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1. 发明申请

US20080004407A1 Method for Making Molded Polycarbonate Articles with Improved Color 有权
标题翻译：制造具有改进颜色的模制聚碳酸酯制品的方法
公开(公告)号：US20080004407A1
公开(公告)日：2008-01-03
申请号：US11688533
申请日：2007-03-20
申请人： Sjef Berndsen , Hans-Peter Brack , Bernd Jansen , Jan Henk Kamps , Edward Kung , Daniel Lowery , Patrick Joseph McCloskey , Paul Michael Smigelski , Dennis Willemse
发明人： Sjef Berndsen , Hans-Peter Brack , Bernd Jansen , Jan Henk Kamps , Edward Kung , Daniel Lowery , Patrick Joseph McCloskey , Paul Michael Smigelski , Dennis Willemse
IPC分类号： C08G64/14 , C08G65/48
CPC分类号： C08G64/307 , C08G64/14
摘要： A method for preparing a molded article includes the steps of (a) obtaining a polycarbonate resin and (b) molding the polycarbonate resin. The polycarbonate resin is made by a transesterification reaction using an activated diaryl carbonate such that the polycarbonate is susceptible to the formation of internal ester linkages (IEL). The method occurs with the proviso that the polycarbonate resin, the molding conditions or both are selected to control the amount of IEL formed during the molding process to a level of less than 0.4 mol %.
摘要翻译：制备模塑制品的方法包括以下步骤：（a）获得聚碳酸酯树脂和（b）模塑聚碳酸酯树脂。聚碳酸酯树脂通过使用活化的碳酸二芳基酯的酯交换反应制备，使得聚碳酸酯容易形成内部酯键（IEL）。该方法发生，条件是选择聚碳酸酯树脂，成型条件或两者以控制在模制过程中形成的IEL的量至小于0.4mol％的水平。

2. 发明授权

US06500914B1 Method for end-capping polycarbonate resins and composition for use in same 有权
标题翻译：封端聚碳酸酯树脂的方法及其组合物
公开(公告)号：US06500914B1
公开(公告)日：2002-12-31
申请号：US09682724
申请日：2001-10-10
申请人： Hans Peter Brack , James Anthony Cella , Dennis Karlik , Paul Michael Smigelski, Jr.
发明人： Hans Peter Brack , James Anthony Cella , Dennis Karlik , Paul Michael Smigelski, Jr.
IPC分类号： C08G6400
CPC分类号： C08G64/14 , C08G64/42
摘要： A method for end-capping polycarbonate resins, comprising the step of processing a mixture comprising a polycarbonate having free hydroxyl-end groups and an end-capping reagent in a melt transesterification reaction to produce a polycarbonate resin, wherein the end-capping reagent comprises a mixture of:(a) at least one species of a symmetrical activated aromatic carbonate, and (b) at least one species of a symmetrical non-activated aromatic carbonate, whereby said end-capping reagent reacts with at least some of the free hydroxyl end-groups of the polycarbonate to produce an end-capped polycarbonate resin.
摘要翻译：一种封端聚碳酸酯树脂的方法，包括在熔融酯交换反应中处理包含游离羟基端基的聚碳酸酯和封端剂的混合物以制备聚碳酸酯树脂的步骤，其中封端剂包括混合物：（a）至少一种对称活性芳族碳酸酯，和（b）至少一种对称非活化芳族碳酸酯，其中所述封端剂与至少一些游离羟基末端反应的聚碳酸酯组，以制备端封聚碳酸酯树脂。

3. 发明授权

US06252035B1 Salts of chelating agents as polymerization catalysts 失效
标题翻译：螯合剂的盐作为聚合催化剂
公开(公告)号：US06252035B1
公开(公告)日：2001-06-26
申请号：US09451033
申请日：1999-11-29
申请人： Patrick Joseph McCloskey , Timothy Brydon Burnell , Paul Michael Smigelski, Jr.
发明人： Patrick Joseph McCloskey , Timothy Brydon Burnell , Paul Michael Smigelski, Jr.
IPC分类号： C08G6400
CPC分类号： C08G64/307
摘要： The present invention relates to a method for the preparation of polycarbonate comprising preparing a polycarbonate by a melt process by reacting a diphenol and a diaryl carbonate in the presence of a catalytically effective amount of one or more alkali and or alkali earth metal salts of chelating agents. Suitable chelating agents include nitrilotriacetate and EDTA.
摘要翻译：本发明涉及一种制备聚碳酸酯的方法，包括通过使催化有效量的一种或多种螯合剂的碱金属和/或碱土金属盐存在下使二酚和碳酸二芳基酯通过熔融法制备聚碳酸酯。合适的螯合剂包括次氮基三乙酸钠和EDTA。

