IPC分类号： C08L67/00 , C09D133/06 , C08L37/00
CPC分类号： C09D133/068 , C08L67/00 , Y10S525/934
摘要： Clear and pigmented powder paint coatings are based on a thermosetting polymeric binder comprising low molecular weight, carboxylic acid functional, crystalline polyester and a coreactive glycidyl functional addition copolymer, preferably and glycidyl functional acrylic copolymer.
摘要翻译：透明和着色的粉末涂料基于包含低分子量羧酸官能的结晶聚酯和核心缩水甘油基官能加成共聚物，优选和缩水甘油基官能丙烯酸共聚物的热固性聚合物粘合剂。

2. 发明授权

US5270416A Thermosetting glycidyl modified acrylic powder coatings 失效
标题翻译：热固性缩水甘油基改性丙烯酸粉末涂料
公开(公告)号：US5270416A
公开(公告)日：1993-12-14
申请号：US941240
申请日：1992-09-04
申请人： Perry A. Toman , Andrew M. Rohn , Daniel Bode , Susan M. Miller
发明人： Perry A. Toman , Andrew M. Rohn , Daniel Bode , Susan M. Miller
IPC分类号： C08G59/20 , C08G59/32 , C09D5/03 , C09D5/46 , C09D125/00 , C09D125/14 , C09D133/04 , C09D133/06 , C09D133/14 , C09D163/00 , C08L63/00
CPC分类号： C09D133/068 , Y10S524/904
摘要： Thermosetting powder coating compositions are produced based on a low molecular weight glycidyl functional copolymer produced by solvent polymerization of ethylenic monomers in an organic solvent polymerization medium containing at least 15% by weight organic solvent based on the weight of solvent and monomers copolymerized, where the ethylenic monomers copolymerized comprise on a weight basis between about 15% and 35% glycidyl methacrylate, between about 5% and 60% methyl methacrylate, between about 2% and 15% butyl methacrylate, and between about 5% and 50% styrene, to produce glycidyl functional copolymer having a melt viscosity between 150 and 400 poise and a Tg between 80.degree. C. and 100.degree. C., where the copolymer is coreactive with carboxyl functional crosslinking compounds.
摘要翻译：基于通过在含有至少15重量％有机溶剂的有机溶剂聚合介质中的乙烯性单体的溶剂聚合制备的低分子量缩水甘油基官能共聚物来制备热固性粉末涂料组合物，所述有机溶剂基于溶剂和共聚单体的重量，其中烯属单体共聚包含约15％至35％甲基丙烯酸缩水甘油酯，约5％至60％甲基丙烯酸甲酯，约2％至15％甲基丙烯酸丁酯和约5％至50％苯乙烯之间，以产生缩水甘油基该共聚物的熔融粘度在150-400泊之间，Tg在80℃和100℃之间，其中共聚物与羧基官能交联化合物具有核心活性。

3. 发明授权

US4766177A High solids coatings for plastic substrates 失效
标题翻译：用于塑料基材的高固含量涂料
公开(公告)号：US4766177A
公开(公告)日：1988-08-23
申请号：US45081
申请日：1987-05-04
申请人： Susan M. Miller , Gary P. Craun , Perry A. Toman
发明人： Susan M. Miller , Gary P. Craun , Perry A. Toman
IPC分类号： C08L75/06 , C09D133/08
CPC分类号： C09D133/08 , C08L75/06 , Y10T428/12028 , Y10T428/31507 , Y10T428/3158 , Y10T428/31583 , Y10T428/31587 , Y10T428/31609
摘要： Excellent adhesion of acrylic polymer coatings to plastic substrates can be obtained by the addition of an isocyanate modified polyester copolymer to the acrylic polymer coating.
摘要翻译：通过向丙烯酸聚合物涂层中加入异氰酸酯改性的聚酯共聚物可以获得丙烯酸聚合物涂料对塑料基材的优异粘合性。

4. 发明授权

US4877838A High solids coatings with reactive epoxy ester diluent 失效
标题翻译：具有活性环氧酯稀释剂的高固含量涂料
公开(公告)号：US4877838A
公开(公告)日：1989-10-31
申请号：US289257
申请日：1988-12-23
申请人： Perry A. Toman
发明人： Perry A. Toman
IPC分类号： C08L61/20 , C08L67/02 , C09D133/04 , C09D167/00
CPC分类号： C09D133/04 , C09D167/00 , C08L61/20 , C08L67/02
摘要： A high solids protective coating composition based on a coreactive thermosetting binder comprises low molecular weight hydroxyl functional acrylic copolymer, low molecular weight hydroxyl functional polyester polymer, hydroxy ester functional epoxy ester diluent, and a coreactive crosslinking amine material.
摘要翻译：基于活性热固性粘合剂的高固含量保护涂料组合物包括低分子量羟基官能丙烯酸共聚物，低分子量羟基官能聚酯聚合物，羟基酯官能环氧酯稀释剂和共聚活性交联胺材料。

