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1. 发明授权

US6126912A Process and catalyst comprising at least one EU-1 and/or NU-86 and/or NU-87 zeolite for reducing oxides of nitrogen in an oxidizing medium 失效
标题翻译：包含至少一种用于还原氧化介质中的氮氧化物的EU-1和/或NU-86和/或NU-87沸石的方法和催化剂
公开(公告)号：US6126912A
公开(公告)日：2000-10-03
申请号：US222298
申请日：1998-12-28
申请人： Patrick Bourges , Gil Mabilon , Matthias Bouchez , Sylvie Lacombe
发明人： Patrick Bourges , Gil Mabilon , Matthias Bouchez , Sylvie Lacombe
IPC分类号： B01D53/86 , B01D53/94 , B01J29/40 , B01J29/44 , B01J29/70 , B01J29/72 , B01J29/74 , B01J29/76 , B01J29/78 , B01J8/00 , B01J29/06 , B01J21/00 , C01B21/00
CPC分类号： B01J29/7023 , B01D53/8628 , B01D53/9418 , B01J29/70 , B01J29/74 , B01J29/7446 , B01J29/76 , B01J29/7646 , B01D2251/202 , B01D2251/204 , B01D2251/208 , B01D2251/21 , B01D2255/1021 , B01D2255/2063 , B01D2255/20761 , B01D2255/504 , B01D2258/012 , B01J29/40 , B01J29/405 , B01J29/44 , Y02C20/10 , Y02C20/20 , Y02T10/24
摘要： The present invention provides a process for reducing oxides of nitrogen to molecular nitrogen in a medium which is superstoichiometric in oxidizing agent using reducing agents in the presence of a catalyst comprising:at least one refractory inorganic oxide at least in part constituted by a zeolite from the group formed by NU-86, NU-87 and EU-1;optionally, at least one element (A) from groups VIB, VIIB, VIII and IB, the transition metals;optionally, at least one element (B) from group VIII, the noble metals comprising platinum, rhodium, ruthenium, iridium and palladium;and optionally at least one element (C) from group IIA, the alkaline-earths and/or group IIIB, the rare earths.The invention also provides a catalyst comprising at least one refractory inorganic oxide at least in part constituted by at least one zeolite from the group formed by NU-86, NU-87 and EU-1 and at least one element selected from the group formed by elements from groups VIB, VIIB, VIII and IB, the transition metals, and from noble group VIII metals. The invention also concerns the preparation of the catalyst.
摘要翻译：本发明提供了一种在催化剂存在下，使用还原剂在氧化剂中将超氧化物计氮还原成分子氮的方法，所述催化剂包括：至少一种耐火无机氧化物，其至少部分由来自由NU-86，NU-87和EU-1形成的组; 任选地，来自VIB族，VIIB族，VIII族和IB族的至少一种元素（A），过渡金属; 任选地，来自VIII族的至少一种元素（B），贵金属包括铂，铑，钌，铱和钯; 和任选的至少一种元素（C），来自IIA族，碱土金属和/或IIIB族，稀土元素。本发明还提供一种催化剂，其至少部分由至少一种由NU-86，NU-87和EU-1形成的基团的沸石构成的难熔性无机氧化物和至少一种选自由 VIB族，VIIB族，VIII族和IB族的元素，过渡金属和贵金属VIII族金属。本发明还涉及催化剂的制备。