4. 发明授权

US06252013B1 Method for making siloxane copolycarbonates 有权
标题翻译：制备硅氧烷共聚碳酸酯的方法
公开(公告)号：US06252013B1
公开(公告)日：2001-06-26
申请号：US09483959
申请日：2000-01-18
申请人： Timothy Edward Banach , Gary Charles Davis , Paul Michael Smigelski, Jr. , Patrick Joseph McCloskey
发明人： Timothy Edward Banach , Gary Charles Davis , Paul Michael Smigelski, Jr. , Patrick Joseph McCloskey
IPC分类号： C08F446
CPC分类号： C08G64/186 , C08G77/448
摘要： A melt condensation polymerization process for preparing siloxane copolycarbonates is provided. The process includes reacting an aromatic dihydroxy compound, carbonic acid diester, hydroxyaryl terminated polydiorganosiloxane and catalyst with a salt.
摘要翻译：提供了制备硅氧烷共聚碳酸酯的熔融缩聚方法。该方法包括使芳族二羟基化合物，碳酸二酯，羟基芳基封端的聚二有机硅氧烷和催化剂与盐反应。

5. 发明申请

US20120267574A1 MATERIALS FOR OPTOELECTRONIC DEVICES 有权
标题翻译：光电器件材料
公开(公告)号：US20120267574A1
公开(公告)日：2012-10-25
申请号：US13093038
申请日：2011-04-25
申请人： Joseph John Shiang , Paul Michael Smigelski, JR.
发明人： Joseph John Shiang , Paul Michael Smigelski, JR.
IPC分类号： C09K11/06 , C08G75/32 , C07C43/205 , C08G79/00
CPC分类号： C08G61/123 , C08G2261/12 , C08G2261/3142 , C08G2261/3246 , C08G2261/3247 , C08G2261/411 , C08G2261/95 , C08K5/0091 , H01L51/0039 , H01L51/0043 , H01L51/5012 , H01L51/5016 , Y10S428/917 , C08L65/00
摘要： Energy efficient optoelectronic devices include an electroluminescent layer containing a polymer made up of structural units of formula I and II; whereinR1 and R2 are independently C22-44 hydrocarbyl, C22-44 hydrocarbyl containing one or more S, N, O, P, or Si atoms, oxaalkylaryl, or a combination thereof; R3 and R4 are independently H, C1-44 hydrocarbyl or C1-44 hydrocarbyl containing one or more S, N, O, P, or Si atoms, or R3 and R4, taken together, form a C2-10 monocyclic or bicyclic ring containing up to three S, N, O, P, or Si heteroatoms; and X is S, Se, or a combination thereof.
摘要翻译：能量效率的光电器件包括含有由式I和II的结构单元构成的聚合物的电致发光层; 其中R1和R2独立地为C22-44烃基，含有一个或多个S，N，O，P或Si原子的C22-44烃基，氧杂烷基芳基或其组合; R 3和R 4独立地是H，C 1-4烃基或含有一个或多个S，N，O，P或Si原子的C 1-4烃基，或者R 3和R 4一起形成含有C 1-10的单环或双环最多三个S，N，O，P或Si杂原子; X是S，Se或它们的组合。

