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    • 6. 发明申请
    • Synthetic polyisoprene rubber
    • 合成聚异戊二烯橡胶
    • US20060074207A1
    • 2006-04-06
    • US11287562
    • 2005-11-23
    • Adel HalasaWen-Liang HsuAaron RybaJin-Ping ZhouChad JasiunasPaul Sandstrom
    • Adel HalasaWen-Liang HsuAaron RybaJin-Ping ZhouChad JasiunasPaul Sandstrom
    • C08F4/44
    • B01J31/143B01J31/04B60C1/0016C08F36/04C08L9/00C08L21/00C08F4/545C08F4/44C08L2666/08
    • The neodymium catalyst system prepared by the technique of this invention can be used in the polymerization of isoprene monomer into synthetic polyisoprene rubber having an extremely high cis-microstructure content and high stereo regularity. This polyisoprene rubber will crystallize under strain and can be compounded into rubber formulations in a manner similar to natural rubber. This invention more specifically discloses a process for the synthesis of polyisoprene rubber which comprises polymerizing isoprene monomer in the presence of a neodymium catalyst system, wherein the neodymium catalyst system is prepared by a process that comprises (1) reacting a neodymium carboxylate with an organoaluminum compound in an organic solvent to produce neodymium-aluminum catalyst component, and (2) subsequently reacting the neodymium-aluminum catalyst component with an elemental halogen to produce the neodymium catalyst system, wherein the neodymium catalyst system is void of nickel-containing compounds.
    • 通过本发明技术制备的钕催化剂体系可用于将异戊二烯单体聚合成具有非常高的顺式微结构含量和高立体规律性的合成聚异戊二烯橡胶。 该聚异戊二烯橡胶将在应变下结晶,并且可以以与天然橡胶相似的方式配合成橡胶制剂。 本发明更具体地公开了一种用于合成聚异戊二烯橡胶的方法,其包括在钕催化剂体系存在下聚合异戊二烯单体,其中所述钕催化剂体系通过以下方法制备,所述方法包括:(1)使羧酸钕与有机铝化合物 在有机溶剂中制备钕 - 铝催化剂组分,和(2)随后使钕 - 铝催化剂组分与元素卤素反应以产生钕催化剂体系,其中钕催化剂体系不含含镍化合物。
    • 8. 发明申请
    • Rubber composition and tire with component of diene-based elastomer composition with corncob granule dispersion
    • 橡胶组合物和轮胎与二甲基弹性体组合物与玉米芯颗粒分散体组分
    • US20060021688A1
    • 2006-02-02
    • US10902334
    • 2004-07-29
    • Paul Sandstrom
    • Paul Sandstrom
    • B60C11/00B60C1/00
    • C08L7/00B60C1/00B60C1/0016B60C1/0041B60C2001/0075C08K3/013C08K5/548C08K7/02C08L1/00C08L3/00C08L21/00C08L97/00C08L97/02Y10T152/10513Y10T152/1081C08L2666/02
    • This invention relates to a rubber composition and tire having at least one component of a rubber composition comprised of at least one diene-based elastomer, to the exclusion of butyl type elastomers, which contains an internal dispersion of corncob granules. Such tire component may be, for example, a tire tread and/or cord reinforced rubber ply and/or belt. A tire tread intended for winter driving, although not necessarily limited to winter driving, is provided of a rubber composition containing at least one diene-based sulfur vulcanizable elastomer having a Tg below −30° C. and an internal dispersion therein of corncob granules. The running surface of the tire tread is configured with a combination of micro-protrusions of corncob granules from said corncob granule internal dispersion and micro-cavities therein created by a release of a portion of the protruded corncob granules during the abrading, or wearing, of the tire tread running surface as the tire is being run. At least a portion of said corncob granular micro-protrusions may be covered by a relatively thin membrane of tread rubber. The corncob granules may be colored with a suitable colorant of a non-black color to contrast with the tire tread color to better visualize their presence on the tread running surface. The tire tread rubber composition may optionally also contain a starch/plasticizer composite, sorbitan ester, methylene donor compound, methylene acceptor compound or combination of methylene donor and acceptor compounds, and may be reinforced with carbon black, synthetic amorphous silica aggregates or their combination.