2. 发明授权

US06217838B1 Process for reducing emissions of oxides of nitrogen in a medium which is super-stoichiometric in oxidizing agents 失效
标题翻译：在氧化剂中超化学计量的介质中减少氮氧化物排放的方法
公开(公告)号：US06217838B1
公开(公告)日：2001-04-17
申请号：US09415236
申请日：1999-10-12
申请人： Patrick Bourges , Mathias Bouchez , Gil Mabilon , Brigitte Martin
发明人： Patrick Bourges , Mathias Bouchez , Gil Mabilon , Brigitte Martin
IPC分类号： B01J800
CPC分类号： B01D53/9418 , B01D53/8628 , B01D2251/21 , B01D2255/1021 , B01D2255/20761 , B01D2255/50 , Y02A50/2325 , Y02C20/10 , Y02C20/20
摘要： The invention concerns a process for reducing emissions of oxides of nitrogen in a medium which is super-stoichiomeitric in oxidising agents, comprising: a) a step for oxidising at least a portion of the oxides of nitrogen in the presence of an oxidation material; b) a step for injecting organic compounds which comprise at least one atom selected from carbon, hydrogen, oxygen and nitrogen; c) a step for adsorbing at least a portion of the organic compounds onto an adsorption material in the form of molecular species and/or carbonaceous residues; d) a step for selective reduction of at least a portion of the oxides of nitrogen to molecular nitrogen by at least a portion of the molecular species and/or carbonaceous residues formed on the adsorption material.
摘要翻译：本发明涉及一种减少氧化剂中超化学计量的介质中氮氧化物排放的方法，包括：a）在氧化物质存在下氧化至少一部分氮氧化物的步骤; b ）用于注入包含至少一个选自碳，氢，氧和氮的原子的有机化合物的步骤; c）将至少一部分有机化合物以分子种类和/或形式吸附到吸附材料上的步骤碳质残渣; d）通过在吸附材料上形成的分子种类和/或碳质残渣的至少一部分，将至少一部分氮氧化物选择还原成分子氮的步骤。

3. 发明授权

US06508057B1 Process and device intended for nitrogen oxides elimination in an exhaust line of an internal-combustion engine 有权
标题翻译：用于在内燃机的排气管线中消除氮氧化物的方法和装置
公开(公告)号：US06508057B1
公开(公告)日：2003-01-21
申请号：US09457260
申请日：1999-12-09
申请人： Mathias Bouchez , Gil Mabilon , Brigitte Martin , Patrick Bourges
发明人： Mathias Bouchez , Gil Mabilon , Brigitte Martin , Patrick Bourges
IPC分类号： F01N300
CPC分类号： F01N3/0842 , B01D53/9431 , F01N3/0814 , F01N3/0871 , F01N13/009 , F01N2610/03 , F02D2200/0806 , Y02C20/10 , Y02T10/24
摘要： A device for eliminating nitrogen oxides in an exhaust line of a lean-burn internal-combustion engine (1) a NOx trap (3) for trapping the nitrogen oxides, a system for regenerating the nitrogen oxides when the NOx trap is saturated, a hydrocarbon treating catalyst (2) placed upstream from the NOx trap (3), a hydrocarbon injector (4) placed upstream from hydrocarbon treating catalyst (2), a probe (7) for measuring the gas mixture strength. The hydrocarbon treating catalyst (2) is a partial (or controlled) hydrocarbon oxidation catalyst that cooperates with the NOx trap (3) for trapping the nitrogen oxides and that allows to obtain, at the outlet thereof, gases with a low oxygen (O2) concentration and with high carbon monoxide (CO) and hydrogen (H2) concentrations. A control unit is furthermore provided for recording and processing data coming from various detectors and/or stored in order to carry out effective regeneration of the NOx trap (3) without disrupting the smooth running of the engine.
摘要翻译：一种用于消除稀燃内燃机（1）的排气管中的氮氧化物的装置，用于捕获氮氧化物的NOx捕集器（3），当NOx捕集器饱和时再生氮氧化物的系统，处理催化剂（2），放置在NOx捕集器（3）的上游，位于烃处理催化剂（2）上游的烃喷射器（4），用于测量气体混合物强度的探针（7）。烃处理催化剂（2）是与NOx捕集器（3）配合以捕获氮氧化物的部分（或受控）烃氧化催化剂，并且允许在出口处获得具有低氧（O 2）浓度和高一氧化碳的气体 CO）和氢（H 2）浓度。此外还提供用于记录和处理来自各种检测器和/或存储的数据的控制单元，以便在不中断e的平稳运行的情况下进行NOx捕集器（3）的有效再生 ngine。