5. 发明授权

US4742121A Acrylate resin gel coat composition 失效
标题翻译：丙烯酸酯树脂凝胶涂料组合物
公开(公告)号：US4742121A
公开(公告)日：1988-05-03
申请号：US927950
申请日：1986-11-07
申请人： Perry A. Toman
发明人： Perry A. Toman
IPC分类号： C08F299/06 , C08G18/62 , C08G18/68 , C08G18/81 , C08F265/04
CPC分类号： C08G18/6229 , C08F299/06 , C08G18/68 , C08G18/8108 , Y10S525/912 , Y10S525/913
摘要： Improved coating compositions which incorporate acrylate resins having multiple carbon-to-carbon bond unsaturation attached to the polymer chain through ester and/or urethane linkage are derived from the reaction product of:(1) an acrylate resin having multiple epoxide functionality attached to the polymer chain through an ester or ether linkage reacted with an unsaturated carboxylic acid preferably acrylic or methacrylic acid; or(2) an acrylate resin having multiple hydroxyl group functionality reacted with an organoisocyanate having 0.5 to 1.0 unit of carbon-to-carbon unsaturation per mole of isocyanate.Such coatings are particularly useful in formulating gel coat composites which exhibit hydrolytic stability and good weatherability.
摘要翻译：具有通过酯和/或氨基甲酸酯键连接到聚合物链上的具有多个碳 - 碳键不饱和键的丙烯酸酯树脂的改进的涂料组合物衍生自以下的反应产物：（1）具有连接到聚合物上的多个环氧官能团的丙烯酸酯树脂链通过与不饱和羧酸优选丙烯酸或甲基丙烯酸反应的酯或醚键; 或（2）具有多个羟基官能团的丙烯酸酯树脂与每摩尔异氰酸酯具有0.5至1.0单位碳 - 碳不饱和度的有机异氰酸酯反应。这种涂层特别可用于配制表现出水解稳定性和良好耐候性的凝胶涂层复合材料。

6. 发明授权

US4968775A Thermosetting polyester coating 失效
标题翻译：热固性聚酯涂层
公开(公告)号：US4968775A
公开(公告)日：1990-11-06
申请号：US507782
申请日：1990-04-12
申请人： Perry A. Toman , Alistair J. Ross
发明人： Perry A. Toman , Alistair J. Ross
IPC分类号： C09D167/02
CPC分类号： C09D167/02
摘要： An improved thermosetting coil coating composition contains a binder of a thermosetting polyester polymer particularly resistant to crystallization and adapted to be crosslinked with an aminoplast resin. The polyester comprises the condensation copolymer of 2-methyl-1,3-propane diol, neopentyl glycol, isophthalic acid, and terephthalic acid.
摘要翻译：改进的热固性线圈涂料组合物包含热固性聚酯聚合物的粘合剂，其特别耐结晶性，并且适于与氨基塑料树脂交联。聚酯包括2-甲基-1,3-丙二醇，新戊二醇，间苯二甲酸和对苯二甲酸的缩合共聚物。

7. 发明授权

US4812523A High solids coatings with reactive diluent 失效
标题翻译：高活性稀释剂固体涂料
公开(公告)号：US4812523A
公开(公告)日：1989-03-14
申请号：US147440
申请日：1988-01-25
申请人： Perry A. Toman
发明人： Perry A. Toman
IPC分类号： C08L61/20 , C08L67/02 , C09D133/04 , C09D167/00 , C08L61/00
CPC分类号： C09D133/04 , C09D167/00 , C08L61/20 , C08L67/02
摘要： A high solids, thermosetting coating composition for painting substrates comprises low molecular weight acrylic polymer, low molecular weight polyester polymer, and low molecular weight urethane diluent, where the acrylic and polyester and urethane components each contain hydroxyl functionality and are coreactive with an amine derivative crosslinking resin to render the coating thermosetting.
摘要翻译：用于涂布基质的高固含量热固性涂料组合物包括低分子量丙烯酸聚合物，低分子量聚酯聚合物和低分子量聚氨酯稀释剂，其中丙烯酸和聚酯和氨基甲酸酯组分各自含有羟基官能团并且与胺衍生物交联树脂以使涂层具有热固性。

8. 发明授权

US4587323A Polyester resin gelkote composition 失效
标题翻译：聚酯树脂凝胶组成
公开(公告)号：US4587323A
公开(公告)日：1986-05-06
申请号：US728398
申请日：1985-04-29
申请人： Perry A. Toman
发明人： Perry A. Toman
IPC分类号： C08G18/68 , C08G18/62
CPC分类号： C08G18/68
摘要： An improved hydroxyl functional urethane-extended polyester is based on the condensation reaction of fumaric acid, one or more non-aromatic polyols, azelaic acid and optionally one or more non-aromatic carboxylic acids including lauric acid or stearic acid. The hydroxylated polyester urethane oligomer possesses a molecular weight below 2600 and a mole ratio of hydroxyl groups to urethane linkage of from 0.5 to 6. Gel coats prepared from these oligomers exhibit superior water resistance and improved weathering characteristics.
摘要翻译：改进的羟基官能聚氨酯延伸的聚酯基于富马酸，一种或多种非芳族多元醇，壬二酸和任选的一种或多种非芳族羧酸（包括月桂酸或硬脂酸）的缩合反应。羟基化聚酯氨基甲酸酯低聚物的分子量低于2600，羟基与氨基甲酸酯键的摩尔比为0.5至6.由这些低聚物制备的凝胶涂层显示出优异的耐水性和改善的耐候性。

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