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1. 发明授权

US06420512B1 Extrusion method for making polycarbonate 有权
标题翻译：制造聚碳酸酯的挤出方法
公开(公告)号：US06420512B1
公开(公告)日：2002-07-16
申请号：US09911439
申请日：2001-07-24
申请人： Patrick Joseph McCloskey , James Day , Paul Michael Smigelski , John Lester Maxam , John Aibangbee Osaheni
发明人： Patrick Joseph McCloskey , James Day , Paul Michael Smigelski , John Lester Maxam , John Aibangbee Osaheni
IPC分类号： C08G6400
CPC分类号： C08G64/307
摘要： Extrusion of a mixture of an ester-substituted diaryl carbonate, such as bis-methyl salicyl carbonate, a dihydroxy aromatic compound such as bisphenol A and a transesterification catalyst such as tetrabutyl phosphonium acetate (TBPA) affords polycarbonate having a weight average molecular weight of greater than 20,000 Daltons. The extruder is equipped with one or more vacuum vents to remove by-product ester-substituted phenol. Similarly, a precursor polycarbonate having ester-substituted phenoxy endgroups, for example methyl salicyl endgroups, when subjected to extrusion affords a polycarbonate having a significantly increased molecular weight relative to the precursor polycarbonate. The reaction to form a higher molecular weight polycarbonate may be catalyzed by residual transesterification catalyst present in the precursor polycarbonate, or by a combination of any residual catalyst and an additional catalyst such as TBPA introduced in the extrusion step. Fries rearrangement products are not observed in the product polycarbonates.
摘要翻译：酯取代的碳酸二芳基酯如碳酸双甲酯，双酚A等二羟基芳族化合物和乙酸四丁基鏻（TBPA）等酯交换催化剂的混合物的挤出，得到重均分子量大的聚碳酸酯超过20,000道尔顿。挤出机配备有一个或多个真空通风口以除去副产物酯取代的苯酚。类似地，具有酯取代的苯氧基端基的前体聚碳酸酯，例如甲基水杨基端基，当进行挤出时，得到相对于前体聚碳酸酯具有显着增加的分子量的聚碳酸酯。形成较高分子量聚碳酸酯的反应可以通过存在于前体聚碳酸酯中的残留酯交换催化剂，或者通过任何残余催化剂和另外的催化剂如在挤出步骤中引入的TBPA的组合来催化。在产品聚碳酸酯中没有观察到薯条重排产物。

2. 发明授权

US06600004B1 Method of preparing polyestercarbonates 有权
标题翻译：聚碳酸酯的制备方法
公开(公告)号：US06600004B1
公开(公告)日：2003-07-29
申请号：US10118634
申请日：2002-04-10
申请人： Patrick Joseph McCloskey , Paul Michael Smigelski
发明人： Patrick Joseph McCloskey , Paul Michael Smigelski
IPC分类号： C08G6400
CPC分类号： C08G63/64
摘要： A method of preparing polyestercarbonates is presented in which a mixture of at least one activated diaryl carbonate is reacted under melt polymerization conditions with at least one aromatic dihydroxy compound together with at least one dicarboxylic acid. Polyestercarbonates possessing up to about percent 10 mole dicarboxylic acid residues based on the total amount of structural units derived from aromatic dihydroxy compounds are obtained. The method provides both for high levels of incorporation of the dicarboxylic acid into the polyestercarbonate backbone and a high level of polymer endcapping.
摘要翻译：提出了一种制备聚酯碳酸酯的方法，其中至少一种活化的碳酸二芳基酯的混合物在熔融聚合条件下与至少一种芳族二羟基化合物与至少一种二羧酸一起反应。得到基于衍生自芳族二羟基化合物的结构单元的总量，具有高达约10摩尔二羧酸残基的聚酯碳酸酯。该方法既提供高水平的二羧酸结合到聚酯碳酸酯骨架中，也提供高水平的聚合物封端。