6. 再颁专利

USRE40697E1 Method for making an aromatic polycarbonate 有权
标题翻译：制备芳族聚碳酸酯的方法
公开(公告)号：USRE40697E1
公开(公告)日：2009-04-07
申请号：US11345691
申请日：2006-01-31
申请人： Norberto Silvi , Mark Howard Giammattei , Patrick Joseph McCloskey , Alberto Nisoli , James Day , Narayan Ramesh , Paul Michael Smigelski, Jr. , Paul Russell Wilson
发明人： Norberto Silvi , Mark Howard Giammattei , Patrick Joseph McCloskey , Alberto Nisoli , James Day , Narayan Ramesh , Paul Michael Smigelski, Jr. , Paul Russell Wilson
IPC分类号： C08G64/00
CPC分类号： B29C47/0004 , B29C47/0009 , B29C47/60 , B29C47/76 , B29C47/767 , B29C67/246 , B29K2069/00 , C08G64/081 , C08G64/14 , C08G64/205 , C08G64/307
摘要： This invention relates to an extrusion method preparing polycarbonates from a solution of an oligomeric polycarbonate. A mixture of bis(methyl salicyl)carbonate (BMSC), BPA and a transesterification catalyst are first equilibrated at moderate temperatures to provide a solution of polycarbonate oligomer in methyl salicylate. The solution is then fed to a devolatilizing extruder, where the polymerization reaction is completed and the methyl salicylate solvent is removed. The solution comprising the oligomeric polycarbonate can also be pre-heated under pressure to a temperature above the boiling point of methyl salicylate and subsequently fed to a devolatilizing extruder equipped for rapid flashing off the solvent. The method provides polycarbonate with greater efficiency than the corresponding process in which unreacted monomers are fed to the extruder. Additionally, the method of the invention does not require the isolation of a precursor polycarbonate comprising ester-substituted phenoxy terminal groups.
摘要翻译：本发明涉及从低聚聚碳酸酯溶液制备聚碳酸酯的挤压方法。首先在中等温度下平衡双（甲基水杨酸）碳酸酯（BMSC），BPA和酯交换催化剂的混合物，以提供聚碳酸酯低聚物在水杨酸甲酯中的溶液。然后将溶液进料到脱挥发分挤出机中，其中聚合反应完成并除去水杨酸甲酯溶剂。包含低聚物聚碳酸酯的溶液也可以在压力下预加热到高于水杨酸甲酯沸点的温度，随后进料到脱挥发分的挤出机中，以便迅速地从溶剂中闪蒸。该方法提供聚碳酸酯比未反应的单体进料到挤出机的相应方法具有更高的效率。另外，本发明的方法不需要分离包含酯取代的苯氧基末端基团的前体聚碳酸酯。

7. 发明授权

US07482423B2 Polycarbonates and method of preparing same 有权
标题翻译：聚碳酸酯及其制备方法
公开(公告)号：US07482423B2
公开(公告)日：2009-01-27
申请号：US11427861
申请日：2006-06-30
申请人： Bernd Jansen , Jan Henk Kamps , Edward Kung , Patrick Joseph McCloskey , Paul Michael Smigelski, Jr.
发明人： Bernd Jansen , Jan Henk Kamps , Edward Kung , Patrick Joseph McCloskey , Paul Michael Smigelski, Jr.
IPC分类号： C08G64/00 , C08G63/02
CPC分类号： C08G64/307 , C08G64/04
摘要： Polycarbonates incorporating terminal carbonate groups derived from ester-substituted activated carbonates, for example terminal methyl salicyl carbonate (TMSC) derived from the use of BMSC as the activated carbonate in a transesterification process, have unfavorable properties with respect to color, hydrolytic stability and thermal stability, particularly when the polycarbonate containing such end groups is molded. The number of activated carbonate end groups formed during the melt transesterification formation of polycarbonate can be reduced, however, without sacrificing the benefits of using an activated diaryl carbonate, and without requiring a separate reaction or additional additives by reacting a dihydroxy compound with an activated diaryl carbonate in the presence of an esterification catalyst to produce a polycarbonate, wherein the molar ratio of activated diaryl carbonate to dihydroxy compound is less than 1 when expressed to at least three decimal places, for example 0.996 or less.
摘要翻译：由酯取代的活性碳酸酯衍生的末端碳酸酯基团的聚碳酸酯，例如在酯交换法中使用BMSC作为活性碳酸酯的末端甲基水杨酸碳酸酯（TMSC）在颜色，水解稳定性和热稳定性方面具有不利的性质特别是当含有这种端基的聚碳酸酯被模制时。然而，在聚碳酸酯的熔融酯交换形成期间形成的活化碳酸酯端基的数量可以降低，但不会牺牲使用活性碳酸二芳基酯的优点，并且不需要单独的反应或另外的添加剂，通过使二羟基化合物与活化的二芳基在酯化催化剂存在下制备碳酸酯以制备聚碳酸酯，其中活化的碳酸二芳酯与二羟基化合物的摩尔比当表示至少三位小数，例如0.996或更小时小于1。

