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1. 发明申请

US20050245688A1 Tire with tread of specialized trans 1,4-polybutadiene polymer and CIS 1,4-polyisoprene natural rubber 审中-公开
标题翻译：专用反式1,4-聚丁二烯聚合物和CIS 1,4-聚异戊二烯天然橡胶的胎面轮胎
公开(公告)号：US20050245688A1
公开(公告)日：2005-11-03
申请号：US10837740
申请日：2004-05-03
申请人： Paul Sandstrom , Adel Halasa , Wen-Liang Hsu , Roger Beers , Chad Jasiunas
发明人： Paul Sandstrom , Adel Halasa , Wen-Liang Hsu , Roger Beers , Chad Jasiunas
IPC分类号： B60C1/00 , C08K3/04 , C08K3/36 , C08L7/00 , C08L9/00 , C08L9/06 , C08L21/00
CPC分类号： B60C1/0016 , C08K3/04 , C08K3/36 , C08L7/00 , C08L9/06 , C08L21/00 , C08L2666/02 , C08L2666/08
摘要： This invention relates to a tire with a tread of a natural rubber-rich rubber composition. A partial replacement of the natural rubber in the tire tread is accomplished by an inclusion of a relatively low Mooney viscosity specialized trans 1,4-polybutadiene. The tire tread rubber composition is comprised of a blend of the specialized trans 1,4-polybutadiene polymer and cis 1,4-polyisoprene natural rubber optionally together with at least one additional diene-based elastomer in which the natural rubber remains a major portion of the elastomers in the tread rubber composition. A significant aspect of the invention is a partial replacement of natural cis 1,4-polyisoprene rubber in the tread rubber composition. The specialized trans 1,4-polybutadiene polymer has a relatively low Mooney (ML1+4), 100° C., viscosity within a range of 25 to 55. The specialized trans 1,4-polybutadiene polymer has a weight average molecular weight (Mw) of less than 220,000, preferably within a range of from 100,000 to 220,000, a number average molecular weight (Mn) of less than 120,000, preferably within a range of from 60,000 to 120,000 and a microstructure comprised of a trans 1,4-isomeric unit content in a range of from 75 to 85 percent, a cis 1,4-isomeric unit content in a range of from 10 to 20 percent and a vinyl 1,2-content in a range of from 3 to 5 percent.
摘要翻译：本发明涉及具有天然橡胶丰富橡胶组合物的胎面的轮胎。轮胎胎面中天然橡胶的部分替换通过包含相对较低的门尼粘度的特殊的反式1,4-聚丁二烯来实现。轮胎胎面橡胶组合物由专门的反式1,4-聚丁二烯聚合物和顺式1,4-聚异戊二烯天然橡胶的混合物组成，任选地与至少一种另外的二烯基弹性体共混，其中天然橡胶保留主要部分胎面橡胶组合物中的弹性体。本发明的一个重要方面是在胎面橡胶组合物中部分替代天然顺式1,4-聚异戊二烯橡胶。专用的反式1,4-聚丁二烯聚合物具有相对较低的门尼（ML1 + 4），100℃，粘度在25至55的范围内。专用的反式1,4-聚丁二烯聚合物具有重均分子量（ Mw）小于220,000，优选在100,000至220,000的范围内，数均分子量（Mn）小于120,000，优选在60,000至120,000的范围内，以及由反式1,4- 异构单元含量在75至85％的范围内，顺式1,4-异构体单元含量在10至20％范围内，乙烯基1,2-含量在3至5％的范围内。

2. 发明申请

US20060106149A1 Preparation of natural rubber-rich composition and tire with tread thereof 审中-公开
标题翻译：制备富含天然橡胶的组合物和具有胎面的轮胎
公开(公告)号：US20060106149A1
公开(公告)日：2006-05-18
申请号：US10992054
申请日：2004-11-18
申请人： Paul Sandstrom , Roger Beers
发明人： Paul Sandstrom , Roger Beers
IPC分类号： C08K3/34
CPC分类号： C08J3/226 , C08J2407/00 , C08K3/013 , C08L7/00 , C08L9/06 , C08L2666/08
摘要： This invention relates to the preparation of a natural rubber-rich rubber composition and tire with tread thereof wherein a portion of the natural rubber is replaced with an inclusion of a specialized trans 1,4-styrene/butadiene copolymer rubber. The process involves preparing a pre-formed masterbatch of a first phase.
摘要翻译：本发明涉及具有天然橡胶的橡胶组合物和具有胎面的轮胎的制备，其中天然橡胶的一部分被包含专门的反式1,4-苯乙烯/丁二烯共聚物橡胶所代替。该方法包括制备第一阶段的预形成母料。

3. 发明申请

US20050112223A1 Self-releasing curing bladder containing a micro-encapsulated lubricant and use thereof to cure rubber products such as tires 失效
标题翻译：含有微胶囊化润滑剂的自释放固化剂及其用于固化橡胶制品如轮胎的用途
公开(公告)号：US20050112223A1
公开(公告)日：2005-05-26
申请号：US10719271
申请日：2003-11-21
申请人： Roger Beers , Paul Sandstrom
发明人： Roger Beers , Paul Sandstrom
IPC分类号： B29C35/02 , B29C37/00 , B29D30/06
CPC分类号： B29D30/0654 , B29C35/02 , B29C37/0067 , B29D30/0662 , B29D2030/0655 , B29L2030/00
摘要： This invention relates to an expandable curing bladder of a butyl rubber composition containing a micro-encapsulated polysiloxane lubricant for delivering lubricity to the surface of the bladder. The invention further relates to a process of curing tires with such bladder.
摘要翻译：本发明涉及一种丁基橡胶组合物的可膨胀固化胶囊，其包含用于向膀胱表面输送润滑性的微胶囊化聚硅氧烷润滑剂。本发明还涉及一种用这种膀胱固化轮胎的方法。

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