3. 发明申请

US20080004407A1 Method for Making Molded Polycarbonate Articles with Improved Color 有权
标题翻译：制造具有改进颜色的模制聚碳酸酯制品的方法
公开(公告)号：US20080004407A1
公开(公告)日：2008-01-03
申请号：US11688533
申请日：2007-03-20
申请人： Sjef Berndsen , Hans-Peter Brack , Bernd Jansen , Jan Henk Kamps , Edward Kung , Daniel Lowery , Patrick Joseph McCloskey , Paul Michael Smigelski , Dennis Willemse
发明人： Sjef Berndsen , Hans-Peter Brack , Bernd Jansen , Jan Henk Kamps , Edward Kung , Daniel Lowery , Patrick Joseph McCloskey , Paul Michael Smigelski , Dennis Willemse
IPC分类号： C08G64/14 , C08G65/48
CPC分类号： C08G64/307 , C08G64/14
摘要： A method for preparing a molded article includes the steps of (a) obtaining a polycarbonate resin and (b) molding the polycarbonate resin. The polycarbonate resin is made by a transesterification reaction using an activated diaryl carbonate such that the polycarbonate is susceptible to the formation of internal ester linkages (IEL). The method occurs with the proviso that the polycarbonate resin, the molding conditions or both are selected to control the amount of IEL formed during the molding process to a level of less than 0.4 mol %.
摘要翻译：制备模塑制品的方法包括以下步骤：（a）获得聚碳酸酯树脂和（b）模塑聚碳酸酯树脂。聚碳酸酯树脂通过使用活化的碳酸二芳基酯的酯交换反应制备，使得聚碳酸酯容易形成内部酯键（IEL）。该方法发生，条件是选择聚碳酸酯树脂，成型条件或两者以控制在模制过程中形成的IEL的量至小于0.4mol％的水平。

4. 发明申请

US20080004417A1 Polycarbonates and method of preparing same 有权
标题翻译：聚碳酸酯及其制备方法
公开(公告)号：US20080004417A1
公开(公告)日：2008-01-03
申请号：US11427861
申请日：2006-06-30
申请人： Bernd Jansen , Jan Henk Kamps , Edward Kung , Patrick Joseph McCloskey , Paul Michael Smigelski
发明人： Bernd Jansen , Jan Henk Kamps , Edward Kung , Patrick Joseph McCloskey , Paul Michael Smigelski
IPC分类号： C08G64/00
CPC分类号： C08G64/307 , C08G64/04
摘要： Polycarbonates incorporating terminal carbonate groups derived from ester-substituted activated carbonates, for example terminal methyl salicyl carbonate (TMSC) derived from the use of BMSC as the activated carbonate in a transesterification process, have unfavorable properties with respect to color, hydrolytic stability and thermal stability, particularly when the polycarbonate containing such end groups is molded. The number of activated carbonate end groups formed during the melt transesterification formation of polycarbonate can be reduced, however, without sacrificing the benefits of using an activated diaryl carbonate, and without requiring a separate reaction or additional additives by reacting a dihydroxy compound with an activated diaryl carbonate in the presence of an esterification catalyst to produce a polycarbonate, wherein the molar ratio of activated diaryl carbonate to dihydroxy compound is less than 1 when expressed to at least three decimal places, for example 0.996 or less.
摘要翻译：由酯取代的活性碳酸酯衍生的末端碳酸酯基团的聚碳酸酯，例如在酯交换法中使用BMSC作为活性碳酸酯的末端甲基水杨酸碳酸酯（TMSC）在颜色，水解稳定性和热稳定性方面具有不利的性质特别是当含有这种端基的聚碳酸酯被模制时。然而，在聚碳酸酯的熔融酯交换形成期间形成的活化碳酸酯端基的数量可以降低，但不会牺牲使用活性碳酸二芳基酯的优点，并且不需要单独的反应或另外的添加剂，通过使二羟基化合物与活化的二芳基在酯化催化剂存在下制备碳酸酯以制备聚碳酸酯，其中活化的碳酸二芳酯与二羟基化合物的摩尔比当表示至少三位小数，例如0.996或更小时小于1。

5. 发明申请

US20080004418A1 Method of Preparing Polycarbonate 有权
标题翻译：聚碳酸酯的制备方法
公开(公告)号：US20080004418A1
公开(公告)日：2008-01-03
申请号：US11427885
申请日：2006-06-30
申请人： Bernd Jansen , Jan Henk Kamps , Edward Kung , Patrick Joseph McCloskey , Paul Michael Smigelski
发明人： Bernd Jansen , Jan Henk Kamps , Edward Kung , Patrick Joseph McCloskey , Paul Michael Smigelski
IPC分类号： C08G64/00
CPC分类号： C08G64/14 , C08G64/307
摘要： Polycarbonates incorporating terminal carbonate groups derived from ester-substituted activated carbonates in a transesterification process have unfavorable properties with respect to color, hydrolytic stability and thermal stability, particularly when the polycarbonate containing such end groups is molded. The number of activated carbonate end groups formed during the melt transesterification formation of polycarbonate can be reduced by reacting a dihydroxy compound with an activated diaryl carbonate in the presence of an esterification catalyst to produce a polycarbonate, in the presence of a monohydroxy chainstopper such as para-cumyl phenol in an amount that results in 35 to 65 mol % of the end groups being derived from the monohydroxy chainstopper. Suitably, the reactants are provided such that the molar ratio of activated diaryl carbonate to the total of dihydroxy compound plus ½ the chainstopping reagent that is less than 1.
摘要翻译：在酯交换方法中，衍生自酯取代的活性碳酸酯的末端碳酸酯基团的聚碳酸酯在颜色，水解稳定性和热稳定性方面具有不利的性质，特别是当含有这样的端基的聚碳酸酯被成型时。在聚碳酸酯的熔融酯交换形成期间形成的活化碳酸酯端基的数量可以通过在酯化催化剂的存在下使二羟基化合物与活化的碳酸二芳基酯反应来制备聚碳酸酯，在单羟基链断裂剂例如对 - 辛基苯酚，其量导致35-65mol％端基衍生自单羟基链断裂剂。适当地，提供反应物使得活化的碳酸二芳基酯与二羟基化合物的总和加上1/2的阻滞剂的摩尔比小于1。