4. 发明授权

US07588678B2 Hydrocracking process with recycle, comprising adsorption of polyaromatic compounds from the recycled fraction on an absorbant based on silica-alumina with a limited macropore content 有权
$Hydrocracking process with recycle, comprising adsorption of polyaromatic compounds from the recycled fraction on an absorbant based on silica-alumina with a limited macropore content$
标题翻译：含有再循环的加氢裂化方法，包括从具有有限大孔含量的二氧化硅 - 氧化铝吸附剂上的回收级分吸附多芳族化合物
公开(公告)号：US07588678B2
公开(公告)日：2009-09-15
申请号：US11370186
申请日：2006-03-08
申请人： Karin Barthelet , Patrick Euzen , Hugues Dulot , Patrick Bourges
发明人： Karin Barthelet , Patrick Euzen , Hugues Dulot , Patrick Bourges
IPC分类号： C10G47/02
CPC分类号： C10G67/06 , C10G25/003 , C10G2300/201 , C10G2300/4081 , C10G2300/4093
摘要： The invention concerns an improved hydrocracking process having a step for eliminating polyaromatic compounds from at least a portion of a recycled fraction by adsorption on a particular adsorbent based on alumina-silica with a limited macropore content.
摘要翻译：本发明涉及一种改进的加氢裂化方法，其具有通过在具有有限的大孔含量的氧化铝 - 二氧化硅的特定吸附剂上吸附来从至少一部分循环级分消除多芳族化合物的步骤。

5. 发明授权

US07270738B2 Catalyst and process for hydrocracking hydrocarbon-containing feedstocks 有权
标题翻译：用于加氢裂化含烃原料的催化剂和方法
公开(公告)号：US07270738B2
公开(公告)日：2007-09-18
申请号：US10696561
申请日：2003-10-30
申请人： Patrick Euzen , Carole Bobin , Magalie Roy-Auberger , Eric Benazzi , Patrick Bourges , Christophe Gueret
发明人： Patrick Euzen , Carole Bobin , Magalie Roy-Auberger , Eric Benazzi , Patrick Bourges , Christophe Gueret
IPC分类号： C01G47/00 , C01G45/00 , C01G17/00 , B01J23/00 , B01J21/00
CPC分类号： B01J35/10 , B01J21/12 , B01J23/24 , B01J23/42 , B01J23/74 , B01J23/85 , B01J23/888 , B01J35/002 , B01J35/1019 , B01J35/1038 , B01J35/1061 , B01J35/108 , B01J37/0009 , C10G47/12 , C10G47/14 , C10G47/16 , C10G47/20 , C10G65/12 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018 , C10G2300/70
摘要： This invention relates to silico-aluminum substrates, catalysts, and the hydrocracking and hydrotreatment processes that use them. The catalyst comprises at least one hydro-dehydrogenating element that is selected from the group that is formed by elements of group VIB and group VIII of the periodic table and a non-zeolitic silica-alumina-based substrate that contains an amount of more than 5% by weight and less than or equal to 95% by weight of silica (SiO2) and has the following characteristics: A mean pore diameter, measured by mercury porosimetry, encompassed between 20 and 140 Å, a total pore volume, measured by mercury porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a total pore volume, measured by nitrogen porosimetry, encompassed between 0.1 ml/g and 0.6 ml/g, a BET specific surface area encompassed between 100 and 550 m2/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 140 Å, of less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 160 Å, of less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 200 Å, of less than 0.1 ml/g, a pore volume, measured by mercury porosimetry, encompassed in the pores with diameters of more than 500 Å, of less than 0.01 ml/g, an X diffraction diagram contains at least the main lines that are characteristic of at least one of the transition aluminas contained in the group that consists of the alpha, rho, chi, eta, gamma, kappa, theta and delta aluminas.
摘要翻译：本发明涉及硅铝基板，催化剂以及使用它们的加氢裂化和加氢处理方法。该催化剂包含至少一种选自由元素周期表VIB族和VIII族的元素形成的基团和非沸石二氧化硅 - 氧化铝基底物的含氢量超过5的氢脱氢元件重量百分比和小于或等于95重量％的二氧化硅（SiO 2/2），并具有以下特征：通过水银孔率法测量的平均孔径包含在20和140之间，a 通过水银孔率法测量的总孔体积在0.1ml / g至0.6ml / g之间，通过氮气孔率法测量的总孔体积在0.1ml / g至0.6ml / g之间，包括在 100和550m 2 / g，通过水银孔率法测量的孔体积包含在直径大于140埃，小于0.1ml / g的孔中，孔体积由包含在直径大于160埃，小于0的孔中的水银孔率法。 1毫升/克，通过水银孔率测定法测量的孔体积，直径大于200埃，小于0.1毫升/克，通过水银孔率法测定的孔体积，包含在直径为大于500埃，小于0.01ml / g，X衍射图至少包含由α，rho，chi，eta等组成的组中包含的至少一种过渡氧化铝的特征的主线， γ，κ，θ和δ氧化铝。