    • 本发明涉及一种橡胶组合物和轮胎,其具有由至少一种二烯基弹性体组成的橡胶组合物的至少一种组分,而不包括含有玉米芯颗粒的内部分散体的丁基型弹性体。 这种轮胎部件可以是例如轮胎胎面和/或帘线增强橡胶帘布层和/或带。 提供冬季驾驶的轮胎胎面,虽然不一定限于冬季驾驶,但是由含有至少一种Tg低于-30℃的二烯基硫可硫化弹性体和玉米芯颗粒的内部分散体的橡胶组合物提供。 轮胎胎面的运行表面配置有来自所述玉米芯粒颗粒内部分散体的玉米芯颗粒的微突起和其中的微腔,其通过在研磨或穿着期间释放一部分突出的玉米芯粒而产生 轮胎正在运行时的轮胎胎面行驶面。 所述玉米芯颗粒状微突起的至少一部分可以被相对薄的胎面胶膜覆盖。 可以用合适的非黑色着色剂着色玉米芯颗粒,以与轮胎胎面颜色形成对照,以更好地显现其在胎面运行表面上的存在。 轮胎胎面橡胶组合物可以任选地还含有淀粉/增塑剂复合材料,脱水山梨醇酯,亚甲基供体化合物,亚甲基受体化合物或亚甲基供体和受体化合物的组合,并且可以用炭黑,合成的无定形二氧化硅聚集体或它们的组合来增强。
    • 10. 发明申请
    • Tire with rubber tread composed of a primary and at least one lateral tread portion containing a dispersion of short carbon fibers
    • 具有橡胶胎面的轮胎,其由包含短碳纤维分散体的初级和至少一个侧向胎面部分组成
    • US20070221303A1
    • 2007-09-27
    • US11389912
    • 2006-03-27
    • Paul SandstromWalter WestgateBina BottsRachel Barnette
    • Paul SandstromWalter WestgateBina BottsRachel Barnette
    • B60C11/00
    • B60C1/0016B60C11/005B60C11/0058B60C11/14B60C2011/0025C08K3/013C08K3/04C08K7/06Y10T152/10513C08K3/0033C08L21/00
    • The invention relates to a tire having a circumferential rubber tread of a cap/base construction composed of a cap rubber layer as the tire running surface and an internal base rubber layer underlying said tread cap layer. The said tread cap layer is composed of a primary tread cap portion and one or two lateral tread cap portions of rubber compositions containing precipitated silica and/or rubber reinforcing carbon black reinforcement and wherein the rubber composition of at least one of said lateral tread cap portions contains a dispersion of short carbon fibers. Said primary tread cap portion contains a major portion of the running surface of the tread and is comprised of a silica-rich or carbon black-rich, preferably silica-rich, reinforcement-containing rubber composition, and said lateral tread portion(s) contains a minor portion of the running surface of the tread and is comprised of a silica-rich or carbon black-rich, preferably carbon black-rich, reinforcement-containing rubber composition. Where said primary tread cap portion is comprised of a silica-rich rubber composition, said lateral tread cap portion(s) is comprised of a carbon black-rich rubber composition and visa versa. The said tread cap portions are load bearing portions in the sense of extending from the running surface of the tread radially inward to said underlying tread base layer. In one aspect, the portioned rubber tread cap layer and the rubber tread base layer are co-extruded together to form a unitary composite thereof.
    • 本发明涉及一种轮胎,其具有由作为轮胎行驶表面的帽橡胶层和位于所述胎冠覆盖层下面的内基底橡胶层构成的帽/底座结构的圆周橡胶胎面。 所述胎面覆盖层由主要胎冠部分和含有沉淀二氧化硅和/或橡胶增强炭黑增强物的橡胶组合物的一个或两个侧向胎冠部分组成,并且其中所述侧向胎冠部分中的至少一个的橡胶组合物 含有短碳纤维的分散体。 所述主胎面部分包含胎面的运行表面的主要部分,并且由富含二氧化硅或富含炭黑的富含优选二氧化硅的增强橡胶组合物组成,并且所述侧向胎面部分包含 是胎面的运行表面的一小部分,并且由富含二氧化硅或富含炭黑的富碳含氟橡胶组合物构成。 当所述初级胎面盖部分由富含二氧化硅的橡胶组合物组成时,所述侧面胎冠部分由富含炭黑的橡胶组合物组成,反之亦然。 所述胎冠部分是承载部分,从胎面的行进表面径向向内延伸到所述下面的胎面基底层。 在一个方面,将分段的橡胶胎冠层和橡胶胎面基层共同挤压在一起以形成其整体复合物。