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1. 发明授权

US5273663A Oxidative removal of aqueous cyanide under acidic conditions 失效
标题翻译：在酸性条件下氧化氰化水
公开(公告)号：US5273663A
公开(公告)日：1993-12-28
申请号：US16355
申请日：1993-02-11
申请人： Paul R. Kurek , Robert R. Frame , Tom N. Kalnes , Mark D. Moser
发明人： Paul R. Kurek , Robert R. Frame , Tom N. Kalnes , Mark D. Moser
IPC分类号： C02F1/72 , C02F1/78 , C02F9/00 , C02F11/08
CPC分类号： C02F9/00 , C02F11/08 , C02F1/72 , C02F1/722 , C02F1/725 , C02F1/78 , C02F2101/18 , Y10S210/904
摘要： The oxidation of cyanide under acid conditions using oxygen as the oxidizing agent can be effected under mild reaction conditions when certain metal chelates are used as catalysts. Especially effective chelates are metal phthalocyanines, particularly where the metal is vanadium or a member of the iron group metals. The oxidation can be effected homogeneously using water soluble metal chelates, or can be performed heterogeneously, especially in a continuous fashion using a packed bed reactor, by using suitable water-insoluble metal chelates, especially when supported on appropriate carriers.
摘要翻译：使用氧作为氧化剂的酸性条件下氰化物的氧化可以在温和的反应条件下进行，当某些金属螯合物用作催化剂时。特别有效的螯合物是金属酞菁，特别是金属是钒或铁族金属的成分时。可以使用水溶性金属螯合物均匀地进行氧化，或者通过使用合适的水不溶性金属螯合物，特别是当在适当的载体上负载时，可以使用填充床反应器，特别是以连续的方式进行非均匀地进行氧化。

2. 发明授权

US5376285A Oxidative removal of aqueous metal-complexed cyanide under acidic conditions 失效
标题翻译：在酸性条件下氧化除去金属络合的氰化物水溶液
公开(公告)号：US5376285A
公开(公告)日：1994-12-27
申请号：US150294
申请日：1993-11-12
申请人： Paul R. Kurek , Robert R. Frame , Tom N. Kalnes , Mark D. Moser
发明人： Paul R. Kurek , Robert R. Frame , Tom N. Kalnes , Mark D. Moser
IPC分类号： C02F1/72 , C02F1/78 , C02F9/00 , C02F11/08
CPC分类号： C02F9/00 , C02F11/08 , C02F1/72 , C02F1/722 , C02F1/725 , C02F1/78 , C02F2101/18 , Y10S210/904
摘要： The oxidation of metal-complexed cyanide under acid conditions using oxygen as the oxidizing agent can be performed effectively with certain metal chelates as catalysts. Especially effective chelates are metal phthalocyanines, particularly where the metal is vanadium or a member of the iron group metals. The oxidation can be effected homogeneously using water soluble metal chelates, or can be performed heterogeneously, especially in a continuous fashion using a packed bed reactor, by using suitable water-insoluble metal chelates, especially when supported on appropriate carriers.
摘要翻译：使用氧作为氧化剂的酸性条件下金属络合的氰化物的氧化可以用某些金属螯合物作为催化剂有效地进行。特别有效的螯合物是金属酞菁，特别是金属是钒或铁族金属成分时。可以使用水溶性金属螯合物均匀地进行氧化，或者通过使用合适的水不溶性金属螯合物，特别是当在适当的载体上负载时，可以使用填充床反应器，特别是以连续的方式进行非均匀地进行氧化。