8. 发明授权

US07294657B2 Curable acrylate compositions, methods of making the compositions and articles made therefrom 失效
标题翻译：可固化丙烯酸酯组合物，由其制备的组合物和制品的方法
公开(公告)号：US07294657B2
公开(公告)日：2007-11-13
申请号：US11074272
申请日：2005-03-07
申请人： Daniel Robert Olson , Dennis Joseph Coyle , Christian Andrew Huntley , Bret Ja Chisholm , Paul Michael Smigelski, Jr. , Alvin Un-Teh Chen
发明人： Daniel Robert Olson , Dennis Joseph Coyle , Christian Andrew Huntley , Bret Ja Chisholm , Paul Michael Smigelski, Jr. , Alvin Un-Teh Chen
IPC分类号： C08F12/30 , G02B5/00 , G02B1/10
CPC分类号： C09D133/14 , Y10T428/31855
摘要： A composition comprising a phenylthioethylacrylate, a multifunctional (meth)acrylate, a curing agent, wherein the phenylthioethylacrylate comprises less than about 400 parts per million tin and less than about 2 percent by weight of the corresponding phenylthioethanol. The composition may further comprise at least one unsaturated acid.
摘要翻译：包含苯基硫代乙基丙烯酸酯，多官能（甲基）丙烯酸酯，固化剂的组合物，其中所述苯基硫代乙基丙烯酸酯包含小于约400ppm，小于约2重量％的相应的苯基硫代乙醇。该组合物还可以包含至少一种不饱和酸。

9. 发明授权

US06600004B1 Method of preparing polyestercarbonates 有权
标题翻译：聚碳酸酯的制备方法
公开(公告)号：US06600004B1
公开(公告)日：2003-07-29
申请号：US10118634
申请日：2002-04-10
申请人： Patrick Joseph McCloskey , Paul Michael Smigelski
发明人： Patrick Joseph McCloskey , Paul Michael Smigelski
IPC分类号： C08G6400
CPC分类号： C08G63/64
摘要： A method of preparing polyestercarbonates is presented in which a mixture of at least one activated diaryl carbonate is reacted under melt polymerization conditions with at least one aromatic dihydroxy compound together with at least one dicarboxylic acid. Polyestercarbonates possessing up to about percent 10 mole dicarboxylic acid residues based on the total amount of structural units derived from aromatic dihydroxy compounds are obtained. The method provides both for high levels of incorporation of the dicarboxylic acid into the polyestercarbonate backbone and a high level of polymer endcapping.
摘要翻译：提出了一种制备聚酯碳酸酯的方法，其中至少一种活化的碳酸二芳基酯的混合物在熔融聚合条件下与至少一种芳族二羟基化合物与至少一种二羧酸一起反应。得到基于衍生自芳族二羟基化合物的结构单元的总量，具有高达约10摩尔二羧酸残基的聚酯碳酸酯。该方法既提供高水平的二羧酸结合到聚酯碳酸酯骨架中，也提供高水平的聚合物封端。

10. 发明授权

US06548623B2 Method of polycarbonate preparation 有权
标题翻译：聚碳酸酯制备方法
公开(公告)号：US06548623B2
公开(公告)日：2003-04-15
申请号：US09911443
申请日：2001-07-24
申请人： Daniel Joseph Brunelle , Patrick Joseph McCloskey , Paul Michael Smigelski, Jr. , Timothy Brydon Burnell , Ganesh Kailasam
发明人： Daniel Joseph Brunelle , Patrick Joseph McCloskey , Paul Michael Smigelski, Jr. , Timothy Brydon Burnell , Ganesh Kailasam
IPC分类号： C08G6400
CPC分类号： C08G64/06 , C08G64/04 , C08G64/14 , C08G64/307
摘要： Polycarbonates containing low or undetectable levels of Fries rearrangement product may be prepared by the melt reaction of a dihydroxy aromatic compound such as bisphenol A with an ester-substituted diaryl carbonate such as the diaryl carbonate of methyl salicylate, bis-methyl salicyl carbonate. Low levels of Fries product are obtained as the combined result of a highly effective catalyst system which suppresses the Fries reaction and the use of lower melt polymerization temperatures relative to temperatures required for the analogous polymerization reaction using diphenyl carbonate.
摘要翻译：含有低或不可检测水平的Fries重排产物的聚碳酸酯可以通过二羟基芳族化合物如双酚A与酯取代的二芳基碳酸酯例如水杨酸甲酯的碳酸二芳基酯，碳酸双甲基酯的熔融反应来制备。通过抑制Fries反应的高效催化剂体系和相对于使用碳酸二苯酯的类似聚合反应所需的温度使用较低熔融聚合温度的综合结果，可以获得低水平的油炸产品。

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