6. 发明授权

US07025948B2 ITQ-31 crystalline solid, and a process for its preparation 失效
标题翻译： ITQ-31结晶固体及其制备方法
公开(公告)号：US07025948B2
公开(公告)日：2006-04-11
申请号：US11102879
申请日：2005-04-11
申请人： Eva Barea , Vicente Fornes , Avelino Corma , Patrick Bourges , Emmanuelle Guillon
发明人： Eva Barea , Vicente Fornes , Avelino Corma , Patrick Bourges , Emmanuelle Guillon
IPC分类号： C01B39/48
CPC分类号： C01B37/005 , C01B39/06
摘要： The invention concerns a crystalline solid, designated ITQ-31, which has the X ray diffraction diagram given below. Said solid has a chemical composition, expressed as the anhydrous base in terms of moles of oxide, defined by the general formula XO2: mYO2:pZ2O3:qR:sF, in which R represents an organic nitrogen-containing template, X represents one or more tetravalent elements other than germanium, Y represents germanium, Z represents at least one trivalent element and F is fluorine.
摘要翻译：本发明涉及一种称为ITQ-31的结晶固体，其具有以下给出的X射线衍射图。所述固体具有以通式XO 2定义的氧化物摩尔数表示为无水碱的化学组成：mYO 2：pZ 2 qR：sF，其中R表示有机含氮模板，X表示一种或多种除锗以外的四价元素，Y表示锗，Z表示至少一种三价元素 F是氟。

7. 发明申请

US20050244330A1 ITQ-31 crystalline solid, and a process for its preparation 失效
标题翻译： ITQ-31结晶固体及其制备方法
公开(公告)号：US20050244330A1
公开(公告)日：2005-11-03
申请号：US11102879
申请日：2005-04-11
申请人： Eva Barea , Vicente Fornes , Avelino Corma , Patrick Bourges , Emmanuelle Guillon
发明人： Eva Barea , Vicente Fornes , Avelino Corma , Patrick Bourges , Emmanuelle Guillon
IPC分类号： C01B39/46 , C01B37/00 , C01B39/06 , C01B39/48
CPC分类号： C01B37/005 , C01B39/06
摘要： The invention concerns a crystalline solid, designated ITQ-31, which has the X ray diffraction diagram given below. Said solid has a chemical composition, expressed as the anhydrous base in terms of moles of oxide, defined by the general formula XO2: mYO2:pZ2O3:qR:sF, in which R represents an organic nitrogen-containing template, X represents one or more tetravalent elements other than germanium, Y represents germanium, Z represents at least one trivalent element and F is fluorine.
摘要翻译：本发明涉及一种称为ITQ-31的结晶固体，其具有以下给出的X射线衍射图。所述固体具有以通式XO 2定义的氧化物摩尔数表示为无水碱的化学组成：mYO 2：pZ 2 qR：sF，其中R表示有机含氮模板，X表示一种或多种除锗以外的四价元素，Y表示锗，Z表示至少一种三价元素 F是氟。