3. 发明授权

US5238581A Oxidative removal of cyanide from aqueous streams abetted by ultraviolet irradiation 失效
标题翻译：通过紫外线照射从水流中氧化除去氰化物
公开(公告)号：US5238581A
公开(公告)日：1993-08-24
申请号：US862149
申请日：1992-04-02
申请人： Robert R. Frame , Tom N. Kalnes , Mark D. Moser
发明人： Robert R. Frame , Tom N. Kalnes , Mark D. Moser
IPC分类号： C02F1/58 , B01J31/12 , B01J31/16 , B01J31/18 , C02F20060101 , C02F1/32 , C02F1/72 , C02F1/74 , C02F1/78 , C02F9/00
CPC分类号： B01J31/183 , B01J31/1616 , B01J31/1815 , C02F1/72 , C02F1/725 , B01J2531/025 , B01J2531/56 , B01J2531/842 , B01J2531/845 , B01J2531/96 , C02F1/32 , C02F1/722 , C02F1/74 , C02F1/78 , C02F2101/18 , C02F2101/20 , Y10S210/904
摘要： The oxidation of complexed cyanide using oxygen as the oxidizing agent when certain metal chelates are used as catalysts may be enhanced by irradiating the complexed cyanide with ultraviolet light prior to or concurrent with the oxidation. Especially effective chelates are metal phthalocyanines, particularly where the metal is vanadium or a member of the iron group metals. The oxidation can be effected homogeneously using water soluble metal chelates, or can be performed heterogeneously, especially in a continuous fashion using a packed bed reactor, by using suitable water-insoluble metal chelates, especially when supported on appropriate carriers.
摘要翻译：当使用某些金属螯合物作为催化剂时，使用氧作为氧化剂的络合氰化物的氧化可以通过在氧化之前或同时用紫外线照射络合的氰化物来增强。特别有效的螯合物是金属酞菁，特别是金属是钒或铁族金属的成分时。可以使用水溶性金属螯合物均匀地进行氧化，或者通过使用合适的水不溶性金属螯合物，特别是当在适当的载体上负载时，可以使用填充床反应器，特别是以连续的方式进行非均匀地进行氧化。

4. 发明授权

US5120453A Oxidative removal of cyanide from aqueous streams 失效
标题翻译：从水流中氧化氰化物
公开(公告)号：US5120453A
公开(公告)日：1992-06-09
申请号：US632798
申请日：1990-12-24
申请人： Robert R. Frame , Tom N. Kalnes , Mark D. Moser
发明人： Robert R. Frame , Tom N. Kalnes , Mark D. Moser
IPC分类号： C02F1/58 , B01J31/12 , B01J31/16 , B01J31/18 , C02F20060101 , C02F1/32 , C02F1/72 , C02F1/74 , C02F1/78 , C02F9/00
CPC分类号： B01J31/183 , B01J31/1616 , B01J31/1815 , C02F1/72 , C02F1/725 , B01J2531/025 , B01J2531/56 , B01J2531/842 , B01J2531/845 , B01J2531/96 , C02F1/32 , C02F1/722 , C02F1/74 , C02F1/78 , C02F2101/18 , C02F2101/20 , Y10S210/904
摘要： The oxidation of cyanide using oxygen as the oxidizing agent can be effected under mild reaction conditions when certain metal chelates are used as catalysts. Especially effective chelates are metal phthalocyanines, particularly where the metal is vanadium or a member of the iron group metals. The oxidation can be effected homogeneously using water soluble metal chelates, or can be performed heterogeneously, especially in a continuous fashion using a packed bed reactor, by using suitable water-insoluble metal chelates, especially when supported on appropriate carriers.
摘要翻译：使用氧作为氧化剂的氰化物的氧化可以在温和的反应条件下，当某些金属螯合物用作催化剂时。特别有效的螯合物是金属酞菁，特别是金属是钒或铁族金属的成分时。可以使用水溶性金属螯合物均匀地进行氧化，或者通过使用合适的水不溶性金属螯合物，特别是当在适当的载体上负载时，可以使用填充床反应器，特别是以连续的方式进行非均匀地进行氧化。

5. 发明授权

US06395943B1 Process for inhibiting the polymerization of vinyl aromatic compounds 失效
标题翻译：抑制乙烯基芳族化合物聚合的方法
公开(公告)号：US06395943B1
公开(公告)日：2002-05-28
申请号：US09371455
申请日：1999-08-10
申请人： Paul R. Kurek , Robert R. Frame
发明人： Paul R. Kurek , Robert R. Frame
IPC分类号： C07C720
CPC分类号： C07B63/04 , C08F2/40
摘要： A process is disclosed for inhibiting the polymerization of vinyl aromatic compounds, such as styrene, during its distillation. The process involves adding a mixture of at least two inhibitors to the vinyl aromatic compound. One such combination is N,N′-di-2-butyl-N,N′,4-dinitroso-1,4-diaminobenzene and dinitrocresol. A stabilizer such as N,N′-di-2-butyl-1,4-diaminobenzene can also be added.
摘要翻译：公开了一种在蒸馏期间抑制乙烯基芳族化合物如苯乙烯的聚合的方法。该方法包括向乙烯基芳族化合物中加入至少两种抑制剂的混合物。一种这样的组合是N，N'-二-2-丁基-N，N'，4-二亚硝基1,4-二氨基苯和二硝基甲酚。也可以加入N，N'-二-2-丁基-1,4-二氨基苯等稳定剂。