6. 发明授权

US07731866B2 2,5-linked polyfluorenes for optoelectronic devices 有权
标题翻译：用于光电器件的2,5-连接聚芴
公开(公告)号：US07731866B2
公开(公告)日：2010-06-08
申请号：US12250826
申请日：2008-10-14
申请人： James Anthony Cella , Joseph John Shiang , Elliott West Shanklin , Paul Michael Smigelski
发明人： James Anthony Cella , Joseph John Shiang , Elliott West Shanklin , Paul Michael Smigelski
IPC分类号： C08G79/08 , C08G61/00 , C09K11/06 , H01J1/63 , H01J63/04
CPC分类号： C08G61/02 , C08G61/12 , C08G2261/3142 , C08G2261/3162 , Y10S428/917
摘要： Polyfluorene polymers and copolymers having substantial amounts (10-100%) of fluorenes coupled at the 2 and 5 positions of fluorene are useful as active layers in OLED devices where triplet energies >2.10 eV are required.
摘要翻译：在芴的2和5位上具有大量（10-100％）芴的聚芴聚合物和共聚物可用作需要三元组能量> 2.10eV的OLED器件中的有源层。

7. 发明授权

US07635792B1 2,5-linked polyfluorenes for optoelectronic devices 有权
标题翻译：用于光电器件的2,5-连接聚芴
公开(公告)号：US07635792B1
公开(公告)日：2009-12-22
申请号：US12250807
申请日：2008-10-14
申请人： James Anthony Cella , Joseph John Shiang , Elliott West Shanklin , Paul Michael Smigelski
发明人： James Anthony Cella , Joseph John Shiang , Elliott West Shanklin , Paul Michael Smigelski
IPC分类号： C07C22/00
CPC分类号： C07F5/025 , C07C39/42 , C07C43/225 , C07C2603/18 , C07D295/088 , C09K11/06 , C09K2211/1416 , C09K2211/1425 , H05B33/14
摘要： Polyfluorene polymers and copolymers having substantial amounts (10-100%) of fluorenes coupled at the 2 and 5 positions of fluorene are useful as active layers in OLED devices where triplet energies >2.10 eV are required.
摘要翻译：在芴的2和5位上具有大量（10-100％）芴的聚芴聚合物和共聚物可用作需要三元组能量> 2.10eV的OLED器件中的有源层。

8. 发明授权

US07480977B2 Method of replacing slot armor and slot liners in a generator rotor 失效
标题翻译：更换发电机转子中的槽铠装和槽衬的方法
公开(公告)号：US07480977B2
公开(公告)日：2009-01-27
申请号：US11639244
申请日：2006-12-15
申请人： Paul Michael Smigelski
发明人： Paul Michael Smigelski
IPC分类号： H02K15/09
CPC分类号： H02K3/48 , H02K3/345 , Y10T29/49012 , Y10T29/49716
摘要： A method of replacing slot armor and slot liners in radial slots of generator rotors comprising: (a) removing a winding from respective radial slots in the generator rotor; (b) removing existing slot armors and slot liners from each of the radial slots in the generator rotor; (c) installing a pair of L-shaped slot armor components in each radial slot, each L-shaped armor component constructed of a powder-coated metal; and (d) installing a winding in the radial slots, wherein the L-shaped slot armor components substantially fill any space between the winding and adjacent walls of the radial slots.
摘要翻译：一种在发电机转子的径向槽中更换槽铠装和槽衬的方法，包括：（a）从发电机转子中相应的径向槽中取出绕组; （b）从发电机转子中的每个径向槽中移除现有的槽铠装和槽衬; （c）在每个径向槽中安装一对L形槽装甲部件，每个由粉末涂覆的金属构成的L形装甲部件; 以及（d）在所述径向槽中安装绕组，其中所述L形槽装甲部件基本上填充所述径向狭槽的绕组和相邻壁之间的任何空间。

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