8. 发明授权

US08821714B2 Catalyst based on a material with a hierarchical porosity comprising silicon, and a process for hydrocracking/hydroconversion and hydrotreatment of hydrocarbon feeds 有权
标题翻译：基于具有分层孔隙率的材料的催化剂，包括硅，以及用于烃进料的加氢裂化/加氢转化和加氢处理的方法
公开(公告)号：US08821714B2
公开(公告)日：2014-09-02
申请号：US12515862
申请日：2007-10-29
申请人： Alexandra Chaumonnot , Patrick Bourges
发明人： Alexandra Chaumonnot , Patrick Bourges
IPC分类号： C10G47/02
CPC分类号： C10G65/12 , B01J29/005 , B01J29/0308 , B01J29/041 , B01J29/06 , B01J29/072 , B01J29/076 , B01J29/084 , B01J29/126 , B01J29/146 , B01J29/166 , B01J29/40 , B01J29/46 , B01J29/48 , B01J35/023 , B01J37/0045 , B01J2229/20 , B01J2229/62 , C10G47/20 , C10G49/08
摘要： The invention describes a catalyst comprising at least one material with a hierarchical porosity comprising silicon and at least one hydrodehydrogenating element from group VIB and/or group VIII of the periodic table of the elements. Said material with a hierarchical porosity comprising silicon is constituted by at least two elementary spherical particles, each of said spherical particles comprising zeolitic nanocrystals having a pore size in the range 0.2 to 2 nm and a matrix based on silicon oxide, which is mesostructured, having a pore size in the range 1.5 to 30 nm and having amorphous walls with a thickness in the range 1 to 30 nm, said elementary spherical particles having a maximum diameter of 100 μm. The matrix based on silicon oxide may contain aluminum. The catalyst also optionally comprises at least one doping element in a controlled quantity selected from phosphorus, boron and silicon, optionally at least one element from group VB of the periodic table of the elements, and optionally an element from group VIIA. The invention also concerns hydrocracking/hydroconversion and hydrotreatment processes employing said catalyst.
摘要翻译：本发明描述了一种催化剂，其包含至少一种具有分层孔隙率的材料，其包含硅和来自元素周期表的VIB族组和/或VIII族的至少一种脱氢元素。具有包含硅的层状孔隙的所述材料由至少两个基本球形颗粒构成，每个所述球形颗粒包含孔径在0.2至2nm范围内的沸石纳米晶体和基于氧化硅的基体，其被介孔结构化，具有孔径在1.5至30nm范围内，具有厚度在1至30nm范围内的非晶壁，所述基本球形颗粒的最大直径为100μm。基于氧化硅的基体可以含有铝。催化剂还任选地包含选自磷，硼和硅的受控量的至少一种掺杂元素，任选地，元素周期表的第VB族元素中的至少一种元素，以及任选的来自VIIA族的元素。本发明还涉及使用所述催化剂的加氢裂化/加氢转化和加氢处理方法。

