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    • 5. 发明授权
    • Apparatus for improving film stability of halogen-doped silicon oxide films
    • 用于提高卤素掺杂氧化硅膜的膜稳定性的装置
    • US06374770B1
    • 2002-04-23
    • US09597856
    • 2000-06-20
    • Peter W. LeeStuardo RoblesAnand GuptaVirendra V. S. RanaAmrita Verma
    • Peter W. LeeStuardo RoblesAnand GuptaVirendra V. S. RanaAmrita Verma
    • C23C1600
    • H01L21/02131C23C16/401C23C16/56H01L21/02274H01L21/0234H01L21/02362H01L21/3105H01L21/31629
    • A chemical vapor deposition system that includes a housing configured to form a processing chamber, a substrate holder configured to hold a substrate within the processing chamber, a gas distribution system configured to introduce gases into the processing chamber, a plasma generation system configured to form a plasma within the processing chamber, a processor operatively coupled to control the gas distribution system and the plasma generation system, and a computer-readable memory coupled to the processor that stores a computer-readable program which directs the operation of the chemical vapor deposition system. In one embodiment the computer-readable program comprises instructions that control the gas distribution system to flow a process gas comprising silicon, oxygen and a halogen family member into the chamber to deposit a halogen-doped silicon oxide film on a substrate positioned on the substrate holder and instructions that control the gas distribution system and plasma generation system to densify the halogen-doped silicon oxide film by bombarding the film with ionic species from a plasma of an argon-containing gas source. In another embodiment, the computer-readable program comprises instructions that control the gas distribution system to flow a process gas comprising silicon, oxygen and a halogen family member into the chamber to deposit a halogen-doped silicon oxide film on said substrate and instructions that control the gas distribution system and plasma generation system to form a plasma from a hydrogen containing source gas to bombard the halogen-doped silicon oxide film with hydrogen ions to remove loosely bound halogen atoms from the film.
    • 一种化学气相沉积系统,其包括构造成形成处理室的壳体,被配置为在处理室内保持衬底的衬底保持器,配置成将气体引入到处理室中的气体分配系统;等离子体生成系统, 处理室内的等离子体,可操作地耦合以控制气体分配系统和等离子体生成系统的处理器以及耦合到处理器的计算机可读存储器,其存储引导化学气相沉积系统的操作的计算机可读程序。 在一个实施例中,计算机可读程序包括控制气体分配系统以将包含硅,氧和卤素族成员的工艺气体流入室中的指令,以将沉积卤素掺杂的氧化硅膜沉积在位于衬底保持器 以及控制气体分配系统和等离子体发生系统通过用来自含氩气体源的等离子体的离子物质轰击膜来致密化掺杂氧化硅膜的指令。 在另一个实施例中,计算机可读程序包括控制气体分配系统以使包含硅,氧和卤素族成员的工艺气体流入腔室中以在所述衬底上沉积卤素掺杂的氧化硅膜的指令,以及控制 气体分配系统和等离子体发生系统,以形成来自含氢源气体的等离子体,用氢离子轰击卤素掺杂的氧化硅膜,以从薄膜中去除松散结合的卤素原子。
    • 6. 发明授权
    • Film to tie up loose fluorine in the chamber after a clean process
    • 在清洁过程之后,电影将室内的松散的氟结合起来
    • US06223685B1
    • 2001-05-01
    • US09452551
    • 1999-12-01
    • Anand GuptaMohan BhanSudhakar Subrahmanyam
    • Anand GuptaMohan BhanSudhakar Subrahmanyam
    • C23C1600
    • C23C14/564C23C16/4404C23C16/5096C23C16/52H01J37/32477H01J37/32862H01L21/02131H01L21/02164H01L21/02274H01L21/31612Y10S438/905
    • An improved method of reducing the level of contaminants (e.g., fluorine) absorbed in films deposited within a substrate processing chamber. A seasoning layer is deposited within the substrate processing chamber to cover contaminants that may be absorbed within walls or insulation areas of the chamber interior. The deposited seasoning layer is more stable than prior art seasoning layers and is thus less likely to release the absorbed contaminants into the substrate processing chamber during the subsequent deposition of films. In a preferred embodiment, the seasoning layer is formed from a mixed frequency PECVD process in which the low frequency RF signal is supplied at a high power level to increase ion bombardment and enhance film stability. The increased bombardment favors the formation of stable SiF bonds between silicon and fluorine atoms in the lattice structure of the film rather than unstable SiF2 or other bonds. When residual fluorine atoms (e.g., fluorine atoms absorbed within the chamber walls) are incorporated into the deposited seasoning layer, fewer loosely bonded fluorine atoms are incorporated into the layer than in prior art silicon oxide seasoning layers. Fewer loosely bonded fluorine atoms in the seasoning film results in fewer contaminants being incorporated into films deposited over substrates in subsequent processing steps.
    • 一种降低在衬底处理室内沉积的膜中吸收的污染物(例如氟)的水平的改进​​方法。 在基材处理室内沉积调味料层以覆盖可能被吸收在室内部的壁或绝缘区域内的污染物。 沉积的调味剂层比现有技术的调味料层更稳定,因此在随后的膜沉积期间不太可能将吸收的污染物释放到基材处理室中。 在优选实施例中,调味层由混合频率PECVD工艺形成,其中以高功率水平提供低频RF信号以增加离子轰击并提高膜的稳定性。 增加的轰击有利于在膜的晶格结构中硅和氟原子之间形成稳定的SiF键,而不是不稳定的SiF 2或其它键。 当剩余的氟原子(例如在室壁内吸收的氟原子)被并入沉积的调味层中时,与现有技术的氧化硅调味层相比,较少的松散键合的氟原子被掺入到该层中。 在调味膜中较少松散粘合的氟原子导致在随后的加工步骤中将沉积在基材上的薄膜中的污染物掺入较少。