6. 发明授权

US06395942B1 Increasing the thermal stability of a vinyl aromatic polymerization inhibitor 失效
标题翻译：提高乙烯基芳族聚合抑制剂的热稳定性
公开(公告)号：US06395942B1
公开(公告)日：2002-05-28
申请号：US09371349
申请日：1999-08-10
申请人： Paul R. Kurek , Robert R. Frame
发明人： Paul R. Kurek , Robert R. Frame
IPC分类号： C07C720
CPC分类号： C07C7/20 , C07C15/58 , C07C15/46 , C07C15/44
摘要： Compounds that inhibit polymerization of vinyl aromatic compounds need to operate at temperatures of about 90° C. to about 150° C. A process for increasing the thermal stability of inhibitors such as N,N′-di-2-butyl-N,N′-dinitroso-1,4-diaminobenzene is disclosed. The process comprises adding to the inhibitor a stabilizer such as N,N′-di-2-butyl-1,4-diaminobenzene. The mixture of inhibitor and stabilizer is also used to inhibit polymerization of vinyl aromatic compounds.
摘要翻译：抑制乙烯基芳族化合物聚合的化合物需要在约90℃至约150℃的温度下操作。提高抑制剂如N，N'-二-2-丁基-N，N 公开了'二亚硝基-1,4-二氨基苯。该方法包括向抑制剂中加入稳定剂如N，N'-二-2-丁基-1,4-二氨基苯。抑制剂和稳定剂的混合物也用于抑制乙烯基芳族化合物的聚合。

7. 发明授权

US5869717A Process for inhibiting the polymerization of vinyl aromatics 失效
标题翻译：抑制乙烯基芳烃聚合的方法
公开(公告)号：US5869717A
公开(公告)日：1999-02-09
申请号：US932202
申请日：1997-09-17
申请人： Robert R. Frame , Paul R. Kurek
发明人： Robert R. Frame , Paul R. Kurek
IPC分类号： C07C7/20 , C07C15/46
CPC分类号： C07C7/20 , Y10S585/952
摘要： Applicants have developed a process for inhibiting the polymerization of vinyl aromatic compound during the distillation of the vinyl aromatic compounds. The process involves adding to the vinyl aromatic compound, e.g., styrene, a nitroso compound such as N-nitroso-N, N'-di-3-pentyl-p-phenylenediamine.
摘要翻译：申请人开发了在乙烯基芳族化合物的蒸馏期间抑制乙烯基芳族化合物的聚合的方法。该方法包括加入乙烯基芳族化合物，例如苯乙烯，亚硝基化合物如N-亚硝基-N，N'-二-3-戊基 - 对苯二胺。