9. 发明授权

US07790019B2 Zeolitic catalyst, substrate based on a silica-alumina matrix and zeolite, and hydrocracking process for hydrocarbon feedstocks 有权
标题翻译：沸石催化剂，基于二氧化硅 - 氧化铝基质和沸石的底物，以及烃原料的加氢裂化方法
公开(公告)号：US07790019B2
公开(公告)日：2010-09-07
申请号：US10584144
申请日：2004-12-16
申请人： Patrick Euzen , Patrick Bourges , Hugues Dulot , Christophe Gueret
发明人： Patrick Euzen , Patrick Bourges , Hugues Dulot , Christophe Gueret
IPC分类号： C10G47/24 , C10G47/02 , B01J29/06
CPC分类号： B01J29/70 , B01J21/12 , B01J23/883 , B01J27/1853 , B01J27/19 , B01J29/064 , B01J29/076 , B01J29/084 , B01J29/74 , B01J29/78 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J35/108 , B01J2229/42 , C10G45/64 , C10G47/12 , C10G65/12
摘要： The invention relates to a catalyst including at least one hydro-dehydrogenating element chosen from the group formed by the group VIB and group VIII elements of the periodic table and a substrate based on a silica-alumina matrix with a reduced content of macropores containing a quantity greater than 5% by weight and less than or equal to 95% by weight of silica (SiO2) and based on at least one zeolite.The invention also relates to a substrate based on a silica-alumina matrix with a reduced content of macropores containing a quantity greater than 5% by weight and less than or equal to 95% by weight of silica (SiO2) and based on at least one zeolite.The invention also relates to hydrocracking and/or hydroconversion processes and hydrotreating processes utilizing a catalyst according to the invention.
摘要翻译：本发明涉及一种催化剂，其包括至少一种选自由元素周期表VIB族和VIII族元素形成的加氢脱氢元素，以及基于二氧化硅 - 氧化铝基质的底物，其中含有大量的大孔大于5重量％且小于或等于95重量％的二氧化硅（SiO 2）并且基于至少一种沸石。本发明还涉及一种基于二氧化硅 - 氧化铝基质的底物，其具有含量大于5重量％且小于或等于95重量％的二氧化硅（SiO 2）的量的大孔含量，并基于至少一种沸石。本发明还涉及利用根据本发明的催化剂的加氢裂化和/或加氢转化方法和加氢处理方法。

10. 发明授权

US07332071B2 Process for improving aromatic and naphtheno-aromatic gas oil fractions 有权
$Process for improving aromatic and naphtheno-aromatic gas oil fractions$
标题翻译：用于改进芳族和环烷 - 芳烃瓦斯油馏分的方法
公开(公告)号：US07332071B2
公开(公告)日：2008-02-19
申请号：US10367963
申请日：2003-02-19
申请人： Eric Benazzi , Patrick Bourges , Christophe Gueret , Pierre Marion
发明人： Eric Benazzi , Patrick Bourges , Christophe Gueret , Pierre Marion
IPC分类号： C10G45/00 , C10G65/02
CPC分类号： C10G65/04
摘要： Process for transforming a gas oil fraction that makes it possible to produce a fuel that has a quality according to stringent requirements in terms of sulfur content, aromatic compound content, cetane number, boiling point, T95, of 95% of the compounds and density, d15/4, at 15° C. This process comprises a hydrorefining stage and a subsequent stage, whereby the latter uses a catalyst that is selected from the group that consists of hydrorefining catalysts and catalysts that comprise at least one mixed oxide, a metal of group VIB, and a non-noble metal of group VIII. The conversion of products that have a boiling point of less than 150° C. is, for the hydrorefining stage, between 1 and 15% by weight. The temperature, TR2, of the subsequent stage is less than the temperature, TR1, of the hydrorefining stage, and the variation between temperatures TR1 and TR2 is between 0 and 80° C.
摘要翻译：用于转化瓦斯油馏分的方法，其使得可以生产具有根据硫含量，芳族化合物含量，十六烷值，沸点，T95的严格要求的质量为95％的化合物和密度的燃料， d15 / 4，在15℃。该方法包括加氢精制阶段和后续阶段，其中后者使用选自由加氢精制催化剂和催化剂组成的组的催化剂，催化剂和催化剂包含至少一种混合氧化物， VIB族和VIII族的非贵金属。对于加氢精制阶段，沸点低于150℃的产物的转化率为1至15重量％。后续阶段的温度TR2小于加氢精制阶段的温度TR1，温度TR1和TR2之间的变化在0和80℃之间。

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