8. 发明授权

US06403853B1 Olefin oligomerization using surface modified molecular sieve catalyst 失效
标题翻译：烯烃低聚使用表面改性分子筛催化剂
公开(公告)号：US06403853B1
公开(公告)日：2002-06-11
申请号：US09667167
申请日：2000-09-21
申请人： Hayim Abrevaya , Robert R. Frame
发明人： Hayim Abrevaya , Robert R. Frame
IPC分类号： C07C224
CPC分类号： C07C2/12 , B01J29/85 , B01J37/0246 , B01J2229/37 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2521/12 , C07C2527/167 , C07C2529/85
摘要： In a process for the oligomerization of light olefins (e.g. propylene) to more valuable higher olefins (e.g. hexene), the use of a molecular sieve (e.g. SAPO-11) that has been acid washed has shown to provide superior selectivity to, and yield of, the desired product. These benefits are attributed to a reduction in non-selective acid sites as well as an increase in phosphorous content (in the case of SAPO molecular sieves) at the molecular sieve crystallite surface, a probable result of removing amorphous silicon aluminum phosphate acid, silicophosphorous acids, and/or phosphoric acids. Furthermore, this removal is likely accompanied by an increased accessibility of olefinic feed components to the so-called “selective” acid sites within the sieve pores. Post-synthesis acid washing of the molecular sieve has not only demonstrated a narrower carbon number distribution of olefin oligomers, but also improved the linearity of the oligomerized olefinic product slate in general. Such increases in linearity generally correspond to overall higher product values, when downstream applications such as plasticizer intermediates are considered.
摘要翻译：在将轻质烯烃（例如丙烯）低聚成更有价值的高级烯烃（例如己烯）的方法中，使用已经被酸洗的分子筛（例如SAPO-11）显示出提供优异的选择性和产率的，所需的产品。这些优点归因于在分子筛微晶表面上非选择酸性位点的减少以及磷含量的增加（在SAPO分子筛的情况下），去除非晶硅磷酸铝，硅磷酸的可能结果，和/或磷酸。此外，这种去除可能伴随着烯烃进料组分对筛孔内所谓的“选择性”酸性位点的可接近性增加。分子筛的合成后酸洗不仅表现出烯烃低聚物的较窄的碳数分布，而且通常改善了低聚烯烃产物的线性。当下游应用如增塑剂中间体被考虑时，线性的这种增加通常对应于总体较高的产品值。

9. 发明授权

US5273646A Process for improving the activity of a mercaptan oxidation catalyst 失效
标题翻译：改进硫醇氧化催化剂活性的方法
公开(公告)号：US5273646A
公开(公告)日：1993-12-28
申请号：US963193
申请日：1992-10-19
申请人： Robert R. Frame , Jeffery C. Bricker , Laurence O. Stine , Thomas A. Verachtert
发明人： Robert R. Frame , Jeffery C. Bricker , Laurence O. Stine , Thomas A. Verachtert
IPC分类号： B01J31/02 , B01J31/12 , B01J31/18 , C10G27/10 , C10G29/00
CPC分类号： B01J31/0239 , B01J31/183 , B01J2231/70 , B01J2531/025 , B01J2531/845
摘要： This invention relates to a process for improving the activity of a catalyst effective in sweetening a hydrocarbon fraction containing mercaptans. The process involves adding to the hydrocarbon fraction an effective amount of an aqueous solution comprising ammonium hydroxide, a metal chelate and an onium compound.
摘要翻译：本发明涉及一种改善催化剂活性的方法，该催化剂有效地使含有硫醇的烃馏分变甜。该方法包括向烃馏分中加入有效量的包含氢氧化铵，金属螯合物和鎓化合物的水溶液。

10. 发明授权

US5180484A Caustic free liquid/liquid process for sweeting a sour hydrocarbon fraction 失效
$Caustic free liquid/liquid process for sweeting a sour hydrocarbon fraction$
标题翻译：无碱液体/液体工艺，用于酿造酸性碳氢化合物馏分
公开(公告)号：US5180484A
公开(公告)日：1993-01-19
申请号：US799798
申请日：1991-11-29
申请人： Robert R. Frame , Jeffery C. Bricker , Laurence O. Stine , Thomas A. Verachtert
发明人： Robert R. Frame , Jeffery C. Bricker , Laurence O. Stine , Thomas A. Verachtert
IPC分类号： B01J31/02 , B01J31/12 , B01J31/18
CPC分类号： B01J31/0239 , B01J31/122 , B01J31/183 , C10G27/10 , B01J2231/70 , B01J2531/025 , B01J2531/845
摘要： This invention relates to a liquid-liquid process for treating a sour hydrocarbon fraction. The process comprises contacting the hydrocarbon fraction in the presence of an oxidizing agent with an aqueous solution containing ammonium hydroxide, a metal chelate and an onium compound selected from the group consisting of quaternary ammonium, phosphonium, arsonium, stibonium, oxonium and sulfonium compounds. A preferred onium compound is a quaternary ammonium compound with an especially preferred compound being a quaternary ammonium halide.
摘要翻译：本发明涉及一种用于处理酸性烃馏分的液 - 液方法。该方法包括在氧化剂存在下将烃馏分与含有氢氧化铵的水溶液，金属螯合物和选自季铵，鏻，砷，锑，氧鎓和锍化合物的鎓化合物接触。优选的鎓化合物是季铵化合物，特别优选的化合物是季铵卤化物。

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